公开(公告)号：US09534160B2

公开(公告)日：2017-01-03

申请号：US15010795

申请日：2016-01-29

Applicant: Essilor International (Compagnie Generale d'Optique)

Inventor： Mamonjy Cadet ,  Mathieu Feuillade

IPC: B05D5/00 ,  C09K3/16 ,  C01B33/145 ,  C01B33/149 ,  C01B37/02 ,  C03C1/00 ,  C03C17/30 ,  C09D183/04 ,  C09D183/08 ,  G02B1/04 ,  G03B3/00 ,  G02B1/16 ,  G02B1/18 ,  G02B1/11 ,  C08G77/26

CPC classification number: G02B1/16 ,  B05D5/00 ,  C01B33/145 ,  C01B33/149 ,  C01B37/02 ,  C03C1/008 ,  C03C17/30 ,  C03C2217/73 ,  C03C2217/76 ,  C03C2218/113 ,  C08G77/26 ,  C09D183/04 ,  C09D183/08 ,  C09K3/16 ,  G02B1/041 ,  G02B1/043 ,  G02B1/11 ,  G02B1/18 ,  G03B3/00 ,  Y10T428/249969 ,  C08L83/04

Abstract: The present invention relates to an article comprising a substrate having a main surface coated with a mesoporous antistatic coating, said coating having a refractive index lower than or equal to 1.5, and a silica based matrix functionalized by ammonium groups, said matrix having a hydrophobic character. Under certain conditions, the mesoporous antistatic coating is a single-layer anti-reflection coating or is part of a multi-layer anti-reflection coating. This invention further relates to a method for manufacturing said article, and to the use of a mesoporous coating having a silica based matrix functionalized by ammonium groups, as an antistatic coating.

Abstract translation: 本发明涉及一种包括基材的制品，所述基材具有涂覆有介孔抗静电涂层的主表面，所述涂层具有低于或等于1.5的折射率，以及由铵基团官能化的二氧化硅基的基体，所述基质具有疏水性 。 在某些条件下，介孔抗静电涂层是单层抗反射涂层，或是多层抗反射涂层的一部分。 本发明还涉及一种用于制造所述制品的方法，以及使用具有由铵基团官能化的二氧化硅基的介孔作为抗静电涂层的介孔涂层。

公开(公告)号：US20150376441A1

公开(公告)日：2015-12-31

申请号：US14592073

申请日：2015-01-08

Applicant: CAMBRIDGE ENTERPRISE LIMITED

Inventor： Stefan Guldin ,  Ullrich Steiner

IPC: C09D153/00 ,  G02B1/18 ,  B05D5/08 ,  G02B1/111 ,  C09D5/00 ,  B05D1/00

CPC classification number: C09D153/00 ,  B01J21/063 ,  B01J35/0013 ,  B01J35/002 ,  B01J35/004 ,  B01J35/1057 ,  B01J35/1061 ,  B01J35/1066 ,  B01J37/0018 ,  B01J37/0215 ,  B01J37/0219 ,  B05D1/005 ,  B05D5/08 ,  C03C1/008 ,  C03C17/007 ,  C03C17/009 ,  C03C2217/425 ,  C03C2217/452 ,  C03C2217/477 ,  C03C2217/48 ,  C03C2217/71 ,  C03C2217/732 ,  C08J7/045 ,  C08J2383/04 ,  C09D5/006 ,  G02B1/111 ,  G02B1/113 ,  G02B1/18 ,  G02B27/0006 ,  G02B2207/107

Abstract: This invention relates to coatings for substrates, in particular antireflective coatings (ARCs) and self-cleaning coatings (SCCs). A coating for a substrate comprises a mesoporous inorganic skeleton having photocatalytic particles provided therein and/or thereon, the coating having a porosity in excess of 50 v/v %, for example, greater than 55%, 60%, 65%, 70 v/v %.

Abstract translation: 本发明涉及用于基材，特别是抗反射涂层（ARC）和自清洁涂层（SCC）的涂层。 用于基材的涂层包括其中提供光催化颗粒的介孔无机骨架和/或其上的孔隙率超过50v / v％的涂层，例如大于55％，60％，65％，70v / v％。

公开(公告)号：US20150322269A1

公开(公告)日：2015-11-12

申请号：US14410081

申请日：2013-06-21

Applicant: Nanofluor GmbH

Inventor： Erhard KEMNITZ

IPC: C09D1/00 ,  C08K3/34 ,  C08K3/16 ,  C08K5/5415 ,  C08K5/56

CPC classification number: C09D1/00 ,  C01F11/22 ,  C01P2002/86 ,  C01P2004/03 ,  C03C1/008 ,  C03C17/22 ,  C03C2217/285 ,  C03C2217/732 ,  C03C2218/113 ,  C08J7/06 ,  C08K3/16 ,  C08K3/34 ,  C08K5/5415 ,  C08K5/56 ,  C08K2003/162 ,  C08K2003/164 ,  C09D7/61 ,  C23C18/1204 ,  C23C18/1254 ,  C23C18/127 ,  C23C18/1283 ,  G02B1/113 ,  G02B2207/109

