POROUS VINYLIDENE FLUORIDE RESIN MEMBRANE AND PROCESS FOR PRODUCING SAME

    公开(公告)号:US20120160764A1

    公开(公告)日:2012-06-28

    申请号:US13393628

    申请日:2010-09-06

    摘要: A porous membrane of vinylidene fluoride resin, comprising a substantially single layer membrane of vinylidene fluoride resin having two major surfaces sandwiching a certain thickness, including a dense layer that has a small pore size and governs a filtration performance on one major surface side thereof, having an asymmetrical gradient network structure wherein pore sizes continuously increase from the one major surface side to the other opposite major surface side, and satisfying conditions: (a) the dense layer includes a 5 μm-thick portion contiguous to the one major surface showing a porosity A1 of at least 60%, (b) the one major surface shows a pore size P1 of at most 0.30 μm, and (c) the porous membrane shows a ratio Q/P14 of at least 5×104 (m/day·μm4), wherein the ratio Q/P14 denotes a ratio between Q (m/day) which is a value normalized to a whole layer porosity A2=80% of a water permeation rate measured at a test length L=200 mm under the conditions of a pressure difference of 100 kPa and a water temperature of 25° C., and a fourth power P14 of the pore size P1 on the one major surface. The porous membrane is produced through a process including: extruding a melt-kneaded mixture of a vinylidene fluoride resin and a plasticizer through a die into a form of a film, followed by cooling, to form a solidified film; and extracting the plasticizer to recover a porous membrane; wherein the plasticizer is mutually soluble with the vinylidene fluoride resin at a temperature forming the melt-kneaded mixture and further satisfies properties: (i) giving the melt-kneaded mixture with the vinylidene fluoride resin with a crystallization temperature Tc′ (° C.) which is lower by at least 6° C. than a crystallization temperature Tc of the vinylidene fluoride alone, (ii) giving the cooled and solidified product of the melt-kneaded mixture a crystal melting enthalpy ΔH′ (J/g) of at least 53 J/g per weight of the vinylidene fluoride resin as measured by a differential scanning calorimeter (DSC), and (iii) the plasticizer alone showing a viscosity of 200 mPa-s-1000 Pa-s at a temperature of 25° C. as measured according to JIS K7117-2 (using a cone-plate-type rotational viscometer).

    OPTICAL FILM AND METHOD AND APPARATUS FOR MANUFACTURING THE SAME
    6.
    发明申请
    OPTICAL FILM AND METHOD AND APPARATUS FOR MANUFACTURING THE SAME 审中-公开
    光学膜及其制造方法和装置

    公开(公告)号:US20110018149A1

    公开(公告)日:2011-01-27

    申请号:US12933842

    申请日:2009-03-18

    申请人: Kenichi Kazama

    发明人: Kenichi Kazama

    IPC分类号: B29D11/00

    摘要: Disclosed is a method of manufacturing an optical film in which thickness unevenness and optical distortion are sufficiently prevented, employing a melt casting film formation method. The method is one manufacturing an optical film by extruding a melted film forming composition containing a thermoplastic resin from lip portions of a casting die to form a melted product in the form of a film and then holding the resulting melted product between a pair of rotary rollers thereby cooling and solidifying the melted product, wherein the method comprises heating a shield plate, which is provided in the vicinity of an inlet of a nip of the pair of rotary rollers and in the vicinity of the surface of at least one of the pair of rotary rollers, thereby heating an air stream occurring upon rotation of the rotary rollers.

    摘要翻译: 公开了一种使用熔体流延膜形成方法制造光学膜的方法,其中充分防止了厚度不均匀性和光学变形。 该方法是通过从铸模的唇部挤出含有热塑性树脂的熔融成膜组合物以形成薄膜形式的熔融产物,然后将所得的熔融产物保持在一对旋转辊之间来制造光学膜 从而冷却和固化熔化的产品,其中所述方法包括加热屏蔽板,所述屏蔽板设置在所述一对旋转辊的辊隙的入口附近并且在所述一对旋转辊中的至少一个的表面附近 旋转辊,从而加热旋转辊旋转时发生的空气流。

    Method for manufacturing extrusion molding with smooth surface and extrusion molding apparatus
    7.
    发明申请
    Method for manufacturing extrusion molding with smooth surface and extrusion molding apparatus 审中-公开
    用于制造具有光滑表面的挤出成型和挤出成型装置的方法

