Abstract:
Disclosed is a process for the conversion of acyclic C5 feedstock to a product comprising cyclic C5 compounds, including cyclopentadiene, and catalyst compositions for use in such process. The process comprises contacting the feedstock and, optionally, hydrogen under acyclic C5 conversion conditions in the presence of a catalyst composition to form said product. The catalyst composition comprises a microporous crystalline metallosilicate, a Group 10 metal or compound thereof, and a Group 11 metal or compound thereof.
Abstract:
Phosphoranimide-metal catalysts and their role in C—O bond hydrogenolysis and hydrodeoxygenation (HDO) are disclosed. The catalysts comprise of first row transition metals such as nickel, cobalt and iron. The catalysts have a metal to anionic phosphoranimide ratio of 1:1 and catalyze C—O bond hydrogenolyses of a range of oxygen-containing organic compounds under lower temperature and pressure conditions than those commonly used in industrial hydrodeoxygenation.
Abstract:
Process for the preparation of cyclopentane derivatives of the formula I in which R is a C1- to C10-alkyl group, which comprises reacting cyclohexanol or cyclohexene or mixtures of both compounds to give 1-methyl-1-cyclopentene (1st stage) and subsequently adding a C1- to C10-alkanol onto the double bond of the 1-methyl-1-cyclopentene (2nd stage).
Abstract:
Hydrogenation feedstock containing cyclopentadiene and dicyclopentadiene which is to be selectively hydrogenated to cyclopentene is vaporized at a temperature above that at which substantial formation of high boiling resin or resinlike residues occurs, prior to the introduction of the feedstock into the hydrogenation zone.
Abstract:
1,3-CYCLOPENTADIENE IS REMOVED FROM ISOPRENE AND/OR CYCLOPENTENE WHEN PRESENT IN AMOUNTS OF LESS THAN 2,000 PPM BY CONTACT WITH A BASIC ION-EXCHANGER WHICH HAS BEEN CONVERTED INTO THE HYDROXY FORM BY PRELIMINARY TREATMENT WITH A STRONG BASE.
Abstract:
A cyclopentene rich fraction, an isoprene rich fraction, and a diolefin (essentially 1,3-pentadiene and cyclopentadiene) rich fraction are recovered from the C5 cut obtained by petroleum cracking. First, said fractions are extracted in a liquid-liquid extraction with 1-oxo-1-methylphospholine. The extractant is then distilled to separate therefrom said fractions.
Abstract:
A TWO-STAGE HYDROGENATION AND SEPARATION PROCESS OF A CYCLOPENTADIENE SOURCE FOR THE MANUFACTURE OF A SUBSTANTIALLY DIOLEFIN FREE, HIGH PURITY CYCLOPENTENE SUITABLE FOR POLYMERIZING.