公开(公告)号：US12128378B2

公开(公告)日：2024-10-29

申请号：US17310072

申请日：2020-01-14

申请人： SABIC Global Technologies B.V.

发明人： Andrew Mark Ward ,  Scott Stevenson ,  Arno Oprins ,  Zhun Zhao ,  Tim Abbott ,  Kenneth Francis Lawson ,  Joseph William Schroer ,  Michael Edward Huckman

IPC分类号： B01J19/00 ,  B01D53/047 ,  B01D53/26 ,  B01J4/00 ,  B01J6/00 ,  B01J19/24 ,  C01B3/12 ,  C01B3/34 ,  C01B3/48 ,  C01B3/56 ,  C01C1/02 ,  C01C1/04 ,  C07C4/00 ,  C07C4/02 ,  C07C4/04 ,  C07C29/132 ,  C07C29/152 ,  F25J3/02 ,  H01M8/04082 ,  H01M8/0606 ,  H01M8/0612 ,  H02J15/00 ,  H01M8/1007

CPC分类号： B01J19/0053 ,  B01D53/047 ,  B01D53/265 ,  B01J4/008 ,  B01J6/008 ,  B01J19/0033 ,  B01J19/2465 ,  C01B3/12 ,  C01B3/342 ,  C01B3/48 ,  C01B3/56 ,  C01C1/02 ,  C01C1/0417 ,  C01C1/0488 ,  C07C4/02 ,  C07C4/04 ,  C07C29/132 ,  C07C29/152 ,  F25J3/0233 ,  H01M8/04201 ,  H01M8/0606 ,  H01M8/0618 ,  H02J15/006 ,  H02J15/008 ,  B01D2256/16 ,  B01D2256/245 ,  B01J2219/00051 ,  B01J2219/00132 ,  B01J2219/00761 ,  B01J2219/0871 ,  C01B2203/0216 ,  C01B2203/0233 ,  C01B2203/0238 ,  C01B2203/0244 ,  C01B2203/0261 ,  C01B2203/0283 ,  C01B2203/0294 ,  C01B2203/04 ,  C01B2203/061 ,  C01B2203/066 ,  C01B2203/068 ,  C01B2203/085 ,  C01B2203/148 ,  H01M8/1007

摘要： An olefin synthesis plant comprising: a feed pretreatment section configured to pretreat a feed stream; a pyrolysis section comprising one or more pyrolysis reactors configured to crack hydrocarbons in the feed stream in the presence of a diluent to produce a cracked gas stream; a primary fractionation and compression section configured to provide heat recovery from and quenching of the cracked gas stream; remove a component from the cracked gas stream; and compress the cracked gas stream, thus providing a compressed cracked gas stream; and/or a product separation section configured to separate a product olefin stream from the compressed cracked gas stream, wherein the olefin synthesis plant is configured such that, relative to a conventional olefin synthesis plant, more of the energy and/or the net energy required by the olefin synthesis plant and/or one or more sections thereof, is provided by a non-carbon based and/or renewable energy source and/or electricity.

公开(公告)号：US20240124377A1

公开(公告)日：2024-04-18

申请号：US18197308

申请日：2023-05-15

申请人： M2X Energy Inc.

发明人： Paul E. Yelvington ,  Bunmi Tolu Adekore ,  Joshua B. Browne ,  John Anthony Dean ,  Andrew Randolph

IPC分类号： C07C29/151 ,  B01D53/02 ,  B01D53/22 ,  B01J12/00 ,  B01J19/00 ,  C01B3/02 ,  C01B3/36 ,  C01C1/04 ,  C07C1/04 ,  C10L3/08 ,  F02C3/30

CPC分类号： C07C29/1518 ,  B01D53/02 ,  B01D53/229 ,  B01J12/005 ,  B01J19/004 ,  C01B3/025 ,  C01B3/36 ,  C01B3/366 ,  C01C1/0488 ,  C07C1/0485 ,  C10L3/08 ,  F02C3/30 ,  B01D2256/16 ,  B01J2219/00182 ,  B01J2219/00186 ,  C01B2203/025 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/068 ,  C01B2203/1241 ,  C01B2203/1614 ,  C01B2203/1628 ,  C01B2203/82 ,  C10L2200/0461 ,  C10L2290/02 ,  C10L2290/145 ,  F05D2220/75

