公开(公告)号：US20100330429A1

公开(公告)日：2010-12-30

申请号：US12819465

申请日：2010-06-21

申请人： Yukinobu YURA ,  Nobuyuki Kobayashi ,  Tsutomu Nanataki ,  Kazuyuki Kaigawa

发明人： Yukinobu YURA ,  Nobuyuki Kobayashi ,  Tsutomu Nanataki ,  Kazuyuki Kaigawa

IPC分类号： H01M4/50 ,  H01M4/90

CPC分类号： H01M10/052 ,  B82Y30/00 ,  C01G45/1221 ,  C01G45/1242 ,  C01P2002/32 ,  C01P2002/72 ,  C01P2004/64 ,  C01P2006/10 ,  C01P2006/12 ,  C01P2006/40 ,  C01P2006/80 ,  H01M4/131 ,  H01M4/505 ,  H01M4/62 ,  H01M10/4235 ,  H01M2004/021 ,  Y10T428/2982

摘要： A positive electrode active material having an average from 1 μm or lager to smaller than 5 μm and containing a large number of crystal grains being composed of lithium manganate of spinel structure containing lithium and manganese as constituent elements, whose crystallite size is 500 to 1,500 nm in powder X-ray diffraction pattern, and whose value of a lattice strain (η) of 0.05×10−3 to 0.9×10−3 in powder X-ray diffraction pattern, and whose D50/DBET ratio is 1 to 4 wherein the D50 (μm) is the median diameter of the positive electrode active material and the DBET (μm) is calculated from the BET specific surface area by using the following general formula (1). DBET=6/(d×S)  (1) [Wherein d is the true density (g/cm3) of the positive electrode active material powder and S is BET specific surface area (m2/g) in the general formula (1).]

摘要翻译： 平均1μm以上且小于5μm的正极活性物质，其含有大量的结晶粒子，所述晶体由以锂和锰为构成元素的尖晶石结构的锰酸锂构成，微晶尺寸为500〜1500nm 在粉末X射线衍射图中，其粉末X射线衍射图中的晶格应变值（＆egr）为0.05×10 -3〜0.9×10 -3，D50 / DBET比为1〜4，其中 D50（μm）是正极活性物质的中值粒径，使用以下通式（1）从BET比表面积算出DBET（μm）。 DBET = 6 /（d×S）（1）其中，d为正极活性物质粉末的真密度（g / cm 3），S为通式（1）中的BET比表面积（m2 / g） 。]

公开(公告)号：US07063908B2

公开(公告)日：2006-06-20

申请号：US10255226

申请日：2002-09-26

申请人： Yoshihiko Yamamura ,  Kazuyuki Kaigawa ,  Shinji Kawasaki ,  Hiroaki Sakai

发明人： Yoshihiko Yamamura ,  Kazuyuki Kaigawa ,  Shinji Kawasaki ,  Hiroaki Sakai

IPC分类号： H01M81/00

CPC分类号： C04B35/44 ,  C01F17/0025 ,  C01G49/0054 ,  C01G51/68 ,  C01P2002/34 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2006/40 ,  C04B2235/3206 ,  C04B2235/3208 ,  C04B2235/3213 ,  C04B2235/3215 ,  C04B2235/3224 ,  C04B2235/3272 ,  C04B2235/3279 ,  C04B2235/6567 ,  C04B2235/768 ,  H01B1/08 ,  H01M8/1246 ,  H01M2008/1293 ,  Y02E60/525 ,  Y02P70/56

摘要： A complex oxide and an oxide-ion conductor made of the complex oxide are provided. The complex oxide has a basic composition of (Sm1-xAx)(Al1-yBy)O3, wherein “A” represents at least one element selected from the group consisting of barium, strontium and calcium, “B” represents an element selected from the group consisting of magnesium, iron and cobalt, x is a value in a range of 0.10 to 0.30, and y is a value in a range of 0 to 0.30.

