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28 条记录 (耗时 0.017 秒)

    Method for catalytic and selective oxidation of aromatic compounds
    11.
    发明授权
    Method for catalytic and selective oxidation of aromatic compounds 失效
    芳香族化合物的催化和选择性氧化方法

    公开(公告)号：US06365762B1

    公开(公告)日：2002-04-02

    申请号：US09403461

    申请日：2000-03-14

    申请人： Richard Walter Fischer ,  Joachim Haider ,  Wolfgang Anton Herrmann ,  Roland Kratzer

    发明人： Richard Walter Fischer ,  Joachim Haider ,  Wolfgang Anton Herrmann ,  Roland Kratzer

    IPC分类号： C07C5012

    CPC分类号： C07C41/26 ,  C07B33/00 ,  C07C37/60 ,  C07C46/04 ,  C07C50/10 ,  C07C39/07 ,  C07C43/23

    摘要： The invention relates to the use of compounds of the formula R1aRebOc.Ld  (I), in which and the total of a, b and c is such as to comply with the pentavalency or heptavalency of rhenium, with the proviso that c is not larger than 3×b, and in which R1 is absent or identical or different, and is an aliphatic hydrocarbon radical having 1 to 10 carbon atoms, an aromatic hydrocarbon radical having 6 to 10 carbon atoms or an arylalkyl radical having 7 to 9 carbon atoms, it being possible for the R1 radicals where appropriate to be substituted identically or differently, independently of one another, as catalysts for oxidizing electron-rich aromatic compounds and their derivatives, the catalysts being employed in a peroxide-containing solution in the presence of an anhydride of a carboxylic acid and/or of a dehydrating agent.

    摘要翻译： 本发明涉及甲醛化合物的用途，并且a，b和c的总量符合铼的五价态或七价态，条件是c不大于3xb，并且其中R1不存在 或相同或不同，并且是具有1至10个碳原子的脂族烃基，具有6至10个碳原子的芳族烃基或具有7至9个碳原子的芳基烷基，在适当的情况下可以使R1基团 取代相同或不同，彼此独立地，作为用于氧化富含电子的芳族化合物及其衍生物的催化剂，所述催化剂用于含羧酸酐和/或脱水剂的过氧化物溶液中 。

    Epoxides produced by the oxidation of olefins with air or oxygen
    12.
    发明授权
    Epoxides produced by the oxidation of olefins with air or oxygen 失效
    用空气或氧气氧化烯烃产生的环氧化物

    公开(公告)号：US5969166A

    公开(公告)日：1999-10-19

    申请号：US860261

    申请日：1997-09-12

    申请人： Bernd Scharbert ,  Gerhard Lobmaier ,  Wolfgang Anton Herrmann

    发明人： Bernd Scharbert ,  Gerhard Lobmaier ,  Wolfgang Anton Herrmann

    IPC分类号： B01J31/16 ,  B01J31/18 ,  B01J31/22 ,  C07D301/06 ,  C07D303/04 ,  C07F11/00 ,  C07F15/00 ,  C07D303/00

    CPC分类号： C07F15/0053 ,  B01J31/181 ,  B01J31/2226 ,  B01J31/226 ,  C07D301/06 ,  C07D303/04 ,  C07F11/005 ,  B01J2231/72 ,  B01J2531/56 ,  B01J2531/64 ,  B01J2531/821 ,  B01J31/2234

    摘要： Catalysts for the selective epoxidization of olefins with atmospheric oxygen, processes for their preparation and processes for the preparation of epoxides by oxidation of olefins with air or oxygen.Compounds of the formula (1) as catalysts for the selective epoxidization of alkenesM.sub.x O.sub.y (L).sub.z (1)in whichthe indices x, y and z have the following meaning:x is a whole number from 1 to 3, y is a whole number from 1 to 2x+1, y being selected so that the sum of x+z gives a metal oxidation number of +5 (vanadium) or +6 (molybdenum, ruthenium); z is a whole number in the range from 2 to 2x;M is molybdenum, ruthenium or vanadium andL is an N, 0 or S donor ligand.Heterogeneous catalysts for the selective oxidation of olefins in the presence of oxygen, comprising an inorganic or organic support material and compounds of the formula (1), and a process for the selective epoxidization of alkenes of the formula ##STR1## with atmospheric oxygen in the presence of a catalyst of the formula (1) are also described.