摘要： There are provided systems and methods for using fuel-rich partial oxidation to produce an end product from waste gases, such as flare gas. In an embodiment, the system and method use air-breathing piston engines and turbine engines for the fuel-rich partial oxidation of the flare gas to form synthesis gas, and reactors to convert the synthesis gas into the end product. In an embodiment the end product is methanol.

公开(公告)号：US11767227B2

公开(公告)日：2023-09-26

申请号：US17412414

申请日：2021-08-26

申请人： Haldor Topsøe A/S

发明人： Pat A. Han ,  Mitra Heidarpanah

IPC分类号： C01C1/04 ,  C07C29/15 ,  C07C29/152 ,  C01B3/34 ,  B01D5/00 ,  B01J8/04 ,  C01B3/02 ,  C01B3/38 ,  C07C29/151

CPC分类号： C01C1/0488 ,  B01D5/009 ,  B01J8/0492 ,  B01J8/0496 ,  C01B3/025 ,  C01B3/38 ,  C07C29/152 ,  C07C29/1518 ,  B01J2219/0004 ,  B01J2219/00038 ,  C01B2203/025 ,  C01B2203/0233 ,  C01B2203/061 ,  C01B2203/068 ,  C01B2203/1241 ,  C01B2203/141 ,  C01B2203/142

摘要： A plant for the co-production of methanol and ammonia from a hydrocarbon feed without venting to the atmosphere carbon dioxide captured from the methanol or ammonia synthesis gas and without using expensive air separation units and water gas shift.

公开(公告)号：US11767226B2

公开(公告)日：2023-09-26

申请号：US17408667

申请日：2021-08-23

申请人： Haldor Topsøe A/S

发明人： Pat A. Han ,  Mitra Heidarpanah

IPC分类号： C01C1/04 ,  C07C29/15 ,  C07C29/152 ,  C01B3/34 ,  C07C273/04 ,  C07C273/10 ,  C01B3/02 ,  C07C29/151 ,  B01J8/04

CPC分类号： C01C1/0488 ,  B01J8/0457 ,  B01J8/0492 ,  B01J8/0496 ,  C01B3/025 ,  C07C29/152 ,  C07C29/1518 ,  C07C273/04 ,  C07C273/10 ,  B01J2208/00548 ,  B01J2219/0004 ,  B01J2219/00038 ,  C01B2203/061 ,  C01B2203/068 ,  C01B2203/141 ,  C01B2203/142

摘要： A process and plant for the co-production of methanol and ammonia together with urea production from a hydrocarbon feed without venting to the atmosphere carbon dioxide captured from the methanol or ammonia synthesis gas and without using expensive air separation units and water gas shift. Carbon dioxide is removed from flue gas from reforming section and used to convert partially or fully all ammonia into urea.

公开(公告)号：US11649201B2

公开(公告)日：2023-05-16

申请号：US17746942

申请日：2022-05-17

申请人： Obantarla Corp.

发明人： Paul E. Yelvington ,  Bunmi Tolu Adekore ,  Joshua B. Browne ,  John Anthony Dean ,  Andrew Randolph

IPC分类号： C07C29/151 ,  C01B3/36 ,  C01B3/02 ,  C01C1/04 ,  C07C1/04

CPC分类号： C07C29/1518 ,  C01B3/025 ,  C01B3/36 ,  C01B3/366 ,  C01C1/0488 ,  C07C1/0485 ,  C01B2203/025 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/068 ,  C01B2203/1241 ,  C01B2203/1614 ,  C01B2203/1628 ,  C01B2203/82

摘要： There are provided systems and methods for using fuel-rich partial oxidation to produce an end product from waste gases, such as flare gas. In an embodiment, the system and method use air-breathing piston engines and turbine engines for the fuel-rich partial oxidation of the flare gas to form synthesis gas, and reactors to convert the synthesis gas into the end product. In an embodiment the end product is methanol.

