公开(公告)号：US5024871A

公开(公告)日：1991-06-18

申请号：US483501

申请日：1990-02-21

Applicant: David J. Arthur ,  Gwo S. Swei

Inventor： David J. Arthur ,  Gwo S. Swei

IPC: C08K3/00 ,  C04B26/08 ,  C04B35/14 ,  C04B41/45 ,  C08K9/00 ,  C08K9/04 ,  C08L27/12 ,  H01B1/22 ,  H01L23/14 ,  H05K1/03 ,  H05K3/38 ,  H05K3/46

CPC classification number: C04B41/009 ,  C04B26/08 ,  C04B35/14 ,  C04B41/4584 ,  C08K9/04 ,  H01L23/145 ,  H05K1/0373 ,  C04B2111/00844 ,  H01L2924/0002 ,  H05K1/034 ,  H05K1/0366 ,  H05K2201/015 ,  H05K2201/0195 ,  H05K2201/0209 ,  H05K2201/0239 ,  H05K3/4626 ,  Y10S428/901 ,  Y10T428/24917 ,  Y10T428/25 ,  Y10T428/259 ,  Y10T428/29 ,  Y10T428/3154

Abstract: A composite material is presented comprised of a ceramic filled fluoropolymer wherein the ceramic is coated with a zirconate coupling agent and/or a titanate coupling agent.

公开(公告)号：US5384181A

公开(公告)日：1995-01-24

申请号：US131870

申请日：1993-10-05

Applicant: David J. Arthur ,  Gwo S. Swei ,  Allen F. Horn, III ,  Brett Kilhenny

Inventor： David J. Arthur ,  Gwo S. Swei ,  Allen F. Horn, III ,  Brett Kilhenny

IPC: C08K9/06 ,  H01B3/44 ,  H01L23/14 ,  H05K1/03 ,  H05K1/05 ,  H05K3/38 ,  H05K3/46 ,  B32B9/00

CPC classification number: H05K1/0373 ,  C08K9/06 ,  H01B3/445 ,  H01L23/145 ,  H01L2924/0002 ,  H05K1/034 ,  H05K1/0366 ,  H05K1/056 ,  H05K2201/015 ,  H05K2201/0195 ,  H05K2201/0209 ,  H05K2201/0239 ,  H05K2201/0251 ,  H05K2201/068 ,  H05K3/389 ,  H05K3/4626 ,  Y10S428/901 ,  Y10T428/24802 ,  Y10T428/252 ,  Y10T428/259 ,  Y10T428/2995 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31663 ,  Y10T428/31692

Abstract: A composite material is presented comprised of a ceramic filled fluoropolymer wherein the ceramic is coated with a silane and the ceramic has a volume % fraction of between about 26-45. The composite of this invention exhibits excellent chemical resistance, particularly to alkaline environments. Preferably, the silane comprises a blend of at least one phenyl silane and at least one fluorosilane. The silane is preferably coated to a level of 10% of the total weight of ceramic filler.

Abstract translation: 提出了一种复合材料，其由陶瓷填充的含氟聚合物组成，其中陶瓷涂覆有硅烷，陶瓷的体积％分数介于约26-45之间。 本发明的复合材料表现出优异的耐化学性，特别是对碱性环境。 优选地，硅烷包含至少一种苯基硅烷和至少一种氟硅烷的共混物。 优选将硅烷涂覆至陶瓷填料总重量的10％的水平。

公开(公告)号：US5374453A

公开(公告)日：1994-12-20

申请号：US90488

申请日：1993-07-13

Applicant: Gwo S. Swei ,  David J. Arthur

Inventor： Gwo S. Swei ,  David J. Arthur

IPC: B29C41/28 ,  B29D7/01 ,  C08J3/00 ,  C08J3/215 ,  C08J9/26 ,  H05K1/03 ,  H05K1/05 ,  H05K3/38 ,  B05D3/02

CPC classification number: C08J9/26 ,  B29C41/28 ,  B29D7/01 ,  C08J3/005 ,  C08J3/215 ,  H05K1/034 ,  H05K1/0373 ,  B29K2027/18 ,  B29K2105/04 ,  B29K2105/16 ,  C08J2327/12 ,  H05K1/056 ,  H05K2201/015 ,  H05K2201/0209 ,  H05K2201/0212 ,  H05K2201/0215 ,  H05K2201/0239 ,  H05K3/386 ,  Y02P20/582