Abstract: The invention relates to a method for obtaining a calcium fluoride (CaF2) sol solution, comprising the steps of providing a calcium precursor in a first volume in a non-aqueous solvent, and adding, in a second volume, 1.85 to 2.05 molar equivalents of anhydrous hydrogen fluoride (nHF) per mole calcium precursor to said first volume, and/or a magnesium additive is added before or after said fluorination with hydrogen fluoride with additional 1.85 to 2.05 molar equivalents of anhydrous hydrogen fluoride (nHF) per mole magnesium additive. Additionally or alternatively at least one metal additive precursor is added before or after the fluorination with hydrogen fluoride wherein an additional amount of hydrogen fluoride (nadHF) is present in the fluorination step. The invention further relates to sol solutions, method of applying the sol solutions of the invention to surfaces as a coating, and to antireflective coatings obtained thereby.

Abstract translation: 本发明涉及一种获得氟化钙（CaF 2）溶胶溶液的方法，包括以下步骤：在非水溶剂中在第一体积中提供钙前体，并在第二体积中加入1.85-2.05摩尔当量的 在氟化氢所述氟化之前或之后加入每摩尔钙前体至所述第一体积的无水氟化氢（nHF），和/或镁添加剂，每摩尔镁添加剂另外加入1.85至2.05摩尔当量无水氟化氢（nHF）。 另外或替代地，在氟化氢氟化之前或之后加入至少一种金属添加剂前体，其中在氟化步骤中存在额外量的氟化氢（nadHF）。 本发明还涉及溶胶溶液，将本发明的溶胶溶液涂布到作为涂层的表面上的方法以及由此获得的抗反射涂层。

公开(公告)号：US08951342B2

公开(公告)日：2015-02-10

申请号：US13286634

申请日：2011-11-01

Applicant: Raymond Nicholas Vrtis ,  Mark Leonard O'Neill ,  Jean Louise Vincent ,  Aaron Scott Lukas ,  Mary Kathryn Haas

Inventor： Raymond Nicholas Vrtis ,  Mark Leonard O'Neill ,  Jean Louise Vincent ,  Aaron Scott Lukas ,  Mary Kathryn Haas

IPC: C09D7/12 ,  C23C16/40 ,  H01L21/02 ,  H01L21/316 ,  C23C16/30 ,  C23C16/56 ,  C03C1/00 ,  C23C30/00

CPC classification number: C23C16/401 ,  C03C1/008 ,  C09D7/63 ,  C23C16/30 ,  C23C16/402 ,  C23C16/56 ,  C23C30/00 ,  H01L21/02126 ,  H01L21/02203 ,  H01L21/02208 ,  H01L21/02214 ,  H01L21/02216 ,  H01L21/02274 ,  H01L21/02348 ,  H01L21/31695

Abstract: A chemical vapor deposition method for producing a porous organosilica glass film comprising: introducing into a vacuum chamber gaseous reagents including at least one precursor selected from the group consisting of an organosilane and an organosiloxane, and a porogen that is distinct from the precursor; applying energy to the gaseous reagents in the vacuum chamber to induce reaction of the gaseous reagents to deposit a preliminary film on the substrate, wherein the preliminary film contains the porogen; and removing from the preliminary film substantially all of the porogen to provide the porous film with pores and a dielectric constant less than 2.6.

Abstract translation: 一种用于生产多孔有机硅玻璃膜的化学气相沉积方法，包括：向真空室中引入包含至少一种选自有机硅烷和有机硅氧烷的前体的气态试剂和与前体不同的致孔剂; 向真空室中的气态试剂施加能量以诱导气态试剂在衬底上沉积初步膜的反应，其中预备膜含有致孔剂; 并且从基本上所有的致孔剂的初步膜上除去，以提供具有小于2.6的孔隙和介电常数的多孔膜。

公开(公告)号：US20150024145A1

公开(公告)日：2015-01-22

申请号：US14122918

申请日：2012-04-13

Applicant: Matthias Bockmeyer ,  Andrea Anton ,  Vera Breier ,  Angelina Milanovska ,  Andreas Gier ,  Axel Kallender ,  Silke Knoche

Inventor： Matthias Bockmeyer ,  Andrea Anton ,  Vera Breier ,  Angelina Milanovska ,  Andreas Gier ,  Axel Kallender ,  Silke Knoche

