摘要:
Unsaturated polymers containing nitrile groups can be hydrogenated with the preservation of the nitrile group in a homogeneous phase with a catalyst of the formula:RuX[(L.sub.1) (L.sub.2).sub.n ]in whichX represents hydrogen, halogen or SnCl.sub.3,L.sub.1 represents optionally substituted indenyl,L.sub.2 represents a phosphane, bisphosphane or arsane and n signifies 1 or 2,if a low-molecular ketone is used as a solvent.
摘要:
Disclosed is a casting resin of reduced viscosity based on methacrylic acid esters with a high content of aluminum hydroxide as filler containing a mixture of at least one organosilicon compound with a functional group, at least one silicic acid ester, and at least one organic metallic acid compound of metals of Groups IVB and/or VB of the Periodic Table of the Elements. The functional group of the organosilicon compound is ethylenically unsaturated and bound to the silicon atom either directly or by alkylene groups. The casting resins of the invention have improved working qualities. Plastic objects and moldings manufactured from these resins have decidedly improved use properties.
摘要:
A hair-conditioning resin composition prepared by modifying a copolymer resin with a zwitterionizing agent is described, said copolymer resin being prepared by copolymerizing in a hydrophilic solvent a polymerizable mixture containing(A) 65-90% by weight of a polymerizable vinyl monomer having the general formula (I) ##STR1## wherein R.sub.1 represents a hydrogen atom or a methyl group, R.sub.2 represents an alkylene group having from 1 to 4 carbon atoms, R.sub.3 and R.sub.4 each represents an alkyl group having from 1 to 4 carbon atoms, and A represents an oxygen atom or an NH group,(B) 10-35% by weight of polymerizable vinyl monomers having the general formula (II) ##STR2## wherein R.sub.5 represents a hydrogen atom or a methyl group, and R.sub.6 represents a saturated or unsaturated alkyl group having from 12 to 24 carbon atoms, and(C) 0-25% by weight of other polymerizable vinyl monomers, said zwitterionizing agent having the general formula (III)XR.sub.7 COOB (III) wherein R.sub.7 represents an alkylene group having from 1 to 4 carbon atoms, X represents a bromine, chlorine or iodine atom, and B represents an alkali metal ion, an ammonium salt or an amine salt.The hair-conditioning resin compositions of the present invention have satisfactory cosmetic properties such as voluminousness, combing-out, softening, moderately moistening, and wavesetting.
摘要:
Normally tacky, pressure sensitive adhesive compositions comprise one or more polymers containing pendant functional groups attached to a polymer backbone and having the formula: ##STR1## in which R.sub.1 is a divalent organic radical at least 3 atoms in length, and X is organoacyl or cyano, and wherein said polymer is selected from the group consisting of(1) conjugated diolefin polymers comprising at least about 30 weight percent of one or more conjugated diene monomers having 4 to about 8 carbon atoms and 0 to about 70 weight percent of one or more alkenyl-substituted monoaromatic monomers,(2) olefin ester interpolymers comprising at least about 1 weight percent of a monoolefin monomer having up to about 4 carbon atoms and at least about 40 weight percent of an alkenyl or alkenol ester of a saturated carboxylic acid,(3) olefinically unsaturated carboxylic acid ester polymers comprising at least about 40 weight percent polymerized olefinically unsaturated carboxylic acid ester monomers,(4) alkenyl ether polymers comprising at least about 30 weight percent alkenyl ether monomer units, and(5) combinations thereof.Such polymers have improved cohesive strength with little or no detriment to adhesive tack or adhesion, and these improvements are realized without the necessity of incorporating crosslinking monomers such as N-methylolamides or other crosslinking agents. Pressure sensitive adhesive, water-based emulsions, hot melts and solutions containing such polymers and adhesive articles having at least a portion of one surface thereof coated with such adhesives are also provided.
摘要:
An information recording disk has a transparent support substrate and a transfer layer formed thereon using a stamper. The transfer layer comprises a precursor having as major components a cycloacetal compound having at least two polymerizable unsaturated groups, a compound having at least two mercapto groups, and an acrylic ester and/or methacrylic ester.
摘要:
An aqueous dispersion of a copolymer offrom about 50 to 60% by weight ethyl acrylatefrom about 30 to 40% by weight methacrylic acidfrom about 5 to 15% by weight acrylic acid andfrom about 0.02 to 0.04% by weight of a polyethylenically copolymerizable monomer, for example ethylene glycol dimethacrylate. The dispersion is suitable as an additive for aqueous, mildly acidic preparations of hydrogen peroxide to impart an increased viscosity to them after neutralization. The hydrogen peroxide preparations in question are particularly suitable for use as a developer composition for oxidative hair dyes and hair bleaches.
摘要:
An aqueous resin emulsion is disclosed. The emulsion is obtained by emulsion copolymerizing a monomer mixture comprising (a) an acrylic acid fluoroalkyl ester derivative, (b) an acrylic acid derivative, and (c) a polyfunctional monomer for internal cross-linking, in an aqueous medium. The emulsion shows excellent polymerization stability in emulsion copolymerization for the preparation thereof and excellent dispersion stability in an aqueous medium.
摘要:
New, highly effective cationic sizing agents for paper have been provided. They can be obtained by a method in which a water-soluble cationic chemically pure terpolymer compound consisting of(a) 7-40% by weight of N,N-dimethylaminoethyl acrylate and/or methacrylate,(b) 40-80% by weight of styrene and(c) 4-40% by weight of acrylonitrileis dissolved in an aqueous medium, the sum of the components (a) to (c) always being 100% by weight and at least 10% of the N,N-dimethylamino groups of the terpolymer being quaternized and the remainder being protonated, and, in the presence of 10 to 70% by weight, relative to the monomer mixture below, of this emulsifier,(d) 0 to 90% by weight of acrylonitrile and/or methacrylonitrile,(e) 5 to 95% by weight of styrene and(f) 5 to 95% by weight of acrylates and/or methacrylates having 1 to 12 C atoms in the alcohol radical,the sum of the components (d) to (f) always being 100% by weight, are emulsified, and the emulsion thus obtained is subjected to free radical-initiated emulsion polymerization at temperatures from 20.degree. to 150.degree. C.
摘要:
A heat developable light-sensitive material is described, comprising a polymer containing as a constituent a repeating unit represented by formula (I) ##STR1## wherein R.sub.1 represents a hydrogen atom or a substituted or unsubstituted alkyl group having from 1 to 6 carbon atoms; L represents a divalent connecting group having from 1 to 20 carbon atoms; M represents a cation and x represents a number which is the same as the charge number of the cation represented by M.The polymer containing the repeating unit represented by formula (I) is a base precursor which is stable at normal temperature, but rapidly decomposes to release a base by heating; therefore, the heat developable light-sensitive material containing the base precursor has excellent preservability and provides images having good image quality, i.e., low fog density and high image density, upon a short period of developing time.
摘要:
Insoluble polymer powders which are only slightly swellable and are based on N-vinylpyrrolidone are prepared by polymerization of N-vinylpyrrolidone or a mixture of this with copolymerizable monomers and from 0.1 to 10% by weight, based on the total amount of monomers, of a crosslinking agent in a powder bed in the presence of a heat-transfer medium, which is inert to the reactants, and in the absence of oxygen and polymerization initiators, at from 90.degree. to 220.degree. C., while maintaining the powder state, circulating the reaction mass and evaporating the heat-transfer medium from the polymerization zone. The resulting insoluble polymers which are only slightly swellable are used as adsorbents or formulation assistants for fertilizers and crop protection agents.