    摘要翻译： PCT No.PCT / EP95 / 05027 Sec。 371日期：1997年9月12日 102（e）1997年9月12日PCT PCT 1995年12月19日PCT公布。 公开号WO96 / 20788 日期1996年7月11日用于大气氧的烯烃选择性环氧化的催化剂，其制备方法和通过用空气或氧气氧化烯烃制备环氧化物的方法。 式（1）的化合物作为选择性环氧化烯烃M x O y（L）z（1）的催化剂，其中指数x，y和z具有以下含义：x为1至3的整数，y为整数 选择1至2x + 1的y，使得x + z的和得到+5（钒）或+6（钼，钌）的金属氧化数; z是2到2之间的整数; M是钼，钌或钒，L是N，O或S供体配体。 包含无机或有机载体材料和式（1）化合物的在氧气存在下选择性氧化烯烃的非均相催化剂，以及一种在大气氧气存在下用式（I）选择性环氧化式 还描述了式（1）的催化剂。

    Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis
    15.
    发明授权
    Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis 有权
    含有N-杂环卡宾配体的钌亚烷基络合物; 用作烯烃复分解的高活性选择性催化剂

    公开(公告)号：US08153810B2

    公开(公告)日：2012-04-10

    申请号：US13090688

    申请日：2011-04-20

    申请人： Wolfgang Anton Herrmann ,  Wolfgang Schattenmann ,  Thomas Weskamp

    发明人： Wolfgang Anton Herrmann ,  Wolfgang Schattenmann ,  Thomas Weskamp

    IPC分类号： C07F15/00 ,  C07C2/02 ,  C07C6/00

    CPC分类号： C07F15/0046 ,  B01J31/18 ,  B01J31/2208 ,  B01J31/2265 ,  B01J31/2273 ,  B01J31/2404 ,  B01J31/26 ,  B01J2231/14 ,  B01J2231/54 ,  B01J2231/543 ,  B01J2531/0263 ,  B01J2531/821 ,  C07C2/32 ,  C07C6/04 ,  C07C67/313 ,  C07C67/475 ,  C07C2531/22 ,  C07C2531/24 ,  C08G61/08 ,  C07C69/593 ,  C07C13/20 ,  C07C11/02

    摘要： The invention relates to a complex of ruthenium of the structural formula I, where X1 and X2 are identical or different and are each an anionic ligand, R1 and R2 are identical or different and can also contain a ring, and R1 and R2 are each hydrogen or/and a hydrocarbon group, the ligand L1 is an N-heterocyclic carbene and the ligand L2 is an uncharged electron donor, in particular an N-heterocyclic carbene or an amine, imine, phosphine, phosphate, stibine, arsine, carbonyl compound, carboxyl compound, nitrile, alcohol, ether, thiol or thioether, where R1, R2, R3 and R4 are hydrogen or/and hydrocarbon groups. The invention further relates to a process for preparing acyclic olefins having two or more carbon atoms or/and cyclic olefins having four or more carbon atoms from acyclic olefins having two or more carbon atoms or/and from cyclic olefins having four or more carbon atoms by an olefin metathesis reaction in the presence of at least one catalyst, wherein a complex is used as catalyst and R′1, R′2, R′3 and R′4 are hydrogen or/and hydrocarbon groups.

