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    ORGANO-1-OXA-4-AZONIUM CYCLOHEXANE COMPOUNDS
    62.
    发明申请
    ORGANO-1-OXA-4-AZONIUM CYCLOHEXANE COMPOUNDS 审中-公开
    有机-1-氧代-4-氮杂环己烷化合物

    公开(公告)号：US20170044120A1

    公开(公告)日：2017-02-16

    申请号：US15334154

    申请日：2016-10-25

    申请人： UOP LLC

    发明人： Christopher P. Nicholas ,  Mark A. Miller ,  Melissa M. Galey ,  Benjamin D. Yuhas ,  Sesh Prabhakar

    IPC分类号： C07D295/037

    CPC分类号： C07D295/037 ,  C07D295/023 ,  C07D295/027

    摘要： Novel 1-oxa-4-azonium cyclohexane salts are described. These compounds can be used as structure directing agents, and they overcome many of the typical problems associated with OSDA synthesis and subsequent zeolite synthesis. Methods for synthesis of the 1-oxa-4-azonium cyclohexane salts from a variety of starting materials are also described. A substituted hydrocarbon is added to water to form a mixture, and a 1-oxa-4-azacyclohexane derivative is then added. The reaction mixture stirred until a solution containing the 1-oxa-4-azonium cyclohexane salt is obtained.

    摘要翻译： 描述了新的1-氧杂-4-氮鎓环己烷盐。 这些化合物可以用作结构导向剂，并且它们克服了与OSDA合成和随后的沸石合成相关的许多典型问题。 还描述了用于从各种原料合成1-氧杂-4-氮鎓环己烷盐的方法。 将取代的烃加入到水中以形成混合物，然后加入1-氧杂-4-氮杂环己烷衍生物。 将反应混合物搅拌直到获得含有1-氧杂-4-氮鎓环己烷盐的溶液。

    ALUMINOPHOSPHATE MOLECULAR SIEVES USING AN ORGANO-1-OXA-4-AZONIUMCYCLOHEXANE COMPOUND
    63.
    发明申请
    ALUMINOPHOSPHATE MOLECULAR SIEVES USING AN ORGANO-1-OXA-4-AZONIUMCYCLOHEXANE COMPOUND 有权
    使用有机基-1-氧代-4-亚氨基半乳糖苷化合物的二磷酸分子筛

    公开(公告)号：US20160159656A1

    公开(公告)日：2016-06-09

    申请号：US14561121

    申请日：2014-12-04

    申请人： UOP LLC

    发明人： Benjamin D. Yuhas ,  Christopher P. Nicholas ,  Mark A. Miller ,  Melissa M. Galey

    IPC分类号： C01B39/54 ,  B01J29/85 ,  B01J37/10 ,  B01J37/00

    CPC分类号： C01B39/54 ,  B01J29/83 ,  B01J29/84 ,  B01J29/85 ,  B01J37/0018 ,  B01J37/10 ,  C01B37/08

    摘要： A method for synthesizing an aluminophosphate based molecular sieve is described. The method may include the steps of: (a) preparing an aqueous mixture comprising water, a substituted hydrocarbon, and a 1-oxa-4-azacyclohexane derivative; (b) reacting the aqueous mixture; (c) obtaining a solution comprising an organo-1-oxa-4-azoniumcyclohexane compound; (d) forming a reaction mixture comprising reactive sources of Al, and P, and the solution; and (e) heating the reaction mixture to form the molecular sieve.

    摘要翻译： 描述了一种用于合成基于磷酸铝的分子筛的方法。 该方法可以包括以下步骤：（a）制备含水，取代的烃和1-氧杂-4-氮杂环己烷衍生物的含水混合物; （b）使含水混合物反应; （c）得到包含有机-1-氧杂-4-氮鎓环己烷化合物的溶液; （d）形成包含Al和P的反应源和所述溶液的反应混合物; 和（e）加热反应混合物以形成分子筛。

    SYNTHESIS OF ZEOLITES USING AN ORGANOAMMONIUM COMPOUND
    64.
    发明申请
    SYNTHESIS OF ZEOLITES USING AN ORGANOAMMONIUM COMPOUND 审中-公开
    使用有机金属化合物合成ZOOLITE

    公开(公告)号：US20150158020A1

    公开(公告)日：2015-06-11

    申请号：US14552654

    申请日：2014-11-25

    申请人： UOP LLC

    发明人： Christopher P. Nicholas ,  Mark A. Miller

    IPC分类号： B01J29/80 ,  C07D211/06 ,  C07D295/037 ,  C07D471/10 ,  B01J29/70 ,  C07D207/04

    CPC分类号： C07D211/06 ,  B01J29/70 ,  B01J35/002 ,  C01B39/48 ,  C07D207/04 ,  C07D295/037 ,  C07D471/10

    摘要： A method for synthesizing a zeolite includes the steps of: (a) preparing an aqueous mixture comprising water, a substituted hydrocarbon and an amine; (b) reacting the aqueous mixture; (c) obtaining a solution comprising an organoammonium product; (d) forming a reaction mixture including reactive sources of M, Al, Si, optionally seeds of a layered material L, and the solution, wherein M is a metal; and (e) heating the reaction mixture to form the zeolite. The substituted hydrocarbon can be an α,ω-dihalogen substituted alkane, and the amine is preferably essentially incapable of undergoing pyramidal inversion.