Abstract: A method for making a particulate filled polymeric matrix composite film includes mixing a polymeric matrix material with a dispersion of particulate filler in a carrier liquid to form a casting composition and adjusting the viscosity of the casting composition to retard separation of the particulate filler from the composition. A layer of the viscosity-adjusted casting composition is cast on a substrate and the layer is consolidated to form the particulate filled polymer matrix composite film. Films made by the method include very thin, e.g less than 1.0 mil, fluoropolymeric matrix films highly filled with very small diameter, preferably spherical, particles for use as, e.g. dielectric substrate materials in laminar electrical circuits.

Abstract translation: 制备颗粒填充的聚合物基质复合膜的方法包括将聚合物基体材料与颗粒填料的分散体混合在载体液体中以形成流延组合物并调节流延组合物的粘度以阻止颗粒填料与组合物的分离 。 将粘度调节的浇铸组合物的一层浇铸在基材上，并将该层固结以形成填充颗粒的聚合物基质复合膜。 通过该方法制备的膜包括非常薄的，例如小于1.0密耳的高度填充有非常小直径，优选球形的颗粒的含氟聚合物基质膜，用于例如， 层状电路中的电介质基片材料。

公开(公告)号：US5281466A

公开(公告)日：1994-01-25

申请号：US703633

申请日：1991-05-22

Applicant: David J. Arthur ,  Gwo S. Swei ,  Allen F. Horn, III ,  Brett Kilhenny

Inventor： David J. Arthur ,  Gwo S. Swei ,  Allen F. Horn, III ,  Brett Kilhenny

IPC: C04B26/08 ,  C04B35/14 ,  C04B41/45 ,  C08K9/02 ,  C08K9/04 ,  C08K9/06 ,  H01B3/44 ,  H01L23/14 ,  H05K1/03 ,  H05K1/05 ,  H05K3/38 ,  H05K3/46 ,  B32B3/00

CPC classification number: H05K3/4626 ,  C04B26/08 ,  C04B35/14 ,  C04B41/4584 ,  C08K9/02 ,  C08K9/04 ,  C08K9/06 ,  H01B3/445 ,  H01L23/145 ,  H05K1/0373 ,  H01L2924/0002 ,  H05K1/034 ,  H05K1/0366 ,  H05K1/05 ,  H05K1/056 ,  H05K2201/015 ,  H05K2201/0195 ,  H05K2201/0209 ,  H05K2201/0239 ,  H05K2201/0251 ,  H05K2201/068 ,  H05K3/389 ,  H05K3/4611 ,  Y10S428/901 ,  Y10T428/24802 ,  Y10T428/252 ,  Y10T428/259 ,  Y10T428/2995 ,  Y10T428/3154 ,  Y10T428/31544 ,  Y10T428/31692

Abstract: A composite material is presented comprised of a ceramic filled fluoropolymer wherein the ceramic is coated with a zirconate coupling agent and/or a titanate coupling agent and the ceramic has a volume % fraction of between about 26-45.

Abstract translation: 提出了一种复合材料，其由陶瓷填充的含氟聚合物组成，其中陶瓷涂覆有锆酸酯偶联剂和/或钛酸酯偶联剂，陶瓷的体积％分数为约26-45。

公开(公告)号：US06172139B2

公开(公告)日：2001-01-09

申请号：US08146981

申请日：1993-11-02

Applicant: Gwo S. Swei ,  David J. Arthur

Inventor： Gwo S. Swei ,  David J. Arthur

IPC: C08J305

CPC classification number: C08J9/26 ,  B29C41/28 ,  B29D7/01 ,  B29K2027/18 ,  B29K2105/04 ,  B29K2105/16 ,  B29K2995/0006 ,  C08J3/005 ,  C08J3/215 ,  C08J2327/12 ,  H05K1/034 ,  H05K1/0373 ,  H05K1/056 ,  H05K3/386 ,  H05K2201/015 ,  H05K2201/0209 ,  H05K2201/0212 ,  H05K2201/0215 ,  H05K2201/0239 ,  Y02P20/582

Abstract: A method for making a particulate filled polymeric matrix composite film includes mixing a polymeric matrix material with a dispersion of particulate filler in a carrier liquid to form a casting composition and adjusting the viscosity of the casting composition to retard separation of the particulate filler from the composition. A layer of the viscosity-adjusted casting composition is cast on a substrate and the layer is consolidated to form the particulate filled polymer matrix composite film. Films made by the method include very thin, e.g less than 1.0 mil, fluoropolymeric matrix films highly filled with very small diameter, preferably spherical, particles for use as, e.g. dielectric substrate materials in laminar electrical circuits.