    摘要翻译： 本发明涉及结构式I的钌络合物，其中X1和X2相同或不同并且各自为阴离子配体，R 1和R 2相同或不同，并且还可以含有环，R 1和R 2各自为氢 或/或烃基，配体L1为N-杂环卡宾，配体L2为不带电子的电子给体，特别是N-杂环卡宾或胺，亚胺，膦，磷酸，锑，胂，羰基化合物， 羧基化合物，腈，醇，醚，硫醇或硫醚，其中R 1，R 2，R 3和R 4是氢或/和烃基。 本发明还涉及一种制备具有两个或多个碳原子的非环烯烃或/或具有四个以上碳原子的环烯烃的环烯烃的方法，所述环烯烃具有两个或更多个碳原子的无环烯烃和/或具有四个以上碳原子的环状烯烃， 在至少一种催化剂存在下进行烯烃复分解反应，其中使用络合物作为催化剂，R'1，R'2，R'3和R'4是氢或/和烃基。

    Homobimetallic and heterobimetallic alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands
    16.
    发明授权
    Homobimetallic and heterobimetallic alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands 失效
    含有N-杂环卡宾配体的钌的同双金属和异双金属亚烷基络合物

    公开(公告)号：US06787620B2

    公开(公告)日：2004-09-07

    申请号：US10371955

    申请日：2003-02-20

    申请人： Wolfgang Anton Herrmann ,  Florian J. Kohl ,  Thomas Weskamp

    发明人： Wolfgang Anton Herrmann ,  Florian J. Kohl ,  Thomas Weskamp

    IPC分类号： C08F480

    CPC分类号： C07C6/04 ,  C07C2527/1213 ,  C07C2527/122 ,  C07C2527/138 ,  C07C2531/22 ,  C07C2531/26 ,  C07C2531/30 ,  C07F15/0046

    摘要： The invention relates to complexes of ruthenium of the structural formula I where X is an anionic ligand, Z is a monodentate to tridentate ligand which contains a metal and is nonionically bound to the ruthenium center, R1 and R2 are identical or different and are each hydrogen or/and a hydrocarbon group, but may also form a ring, and Ligand L is an N-heterocyclic carbene, and also to a process for preparing acyclic olefins having two or more carbon atoms or/and cyclic olefins having three or more carbon atoms and the use of at least one complex of the formula I in olefin metathesis.

    摘要翻译： 本发明涉及结构式I的钌络合物，其中X是阴离子配位体，Z是含有金属并且与钌中心非离子键合的三齿配体的单齿配位体，R 1和R 2是相同或不同的 并且各自为氢或/和烃基，但也可以形成环，并且L是N-杂环卡宾，并且还涉及制备具有两个或更多个碳原子的非环烯烃或/或具有三个或更多个碳原子的环烯烃的方法， 更多的碳原子和在烯烃复分解中使用至少一种式I的络合物。

    Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis
    17.
    发明授权
    Alkylidene complexes of ruthenium containing N-heterocyclic carbene ligands; use as highly active, selective catalysts for olefin metathesis 有权
    含有N-杂环卡宾配体的钌亚烷基络合物; 用作烯烃复分解的高活性选择性催化剂

    公开(公告)号：US06635768B1

    公开(公告)日：2003-10-21

    申请号：US09647742

    申请日：2000-11-27

    申请人： Wolfgang Anton Herrmann ,  Wolfgang Schattenmann ,  Thomas Weskamp

    发明人： Wolfgang Anton Herrmann ,  Wolfgang Schattenmann ,  Thomas Weskamp

    IPC分类号： C07F1500

    CPC分类号： C07F15/0046 ,  B01J31/18 ,  B01J31/2208 ,  B01J31/2265 ,  B01J31/2273 ,  B01J31/2404 ,  B01J31/26 ,  B01J2231/14 ,  B01J2231/54 ,  B01J2231/543 ,  B01J2531/0263 ,  B01J2531/821 ,  C07C2/32 ,  C07C6/04 ,  C07C67/313 ,  C07C67/475 ,  C07C2531/22 ,  C07C2531/24 ,  C08G61/08 ,  C07C69/593 ,  C07C13/20 ,  C07C11/02

