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公开(公告)号：US10144006B2
公开(公告)日：2018-12-04
申请号：US14802631
申请日：2015-07-17
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jane C. Cheng , Xiaobo Zheng , Hari Nair
IPC: C07C5/27 , B01J29/04 , B01J35/02 , B01J19/00 , B01J8/04 , B01J23/36 , B01J29/40 , B01J29/80 , B01J37/00 , B01J37/02
Abstract: A catalyst system is disclosed for producing para-xylene from a C8 hydrocarbon mixture comprising ethylbenzene and at least one xylene isomer other than para-xylene. The catalyst system comprises a first catalyst bed and a second catalyst bed. The first catalyst bed comprises a first zeolite and a rhenium hydrogenation component. The first zeolite has a constraint index from 1 to 12, an average crystal size from 0.1 to 1 micron and has been selectivated to have an ortho-xylene sorption time of greater than 1200 minutes based on its capacity to sorb 30% of the equilibrium capacity of ortho-xylene at 120° C. and an ortho-xylene partial pressure of 4.5±0.8 mm of mercury. The second catalyst bed comprises a second zeolite and a rhenium hydrogenation component. The second zeolite has a constraint index ranging from 1 to 12 and an average crystal size of less than 0.1 micron.
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公开(公告)号：US09856187B2
公开(公告)日：2018-01-02
申请号：US15288452
申请日：2016-10-07
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Larry L. Iaccino , Jeremy W. Bedard , Wenyih F. Lai , Christopher M. Evans , Jane C. Cheng
CPC classification number: C07C5/373 , B01J29/44 , B01J29/46 , B01J29/62 , C07C5/42 , C07C2101/10 , C07C2529/44 , C07C2529/46 , C07C2529/62 , C07C2601/06 , C07C2601/10 , C07C13/10 , C07C13/12 , C07C13/15
Abstract: Disclosed is a process for the conversion of acyclic C5 feedstock to a product comprising cyclic C5 compounds, such as for example, cyclopentadiene, and catalyst compositions for use in such process. The process comprising the steps of contacting said feedstock and, optionally, hydrogen under acyclic C5 conversion conditions in the presence of a catalyst composition to form said product. The catalyst composition comprising a microporous crystalline ferrosilicate, a Group 10 metal, and, optionally, a Group 11 metal, in combination with an optional Group 1 alkali metal and/or an optional Group 2 alkaline earth metal.
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公开(公告)号：US20170121253A1
公开(公告)日：2017-05-04
申请号：US15288447
申请日：2016-10-07
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Larry L. Iaccino , Jeremy W. Bedard , Wenyih F. Lai , Robert T. Carr , Jane C. Cheng
CPC classification number: C07C5/373 , B01J29/44 , B01J29/46 , B01J29/62 , C07C5/42 , C07C2101/10 , C07C2529/44 , C07C2529/46 , C07C2529/62 , C07C2601/06 , C07C2601/10 , C07C13/10 , C07C13/12 , C07C13/15
Abstract: Disclosed is a process for the conversion of acyclic C5 feedstock to a product comprising cyclic C5 compounds, such as, for example, cyclopentadiene, and catalyst compositions for use in such process. The process comprises the steps of contacting said feedstock and, optionally, hydrogen under acyclic C5 conversion conditions in the presence of a catalyst composition to form said product. The catalyst composition comprising a microporous crystalline aluminosilicate having a constraint index in the range of 3 to 12, a Group 10 metal, and, optionally, a Group 11 metal, in combination with a Group 1 alkali metal and/or a Group 2 alkaline earth metal.