摘要翻译： 提供由复合氧化物制成的复合氧化物和氧化物离子导体。 复合氧化物具有（Sm 1-x A A x S）（Al 1-y B a Y z）的基本组成 >）O 3，其中“A”表示选自钡，锶和钙中的至少一种元素，“B”表示选自镁，铁和钴的元素 ，x为0.10〜0.30的范围的值，y为0〜0.30的范围的值。

公开(公告)号：US20110210281A1

公开(公告)日：2011-09-01

申请号：US12965947

申请日：2010-12-13

申请人： Kazuyuki KAIGAWA ,  Ritsu Tanaka

发明人： Kazuyuki KAIGAWA ,  Ritsu Tanaka

IPC分类号： H01L41/187

CPC分类号： C04B35/495 ,  C04B35/6262 ,  C04B35/62645 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3255 ,  C04B2235/3262 ,  C04B2235/3294 ,  C04B2235/3298 ,  C04B2235/5436 ,  C04B2235/5445 ,  C04B2235/765 ,  C04B2235/768 ,  C04B2235/787 ,  C04B2235/79 ,  H01L41/1873 ,  H01L41/314

摘要： A piezoelectric/electrostrictive ceramic sintered body has a microstructure in which a matrix phase and an additional material phase having different compositions coexist and the additional material phase is dispersed in the matrix phase. A residual strain ratio of the additional material phase alone is larger than a residual strain ratio of the matrix phase alone. The matrix phase and the additional material phase have a composition in which a Mn compound containing Mn atoms of 0 parts by mole or more and 3 parts by mole or less and a Ba compound containing Ba atoms of 0 parts by mole or more and 1 part by mole or less are contained in a composite of 100 parts by mole represented by a general formula {Liy(Na1-xKx)1-y}a(Nb1-z-wTazSbw)O3, where a, x, y, z and w satisfy 0.9≦a≦1.2, 0.2≦x≦0.8, 0.0≦y≦0.2, 0≦z≦0.5 and 0≦w≦0.1, respectively.

摘要翻译： 压电/电致伸缩陶瓷烧结体具有其中基体相和具有不同组成的附加材料相共存并且附加材料相分散在基体相中的微结构。 单独的附加材料相的残余应变比大于单独的基质相的残余应变比。 基体相和附加材料相的组成为：含有Mn原子的Mn化合物为0份摩尔以上且3份以下，Ba原子的Ba化合物为0份以上，1份以上 （Nb 1-x K x）1-y} a（Nb 1-z-w T z S b w）O 3表示的100份摩尔的复合物，其中a，x，y，z和w 分别满足0.9＆nlE; a＆nlE; 1.2,0.2＆nlE; x＆nlE; 0.8,0.0＆nlE; y＆nlE; 0.2,0＆amp; nlE; z＆nlE; 0.5和0＆lt; nEE; w＆nlE; 0.1。

公开(公告)号：US07893601B2

公开(公告)日：2011-02-22

申请号：US12267717

申请日：2008-11-10

申请人： Kazuyuki Kaigawa ,  Hirofumi Yamaguchi

发明人： Kazuyuki Kaigawa ,  Hirofumi Yamaguchi

IPC分类号： H01L41/187

CPC分类号： C04B35/495 ,  C01G33/006 ,  C01G35/006 ,  C01P2002/34 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2006/10 ,  C01P2006/40 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3241 ,  C04B2235/3251 ,  C04B2235/3267 ,  C04B2235/3272 ,  C04B2235/3275 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/3284 ,  C04B2235/449 ,  C04B2235/5445 ,  C04B2235/656 ,  C04B2235/6562 ,  C04B2235/661 ,  C04B2235/768 ,  C04B2235/77 ,  C04B2235/783 ,  C04B2235/785 ,  C04B2235/786 ,  C04B2235/79 ,  H01L41/1873 ,  H01L41/43 ,  Y10T29/42

摘要： Manufacturing sintered bodies having microstructures including microscopic grains having a grain diameter of less than 5 μm, intermediate grains having a grain diameter of 5 μm or more and less than 15 μm, and coarse grains having a grain diameter of 15 μm or more and 100 μm or less enables to obtain high electric characteristics. Chemical compounds including metal elements are mixed so that the ratio of the elements is a composition expressed by (Li, Na, K)(Nb, Ta)O3, the mixture is calcined and crushed to obtain calcined/crushed powder. The powder is sintered in a constant temperature keeping process wherein temperature is kept constantly at a predetermined temperature within a range from 800 to 900° C. for a predetermined period of time in a heating process, and then the powder is further sintered by raising temperature to firing temperature, thereby the piezoelectric materials having superior electric characteristics are manufactured.

