Salt-templated microporous solids
    2.
    发明授权
    Salt-templated microporous solids 失效
    盐模微孔固体

    公开(公告)号:US06890500B2

    公开(公告)日:2005-05-10

    申请号:US10755872

    申请日:2004-01-12

    Abstract: The invention is directed to open-framework and microporous solids well suited for use in catalysis and ion exchange. The microporous solids are constructed by using a salt template which can be readily removed without destroying the framework of the micropore. Various microporous solids can be formed having different geometric structures depending upon the templating salt used and the concentration. Examples of two compounds include Na2Cs[Mn3(P2O7)2]Cl and K2.02Cs2.90[Cu3(P2O7)2]Cl2.92. Both compounds have 3-D (Mn, Cu)—P—O frameworks.

    Abstract translation: 本发明涉及非常适合用于催化和离子交换的开放框架和微孔固体。 通过使用可以容易地除去的盐模板来构建微孔固体,而不会破坏微孔的骨架。 根据所使用的模板盐和浓度,可以形成具有不同几何结构的各种微孔固体。 两种化合物的实例包括Na 2 C 3 [Mn 3 N 2(N 2 O 7)2 C 1和K 2 O 2 C 2 O 2·C 2 O 2·C 3 N 2(P 2 N 2) / SUB>)2 2.92。 两种化合物都具有3-D(Mn,Cu)-P-O骨架。

    Phosphorous containing zeolite having MFI type structure
    3.
    发明授权
    Phosphorous containing zeolite having MFI type structure 失效
    含有MFI型结构的含磷沸石

    公开(公告)号:US5951963A

    公开(公告)日:1999-09-14

    申请号:US46630

    申请日:1998-03-24

    Abstract: The present invention discloses a phosphorus-containing zeolite having MFI type structure. The anhydrous composition (based on the mole ratios of oxides) of the above zeolite is0.01-0.3Na.sub.2 O.Al.sub.2 O.sub.3.0.2-1.5P.sub.2 O.sub.5.30-90SiO.sub.2Said zeolite possesses a X-ray diffraction pattern listed in Table 1. The pore volume ratio of 1.0-10 nm mesopore to 10-membered ring pore is no less than 0.5. The crystal particle size of said zeolite is in the range of 0.8-2.0 micron. Said zeolite exhibits superior hydrothermal stability in catalytic conversion of hydrocarbons. Especially, when said zeolite is applied in catalytic cracking of hydrocarbons, it will enhance the crackability of large molecules, improve gasoline octane value and stability, and reduce the sulfur content in the gasoline as well.

    Abstract translation: 本发明公开了具有MFI型结构的含磷沸石。 上述沸石的无水组成(基于氧化物的摩尔比)为0.01-0.3Na2O.Al2O3.0.2-1.5P2O5.30-90SiO2所述沸石具有表1中列出的X射线衍射图。孔体积 1.0-10nm中孔与10元环孔的比例不小于0.5。 所述沸石的晶体粒度在0.8-2.0微米的范围内。 所述沸石在烃的催化转化中表现出优异的水热稳定性。 特别是当所述沸石用于烃的催化裂化时,会提高大分子的裂解性,提高汽油辛烷值和稳定性,并降低汽油中的硫含量。

    Method of purifying a waste stream using a microporous composition
    4.
    发明授权
    Method of purifying a waste stream using a microporous composition 失效
    使用微孔组合物纯化废物流的方法

    公开(公告)号:US07097772B2

    公开(公告)日:2006-08-29

    申请号:US11084884

    申请日:2005-03-21

    Abstract: The invention is directed to open-framework and microporous solids well suited for use in catalysis and ion exchange. The microporous solids are constructed by using a salt template which can be readily removed without destroying the framework of the micropore. Various microporous solids can be formed having different geometric structures depending upon the templating salt used and the concentration. Examples of two compounds include Na2Cs[Mn3(P2O7)2]Cl and K2.02Cs2.90[Cu3(P2O7)2]Cl2.92. Both compounds have 3-D (Mn, Cu)-P-O frameworks.

    Abstract translation: 本发明涉及非常适合用于催化和离子交换的开放框架和微孔固体。 通过使用可以容易地除去的盐模板来构建微孔固体,而不会破坏微孔的骨架。 根据所使用的模板盐和浓度,可以形成具有不同几何结构的各种微孔固体。 两种化合物的实例包括Na 2 C 3 [Mn 3 N 2(N 2 O 7)2 C 1和K 2 O 2 C 2 O 2·C 2 O 2·C 3 N 2(P 2 N 2) / SUB>)2 2.92。 两种化合物都具有3-D(Mn,Cu)-P-O骨架。

    Salt-templated microporous solids
    5.
    发明申请
    Salt-templated microporous solids 失效
    盐模微孔固体

