摘要:
A porous membrane of vinylidene fluoride resin, comprising a substantially single layer membrane of vinylidene fluoride resin having two major surfaces sandwiching a certain thickness, including a dense layer that has a small pore size and governs a filtration performance on one major surface side thereof, having an asymmetrical gradient network structure wherein pore sizes continuously increase from the one major surface side to the other opposite major surface side, and satisfying conditions: (a) the dense layer includes a 5 μm-thick portion contiguous to the one major surface showing a porosity A1 of at least 60%, (b) the one major surface shows a pore size P1 of at most 0.30 μm, and (c) the porous membrane shows a ratio Q/P14 of at least 5×104 (m/day·μm4), wherein the ratio Q/P14 denotes a ratio between Q (m/day) which is a value normalized to a whole layer porosity A2=80% of a water permeation rate measured at a test length L=200 mm under the conditions of a pressure difference of 100 kPa and a water temperature of 25° C., and a fourth power P14 of the pore size P1 on the one major surface. The porous membrane is produced through a process including: extruding a melt-kneaded mixture of a vinylidene fluoride resin and a plasticizer through a die into a form of a film, followed by cooling, to form a solidified film; and extracting the plasticizer to recover a porous membrane; wherein the plasticizer is mutually soluble with the vinylidene fluoride resin at a temperature forming the melt-kneaded mixture and further satisfies properties: (i) giving the melt-kneaded mixture with the vinylidene fluoride resin with a crystallization temperature Tc′ (° C.) which is lower by at least 6° C. than a crystallization temperature Tc of the vinylidene fluoride alone, (ii) giving the cooled and solidified product of the melt-kneaded mixture a crystal melting enthalpy ΔH′ (J/g) of at least 53 J/g per weight of the vinylidene fluoride resin as measured by a differential scanning calorimeter (DSC), and (iii) the plasticizer alone showing a viscosity of 200 mPa-s-1000 Pa-s at a temperature of 25° C. as measured according to JIS K7117-2 (using a cone-plate-type rotational viscometer).
摘要:
A method for producing a crystalline polymer microporous membrane, which contains: placing a first crystalline polymer in a metal mold, and compressing the first crystalline polymer to form a first preforming body; placing a second crystalline polymer in a metal mold, and compressing the second crystalline polymer to form a second preforming body; extruding each of the first preforming body and the second preforming body to form a first extrusion body and a second extrusion body, respectively; laminating the first extrusion body and the second extrusion body to form a laminate; rolling the laminate; heating a surface of the laminate to perform asymmetric heating to thereby give a temperature gradient in a thickness direction of the laminate; and drawing the laminate.
摘要:
A method for producing an extruded food product comprising from about 25% to about 77% meat and vegetable protein by continuously introducing components of the food product to an extruder wherein the components include meat and vegetable protein; mixing the components to produce a mixture in the extruder; heating the mixture in the extruder to produce the food product; extruding the food product from the extruder through the extruder die; and cooling the food product. The product may further comprise plasticizers and be substantially free of cross-linking compounds. Generally, the product is a meat analog having a fibrous texturized appearance characteristic of meat.
摘要:
A manufacturing device for an optical sheet according to the present invention includes a first belt 34 extending on a first heating roll 31 and a first chill roll 32 and a second belt 44 extending on a second heating roll 41 and a second chill roll 42. The first heating roll 31 presses, from the surface of the second belt 44, a second belt non-contact portion PT2 of the second belt 44 facing the first belt 34 where the second heating roll 41 is not in contact with the second chill roll 42. The second chill roll 42 presses, from the surface of the first belt, a first belt non-contact portion PT1 of the first belt 34 facing the second belt 44 where the first heating roll 31 is not in contact with the first chill roll 32.
摘要:
The invention provides a polyvinylidene fluoride resin (PVDF) film in which a crystal structure determined from an absorbance by an infrared absorption spectrum is such that a proportion of a β-type crystal is 10% or more based on the sum total of an α-type crystal and the β-type crystal, further preferably a film whose tensile modulus in TD at 120° C. is 90 MPa or less, or a film in which a ratio of its tensile modulus in TD at a temperature of 100° C. to its tensile modulus in TD at a temperature of 23° C. is 4% or less, in particular an extruded film, a backsheet for solar cell module, which comprises the film, and a production process of the film, which comprises quenching a PVDF sheet-shaped material melt-extruded at 5 to 70° C. and preferably then subjecting the quenched material to a heat treatment.
摘要:
Disclosed is a method of manufacturing an optical film in which thickness unevenness and optical distortion are sufficiently prevented, employing a melt casting film formation method. The method is one manufacturing an optical film by extruding a melted film forming composition containing a thermoplastic resin from lip portions of a casting die to form a melted product in the form of a film and then holding the resulting melted product between a pair of rotary rollers thereby cooling and solidifying the melted product, wherein the method comprises heating a shield plate, which is provided in the vicinity of an inlet of a nip of the pair of rotary rollers and in the vicinity of the surface of at least one of the pair of rotary rollers, thereby heating an air stream occurring upon rotation of the rotary rollers.
摘要:
A method for manufacturing an extrusion molding with a smooth surface. An apparatus having a die and a sizing equipment is supplied with a molding material of thermoplastic resin. A heat conducting member is disposed within a flow channel of the die, and its tapered distal end portion is penetrated into a shaping flow channel beyond an orifice of the die. The molding material in molten state is introduced through the orifice into the shaping flow channel, and a solidified extrusion molding having a predetermined cross-sectional shape is exhausted out of the sizing equipment. Heat is supplied from the heat conducting member to the molding material, so that a molten portion remains when the molding material passes the distal end portion. Surface of the molding material is pressed against an inner wall face of the shaping flow channel due to a pressing force of the molten portion.
摘要:
The inner cannula (3) of a tracheostomy tube includes a shaft (30) extruded of an ePTFE material. The axial strength of the shaft is increased by heating elongate portions (34 and 35) along the shaft such as by contact with a heated roller (205). The heating is sufficient to alter the structure of the material and make the heated portions (34 and 35) more rigid than the remainder of the shaft.
摘要:
A polycarbonate resin sheet which has a small heat shrinkage factor and small variations thereof and is useful for thermoforming and a production process therefor.The sheet is made of a polycarbonate resin and has a thickness of 0.2 to 2.0 mm, a heat shrinkage factor in the extrusion direction (MD) of 2 to 8% when it is heated at 180° C. for 10 minutes and a standard deviation of heat shrinkage factor in the transverse direction (TD) of 1.5 or less.
摘要:
The invention relates to a shaping device (3) for shaping and cooling articles produced from a plastic melt, whereby said device can be arranged downstream of an extruder. The shaping device (3) comprises, arranged in an entry area (19), an inlet opening (20) for the plastic melt, at least one channel (21) extending in the direction of an outlet area (22) and having channel walls (23, 24) delimiting the same, and at least one cooling device (27) associated with the channel walls (23, 24). An additional cooling device (28) for the plastic melt to be passed through is provided inside the channel (21) in the area directly adjacent to the inlet area (19).