Abstract:
A process for preparing a tin-containing zeolitic material having framework type BEA, comprising providing an aqueous synthesis mixture comprising a boron source, a silicon source, and a BEA structure directing agent; subjecting the synthesis mixture provided in to hydrothermal pre-crystallization conditions; adding the tin source to the obtained mixture; subjecting the obtained aqueous synthesis mixture to hydrothermal crystallization conditions, obtaining a tin-containing zeolitic material having framework type BEA comprised in its mother liquor.
Abstract:
A process for preparing an anticorrosion component for an antifreeze by oxidizing an oxydiol (I) in which x is 0 (zero) or a positive integer from 1 to 10 with molecular oxygen at a temperature of 20 to 100° C. and a partial oxygen pressure of 0.01 to 2 MPa in the presence of water and of a heterogeneous catalyst comprising platinum to form an oxydicarboxylic acid (II) in which y is 0 (zero) or a positive integer from 1 to 10, in which the oxidation is conducted (a) at a molar ratio of 0.002≤n(Pt)/[n(oxydiol (I))+n(oxydicarboxylic acid (II))]≤0.019 where “n(Pt)” Is the molar amount of platinum, “n(oxydiol (I))” is the molar amount of oxydiol (I) and “n(oxydicarboxylic acid (II))” Is the molar amount of oxydicarboxylic acid (II); (b) at a concentration of water of 50% to 95% by weight in the liquid phase; and (c) at a pH of 1 to 7.
Abstract:
A process for preparing a tin-containing zeolitic material having a BEA framework structure comprising providing a zeolitic material having a BEA framework structure having vacant tetrahedral framework sites, providing a tin-ion source in solid form, incorporating tin into the zeolitic material via solid-state ion exchange, calcining the zeolitic material, and treating the calcined zeolitic material with an aqueous solution having a pH of at most 5.
Abstract:
A process for preparing a tin-containing zeolitic material having an MWW-type framework structure comprising providing a zeolitic material having an MWW-type framework structure having vacant tetrahedral framework sites, providing a tin-ion source in solid form, and incorporating tin into the zeolitic material via solid-state ion exchange.
Abstract:
The present invention is directed towards a process for the synthesis of compounds with the general formula (II) or their respective alkali metal salts by oxidation of compounds of general formula (I) with oxygen
in the presence of a heterogeneous catalyst containing a metal of group 10 of the periodic table of the elements, wherein R1 and R2 and R3 are same or different and selected from H and C1-C6-alkyl, non-substituted or substituted with one or more moieties selected from COOH and O-R4 with R4 being selected from H and C1-C4-alkyl.
Abstract:
The present invention relates to the use of diesters of 2,5-dimethyl-2-hexenedioic acid, 2,5-dimethyl-3-hexenedioic acid and 2,5-dimethyladipic acid or a mixture thereof as a fragrance or as flavor, to a method for imparting or modifying a scent or a flavor to a composition by including said compounds into such composition, to a fragrance containing composition and/or a fragrance material containing said compounds and to a process for preparing diesters of 2,5-dimethyladipic acid.
Abstract:
A method for producing 2-methoxyacetic acid by oxidizing 2-methoxyethanol in a reaction device using oxygen at a temperature of 20 to 100° C. and an oxygen partial pressure of 0.01 to 2 MPa in the presence of water and a heterogeneous catalyst containing platinum, in which the method is carried out semi-continuously or continuously, and 2-methoxyethanol is added to the reaction device in a temporally and/or spatially distributed manner such that temporally and spatially, the mass ratio of 2-methoxyethanol to 2-methoxyethanol plus water per volume element in the reaction device is constantly ≤0.80 of the mass ratio of the added 2-methoxyethanol to the added 2-methoxyethanol plus water.
Abstract:
A composition comprising compound (I) of formula and compound (II) of formula wherein R2a and R2b independently from each other are a linear alkyl group with 1 to 4 carbon atoms and R1a, R1b, R3a to R6a and R3b to R6b independently from each other are a hydrogen atom or a linear alkyl group with 1 to 4 carbon atoms.
Abstract:
The present invention relates to a process for producing 2,6-dimethyl-5-hepten-1-al, which comprises reacting 3,7-dimethyl-1,6-octadiene (dihydromyrcene, beta-citronellene) with N2O in a solvent or solvent mixture containing at least one solvent having a proton-donating functional group.
Abstract:
The present invention relates to a process for the preparation of compounds or a mixture of compounds of the general formulae I.a or I.b wherein R1 is selected from C1-C12-alkyl, C3-C6-cycloalkyl, —C(═O)OR2, —PO(OR2a)2, aryl and hetaryl, R2, R2a are independently of each other selected from the group consisting of hydrogen, C1-C12-alkyl, C1-C12-alkenyl, where the last two radicals mentioned are unsubstituted, partly or completely halogenated or substituted by 1, 2, 3 or 4 radicals selected from the group consisting of C1-C6-alkoxy and CN, C3-C6-cycloalkyl, C3-C6-cycloalkyl-C1-C4-alkyl, aryl and aryl-C1-C4-alkyl, where the last four radicals mentioned are unsubstituted or substituted by 1, 2, 3 or 4 radicals selected from the group consisting of C1-C6-alkyl, C1-C6-haloalkyl, C1-C6-alkoxy, C1-C6-haloalkoxy, —CN, and halogen, which comprises dimerizing olefin compound of the general formula II, in the presence of at least one N-heterocyclic carbene catalyst.