摘要翻译： 制造具有微观结构的烧结体，其具有粒径小于5μm的微细晶粒，粒径为5μm以上且小于15μm的中间晶粒，以及粒径为15μm以上且100μm以下的粗晶粒 以下能够获得高电特性。 将包含金属元素的化合物混合，使元素的比例为由（Li，Na，K）（Nb，Ta）O 3表示的组成，将混合物煅烧并粉碎以获得煅烧/粉碎的粉末。 将该粉末在恒温保持法中烧结，其中在加热过程中将温度恒定地保持在800-900℃的预定温度下一段预定的时间，然后通过升高温度进一步烧结粉末 烧成温度，由此制造具有优异的电特性的压电材料。

公开(公告)号：US20110006244A1

公开(公告)日：2011-01-13

申请号：US12830625

申请日：2010-07-06

申请人： Kazuyuki KAIGAWA ,  Ritsu Tanaka

发明人： Kazuyuki KAIGAWA ,  Ritsu Tanaka

IPC分类号： H01L41/18

CPC分类号： C04B35/495 ,  C04B35/62645 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3213 ,  C04B2235/3251 ,  C04B2235/3255 ,  C04B2235/3262 ,  C04B2235/3267 ,  C04B2235/3294 ,  C04B2235/449 ,  C04B2235/5445 ,  C04B2235/77 ,  C04B2235/79 ,  C04B2235/80 ,  H01L41/083 ,  H01L41/1873 ,  H01L41/273 ,  H01L41/314 ,  H01L41/43

摘要： A piezoelectric/electrostrictive ceramic sintered body has a microstructure in which a matrix phase and an additional material phase having different compositions coexist and the additional material phase is dispersed in the matrix phase. A residual strain ratio of the additional material phase alone is larger than a residual strain ratio of the matrix phase alone. The matrix phase and the additional material phase have a composition in which a Mn compound containing Mn atoms of 0 parts by mol or more and 3 parts by mol or less and a Sr compound containing Sr atoms of 0 parts by mol or more and 1 part by mol or less are contained in a composite of 100 parts by mol represented by a general formula {Liy(Na1-xKx)1-y}a(Nb1-z-wTazSbw)O3, where a, x, y, z and w satisfy 0.9≦a≦1.2, 0.2≦x≦0.8, 0.0≦y≦0.2, 0≦z≦0.5 and 0≦w≦0.1, respectively.

摘要翻译： 压电/电致伸缩陶瓷烧结体具有其中基体相和具有不同组成的附加材料相共存并且附加材料相分散在基体相中的微结构。 单独的附加材料相的残余应变比大于单独的基质相的残余应变比。 基体相和附加材料相具有Mn含量为0摩尔％以上且3摩尔份以下的Mn化合物和Sr原子数为0摩尔份以上的Sr化合物和1份 以上，通式{Liy（Na1-xKx）1-y} a（Nb1-z-wTazSbw）O3表示的100份摩尔的复合物中含有1摩尔以下，其中a，x，y，z和w 分别满足0.9＆nlE; a＆nlE; 1.2,0.2＆nlE; x＆nlE; 0.8,0.0＆amp; nlE; y＆nlE; 0.2,0＆amp; nlE; z＆nlE; 0.5和0＆lt; nEE; w＆nlE; 0.1。

公开(公告)号：US07621979B2

公开(公告)日：2009-11-24

申请号：US11511204

申请日：2006-08-28

申请人： Kazuyuki Kaigawa ,  Toshihiro Tomita ,  Manabu Yoshida ,  Masamichi Obata

发明人： Kazuyuki Kaigawa ,  Toshihiro Tomita ,  Manabu Yoshida ,  Masamichi Obata

IPC分类号： B01D53/22 ,  B01D69/12 ,  B01D71/02

CPC分类号： B01D71/021 ,  B01D53/02 ,  B01D67/0067 ,  B01D69/10 ,  B01D2253/102 ,  B01D2257/102 ,  B01D2257/104 ,  B01D2257/708 ,  B01D2325/04 ,  B01J20/20 ,  B01J20/28035 ,  C01B32/05 ,  Y02A50/235

摘要： A carbon film laminate 1 having a porous substrate 6 formed of a plurality of particles and a carbon film 2 provided on a surface of the porous substrate 6, wherein the porous substrate 6 includes a surface layer 3 which is in contact with the carbon film 2 and which is formed of particles 3a having a mean particle size of 0.01 to 0.11 μm, and a porous body 5 formed of particles having a mean particle size differing from that of the particles 3a forming the surface layer 3. The invention provides a carbon film laminate which does not generate cracks and pinholes of the carbon film and which is suitable for producing thin film thereof.