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公开(公告)号：US09018121B2
公开(公告)日：2015-04-28
申请号：US13747905
申请日：2013-01-23
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： April D. Ross , Jane C. Cheng
IPC: B01J29/06 , B01J8/04 , B01J16/00 , C07C5/27 , B01J29/40 , B01J29/44 , B01J29/46 , B01J37/00 , B01J23/42 , B01J23/50 , B01J23/60 , B01J23/62 , B01J23/89
CPC classification number: C07C5/2708 , B01J16/005 , B01J23/42 , B01J23/50 , B01J23/60 , B01J23/62 , B01J23/626 , B01J23/628 , B01J23/8926 , B01J29/405 , B01J29/44 , B01J29/46 , B01J37/0018 , B01J2229/186 , B01J2229/36 , B01J2229/42 , C07C5/222 , C07C5/2556 , C07C5/2737 , C07C5/2754 , C07C15/08 , C07C2529/44 , Y02P20/52
Abstract: The invention is directed to a bimetallic catalyst system adapted for the manufacture of xylenes, a process for making said catalyst system, and to the process of manufacture of xylenes using said catalyst system, providing, in embodiments, improved selectivity by at least one of higher ethylene saturation and low xylene loss, decreased susceptibility to poisoning from feedstream impurities, and ability to operate at less severe conditions.
Abstract translation: 本发明涉及适用于制造二甲苯的双金属催化剂体系，制备所述催化剂体系的方法，以及使用所述催化剂体系制备二甲苯的方法，在实施方案中，提供了至少一种较高的选择性 乙烯饱和度低，二甲苯损失低，对原料杂质中毒的易感性降低，在恶劣条件下操作能力差。
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公开(公告)号：US20150025283A1
公开(公告)日：2015-01-22
申请号：US14311393
申请日：2014-06-23
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Jane C. Cheng , Christopher G. Oliveri
IPC: C07C6/06
CPC classification number: C07C4/18 , B01J8/0453 , B01J8/0457 , B01J23/02 , B01J23/14 , B01J23/50 , B01J23/72 , B01J29/44 , B01J37/0201 , B01J38/06 , B01J2208/00522 , B01J2208/025 , B01J2229/36 , C07C6/126 , C07C7/14858 , C07C2529/44 , C07C2529/46 , C07C2529/70 , Y02P20/52 , Y02P20/584 , C07C15/08 , C07C15/02
Abstract: The invention is directed to a multimetallic catalyst and its use in a reactor system in a C9+ aromatics conversion process in order to reduce the saturation of aromatic species, reduce the production of C6+ non-aromatics byproducts, and achieve higher benzene purity. The multimetallic catalyst exhibits improved selectivity towards aromatic hydrocarbons in comparison to a traditional Pt/ZSM-5 catalyst and comprises ZSM-5, a Group 6-10 metal, and an additional metal not in Group 6-10. The C9+ aromatics conversion reactor system comprises a top bed containing the multimetallic catalyst for dealkylation of ethyl and propyl side chains, a second bed containing a catalyst comprising a hydrogenation component for transalkylation, and an optional third bed containing a catalyst without a hydrogenation component to convert non-aromatic hydrocarbons to gas products.
Abstract translation: 本发明涉及一种多金属催化剂及其在C9 +芳族化合物转化方法中的反应器系统中的用途，以减少芳族物质的饱和度，减少C6 +非芳族化合物副产物的产生，并获得更高的苯纯度。 与传统的Pt / ZSM-5催化剂相比，多金属催化剂对芳族烃的选择性提高，并且包含ZSM-5，6-10族金属和不在6-10族中的另外的金属。 C9 +芳族化合物转化反应器系统包括含有用于乙基和丙基侧链脱烷基化的多金属催化剂的顶层，含有包含用于烷基转移的氢化组分的催化剂的第二床和含有不具有氢化组分以转化的催化剂的任选的第三床 非芳香烃气体产品。
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Patent Agency Ranking
公开(公告)号：US10118165B2
公开(公告)日：2018-11-06
申请号：US14870848
申请日：2015-09-30
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Wenyih F. Lai , Christine N. Elia , Jane C. Cheng , Shifang L. Luo , Hari Nair , Joshua I. Cutler , Doron Levin
IPC: C07C6/12 , C07C4/18 , B01J29/80 , B01J8/04 , B01J29/22 , B01J29/24 , B01J29/44 , B01J29/46 , B01J29/67 , B01J29/68 , B01J29/74 , B01J29/76 , B01J35/00 , B01J35/02 , B01J35/10 , B01J37/18 , C01B39/26
Abstract: Disclosed is a catalyst composition and its use in a process for the conversion of a feedstock containing C8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst composition comprises a first zeolite having a constraint index of 3 to 12, a second zeolite comprising a mordenite zeolite synthesized from TEA or MTEA, at least one first metal of Group 10 of the IUPAC Periodic Table, and at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said mordenite zeolite has a mesopore surface area of greater than 30 m2/g and said mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.