IPC: C03C17/32 ,  C03C17/30 ,  C08K3/36 ,  C09D11/102 ,  C08K3/28

CPC classification number: C03C17/007 ,  C03C1/008 ,  C03C17/001 ,  C03C17/30 ,  C03C17/326 ,  C03C2203/27 ,  C03C2203/28 ,  C03C2203/30 ,  C03C2217/44 ,  C03C2217/475 ,  C03C2217/478 ,  C03C2217/78 ,  C03C2218/119 ,  C08K3/28 ,  C08K3/36 ,  C09D11/102 ,  Y10T428/24997 ,  Y10T428/31612

Abstract: A semi-transparent coating material for coating glass or glass ceramics includes at least one sol-gel hybrid-polymer coating system having a hybrid-polymer or inorganic sol-gel-based matrix, and nanoparticles and nanoscale pigments and/or dyes are added to the hybrid-polymer or inorganic sol-gel-based matrix.

Abstract translation: 用于涂覆玻璃或玻璃陶瓷的半透明涂料包括至少一种具有混合聚合物或无机溶胶 - 凝胶基质的溶胶 - 凝胶混合聚合物涂覆体系，并且将纳米颗粒和纳米级颜料和/或染料加入 混合聚合物或无机溶胶 - 凝胶基质。

公开(公告)号：US20140299573A1

公开(公告)日：2014-10-09

申请号：US14365055

申请日：2012-12-11

Applicant: CANON KABUSHIKI KAISHA

Inventor： Kenji Takashima ,  Zuyi Zhang ,  Yoshinori Kotani ,  Akiko Takei ,  Akira Sugiyama ,  Naoyuki Koketsu

IPC: C03C15/00

CPC classification number: G02B1/12 ,  C03C1/008 ,  C03C11/00 ,  C03C15/00 ,  C03C17/007 ,  C03C17/02 ,  C03C17/3411 ,  C03C23/008 ,  C03C2217/425 ,  C03C2217/732 ,  C03C2217/91 ,  C03C2218/33 ,  G02B1/113 ,  G02B1/118 ,  G02B2207/107

Abstract: The present invention provides a method for producing a porous glass layer easily, wherein a ripple is suppressed.A method for manufacturing an optical member provided with a porous glass layer on a base member includes the steps of forming an intermediate layer containing at least one of silicon, potassium, and aluminum on the base member, forming a phase-separable glass layer on the intermediate layer, forming a phase-separated glass layer on the base member by heating the intermediate layer and the phase-separable glass layer at a temperature higher than or equal to the glass transition temperature of the phase-separable glass layer, and forming a porous glass layer on the base member by subjecting the phase-separated glass layer to an etching treatment.

Abstract translation: 本发明提供容易制造多孔玻璃层的方法，其中抑制纹波。 一种制造在基底构件上具有多孔玻璃层的光学构件的方法包括以下步骤：在基底构件上形成含有硅，钾和铝中的至少一种的中间层，在其上形成相分离玻璃层 中间层，通过在高于或等于相分离玻璃层的玻璃化转变温度的温度下加热中间层和相分离玻璃层，在基底构件上形成相分离的玻璃层，并形成多孔 通过对相分离的玻璃层进行蚀刻处理而在基材上形成玻璃层。

公开(公告)号：US20140230899A1

公开(公告)日：2014-08-21

申请号：US14346484

申请日：2012-09-24

Applicant: LISEC AUSTRIA GmbH

Inventor： Vesselinka Petrova-Koch ,  Andreas Mader ,  Markus Jandl ,  Ralf Bohlander

IPC: H01L31/048 ,  H01L31/18

CPC classification number: H01L31/0488 ,  B32B17/10018 ,  B32B17/10036 ,  B32B17/10761 ,  B32B17/10788 ,  C03C1/008 ,  C03C17/02 ,  C03C2217/23 ,  C03C2217/732 ,  C03C2218/113 ,  H01L31/18 ,  Y02E10/50

Abstract: A module, for example a photovoltaic module, includes among other things a glass plate (11) as a front cover facing the direction of light incidence, a component (photovoltaic element) (15), and a plastic layer (14) provided as an embedding material, wherein the surface of the glass plate (11) on the side facing the plastic layer (14) is treated such that the index of refraction of the layer produced by the surface treatment has a value between the index of refraction of the glass of the cover (11) and the index of refraction of the plastic material of the layer (14).

