公开(公告)号：US08772220B2

公开(公告)日：2014-07-08

申请号：US11844464

申请日：2007-08-24

申请人： Richard Vicari ,  Hang Wang ,  Bret Hann

发明人： Richard Vicari ,  Hang Wang ,  Bret Hann

IPC分类号： C11D7/28

CPC分类号： C11D3/395 ,  C01B11/068 ,  C11D3/222 ,  C11D3/3746 ,  C11D3/3753 ,  C11D3/378 ,  C11D3/3951 ,  C11D3/3958 ,  C11D17/0039 ,  C11D17/0082 ,  C11D17/042

摘要： A chemical delivery product for delivering an oxidizing chemical into an aqueous system is disclosed. For instance, in one embodiment, a substrate containing an oxidizing chemical, such as trichloroisocyanuric acid, is coated with a water soluble polymer in order to prevent the oxidizing chemical from degrading prior to use and in order to facilitate handling. In accordance with the present disclosure, a neutralizing agent is contacted with the substrate in order to prevent the substrate from degrading the water soluble coating. In an alternative embodiment, a package is formed from a water soluble film forming composition combined with a base.

摘要翻译： 公开了一种用于将氧化剂输送到水性体系中的化学输送产物。 例如，在一个实施方案中，含有氧化性化学物质如三氯异氰尿酸的底物涂覆有水溶性聚合物，以防止氧化性化学品在使用前降解，并且便于处理。 根据本公开，中和剂与基材接触以防止基材降解水溶性涂层。 在替代实施方式中，由与水溶性成膜组合物组合的基底形成包装。

公开(公告)号：US07994265B2

公开(公告)日：2011-08-09

申请号：US12806482

申请日：2010-08-13

申请人： Richard Vicari

发明人： Richard Vicari

IPC分类号： C08F2/00 ,  C08F20/00 ,  C08F12/28 ,  C08F218/02

CPC分类号： C08F220/58 ,  C08F8/12 ,  C08F8/48 ,  C08F218/08 ,  C08F2800/20 ,  C08F8/28 ,  C08F216/06 ,  C08F2220/585

摘要： In a method of preparing an aqueous dispersion selected from drilling fluids, hydraulic cement compositions, mineral pigment containing coatings, and papermaking furnishes or in a method of preparing a melt extrudate, the improvement comprising: a) producing a copolymer of vinyl alcohol (VOH) and 2-acrylamido-2-methyl propane sulfonic acid or a salt of such acid (AMPS) by steps including continuously feeding with agitation, vinyl acetate (VAM) and AMPS as comonomers, a free radical yielding polymerization initiator, and a solvent for said comonomers, initiator, and copolymer resulting from the copolymerization of said comonomers, maintaining the resulting reaction mass in said first reaction zone under polymerization conditions for a residence time sufficient for a major proportion of AMPS fed to said first reaction zone to polymerize, continuously feeding reaction mass from said first reaction zone with an additional supply of AMPS to a second reaction zone, maintaining the reaction mass in the second reaction zone for a residence time sufficient to polymerize a major proportion of the AMPS added to the second reaction zone, continuously withdrawing reaction mass from the second reaction zone, separating copolymer of VAM and AMPS from the latter reaction mass, and saponifying by hydrolysis and/or alcoholysis a major proportion of the acetate groups in said copolymer to form a copolymer of VOH and AMPS; and b) incorporating the saponified copolymer into the aqueous dispersion or melt extrudate.

公开(公告)号：US07932328B2

公开(公告)日：2011-04-26

申请号：US12806352

申请日：2010-08-11

申请人： Richard Vicari

发明人： Richard Vicari

IPC分类号： C08F2/00 ,  C08F20/00 ,  C08F12/28 ,  C08F218/02

CPC分类号： C08F216/06 ,  C08F8/12 ,  C08F218/08 ,  C08F220/58 ,  C08F2800/10 ,  C08J5/18 ,  C08J2329/04 ,  C11D17/042 ,  C08F2220/606

摘要： A product comprising a cold water soluble film wherein: a) the film comprises a copolymer of vinyl alcohol (VOH) with a minor amount of 2-acrylamido-2-methyl propane sulfonic acid in free acid form or as a salt of the free acid (AMPS); and b) the film has a harsh chemical dissolution time of less than about 80 seconds measured by the harsh chemical dissolution test method after 8 weeks.