摘要翻译： 具有由多个颗粒形成的多孔基材6和设置在多孔基材6的表面上的碳膜2的碳膜层压体1，其中多孔基材6包括与碳膜2接触的表面层3 由平均粒径为0.01〜0.11μm的粒子3a形成的多孔体5以及与构成表面层3的粒子3a的平均粒径不同的粒子形成的多孔体5构成。本发明提供一种碳膜 层压体不会产生碳膜的裂纹和针孔，并且适用于制造其薄膜。

公开(公告)号：US20090121589A1

公开(公告)日：2009-05-14

申请号：US12267717

申请日：2008-11-10

申请人： Kazuyuki KAIGAWA ,  Hirofumi YAMAGUCHI

发明人： Kazuyuki KAIGAWA ,  Hirofumi YAMAGUCHI

IPC分类号： H01L41/04 ,  H01L41/22

CPC分类号： C04B35/495 ,  C01G33/006 ,  C01G35/006 ,  C01P2002/34 ,  C01P2002/52 ,  C01P2004/03 ,  C01P2006/10 ,  C01P2006/40 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3241 ,  C04B2235/3251 ,  C04B2235/3267 ,  C04B2235/3272 ,  C04B2235/3275 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/3284 ,  C04B2235/449 ,  C04B2235/5445 ,  C04B2235/656 ,  C04B2235/6562 ,  C04B2235/661 ,  C04B2235/768 ,  C04B2235/77 ,  C04B2235/783 ,  C04B2235/785 ,  C04B2235/786 ,  C04B2235/79 ,  H01L41/1873 ,  H01L41/43 ,  Y10T29/42

摘要： Manufacturing sintered bodies having microstructures including microscopic grains having a grain diameter of less than 5 μm, intermediate grains having a grain diameter of 5 μm or more and less than 15 μm, and coarse grains having a grain diameter of 15 μm or more and 100 μm or less enables to obtain high electric characteristics. Chemical compounds including metal elements are mixed so that the ratio of the elements is a composition expressed by (Li, Na, K)(Nb, Ta)O3, the mixture is calcined and crushed to obtain calcined/crushed powder. The powder is sintered in a constant temperature keeping process wherein temperature is kept constantly at a predetermined temperature within a range from 800 to 900° C. for a predetermined period of time in a heating process, and then the powder is further sintered by raising temperature to firing temperature, thereby the piezoelectric materials having superior electric characteristics are manufactured.

摘要翻译： 制造具有微观结构的烧结体，其具有粒径小于5μm的微细晶粒，粒径为5μm以上且小于15μm的中间粒子，以及粒径为15μm以上且100μm以下的粗粒 以下能够获得高电特性。 将包含金属元素的化合物混合，使元素的比例为由（Li，Na，K）（Nb，Ta）O 3表示的组成，将混合物煅烧并粉碎以获得煅烧/粉碎的粉末。 将该粉末在恒温保持法中烧结，其中在加热过程中将温度恒定地保持在800-900℃的预定温度下一段预定的时间，然后通过升高温度进一步烧结粉末 烧成温度，由此制造具有优异的电特性的压电材料。

公开(公告)号：US08541102B2

公开(公告)日：2013-09-24

申请号：US12495830

申请日：2009-07-01

申请人： Kazuyuki Kaigawa ,  Ritsu Tanaka ,  Hirofumi Yamaguchi

发明人： Kazuyuki Kaigawa ,  Ritsu Tanaka ,  Hirofumi Yamaguchi

IPC分类号： B32B5/16 ,  H01L41/18

CPC分类号： H01L41/1873 ,  C01G35/006 ,  C01P2004/03 ,  C01P2006/10 ,  C01P2006/40 ,  C04B35/495 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3241 ,  C04B2235/3251 ,  C04B2235/3267 ,  C04B2235/3272 ,  C04B2235/3275 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/3284 ,  C04B2235/3298 ,  C04B2235/449 ,  C04B2235/5445 ,  C04B2235/656 ,  C04B2235/6562 ,  C04B2235/6565 ,  C04B2235/661 ,  C04B2235/765 ,  C04B2235/768 ,  C04B2235/77 ,  C04B2235/783 ,  C04B2235/786 ,  C04B2235/79 ,  H01L41/43

摘要： Piezoelectric materials having improved electrical properties, and manufacturing methods of the same, are provided. In (Li, Na, K, Bi)(Nb, Ta)O3 based piezoelectric materials, the surface microstructures of sintered bodies include microscopic grains having grain diameters of less than 5 μm, intermediate grains having grain diameters of 5 μm or more and less than 15 μm, and coarse grains having grain diameters of 15 μm or more and 100 μm or less.