    摘要： The invention relates to a complex of ruthenium of the structural formula I, where X1 and X2 are identical or different and are each an anionic ligand, R1 and R2 are identical or different and can also contain a ring, and R1 and R2 are each hydrogen or/and a hydrocarbon group, the ligand L1 is an N-heterocyclic carbene and the ligand L2 is an uncharged electron donor, in particular an N-heterocyclic carbene or an amine, imine, phosphine, phosphite, stibine, arsine, carbonyl compound, carboxyl compound, nitrile, alcohol, ether, thiol or thioether, where R1, R2, R3 and R4 are hydrogen or/and hydrocarbon groups. The invention further relates to a process for preparing acyclic olefins having two or more carbon atoms or/and cyclic olefins having four or more carbon atoms from acyclic olefins having two or more carbon atoms or/and from cyclic olefins having four or more carbon atoms by an olefin metathesis reaction in the presence of at least one catalyst, wherein a complex is used as catalyst and R′1, R′2, R′3 and R′4 are hydrogen or/and hydrocarbon groups.

    摘要翻译： 本发明涉及结构式I的钌络合物，其中X 1和X 2相同或不同，并且各自为阴离子配体，R 1和R 2相同或不同，并且可以 还含有环，R 1和R 2各自为氢或/或烃基，配体L 1为N-杂环卡宾，配体L 2为不带电子的电子给体， 特别是N-杂环卡宾或胺，亚胺，膦，亚磷酸酯，锑，胂，羰基化合物，羧基化合物，腈，醇，醚，硫醇或硫醚，其中R 1，R 2， 3>和R 4是氢或/和烃基。本发明还涉及一种制备具有两个或更多个碳原子的非环烯烃或/或具有四个或更多碳原子的环烯烃的方法，所述环烯烃具有两个或更多个无环烯烃 碳原子和/或具有四个或更多个碳原子的环状烯烃，通过在至少一种催化剂的存在下进行烯烃复分解反应，其中完全 x用作催化剂，R''，R'2，R'3和R'4是氢或/或烃基。

    Method for producing epoxides through olefin oxidation with air or oxygen
    18.
    发明授权
    Method for producing epoxides through olefin oxidation with air or oxygen 失效
    用空气或氧气通过烯烃氧化制备环氧化物的方法

    公开(公告)号：US06326502B1

    公开(公告)日：2001-12-04

    申请号：US09462523

    申请日：2000-01-07

    申请人： Rolf Peter Schulz ,  Uwe Dingerdissen ,  Wolfgang Anton Herrmann ,  Gerhard Lobmaier

    发明人： Rolf Peter Schulz ,  Uwe Dingerdissen ,  Wolfgang Anton Herrmann ,  Gerhard Lobmaier

    IPC分类号： C07D30106

    CPC分类号： C07D301/06 ,  C07D303/04

    摘要： The present invention provides a process for the epoxidation of alkenes of the formula (1) where R1, R2, R3 and R4 are, independently of one another, hydrogen, C1-C20-alkyl, C1-C12-alkoxy, C6-C10-aryl, —CHOH—CH3, —CH—NH2—CH3 or carboxy, using air or oxygen over a catalyst comprising compounds of the formula (2) MoxOy(L)z  (2) where x is 1, 2 or 3, y is an integer from 0 to 2x+1, z is an integer from 1 to 2x, where the ligand L is a compound of the formula (3) or (4) where X is a nitrogen, oxygen or sulfur atom, Y is hydrogen, C1-C8-alkyl, C1-C8-alkoxy, F, Cl, Br, I, COOCH3, C6-C14-aryl or C3-C8-cycloalkyl, R7 and R8 form a ring containing from 4 to 8 carbon atoms onto which one or two aromatic rings may be fused, R5 and R6 are hydrogen, branched or straight-chain C1-C12-alkyl or branched or straight-chain C1-C12-haloalkyl which are substituents on the ring formed by R7 and R8 and/or the rings fused onto this ring, or the ligand L is a compound of the formula (5), (6) or (7) where R is hydrogen, C1-C8-alkyl, C1-C8-haloalkyl, C1-C8-alkoxy, COOCH3, C6-C14-aryl or C3-C8-cycloalkyl and n is 1 or 2 and m is from 1 to 6, wherein the reaction is carried out in a pressure vessel which is completely lined with an inert material.