Abstract translation: 制备颗粒填充的聚合物基质复合膜的方法包括将聚合物基体材料与颗粒填料的分散体混合在载体液体中以形成流延组合物并调节流延组合物的粘度以阻止颗粒填料与组合物的分离 。 将粘度调节的浇铸组合物的一层浇铸在基材上，并将该层固结以形成填充颗粒的聚合物基质复合膜。 通过该方法制备的膜包括非常薄的，例如小于1.0密耳的高度填充有非常小直径，优选球形的颗粒的含氟聚合物基质膜，用于例如， 层状电路中的电介质基片材料。

公开(公告)号：US5198295A

公开(公告)日：1993-03-30

申请号：US704303

申请日：1991-05-22

Applicant: David J. Arthur ,  Gwo S. Swei ,  Allen F. Horn, III

Inventor： David J. Arthur ,  Gwo S. Swei ,  Allen F. Horn, III

IPC: C04B26/08 ,  C04B35/14 ,  C04B41/45 ,  C08K9/02 ,  C08K9/04 ,  C08K9/06 ,  H01B3/44 ,  H01L23/14 ,  H05K1/03 ,  H05K1/05 ,  H05K3/38 ,  H05K3/46

CPC classification number: H05K3/4626 ,  C04B26/08 ,  C04B35/14 ,  C04B41/4584 ,  C08K9/02 ,  C08K9/04 ,  C08K9/06 ,  H01B3/445 ,  H01L23/145 ,  H05K1/0373 ,  H01L2924/0002 ,  H05K1/034 ,  H05K1/0366 ,  H05K1/05 ,  H05K1/056 ,  H05K2201/015 ,  H05K2201/0195 ,  H05K2201/0209 ,  H05K2201/0239 ,  H05K2201/0251 ,  H05K2201/068 ,  H05K3/389 ,  H05K3/4611 ,  Y10S428/901 ,  Y10T428/25 ,  Y10T428/252 ,  Y10T428/259 ,  Y10T428/2982 ,  Y10T428/2991 ,  Y10T428/2995 ,  Y10T428/3154 ,  Y10T428/31544

Abstract: A composite material is presented comprised of a ceramic filled fluoropolymer wherein the ceramic is coated with a titanate and/or zirconate and the ceramic has a volume % fraction of between about 45-50.

Abstract translation: 提出了一种复合材料，其由陶瓷填充的含氟聚合物组成，其中陶瓷涂覆有钛酸盐和/或锆酸盐，陶瓷的体积％分数在约45-50之间。

公开(公告)号：US5194326A

公开(公告)日：1993-03-16

申请号：US704320

申请日：1991-05-22

Applicant: David J. Arthur ,  Gwo S. Swei ,  Allen F. Horn, III

Inventor： David J. Arthur ,  Gwo S. Swei ,  Allen F. Horn, III

IPC: B32B15/08 ,  C08K9/06 ,  C09C3/12 ,  C09D127/12 ,  H01B3/00 ,  H01B3/44 ,  H01L23/14 ,  H05K1/03 ,  H05K1/05 ,  H05K3/38 ,  H05K3/46

CPC classification number: H05K3/4626 ,  C08K9/06 ,  H01B3/445 ,  H01L23/145 ,  H05K1/0373 ,  H01L2924/0002 ,  H05K1/034 ,  H05K1/0366 ,  H05K1/05 ,  H05K1/056 ,  H05K2201/015 ,  H05K2201/0195 ,  H05K2201/0209 ,  H05K2201/0239 ,  H05K2201/0251 ,  H05K2201/068 ,  H05K3/389 ,  H05K3/4611 ,  Y10T428/24372 ,  Y10T428/24917 ,  Y10T428/252 ,  Y10T428/254 ,  Y10T428/3154 ,  Y10T428/31544

Abstract: A composite material is presented comprised of a ceramic filled fluoropolymer wherein the ceramic is coated with a fluorosilane and the ceramic has a volume % fraction of between about 45-50.