摘要翻译： 一种包含冷水溶性膜的产品，其中：a）所述膜包含乙烯醇（VOH）与少量游离酸形式的2-丙烯酰氨基-2-甲基丙磺酸的共聚物或游离酸的盐 （AMPS）; 和b）8周后，通过苛刻的化学溶解试验方法测定，该膜具有小于约80秒的苛刻化学溶解时间。

公开(公告)号：US20100234492A1

公开(公告)日：2010-09-16

申请号：US12800576

申请日：2010-05-18

申请人： Richard Vicari ,  Bret F. Hann

发明人： Richard Vicari ,  Bret F. Hann

IPC分类号： C08K5/151

CPC分类号： C08J5/18 ,  B29C41/28 ,  B29K2005/00 ,  B29K2029/00 ,  B29K2995/0062 ,  C02F1/76 ,  C02F2103/42 ,  C02F2303/08 ,  C08J2329/04 ,  C08K5/151 ,  C08K5/34924 ,  Y10T428/1334 ,  Y10T428/1352 ,  C08L29/04

摘要： A water-soluble film which comprises a saccharide component and a vinyl alcohol resin component, where the vinyl alcohol resin may include functional comonomer units such as sulfonic acid functional groups or salts thereof. Preferred are polyvinyl alcohol/2-methylacrylamido-2 methyl propane sulfonic acid resins (PVOH/AMPS) which may be purchased commercially with relatively higher or relatively lower characteristic viscosity. The films exhibit superior resistance to aggressive oxidizing chemicals and remain soluble in water after prolonged exposure thereto. The films are particularly useful for unit-dose packaging of chlorine-containing pool chemicals, such as trichloroisocyanuric acid.

摘要翻译： 包含糖组分和乙烯醇树脂组分的水溶性薄膜，其中乙烯醇树脂可以包括诸如磺酸官能团的官能共聚单体单元或其盐。 优选聚乙烯醇/ 2-甲基丙烯酰胺基-2-甲基丙烷磺酸树脂（PVOH / AMPS），其可以以相对较高或相对较低的特征粘度商购。 该膜表现出优异的耐腐蚀性氧化性化学物质，并且在长时间暴露于其后保持溶于水。 该膜对于含氯池化学品如三氯异氰脲酸的单位剂量包装特别有用。

公开(公告)号：US07745517B2

公开(公告)日：2010-06-29

申请号：US11415768

申请日：2006-05-02

申请人： Richard Vicari ,  Bret F. Hann

发明人： Richard Vicari ,  Bret F. Hann

IPC分类号： C08L5/00

CPC分类号： C08J5/18 ,  B29C41/28 ,  B29K2005/00 ,  B29K2029/00 ,  B29K2995/0062 ,  C02F1/76 ,  C02F2103/42 ,  C02F2303/08 ,  C08J2329/04 ,  C08K5/151 ,  C08K5/34924 ,  Y10T428/1334 ,  Y10T428/1352 ,  C08L29/04

摘要： A water-soluble film which comprises a saceharide component and a vinyl alcohol resin component, where the vinyl alcohol resin may include functional comonomer units such as sulfonic acid functional groups or salts thereof. Preferred are polyvinyl alcohol/2-methylacrylamido-2 methyl propane sulfonic acid resins (PVOH/AMPS) which may be purchased commercially with relatively higher or relatively lower characteristic viscosity. The films exhibit superior resistance to aggressive oxidizing chemicals and remain soluble in water after prolonged exposure thereto. The films are particularly useful for unit-dose packaging of chlorine-containing pool chemicals, such as trichloroisocyanuric acid.