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公开(公告)号：US10058853B2
公开(公告)日：2018-08-28
申请号：US15004623
申请日：2016-01-22
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Wenyih F. Lai , Christine N. Elia , Jane C. Cheng , Shifang L. Luo , Hari Nair , Joshua I. Cutler , Doron Levin , Chuansheng Bai
IPC: C07C6/12 , C07C4/18 , B01J29/80 , B01J35/10 , B01J29/22 , B01J29/24 , B01J29/44 , B01J29/46 , B01J8/04 , B01J37/18 , B01J29/67 , B01J29/68 , B01J29/74 , B01J29/76 , B01J35/00 , B01J35/02 , C01B39/26
CPC classification number: B01J29/80 , B01J8/04 , B01J29/22 , B01J29/24 , B01J29/44 , B01J29/46 , B01J29/67 , B01J29/68 , B01J29/74 , B01J29/7446 , B01J29/7453 , B01J29/7461 , B01J29/7476 , B01J29/7484 , B01J29/7492 , B01J29/76 , B01J29/7646 , B01J29/7653 , B01J29/7661 , B01J29/7676 , B01J29/7684 , B01J29/7692 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1033 , B01J35/1052 , B01J35/108 , B01J37/0201 , B01J37/18 , B01J37/30 , B01J2208/027 , B01J2229/186 , B01J2229/42 , C01B39/265 , C07C4/18 , C07C6/126 , C07C15/06 , C07C2521/04 , C07C2529/18 , C07C2529/22 , C07C2529/24 , C07C2529/26 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/80 , C07C2529/87 , C10G45/62 , C10G45/64 , C10G45/70 , C10G2300/1096 , C10G2300/70 , C10G2400/30 , Y02P20/52
Abstract: Disclosed is a catalyst composition and its use in a process for the conversion of a feedstock containing C8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst composition comprises a mordenite zeolite synthesized from TEA or MTEA, optionally at least one first metal of Group 10 of the IUPAC Periodic Table, and optionally at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said mordenite zeolite has a mesopore surface area of greater than 30 m2/g and said mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.
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公开(公告)号：US10011539B2
公开(公告)日：2018-07-03
申请号：US15288447
申请日：2016-10-07
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Larry L. Iaccino , Jeremy W. Bedard , Wenyih F. Lai , Robert T. Carr , Jane C. Cheng
CPC classification number: C07C5/373 , B01J29/44 , B01J29/46 , B01J29/62 , C07C5/42 , C07C2529/44 , C07C2529/46 , C07C2529/62 , C07C2601/06 , C07C2601/10 , C07C13/10 , C07C13/12 , C07C13/15
Abstract: Disclosed is a process for the conversion of acyclic C5 feedstock to a product comprising cyclic C5 compounds, such as, for example, cyclopentadiene, and catalyst compositions for use in such process. The process comprises the steps of contacting said feedstock and, optionally, hydrogen under acyclic C5 conversion conditions in the presence of a catalyst composition to form said product. The catalyst composition comprising a microporous crystalline aluminosilicate having a constraint index in the range of 3 to 12, a Group 10 metal, and, optionally, a Group 11 metal, in combination with a Group 1 alkali metal and/or a Group 2 alkaline earth metal.