摘要翻译： 提供具有改善的电性能的压电材料及其制造方法。 在（Li，Na，K，Bi）（Nb，Ta）O 3基压电材料中，烧结体的表面微观结构包括粒径小于5μm的微晶粒，粒径为5μm以上的中间粒子 15μm以上的粗粒和15μm以上且100μm以下的粗粒。

公开(公告)号：US08282854B2

公开(公告)日：2012-10-09

申请号：US12343689

申请日：2008-12-24

申请人： Kazuyuki Kaigawa ,  Hirofumi Yamaguchi

发明人： Kazuyuki Kaigawa ,  Hirofumi Yamaguchi

IPC分类号： C09B35/00 ,  H01L41/16

CPC分类号： H01L41/1873 ,  C04B35/495 ,  C04B35/6262 ,  C04B35/62645 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3241 ,  C04B2235/3255 ,  C04B2235/3262 ,  C04B2235/3267 ,  C04B2235/3272 ,  C04B2235/3275 ,  C04B2235/3279 ,  C04B2235/3281 ,  C04B2235/3284 ,  C04B2235/3294 ,  C04B2235/5445 ,  C04B2235/761 ,  C04B2235/765 ,  C04B2235/77 ,  C04B2235/782 ,  C04B2235/786 ,  H01L41/43

摘要： A (Li, Na, K)(Nb, Ta, Sb)O3 based piezoelectric material is a sintered body having a surface microstructure that comprises microscopic grains having a grain diameter of less than 5 μm, intermediate grains having a grain diameter of 5 μm or more and less than 15 μm, and coarse grains having a grain diameter of 15 μm or more and 50 μm or less. The amount of coarse grains is 3% or more in a share of grains in terms of area. The piezoelectric material can be manufactured by mixing metal-containing compounds so as to give the above-mentioned formulation, calcining the mixture and then crushing the resultant to obtain a calcined/crushed powder, then keeping temperature constantly at a temperature within a range from 800 to 950° C. for a predetermined period of time in a constant temperature keeping process, and raising temperature to firing temperature for sintering.

摘要翻译： A（Li，Na，K）（Nb，Ta，Sb）O 3系压电材料是具有包含粒径小于5μm的微细晶粒的表面微结构的烧结体，粒径为5μm的中间晶粒 以上且小于15μm的粒子，以及粒径为15μm以上且50μm以下的粗晶粒。 在谷物的面积份额中，粗粮的量为3％以上。 可以通过混合含金属化合物来制造压电材料，以得到上述配方，煅烧混合物，然后粉碎所得物，得到煅烧/粉碎的粉末，然后将温度恒定在800℃以下的温度 在恒温保持工序中，将其升温至烧成温度950℃。

公开(公告)号：US08124047B2

公开(公告)日：2012-02-28

申请号：US11958636

申请日：2007-12-18

申请人： Kazuyuki Kaigawa ,  Shuichi Ozawa ,  Hirofumi Yamaguchi

发明人： Kazuyuki Kaigawa ,  Shuichi Ozawa ,  Hirofumi Yamaguchi

IPC分类号： C01G33/00 ,  C04B35/468

CPC分类号： C04B35/495 ,  C04B2235/3201 ,  C04B2235/3203 ,  C04B2235/3251 ,  H01L41/1873 ,  H01L41/43

摘要： A method for manufacturing (Li, Na, K)(Nb, Ta)O3 type piezoelectric material having an improved relative dielectric constant and an electric-field-induced strain is provided. The method is a process in which a formed body of powder particles constituted of a composition of (Li, Na, K)(Nb, Ta)O3 is fired to produce the (Li, Na, K)(Nb, Ta)O3 type piezoelectric material, and a constant temperature is kept in a range of 850 to 1000° C. for a constant time before heating to a firing temperature.

摘要翻译： 提供了具有改善的相对介电常数和电场诱导应变的（Li，Na，K）（Nb，Ta）O3型压电材料的制造方法。 该方法是将由（Li，Na，K）（Nb，Ta）O 3的组成构成的粉末粒子的成形体烧成以制造（Li，Na，K）（Nb，Ta）O 3型 压电材料，并将恒温恒定时间保持在850〜1000℃的范围内，再加热至烧成温度。