公开(公告)号：US20190031604A1

公开(公告)日：2019-01-31

申请号：US16062748

申请日：2016-11-28

申请人： JOHNSON MATTHEY PUBLIC LIMITED COMPANY

发明人： Ola ERLANDSSON ,  Andreas Erik Johan MAGNUSSON ,  Kate MCFARLANE ,  John David PACH ,  Daniel Thomas SHELDON ,  Darren WARD

IPC分类号： C07C273/14 ,  C07C273/10 ,  C01C1/04 ,  C01B3/50 ,  C07C45/29 ,  C07C29/151 ,  C07C1/20

CPC分类号： C07C273/14 ,  C01B3/50 ,  C01B2203/0283 ,  C01B2203/061 ,  C01B2203/062 ,  C01B2203/068 ,  C01C1/0405 ,  C01C1/0488 ,  C07C1/20 ,  C07C29/1516 ,  C07C29/1518 ,  C07C45/29 ,  C07C45/38 ,  C07C273/04 ,  C07C273/10 ,  Y02P20/125

摘要： A process for the production of formaldehyde-stabilised urea is described comprising the steps of: (a) generating a synthesis gas comprising hydrogen, nitrogen, carbon monoxide, carbon dioxide and steam in a synthesis gas generation unit, (b) subjecting the synthesis gas to one or more stages of water-gas shift in one or more water-gas shift reactors to form a shifted gas; (c) recovering carbon dioxide from the shifted gas in a carbon dioxide removal unit to form a carbon dioxide-depleted synthesis gas; (d) synthesising methanol from the carbon dioxide-depleted synthesis gas in a methanol synthesis unit and recovering the methanol and a methanol synthesis off-gas comprising nitrogen, hydrogen and residual carbon monoxide; (e) subjecting at least a portion of the recovered methanol to oxidation with air in a formaldehyde production unit; (f) subjecting the methanol synthesis off-gas to methanation in a methanation reactor containing a methanation catalyst to form an ammonia synthesis gas; (g) synthesising ammonia from the ammonia synthesis gas in an ammonia production unit and recovering the ammonia; (h) reacting a portion of the ammonia and at least a portion of the recovered carbon dioxide stream in a urea production unit to form a urea stream; and (i) stabilising the urea by mixing the urea stream and a stabiliser prepared using formaldehyde recovered from the formaldehyde production unit, wherein a portion of the synthesis gas generated by the synthesis gas generation unit by-passes either the one or more water-gas shift reactors; the carbon dioxide removal unit; or the one or more water-gas shift reactors and the carbon dioxide removal unit.

公开(公告)号：US09663381B2

公开(公告)日：2017-05-30

申请号：US15093998

申请日：2016-04-08

申请人： RITAJ INV.

发明人： Khalid T. Alkusayer

IPC分类号： C01C1/04 ,  B01J19/24 ,  C01B3/06 ,  C01B3/58 ,  C07C273/10 ,  B01J19/00 ,  C01B3/02 ,  C01B3/16 ,  C01B3/50

CPC分类号： C01C1/0488 ,  B01J19/0006 ,  B01J19/24 ,  B01J19/2475 ,  B01J2219/00058 ,  B01J2219/24 ,  C01B3/025 ,  C01B3/06 ,  C01B3/16 ,  C01B3/505 ,  C01B3/58 ,  C01B2203/0283 ,  C01B2203/041 ,  C01B2203/0435 ,  C01B2203/066 ,  C01B2203/068 ,  C01B2203/1205 ,  C01C1/0405 ,  C01C1/0411 ,  C01C1/0417 ,  C01C1/0452 ,  C01C1/0458 ,  C07C273/10 ,  C25B5/00 ,  Y02E60/36 ,  Y02P20/52