摘要翻译： 包含西沙星成分和乙烯醇树脂组分的水溶性膜，其中乙烯醇树脂可以包括诸如磺酸官能团的官能共聚单体单元或其盐。 优选聚乙烯醇/ 2-甲基丙烯酰胺基-2-甲基丙烷磺酸树脂（PVOH / AMPS），其可以以相对较高或相对较低的特征粘度商购。 该膜表现出优异的耐腐蚀性氧化性化学物质，并且在长时间暴露于其后保持溶于水。 该膜对于含氯池化学品如三氯异氰脲酸的单位剂量包装特别有用。

公开(公告)号：US20090148758A1

公开(公告)日：2009-06-11

申请号：US12313329

申请日：2008-11-19

申请人： Richard Vicari ,  Bret F. Hann

发明人： Richard Vicari ,  Bret F. Hann

IPC分类号： H01M2/16 ,  H01M4/00 ,  B05D5/12

CPC分类号： H01M4/483 ,  H01M2/1653

摘要： A separator film for an electric battery is provided to substantially eliminate electric contact between an anode component and a cathode component. The film includes a vinyl alcohol copolymer with functional comonomer units such as sulfonic acid functionalized units or salts thereof. The films are desirable for use in battery separators because they exhibit superior resistance to degeneration by oxidation, enabling the manufacture of batteries with improved conductivity, longer discharge times, and longer cycle lives.

摘要翻译： 提供了用于电池的隔膜，以基本上消除阳极部件和阴极部件之间的电接触。 该膜包括具有官能共聚单体的乙烯醇共聚物，例如磺酸官能化单元或其盐。 因为它们通过氧化表现出优异的抗退化性能，因此能够制造具有改善的导电性，更长的放电时间和更长的循环寿命的电池。

公开(公告)号：US06451945B1

公开(公告)日：2002-09-17

申请号：US09253499

申请日：1999-02-19

申请人： Saikumar Jayaraman ,  George Martin Benedikt ,  Larry Funderburk Rhodes ,  Richard Vicari ,  Robert David Allen ,  Richard Anthony DiPietro ,  Ratnam Sooriyakumaran ,  Thomas Wallow

发明人： Saikumar Jayaraman ,  George Martin Benedikt ,  Larry Funderburk Rhodes ,  Richard Vicari ,  Robert David Allen ,  Richard Anthony DiPietro ,  Ratnam Sooriyakumaran ,  Thomas Wallow

IPC分类号： C08F13208

CPC分类号： G03F7/039 ,  C08G61/02 ,  C08G61/08 ,  G03F7/0045 ,  G03F7/0395 ,  G03F7/0397

摘要： The present invention relates to cyclic polymers and their use in photolithographic applications. The cyclic polymers contain a pendant acid labile functional group and a functional group containing a protected hydroxyl moiety. The polymers are post modified by deprotecting the pendant hydroxyl moiety and reacting the deprotected hydroxyl containing moiety with a coreactant. The post-functionalized polymers find application in chemically amplified photoresist compositions.

摘要翻译： 本发明涉及环状聚合物及其在光刻应用中的应用。 环状聚合物含有侧链酸不稳定官能团和含有被保护的羟基部分的官能团。 通过使侧基羟基部分脱保护并使去保护的含羟基的部分与共反应物反应来对聚合物进行后修饰。 后官能化聚合物可用于化学扩增的光致抗蚀剂组合物中。

公开(公告)号：US5710282A

公开(公告)日：1998-01-20

申请号：US516768

申请日：1995-08-18

申请人： Kathleen Nelson Juneau ,  Richard Vicari ,  Carl David Murphy

发明人： Kathleen Nelson Juneau ,  Richard Vicari ,  Carl David Murphy

IPC分类号： C07C231/02 ,  C07C235/52 ,  C07D209/20 ,  C07D403/10

CPC分类号： C07C235/52 ,  C07C231/02 ,  C07D209/20

摘要： The present invention provides a novel one-step process for preparing substituted aryls which can be used as end-capping monomers for preparing highly branched macromolecule polymers that have highly controlled molecular architectures. The process comprises the steps of (a) reacting an aromatic acid with an activating carbodiimide for a sufficient period of time and under suitable conditions of temperature and pressure to form an activated aromatic intermediate, and (b) reacting said intermediate with a suitable nucleophile for a sufficient period of time and under suitable conditions of temperature and pressure to form said substituted aryl compound.