Abstract translation: 模块，例如光伏模块，其中包括作为面向光入射方向的前盖的玻璃板（11），组件（光电元件）（15）和塑料层（14），其设置为 其中处理面对塑料层（14）的一侧的玻璃板（11）的表面，使得由表面处理产生的层的折射率具有在玻璃的折射率之间的值 （11）的塑料材料的折射率和折射率（14）。

公开(公告)号：US08778450B2

公开(公告)日：2014-07-15

申请号：US13010843

申请日：2011-01-21

Applicant: Zhang Zuyi ,  Hiroyuki Tanaka ,  Masayuki Yamada

Inventor： Zhang Zuyi ,  Hiroyuki Tanaka ,  Masayuki Yamada

IPC: B05D5/06

CPC classification number: G02B1/118 ,  C03C1/008 ,  C03C17/007 ,  C03C17/3411 ,  C03C17/3494 ,  C03C2204/08 ,  C03C2217/475 ,  C03C2217/734 ,  C03C2217/78 ,  C03C2218/111 ,  G02B1/02 ,  Y10T428/24355 ,  Y10T428/31

Abstract: An optical member including an oxide layer that has a stable fine textured structure and is excellent in durability is provided. The optical member includes a base material and an antireflection coating on a surface of the base material. The antireflection coating includes at least an oxide layer having a fine textured structure on the surface, and the oxide layer contains a phosphate compound. Furthermore, a method of manufacturing the optical member is provided.

Abstract translation: 提供了包括具有稳定的细纹理结构并且耐久性优异的氧化物层的光学构件。 光学构件在基材的表面上包括基材和抗反射涂层。 抗反射涂层至少包括在表面具有细纹理结构的氧化物层，氧化物层含有磷酸盐化合物。 此外，提供了制造光学构件的方法。

公开(公告)号：US08603923B2

公开(公告)日：2013-12-10

申请号：US13920617

申请日：2013-06-18

Applicant: Masanobu Hayashi

Inventor： Masanobu Hayashi

IPC: H01L21/47 ,  H01L21/471 ,  H01L21/312 ,  H01L21/314 ,  H01L21/3105 ,  H01L21/469 ,  B05D3/02 ,  H01L21/56 ,  C01B15/01

CPC classification number: H01L21/02282 ,  C03C1/008 ,  C03C2203/20 ,  C08G77/62 ,  C09D183/16 ,  C23C18/1212 ,  C23C18/122

Abstract: This invention relates to a dipping solution used in a process for producing a siliceous film. The present invention provides a dipping solution and a siliceous film-production process employing the solution. The dipping solution enables to form a homogeneous siliceous film even in concave portions of a substrate having concave portions and convex portions. The substrate is coated with a polysilazane composition, and then dipped in the solution before fire. The dipping solution comprises hydrogen peroxide, a foam-deposit inhibitor, and a solvent.

Abstract translation: 本发明涉及用于生产硅质膜的方法中的浸渍溶液。 本发明提供一种浸渍溶液和采用该溶液的硅质薄膜生产方法。 浸渍溶液能够在具有凹部和凸部的基板的凹部中形成均匀的硅质膜。 用聚硅氮烷组合物涂覆基材，然后在火焰之前浸入溶液中。 浸渍溶液包括过氧化氢，泡沫沉积抑制剂和溶剂。

公开(公告)号：US20130302599A1

公开(公告)日：2013-11-14

申请号：US13990676

申请日：2011-11-14

Applicant: Kazuaki Oya ,  Kazutaka Kamitani ,  Toyoyuki Teranishi ,  Shuhei Murata

Inventor： Kazuaki Oya ,  Kazutaka Kamitani ,  Toyoyuki Teranishi ,  Shuhei Murata

IPC: C09K3/18

CPC classification number: G02B1/18 ,  C03C1/008 ,  C03C17/006 ,  C03C17/009 ,  C08G77/02 ,  C08K3/36 ,  C09D5/1618 ,  C09D5/1668 ,  C09D129/14 ,  C09K3/18 ,  G02B1/10 ,  G02B27/0006 ,  Y10T428/265 ,  C08K5/0091 ,  C08K13/02

Abstract: The present invention provides an antifog-film-coated article including an antifog film having high hardness while maintaining sufficient antifog performance, which article can be employed in various applications, including antifog mirrors, windowpanes for automobiles, and windowpanes for buildings. The antifog-film-coated article of the present invention includes a hard substrate, and a water-absorbing composite film formed on the substrate, wherein the water-absorbing composite film contains a polyvinyl acetal resin; colloidal silica in an amount of 30 to 80 parts by mass on the basis of 100 parts by mass of the resin; and silica-equivalent particles derived from a hydrolysis product or partial hydrolysis product of a silicon alkoxide compound in an amount of 5 to 55 parts by mass on the basis of 100 parts by mass of the resin.

Abstract translation: 本发明提供一种防雾膜涂布制品，其包含具有高硬度的防雾膜，同时保持足够的防雾性能，该制品可用于各种应用中，包括防雾镜，汽车用窗玻璃和建筑物的窗玻璃。 本发明的防雾膜被覆制品包括硬质基材和形成在基材上的吸水性复合膜，其中吸水性复合膜含有聚乙烯醇缩醛树脂; 基于100质量份树脂30〜80质量份的胶态二氧化硅; 基于100质量份树脂，衍生自硅醇盐化合物的水解产物或部分水解产物的二氧化硅当量颗粒为5至55质量份。