    公开(公告)号:US20050180909A1

    公开(公告)日:2005-08-18

    申请号:US11084884

    申请日:2005-03-21

    Abstract: The present invention is directed to open-framework and microporous solids particularly well suited for use in catalysis and ion exchange. The microporous solids are constructed by using a salt template which can be readily removed without destroying the framework of the micropore. Various microporous solids can be formed having different geometric structures depending upon the templating salt used and the concentration. Examples of two compounds include Na2Cs[Mn3(P2O7)2]Cl(1) and K2.02Cs2.90[Cu3(P2O7)2]C12.92(2). Compound 1 crystallizes in the space group C2/c with a=21.210(8), b=5.272(2), c=13.924(2)Å, beta=119.04(2), and Z=4. Compound 2 crystallizes in the space group 14/mcm with a=b=18.001(3), c=13.530(4)Å, and Z=8. Both compounds have 3-D (Mn, Cu)—P—O frameworks. For 1, two MnO4, two MnO5 polyhedra and four PO4 tetrahedra form small tunnels where Cs+ and Cl− ions reside. For 2, CuO4 and P2O7 groups form two different tunnels, one is similar to that in 1 (ca. 5.3 Å in diameter) while the other formed by eight CuO4 polyhedra and eight PO4 tetrahedra has an approximate diameter of 12 Å.

    Abstract translation: 本发明涉及特别适用于催化和离子交换的开放框架和微孔固体。 通过使用可以容易地除去的盐模板来构建微孔固体,而不会破坏微孔的骨架。 根据所使用的模板盐和浓度,可以形成具有不同几何结构的各种微孔固体。 两种化合物的实例包括Na2C [Mn3(P2O7)2] Cl(1)和K2.02C2.90 [Cu3(P2O7)2] C12.92(2)。 化合物1在空间群C2 / c中结晶,a = 21.210(8),b = 5.272(2),c = 13.924(2),β= 119.04(2),Z = 4。 化合物2在空间群14 / mcm中结晶,a = b = 18.001(3),c = 13.530(4),Z = 8。 两种化合物都具有3-D(Mn,Cu)-P-O骨架。 对于1,两个MnO4,两个MnO5多面体和四个PO4四面体形成Cs +和Cl-离子存在的小隧道。 对于2,CuO 4和P 2 O 7组形成两个不同的隧道,一个类似于1(直径约5.3),而由八个CuO 4多面体和八个PO 4四面体形成的另一个具有大约12的直径。

    Method of preparing silicoaluminophosphate compositions using a reagent
containing both quaternary ammonium and silicon reactive sites in the
same molecule
    6.
    发明授权
    Method of preparing silicoaluminophosphate compositions using a reagent containing both quaternary ammonium and silicon reactive sites in the same molecule 失效
    使用含有同一分子中的季铵和硅反应性位点的试剂制备硅铝磷酸盐组合物的方法

    公开(公告)号:US5227151A

    公开(公告)日:1993-07-13

    申请号:US792573

    申请日:1991-11-15

    Inventor: David C. Calabro

    CPC classification number: B01J29/85 C01B39/10 Y10S423/30

    Abstract: A method of preparing silicoaluminophosphate (SAPO) compositions from a forming mixture which comprises sources of oxides of silicon, aluminum and phosphorus and quaternary ammonium-functionalized organosiliconate directing agent wherein the oxides of silicon are provided at least in part by said directing agent, e.g., N-trimethoxysilylpropyl-N,N,N-trimethylammonium chloride.

    Abstract translation: 一种从形成混合物制备硅铝磷酸盐(SAPO)组合物的方法,所述形成混合物包含硅,铝和磷的氧化物源和季铵官能化的有机硅酸盐定向剂,其中硅的氧化物至少部分地由所述导向剂提供, N-三甲氧基甲硅烷基丙基-N,N,N-三甲基氯化铵。

    Zeolite Nu-5
    7.
    发明授权
    Zeolite Nu-5 失效
    沸石Nu-5

    公开(公告)号:US4420467A

    公开(公告)日:1983-12-13

    申请号:US331832

    申请日:1981-12-17

    Abstract: A synthetic zeolite material, designated zeolite Nu-5, having a molar composition expressed by the formula; 0.5 to 1.5 R.sub.2 O: Y.sub.2 O.sub.3 : at least 10 XO.sub.2 : 0 to 2000 H.sub.2 O wherein R is a monovalent cation or 1/n of a cation of valency n, X is silicon and or germanium, Y is one or more of aluminium, iron, chromium, vanadium, molybdenum, arsenic, manganese, gallium or boron, and H.sub.2 O is water of hydration additional to water notionally present when R is H, and having a defined X-ray diffraction pattern. Zeolite Nu-5 is a useful catalyst.

    Abstract translation: 具有由式表示的摩尔组成的合成沸石材料,称为沸石Nu-5; 0.5至1.5 R2O:Y2O3:至少10XO2:0至2000H2O其中R是一价阳离子或1 / n的价数阳离子n,X是硅或锗,Y是铝,铁, 铬,钒,钼,砷,锰,镓或硼,当R为H时,H 2 O是除水以外的水合水,并且具有确定的X射线衍射图。 沸石Nu-5是一种有用的催化剂。

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