摘要： A method for synthesizing ammonia for agricultural fertilizers employs water (H2O) as the source of hydrogen (H2) in ammonia (NH3) synthesis, and gathers carbon monoxide (CO) as a limiting reagent for combining in a WGS (Water-Gas-Shift) reaction for producing hydrogen. The WGS reaction employs CO with the water to produce Carbon Dioxide (CO2) and H2, consuming undesirable CO from other industrial applications. A by-product of the process includes generating 1.5 mole of CO2 for each mole of ammonia synthesized. An intermediate step consumes 3 moles of hydrogen for each mole of Nitrogen (N2). The use of methane gas is avoided as the process employs CO and the WGS reaction as an exclusive source of H2 without introducing methane (CH4). A downstream synthesis of ammonia can be done through a fuel cell to produce electricity for the ammonia synthesis for further sustainability.

公开(公告)号：US20170009983A1

公开(公告)日：2017-01-12

申请号：US15216432

申请日：2016-07-21

申请人： Grannus LLC

发明人： James Kelly Merritt, JR.

IPC分类号： F23L7/00 ,  C01B3/04 ,  C01B3/58 ,  F23J15/02 ,  C01C1/04 ,  C07C273/10 ,  B01D53/00 ,  B01D53/14 ,  C01B3/36 ,  C01B3/02

CPC分类号： F23L7/007 ,  B01D53/002 ,  B01D53/1431 ,  B01D53/1475 ,  C01B3/025 ,  C01B3/042 ,  C01B3/36 ,  C01B3/583 ,  C01B3/586 ,  C01B2203/025 ,  C01B2203/0415 ,  C01B2203/044 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/0495 ,  C01B2203/068 ,  C01B2203/1235 ,  C01B2203/147 ,  C01C1/0488 ,  C07C273/10 ,  F23J15/02 ,  F23J2219/70 ,  Y02E60/364 ,  Y02P20/52 ,  Y02P30/30

摘要： Method for the production of ammonia, and optionally urea, from a flue gas effluent from an oxy-fired process, wherein the production of ammonia and optionally urea includes a net power production. Also provided is a method to effect cooling in an oxy-fired process with air separation unit exit gases utilizing either closed or open cooling loop cycles.

摘要翻译： 用于从来自氧烧制方法的烟道气流出物生产氨和任选的尿素的方法，其中生产氨和任选的尿素包括净功率产生。 还提供了使用空气分离单元出口气体在使用封闭或开放冷却循环循环的情况下在氧烧制过程中进行冷却的方法。

公开(公告)号：US09321655B2

公开(公告)日：2016-04-26

申请号：US12859714

申请日：2010-08-19

申请人： Shashi Prakash Singh ,  Xueqian Lin

发明人： Shashi Prakash Singh ,  Xueqian Lin

IPC分类号： C01C1/04 ,  C01B3/02 ,  C01B3/38

CPC分类号： C01C1/0405 ,  C01B3/025 ,  C01B3/382 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0283 ,  C01B2203/0405 ,  C01B2203/0415 ,  C01B2203/042 ,  C01B2203/043 ,  C01B2203/0445 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/0495 ,  C01B2203/068 ,  C01B2203/0811 ,  C01B2203/0822 ,  C01B2203/0827 ,  C01B2203/0844 ,  C01B2203/1235 ,  C01B2203/141 ,  C01B2203/142 ,  C01B2203/146 ,  C01B2203/147 ,  C01B2203/148 ,  C01B2203/84 ,  C01C1/0476 ,  C01C1/0488 ,  Y02P20/128 ,  Y02P20/52

摘要： Systems and methods for producing syngas and ammonia are provided. The method can include reforming a hydrocarbon in a first reaction zone in the presence of one or more first catalysts and steam at conditions sufficient to produce an effluent comprising a portion of the hydrocarbon, carbon monoxide, carbon dioxide, and hydrogen. The effluent can be reformed in a second reaction zone in the presence of one or more second catalysts and nitrogen at conditions sufficient to produce a syngas comprising methane, hydrogen, nitrogen, carbon monoxide, and carbon dioxide, or any combination thereof. At least a portion of the nitrogen and hydrogen in the syngas can be converted to ammonia to produce an ammonia effluent. The ammonia effluent can be separated to produce an ammonia product and a purge gas comprising nitrogen. At least a portion of the purge gas can be recycled to the hydrocarbon, the effluent, or a combination thereof.