    摘要翻译： 合成沸石的方法包括以下步骤：（a）制备含水，取代的烃和胺的含水混合物; （b）使含水混合物反应; （c）获得包含有机铵产物的溶液; （d）形成包含M，Al，Si的反应性源的反应混合物，任选的层状材料L的种子和溶液，其中M是金属; 和（e）加热反应混合物以形成沸石。 取代的烃可以是α，ω-二卤素取代的烷烃，并且胺优选基本上不能经历锥体反转。

    Conversion of methane to aromatic compounds using UZM-39 aluminosilicate zeolite
    67.
    发明授权
    Conversion of methane to aromatic compounds using UZM-39 aluminosilicate zeolite 有权
    使用UZM-39铝硅酸盐沸石将甲烷转化为芳族化合物

    公开(公告)号：US08907151B2

    公开(公告)日：2014-12-09

    申请号：US14102993

    申请日：2013-12-11

    申请人： UOP LLC

    发明人： Timur V. Voskoboynikov ,  Christopher P. Nicholas ,  Mark A. Miller ,  Lisa M. King ,  Vincent G. Mezera

    IPC分类号： C07C2/76 ,  B01J29/78

    CPC分类号： B01J29/78 ,  B01J29/70 ,  B01J29/7049 ,  B01J29/72 ,  B01J29/90 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/108 ,  B01J2229/186 ,  C07C2/76 ,  C07C2529/70 ,  C07C2529/78 ,  Y02P20/584 ,  C07C15/02

    摘要： A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and shown to be effective catalysts in processes for converting at least one aliphatic hydrocarbon having from 1 to about 4 carbon atoms in a feedstream to provide at least one aromatic hydrocarbon. These zeolites are represented by the empirical formula. NanMmk+TtAl1-xExSiyOz where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, T is the organic structure directing agent or agents and E is a framework element such as gallium. The process involves contacting a low carbon number aliphatic hydrocarbon with the coherently grown composite of TUN and IMF zeotypes to produce at least an aromatic.

    摘要翻译： 已经合成了一系列TUN和IMF染色体型的相干生长的复合材料，并且显示出在进料流中转化至少一种具有1至约4个碳原子的脂族烃以提供至少一种芳烃的方法中是有效的催化剂。 这些沸石由经验公式表示。 NanMmk + TtAl1-xExSiyOz其中M表示锌或金属或来自组1，组2，组3或周期表的镧系元素的金属，T是有机结构导向剂或试剂，E是骨架元素，例如镓 。 该方法包括使低碳数脂族烃与TUN和IMF zeotype的相干生长的复合物接触以产生至少一种芳族化合物。

    CONVERSION OF METHANE TO AROMATIC COMPOUNDS USING UZM-39 ALUMINOSILICATE ZEOLITE
    69.
    发明申请
    CONVERSION OF METHANE TO AROMATIC COMPOUNDS USING UZM-39 ALUMINOSILICATE ZEOLITE 有权
    使用UZM-39铝酸钠沸石将甲烷转化成芳族化合物

    公开(公告)号：US20140163282A1

    公开(公告)日：2014-06-12

    申请号：US14102993

    申请日：2013-12-11

    申请人： UOP LLC

    发明人： Timur V. Voskoboynikov ,  Christopher P. Nicholas ,  Mark A. Miller ,  Lisa M. King ,  Vincent G. Mezera

    IPC分类号： C07C2/76

    CPC分类号： B01J29/78 ,  B01J29/70 ,  B01J29/7049 ,  B01J29/72 ,  B01J29/90 ,  B01J35/002 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/108 ,  B01J2229/186 ,  C07C2/76 ,  C07C2529/70 ,  C07C2529/78 ,  Y02P20/584 ,  C07C15/02

    摘要： A new family of coherently grown composites of TUN and IMF zeotypes has been synthesized and shown to be effective catalysts in processes for converting at least one aliphatic hydrocarbon having from 1 to about 4 carbon atoms in a feedstream to provide at least one aromatic hydrocarbon. These zeolites are represented by the empirical formula. NanMmk+TtAl1-xExSiyOz where M represents zinc or a metal or metals from Group 1, Group 2, Group 3 or the lanthanide series of the periodic table, T is the organic structure directing agent or agents and E is a framework element such as gallium. The process involves contacting a low carbon number aliphatic hydrocarbon with the coherently grown composite of TUN and IMF zeotypes to produce at least an aromatic.

    摘要翻译： 已经合成了一系列TUN和IMF染色体型的相干生长的复合材料，并且显示出在进料流中转化至少一种具有1至约4个碳原子的脂族烃以提供至少一种芳烃的方法中是有效的催化剂。 这些沸石由经验公式表示。 NanMmk + TtAl1-xExSiyOz其中M表示锌或金属或来自组1，组2，组3或周期表的镧系元素的金属，T是有机结构导向剂或试剂，E是骨架元素，例如镓 。 该方法包括使低碳数脂族烃与TUN和IMF zeotype的相干生长的复合物接触以产生至少一种芳族化合物。