Process for the preparation of azeleic acid from 9-octadecenedioic acid
    2.
    发明授权
    Process for the preparation of azeleic acid from 9-octadecenedioic acid 有权
    从9-十八碳烯酸制备烟酸的方法

    公开(公告)号:US09302972B2

    公开(公告)日:2016-04-05

    申请号:US14366051

    申请日:2012-12-12

    摘要: The invention relates to a process for the preparation of azelaic acid or alkyl azelate starting from mono-unsaturated 9-octadecenedioic acid or its corresponding alkylester characterized in that the process comprises at least the following step: •reacting the mono-unsaturated 9-octadecene dioic acid or its corresponding alkylester with hydrogen peroxide in the presence of an organic carboxylic acid other than 9-octadecene dioic acid and a suitable catalyst to effect cleavage of the double bond in the mono-unsaturated 9-octadecene dioic acid or its corresponding alkylester. The invention further relates to the azelaic acid or alkyl azelate obtainable by the process according to the invention and to the use of azelaic acid or alkyl azelate or monomers derived there from for the preparation of a polymer, especially a polyamide.

    摘要翻译: 本发明涉及从单不饱和9-十八烯二酸或其相应的烷基酯开始制备壬二酸或壬烷二酸烷基酯的方法,其特征在于该方法至少包括以下步骤:使单不饱和9-十八碳烯二辛酸 酸或其相应的烷基酯与过氧化氢在除9-十八烯二酸之外的有机羧酸和合适的催化剂存在下进行,以实现单不饱和9-十八烯二酸或其相应的烷基酯中双键的裂解。 本发明还涉及通过本发明的方法获得的壬二酸或壬基壬磺酸烷基酯,以及由壬二酸或壬二酸烷基酯衍生的单体或其衍生物用于制备聚合物,特别是聚酰胺的用途。

    Double esters
    4.
    发明授权
    Double esters 有权
    双酯

    公开(公告)号:US07629383B2

    公开(公告)日:2009-12-08

    申请号:US10496328

    申请日:2002-11-22

    申请人: Jo Klaveness

    发明人: Jo Klaveness

    IPC分类号: A61K31/225 C07C69/52

    摘要: The invention provides acyloxymethyl esters of C6-14 alkane-dicarboxylic acids, or physiologically tolerable salts or esters thereof, for use in medicine as therapeutic or prophylactic agents.

    摘要翻译: 本发明提供了用作医药或预防药物的C 6-14烷烃二羧酸的酰氧基甲基酯或其生理上可耐受的盐或酯。

    Synthesis of alpha,omega-dicarboxylic acids and esters thereof from unsaturated fatty acid derivatives
    10.
    发明授权
    Synthesis of alpha,omega-dicarboxylic acids and esters thereof from unsaturated fatty acid derivatives 失效
    从不饱和脂肪酸衍生物合成α,ω-二羧酸及其酯

    公开(公告)号:US08703993B2

    公开(公告)日:2014-04-22

    申请号:US13424548

    申请日:2012-03-20

    IPC分类号: C07C69/48

    摘要: A process for preparing an alpha, omega-dicarboxylic acid or an ester thereof, which includes (a) subjecting at least one unsaturated fatty acid or fatty acid derivative to ozonolysis to obtain an ozonolysis reaction mixture; and (b) oxidizing the ozonolysis reaction mixture with an oxidizing agent in the presence of an acid catalyst to obtain an oxidized reaction mixture comprising at least one alpha, omega-dicarboxylic acid or ester; wherein the process is performed using a solvent and the acid catalyst has a pKa of less than or equal to zero, as measured at 25° C.

    摘要翻译: 一种制备α,ω-二羧酸或其酯的方法,其包括(a)使至少一种不饱和脂肪酸或脂肪酸衍生物进行臭氧分解以获得臭氧分解反应混合物; 和(b)在酸催化剂存在下用氧化剂氧化臭氧分解反应混合物,得到包含至少一种α,ω-二羧酸或酯的氧化反应混合物; 其中所述方法使用溶剂进行,并且所述酸催化剂的pKa小于或等于零,如在25℃下测量的。