摘要翻译： 提供了制备合成气和氨的系统和方法。 该方法可以包括在一个或多个第一催化剂和蒸汽的存在下，在足以产生包含一部分烃，一氧化碳，二氧化碳和氢气的流出物的条件下在第一反应区中重整碳氢化合物。 在一个或多个第二催化剂和氮气存在下，在足以产生包含甲烷，氢气，氮气，一氧化碳和二氧化碳的合成气或其任何组合的条件下，流出物可以在第二反应区中重整。 合成气中的氮和氢的至少一部分可以转化成氨以产生氨流出物。 可以将氨流出物分离以产生氨产物和包含氮气的吹扫气体。 净化气体的至少一部分可以再循环到烃，流出物或其组合中。

公开(公告)号：US20160083260A1

公开(公告)日：2016-03-24

申请号：US14787797

申请日：2014-04-16

申请人： HALDOR TOPSØE A/S

发明人： Per Juul Dahl

IPC分类号： C01C1/04 ,  C07C29/151 ,  C07C273/10 ,  C01B3/48 ,  C01B3/50

CPC分类号： C01C1/0488 ,  C01B3/025 ,  C01B3/382 ,  C01B3/48 ,  C01B3/50 ,  C01B3/52 ,  C01B2203/0233 ,  C01B2203/0244 ,  C01B2203/0283 ,  C01B2203/0415 ,  C01B2203/0475 ,  C01B2203/06 ,  C01B2203/061 ,  C01B2203/068 ,  C01B2203/1241 ,  C01B2203/141 ,  C01B2203/145 ,  C07C29/1518 ,  C07C273/04 ,  C07C273/10 ,  F25J3/04539 ,  F25J3/04587 ,  Y02P20/152 ,  Y02P20/52 ,  C07C31/04

摘要： A process for co-production of ammonia, urea and methanol from natural gas, comprising the steps of (a) producing a synthesis gas by simultaneous feeding natural gas to an autothermal reformer (ATR) and to a steam methane reformer (SMR), the two reformers running in parallel, (b) feeding air to an air separation unit (ASU), where the air is split into oxygen, which is fed to the ATR, and nitrogen, (c) subjecting the synthesis gas from the SMR to a water gas shift, (d) removing the carbon dioxide from the synthesis gas from step (c) and leading it to urea synthesis in a urea synthesis unit, (e) combining the hydrogen-rich gas from step (d) with the nitrogen from step (b), removing catalyst poisons from the gases and leading the gas mixture to ammonia synthesis in an ammonia synthesis unit, (f) optionally removing part of the carbon dioxide from the syngas from the ATR in step (a) and leading it to urea synthesis in a urea synthesis unit and (g) leading the syngas from step (f) to the methanol synthesis unit, wherein synthesis gas from step (a) may be led either from the ATR outlet to the SMR outlet upstream from the shift stage or the other way.

摘要翻译： 一种从天然气共同生产氨，尿素和甲醇的方法，包括以下步骤：（a）通过同时将天然气同时供给到自热重整器（ATR）和蒸汽甲烷重整器（SMR）来生产合成气， 两台并联运行的改质器，（b）将空气送入空气分离装置（ASU），空气分离成氧气，送入ATR，氮气，（c）使来自SMR的合成气体 （d）从步骤（c）的合成气中除去二氧化碳，并导致尿素合成单元中的尿素合成，（e）将来自步骤（d）的富氢气体与来自 步骤（b）中，从气体中除去催化剂毒物并将氨气合成装置导入氨合成，（f）在步骤（a）中任选地从合成气中除去部分二氧化碳，并将其导入 在尿素合成单元中的尿素合成和（g）将来自步骤（f）的合成气引导到我 其中来自步骤（a）的合成气可以从ATR出口或从换档级上游的SMR出口或其它方式引导。