Apparatus for making ester
    24.
    发明授权
    Apparatus for making ester 失效
    用于制造酯的装置

    公开(公告)号:US5128107A

    公开(公告)日:1992-07-07

    申请号:US628985

    申请日:1990-12-17

    CPC classification number: C07C67/08 B01D3/32 C04B35/10 C07C69/80

    Abstract: An apparatus for producing ester includes an esterification device, a neutralization device connected to the esterification device, a distillation device connected to the neutralization device, a container connected to the distillation device for storing ester distilled by the distillation device, a filter casing connected to the container, and a ceramic filter set in the filter casing for filtering the distilled ester in a cross flow manner.

    Abstract translation: 用于生产酯的装置包括酯化装置,与酯化装置连接的中和装置,连接到中和装置的蒸馏装置,连接到用于储存由蒸馏装置蒸馏的酯的蒸馏装置的容器,连接到 容器和设置在过滤器壳体中的陶瓷过滤器,用于以交叉流方式过滤蒸馏的酯。

    Mono-iodopropargyl esters of dicarboxylic anhydrides and their use as
antimicrobial agents
    27.
    发明授权
    Mono-iodopropargyl esters of dicarboxylic anhydrides and their use as antimicrobial agents 失效
    二甲氧基苯甲酸的单一碘酸酯及其作为抗微生物剂的用途

    公开(公告)号:US5073570A

    公开(公告)日:1991-12-17

    申请号:US311523

    申请日:1989-02-16

    Abstract: The new compositions of matter of the present invention comprise compounds having one of the following formulas: ##STR1## wherein: R is hydrogen or methyl;n is 1 to 16;R.sub.1 and R.sub.2 are defined as R.sub.3 and R.sub.4 below or are joined to form a cycloalkyl, cycloalkenyl, aromatic or a heterocyclic ring containing an oxygen, nitrogen or sulfur atom or an alkoxy, amino, carboxyl, halo, hydroxyl, keto or a thiocarboxyl substituted derivative thereof;R.sub.3 and R.sub.4 are independently selected from (A) hydrogen, alkyl, cycloalkyo, alkenyl, cycloalkenyl, aryl, a heterocyclic ring containing an oxygen, nitrogen or sulfur atom, alkoxy, amino, carboxyl, halo, hydroxyl, keto or a thiocarboxyl and (B) substituted derivatives of the alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl and the heterocyclic ring wherein the substitutions are alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl, alkoxy, amino, carboxyl, halo, hydroxyl, keto or a thiocarboxyl;W may be a single bond, oxygen, NR.sub.5, or (CR.sub.6 R.sub.7).sub.m, wherein R.sub.5 is hydrogen, alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl or a heterocyclic ring containing an oxygen, nitrogen or sulfur atom or a substituted derivative of alkyl, cycloalkyl, alkenyl, cycloalkenyl or aryl groups wherein the substitutions are alkyl, cycloalkyl, alkenyl, cycloalkenyl, aryl, alkoxy, amino, carboxyl, halo, hydroxyl, keto or a thiocarboxyl where R.sub.6 and R.sub.7 are defined as R.sub.3 and R.sub.4 above and m is an integer from 1 to 12; andX is hydrogen or a salt-forming cation.Examples of such compositions are mono-iodopropargyl succinates, maleates, itaconates, diglycolates and phthalates. Other compounds include the mono-iodopropargyl esters of anhydrides such as dimethylglutaric anhydride and ethylenediamine tetraacetic dianhydride. They are used in microbiocidal formulations and effective microbiocides.

    Process for increasing the direct esterification reaction rate of a
diacid with a glycol
    29.
    发明授权
    Process for increasing the direct esterification reaction rate of a diacid with a glycol 失效
    增加二元酸与二元醇直接酯化反应速率的方法

    公开(公告)号:US5015759A

    公开(公告)日:1991-05-14

    申请号:US450911

    申请日:1989-12-08

    Applicant: David J. Lowe

    Inventor: David J. Lowe

    CPC classification number: C08G63/85 C08G63/78

    Abstract: A process for increasing the direct esterification reaction rate between a diacid and 1,4-butanediol and for directly esterifying greater than 95% of the acid ends of the diacid by mixing in any order the diacid, the 1,4-butanediol and a catalyst compound selected from organo-titanium, organo-tin, and organo-zirconium compounds, to form a reaction mixture wherein the ratio of diol:diacid is at least 2:1 and then reacting the reaction mixture at an average temperature ranging between 190.degree. C. to 200.degree. C. for a period of time no longer than sixty minutes. The same process may be followed substituting ethylene glycol for 1,4-butanediol, provided the catalyst compound is added neat, further provided that the average reaction temperature ranges from 190.degree. C. to 200.degree. C., and also provided that the reaction mixture be reacted for a period of time no longer than seventy minutes. The product resulting from this process may be polycondensed or further treated to form a high molecular weight polymer.

    Polyols from phthalic compounds
    30.
    发明授权
    Polyols from phthalic compounds 失效
    来自邻苯二甲酸酯的多元醇

    公开(公告)号:US4902816A

    公开(公告)日:1990-02-20

    申请号:US173788

    申请日:1988-03-28

    CPC classification number: C07C67/03 C07C69/80

    Abstract: Polyols containing polyether and polyester moieties, based on phthalic acid are described. A phthalic acid derivative is reacted with a polyether polyol to give the novel polyols which are useful not only in polyisocyanurate foams, but also polyurethane foams as well. The phthalic acid derivative may be phthalic acid, phthalic anhydride and an ester of phthalic acid, for example. The polyester polyol is made from an initiator selected from the group consisting of alkanolamines, alkyleneamines, arylamines, sucrose, glycerin, sorbitol, .alpha.-methylglucoside, .beta.-methylglucoside, and mixtures thereof. The polyester polyol may be made by alkoxylating the initiators.

    Abstract translation: 描述了含有基于邻苯二甲酸的聚醚和聚酯部分的多元醇。 使邻苯二甲酸衍生物与聚醚多元醇反应,得到不仅可用于聚异氰脲酸酯泡沫,而且可用于聚氨酯泡沫的新型多元醇。 邻苯二甲酸衍生物可以是例如邻苯二甲酸,邻苯二甲酸酐和邻苯二甲酸的酯。 聚酯多元醇由选自链烷醇胺,亚烷基胺,芳基胺,蔗糖,甘油,山梨糖醇,α-甲基葡糖苷,β-甲基葡糖苷及其混合物的引发剂制成。 聚酯多元醇可以通过使引发剂烷氧基化来制备。

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