Abstract translation: 提出了一种复合材料，其由陶瓷填充的含氟聚合物组成，其中陶瓷涂覆有氟硅烷，陶瓷的体积％分数在约45-50之间。

公开(公告)号：US5077115A

公开(公告)日：1991-12-31

申请号：US521982

申请日：1990-05-08

Applicant: David J. Arthur ,  Allen F. Horn, III ,  Kenneth W. Kristal ,  Gwo S. Swei ,  William R. Zdanis

Inventor： David J. Arthur ,  Allen F. Horn, III ,  Kenneth W. Kristal ,  Gwo S. Swei ,  William R. Zdanis

IPC: C08K3/00 ,  C08K3/22 ,  C08K3/34 ,  C08K3/36 ,  C08K9/00 ,  C08K9/04 ,  C08K9/10 ,  C08L23/00 ,  C08L27/00 ,  C08L27/12 ,  C08L101/00 ,  H01L23/14 ,  H05K1/03 ,  H05K3/46

CPC classification number: H05K3/4626 ,  C08K3/36 ,  C08K9/10 ,  H01L23/145 ,  H05K1/0373 ,  H01L2924/0002 ,  H01L2924/09701 ,  H05K2201/0133 ,  H05K2201/015 ,  H05K2201/0158 ,  H05K2201/0195 ,  H05K2201/0209 ,  Y10S428/901 ,  Y10T428/24322 ,  Y10T428/24802 ,  Y10T428/24917 ,  Y10T428/25 ,  Y10T428/254 ,  Y10T428/256 ,  Y10T428/29 ,  Y10T428/2991

Abstract: A thermoplastic composite material is presented which comprises a thermoplastic matrix which is highly filled with a coated ceramic filler. In an important feature of the present invention, the ceramic filler has been coated with a rubbery polymer that bonds to the filler. In a preferred embodiment, the thermoplastic matrix comprises a fluoropolymer, preferably a chlorofluoropolymer and the ceramic filler is a fused amorphous silica coated with a rubbery polymeric material. The thermoplastic composite material of this invention exhibits numerous advantages which makes it well suited for use as a bonding film, particularly a bonding film for producing multilayer printed wiring boards.

Abstract translation: 提出了一种热塑性复合材料，其包括高度填充有涂覆的陶瓷填料的热塑性基体。 在本发明的一个重要特征中，陶瓷填料已经涂覆有与填料结合的橡胶状聚合物。 在优选的实施方案中，热塑性基质包括含氟聚合物，优选氯氟聚合物，陶瓷填料是用橡胶状聚合物材料涂覆的熔融无定形二氧化硅。 本发明的热塑性复合材料显示出许多优点，使其非常适合用作接合薄膜，特别是用于生产多层印刷线路板的接合薄膜。

公开(公告)号：US5506049A

公开(公告)日：1996-04-09

申请号：US177198

申请日：1993-12-30

Applicant: Gwo S. Swei ,  David J. Arthur

Inventor： Gwo S. Swei ,  David J. Arthur

IPC: B29C41/28 ,  B29D7/01 ,  C08J3/00 ,  C08J3/215 ,  C08J9/26 ,  H05K1/03 ,  H05K1/05 ,  H05K3/38 ,  B32B5/16

CPC classification number: C08J9/26 ,  B29C41/28 ,  B29D7/01 ,  C08J3/005 ,  C08J3/215 ,  H05K1/034 ,  H05K1/0373 ,  B29K2027/18 ,  B29K2105/04 ,  B29K2105/16 ,  C08J2327/12 ,  H05K1/056 ,  H05K2201/015 ,  H05K2201/0209 ,  H05K2201/0212 ,  H05K2201/0215 ,  H05K2201/0239 ,  H05K3/386 ,  Y02P20/582 ,  Y10S428/901 ,  Y10T428/25 ,  Y10T428/252 ,  Y10T428/264