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19.发明申请公开(公告)号：US20160220987A1
公开(公告)日：2016-08-04
申请号：US14870848
申请日：2015-09-30
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Wenyih F. Lai , Christine N. Elia , Jane C. Cheng , Shifang L. Luo , Hari Nair , Joshua I. Cutler , Doron Levin
CPC classification number: B01J29/80 , B01J8/04 , B01J29/22 , B01J29/24 , B01J29/44 , B01J29/46 , B01J29/67 , B01J29/68 , B01J29/74 , B01J29/7446 , B01J29/7453 , B01J29/7461 , B01J29/7476 , B01J29/7484 , B01J29/7492 , B01J29/76 , B01J29/7646 , B01J29/7653 , B01J29/7661 , B01J29/7676 , B01J29/7684 , B01J29/7692 , B01J35/002 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1033 , B01J35/1052 , B01J35/108 , B01J37/0201 , B01J37/18 , B01J37/30 , B01J2208/027 , B01J2229/186 , B01J2229/42 , C01B39/265 , C07C4/18 , C07C6/126 , C07C15/06 , C07C2521/04 , C07C2529/18 , C07C2529/22 , C07C2529/24 , C07C2529/26 , C07C2529/40 , C07C2529/44 , C07C2529/46 , C07C2529/80 , C07C2529/87 , Y02P20/52
Abstract: Disclosed is a catalyst composition and its use in a process for the conversion of a feedstock containing C8+ aromatic hydrocarbons to produce light aromatic products, comprising benzene, toluene and xylene. The catalyst composition comprises a first zeolite having a constraint index of 3 to 12, a second zeolite comprising a mordenite zeolite synthesized from TEA or MTEA, at least one first metal of Group 10 of the IUPAC Periodic Table, and at least one second metal of Group 11 to 15 of the IUPAC Periodic Table, wherein said mordenite zeolite has a mesopore surface area of greater than 30 m2/g and said mordenite zeolite comprises agglomerates composed of primary crystallites, wherein said primary crystallites have an average primary crystal size as measured by TEM of less than 80 nm and an aspect ratio of less than 2.
Abstract translation: 公开了一种催化剂组合物及其在用于转化含有C8 +芳族烃的原料以产生轻芳香族产物（包括苯，甲苯和二甲苯）的方法中的用途。 所述催化剂组合物包括约束指数为3至12的第一沸石，包含由TEA或MTEA合成的丝光沸石的第二沸石，IUPAC元素周期表第10族的至少一种第一金属和至少一种第 IUPAC周期表第11至15组，其中所述丝光沸石具有大于30m 2 / g的中孔表面积，并且所述丝光沸石包括由初级微晶构成的附聚物，其中所述初级晶体具有平均初晶尺寸， TEM小于80nm，纵横比小于2。
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公开(公告)号：US09382171B2
公开(公告)日：2016-07-05
申请号：US14336312
申请日：2014-07-21
Applicant: ExxonMobil Chemical Patents Inc.
Inventor： Stuart L. Soled , Sabato Miseo , Joseph E. Baumgartner , Christine E. Kliewer , Jane C. Cheng
CPC classification number: C07C2/74 , B01J23/468 , B01J37/0203 , B01J37/08 , C07C5/00 , C07C5/31 , C07C13/28 , C07C2521/08 , C07C2531/08 , C07C2601/12 , Y02P20/52 , C07C9/00 , C07C11/02
Abstract: A process is described for producing a catalyst composition comprising an iridium component dispersed on a support. In the process, silica- o group to form an organic iridium complex on the support. The treated support is then heated in an oxidizing atmosphere at a temperature of about 325° C. to about 475° C. to partially decompose the organic metal complex on the support. The treated support is then heated in a reducing atmosphere at a temperature of about 350° C. to about 500° C. to convert the partially decomposed organic iridium complex into the desired iridium component.
Abstract translation: 描述了一种制备包含分散在载体上的铱组分的催化剂组合物的方法。 在该过程中，二氧化硅基团在载体上形成有机铱络合物。 然后将处理的载体在氧化气氛中在约325℃至约475℃的温度下加热以部分分解载体上的有机金属络合物。 然后将处理的载体在约350℃至约500℃的还原气氛中加热，以将部分分解的有机铱络合物转化为所需的铱组分。
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