摘要翻译： 本发明提供了一种用于制备取代芳基的新型一步法，其可用作制备具有高度受控分子结构的高度支化的大分子聚合物的封端单体。 该方法包括以下步骤：（a）使芳族酸与活化碳二亚胺反应足够的时间和温度和压力的合适条件以形成活化的芳族中间体，和（b）使所述中间体与合适的亲核试剂反应， 足够的时间和在合适的温度和压力条件下形成所述取代的芳基化合物。

公开(公告)号：US5462840A

公开(公告)日：1995-10-31

申请号：US673243

申请日：1991-03-19

申请人： Richard Vicari

发明人： Richard Vicari

IPC分类号： C08F8/32 ,  G03F7/023 ,  G03F7/38 ,  G03F7/30 ,  G03F7/40

CPC分类号： G03F7/0233 ,  C08F8/32 ,  C08F8/48 ,  G03F7/38 ,  C08F2800/20 ,  C08F2810/50 ,  Y10S430/11

摘要： A compound, method of manufacture and method for use of an alternating copolymer having the structure ##STR1## wherein X is independently H, C.sub.1 to C.sub.10 alkyl or alkoxy, primary or secondary amino or halogen, and R is aliphatic, cycloaliphatic, or aliphatic heterocyclic, and wherein the molecular weight ranges from about 1,000 to 50,000.

摘要翻译： 一种化合物，制造方法和使用具有结构式（a）的交替共聚物的方法，其中X独立地为H，C 1至C 10烷基或烷氧基，伯或仲氨基或卤素，R为脂族，环脂族或脂族杂环 ，并且其中分子量为约1,000至50,000。

公开(公告)号：US5438142A

公开(公告)日：1995-08-01

申请号：US105824

申请日：1993-08-10

申请人： John R. Fritsch ,  Olan S. Fruchey ,  Debasish Kuila ,  George Kvakovszky ,  Mark A. Murphy ,  Michael T. Sheehan ,  James R Sounik ,  Richard Vicari

发明人： John R. Fritsch ,  Olan S. Fruchey ,  Debasish Kuila ,  George Kvakovszky ,  Mark A. Murphy ,  Michael T. Sheehan ,  James R Sounik ,  Richard Vicari

IPC分类号： C07C37/20 ,  C07C39/15 ,  C07C39/16 ,  C07C43/23 ,  C07C45/00 ,  C07C45/54 ,  C07C45/68 ,  C07C45/69 ,  C07C49/825 ,  C07C49/84 ,  C07C255/32 ,  C07C255/41 ,  C07D211/22 ,  C07D211/46 ,  C07D249/20 ,  C07D295/185 ,  C08G18/38 ,  C08G59/24 ,  C08G59/26 ,  C08G75/20 ,  C08G75/23 ,  C08K5/00 ,  C08K5/07 ,  C08K5/3432 ,  C08K5/3435 ,  C08K5/3472 ,  C08K5/3475 ,  C08L101/00 ,  C09B69/10 ,  C09K3/00 ,  C09K15/08 ,  C09K15/24 ,  C09K15/30 ,  C07D249/16 ,  C08F26/06 ,  C08K5/34

CPC分类号： C07D295/185 ,  C07C255/41 ,  C07C37/14 ,  C07C37/20 ,  C07C39/15 ,  C07C39/16 ,  C07C39/367 ,  C07C45/008 ,  C07C45/54 ,  C07C45/68 ,  C07C45/69 ,  C07D211/46 ,  C07D249/20 ,  C08G18/3851 ,  C08G59/245 ,  C08G59/26 ,  C08G75/20 ,  C08G75/23 ,  C08K5/0008

摘要： Compounds useful as polymer stabilizers which are polymerizable into condensation polymer systems are disclosed and claimed. A particularly preferred embodiment is 1-(3'-(benzotriazol-2"-yl)-4'-hydroxyphenyl)-1,1-bis(4-hydroxyphenyl)ethane.

摘要翻译： 公开并要求保护作为可聚合成缩聚物体系的聚合物稳定剂的化合物。 特别优选的实施方案是1-（3' - （苯并三唑-2“ - 基）-4'-羟基苯基）-1,1-双（4-羟基苯基）乙烷。