Abstract: A particulate filled fluoropolymeric matrix composite article and method of making the same is presented. Preferably, the article comprises an electrical substrate material. The method for making the particulate filled polymeric matrix composite film includes mixing a polymeric matrix material with a dispersion of particulate filler in a carrier liquid to form a casting composition and adjusting the viscosity of the casting composition to retard separation of the particulate filler from the composition. A layer of the viscosity-adjusted casting composition is cast on a substrate and the layer is consolidated to form the particulate filled polymer matrix composite film. Films made by the method include very thin, e.g less than 1.0 mil, fluoropolymeric matrix films highly filled with very small diameter, preferably spherical, particles for use as, e.g. dielectric substrate materials in laminar electrical circuits.

Abstract translation: 提出了一种填充颗粒的含氟聚合物基体复合材料及其制备方法。 优选地，制品包括电气基材材料。 制备颗粒填充的聚合物基质复合膜的方法包括将聚合物基体材料与颗粒填料的分散体混合在载体液体中以形成浇铸组合物并调节浇铸组合物的粘度以阻止颗粒填料与组合物的分离 。 将粘度调节的浇铸组合物的一层浇铸在基材上，并将该层固结以形成填充颗粒的聚合物基质复合膜。 通过该方法制备的膜包括非常薄的，例如小于1.0密耳的高度填充有非常小直径，优选球形的颗粒的含氟聚合物基质膜，用于例如， 层状电路中的电介质基片材料。

公开(公告)号：US5440805A

公开(公告)日：1995-08-15

申请号：US127975

申请日：1993-09-27

Applicant: Robert C. Daigle ,  W. David Smith ,  John A. Olenick ,  David J. Arthur ,  Gwo S. Swei

Inventor： Robert C. Daigle ,  W. David Smith ,  John A. Olenick ,  David J. Arthur ,  Gwo S. Swei

IPC: H01L21/48 ,  H01L23/498 ,  H01L23/538 ,  H05K1/00 ,  H05K1/02 ,  H05K3/20 ,  H05K3/24 ,  H05K3/28 ,  H05K3/32 ,  H05K3/42 ,  H05K3/46 ,  H05K3/36

CPC classification number: H05K3/4632 ,  H01L21/4857 ,  H01L23/49894 ,  H01L23/5383 ,  H05K3/205 ,  H05K3/4617 ,  H05K3/4647 ,  H05K3/4682 ,  H01L2221/68345 ,  H01L2924/0002 ,  H05K1/0206 ,  H05K1/0289 ,  H05K2201/0129 ,  H05K2201/015 ,  H05K2201/09563 ,  H05K2203/0726 ,  H05K2203/0733 ,  H05K2203/1189 ,  H05K3/20 ,  H05K3/243 ,  H05K3/28 ,  H05K3/328 ,  H05K3/423 ,  H05K3/4652 ,  H05K3/4658 ,  Y10T29/49126 ,  Y10T29/49155 ,  Y10T29/49165

Abstract: In accordance with the present invention, a circuit assembly is manufactured in an additive process using at least one layer of a fluoropolymer composite material and a conductive material. The conductive layers are plated, and the fluoropolymer composite layers are laminated. The use of the filled fluoropolymeric composite eliminates the need for a barrier metal layer between the insulation and the conductors. A plurality of these circuit assemblies are stacked, one on top of the other. At least, selected exposed locations of the conductive material comprise a diffusible conductive material (e.g., gold). Once stacked the circuit assemblies are subjected to lamination under heat and pressure to simultaneously fuse adjacent fluoropolymer composite material and diffuse adjacent diffusible conductive material together to form an integral multilayer circuit having solid conductive interconnects.

Abstract translation: 根据本发明，使用至少一层含氟聚合物复合材料和导电材料的添加工艺制造电路组件。 对导电层进行电镀，层压含氟聚合物复合层。 使用填充的氟聚合物复合材料消除了在绝缘体和导体之间的阻挡金属层的需要。 多个这些电路组件一个在另一个之上堆叠。 至少，导电材料的选定的暴露位置包括可扩散的导电材料（例如金）。 一旦堆叠，电路组件在热和压力下进行层压以同时熔化相邻的含氟聚合物复合材料并将相邻的可扩散导电材料扩散在一起以形成具有固体导电互连的整体多层电路。