    公开(公告)号:US20040159966A1

    公开(公告)日:2004-08-19

    申请号:US10754690

    申请日:2004-01-12

    IPC分类号: B29C047/90

    摘要: A method for manufacturing an extrusion molding with a smooth surface. An apparatus having a die and a sizing equipment is supplied with a molding material of thermoplastic resin. A heat conducting member is disposed within a flow channel of the die, and its tapered distal end portion is penetrated into a shaping flow channel beyond an orifice of the die. The molding material in molten state is introduced through the orifice into the shaping flow channel, and a solidified extrusion molding having a predetermined cross-sectional shape is exhausted out of the sizing equipment. Heat is supplied from the heat conducting member to the molding material, so that a molten portion remains when the molding material passes the distal end portion. Surface of the molding material is pressed against an inner wall face of the shaping flow channel due to a pressing force of the molten portion.

    摘要翻译: 一种具有光滑表面的挤压成型方法。 具有模具和尺寸设备的设备被供给热塑性树脂的模塑材料。 导热构件设置在模具的流动通道内,并且其锥形的远端部分穿过超过模具的孔口的成形流动通道。 熔融状态的成型材料通过孔口引入成型流路中,并且将具有预定横截面形状的固化挤出成型件从排料设备中排出。 热量从导热部件供给到成型材料,使得当成型材料通过前端部分时,熔融部分保留。 由于熔融部的按压力,成形材料的表面被挤压在成型流路的内壁面上。

    POLYCARBONATE RESIN SHEET
    9.
    发明申请
    POLYCARBONATE RESIN SHEET 审中-公开
    聚碳酸酯树脂片

    公开(公告)号:US20110097566A1

    公开(公告)日:2011-04-28

    申请号:US13001859

    申请日:2009-06-29

    申请人: Yuji Higaki

    发明人: Yuji Higaki

    摘要: A polycarbonate resin sheet which has a small heat shrinkage factor and small variations thereof and is useful for thermoforming and a production process therefor.The sheet is made of a polycarbonate resin and has a thickness of 0.2 to 2.0 mm, a heat shrinkage factor in the extrusion direction (MD) of 2 to 8% when it is heated at 180° C. for 10 minutes and a standard deviation of heat shrinkage factor in the transverse direction (TD) of 1.5 or less.

    摘要翻译: 一种聚碳酸酯树脂片,其热收缩率小且变化小,可用于热成型及其制造方法。 片材由聚碳酸酯树脂制成,其厚度为0.2-2.0mm,当在180℃下加热10分钟时,挤出方向(MD)的热收缩率为2-8%,标准偏差 的热收缩率在横向(TD)为1.5以下。

    Shaping Device and Method for Shaping and Cooling Articles, Especially Hollow Profiles
    10.
    发明申请
    Shaping Device and Method for Shaping and Cooling Articles, Especially Hollow Profiles 审中-公开
    成型装置和成型和冷却制品,特别是空心型材的方法

    公开(公告)号:US20090174107A1

    公开(公告)日:2009-07-09

    申请号:US11719393

    申请日:2005-11-14

    申请人: Reinhold Kössl

    发明人: Reinhold Kössl

    IPC分类号: B29C47/00

    摘要: The invention relates to a shaping device (3) for shaping and cooling articles produced from a plastic melt, whereby said device can be arranged downstream of an extruder. The shaping device (3) comprises, arranged in an entry area (19), an inlet opening (20) for the plastic melt, at least one channel (21) extending in the direction of an outlet area (22) and having channel walls (23, 24) delimiting the same, and at least one cooling device (27) associated with the channel walls (23, 24). An additional cooling device (28) for the plastic melt to be passed through is provided inside the channel (21) in the area directly adjacent to the inlet area (19).

    摘要翻译: 本发明涉及一种用于成形和冷却由塑料熔体制成的制品的成形装置(3),由此所述装置可以布置在挤出机的下游。 成形装置(3)包括布置在入口区域(19)中的用于塑料熔体的入口开口(20),至少一个在出口区域(22)的方向上延伸并且具有通道壁 (23,24)以及与通道壁(23,24)相关联的至少一个冷却装置(27)。 在与入口区域(19)直接相邻的区域内,在通道(21)内部设置用于塑料熔体通过的另外的冷却装置(28)。