    摘要翻译： 本发明提供了式（1）的烯烃的环氧化方法，其中R 1，R 2，R 3和R 4彼此独立地为氢，C 1 -C 20 - 烷基，C 1 -C 12 - 烷氧基，C 6 -C 10 - 芳基，-CHOH-CH 3，-CH-NH 2 -CH 3或羧基，使用空气或氧气在包含式（2）化合物的催化剂上，其中x为1,2或3，y为0至2×+ 1的整数， z是1至2的整数，其中配体L是式（3）或（4）的化合物，其中X是氮，氧或硫原子，Y是氢，C1-C8-烷基，C1-C8-烷基， 烷氧基，F，Cl，Br，I，COOCH 3，C 6 -C 14 - 芳基或C 3 -C 8 - 环烷基，R 7和R 8形成含有4至8个碳原子的环，一个或两个芳环可以被稠合，R5和 R6是在由R7和R8形成的环和/或稠合在该环上的环上的取代基的氢，支链或直链C 1 -C 12烷基或支链或直链C 1 -C 12 - 卤代烷基，或配体L 是式（5），（6）或（7）的化合物，其中R是氢，C1-C8-烷基，C1-C8 卤代烷基，C 1 -C 8 - 烷氧基，COOCH 3，C 6 -C 14 - 芳基或C 3 -C 8 - 环烷基，n为1或2，m为1至6，其中反应在完全衬里的压力容器中进行 用惰性材料。

    Process for selective catalytic oxidation of olefins to aldehydes, ketones with cleavage of C=C bonds
    19.
    发明授权
    Process for selective catalytic oxidation of olefins to aldehydes, ketones with cleavage of C=C bonds 失效
    将烯烃选择性催化氧化成醛，C = C键裂解的酮的方法

    公开(公告)号：US06303828B1

    公开(公告)日：2001-10-16

    申请号：US09403459

    申请日：2000-02-11

    申请人： Richard Walter Fischer ,  Wolfgang Anton Herrmann ,  Thomas Weskamp

    发明人： Richard Walter Fischer ,  Wolfgang Anton Herrmann ,  Thomas Weskamp

    IPC分类号： C07C4500

    CPC分类号： C07C45/30 ,  C07C29/48 ,  C07C45/28 ,  C07C31/20 ,  C07C49/04 ,  C07C47/02

    摘要： The use of compounds of the formula (I) R1aRebOc•Ld  (I), in which a=zero or an integer from 0 to 6 b=an integer from 1 to 4 c=an integer from 1 to 12 d=an integer from 0 to 4 L=Lewis base and the total of a, b and c is such as to comply with the penta- or hepta-valency of rhenium, with the proviso that c is not greater than 3•b, and in which R1 is absent, identical or different and is an aliphatic hydrocarbon radical having 1 to 10 carbon atoms, an aromatic hydrocarbon radical having 6 to 10 carbon atoms or an arylalkyl radical having 7 to 9 carbon atoms, where the R1 radicals can, where appropriate, be substituted identically or differently, independently of one another, as catalysts for the selective oxidation of olefins with cleavage of C═C bonds to give the corresponding carbonyl compounds in the presence of a peroxide-containing compound, where the amount of substance ratio of olefin to peroxide-containing compound is in a range from 1:2 to 1:14.

    摘要翻译： 使用式（I）的化合物，其中a = 0或0至6b的整数= 1至4c的整数= 1至12d的整数= 0至4L的整数=路易斯碱和a， b和c符合铼的五价或七价，条件是c不大于3.b，其中R1不存在，相同或不同，是具有1个 至10个碳原子，具有6至10个碳原子的芳族烃基或具有7至9个碳原子的芳基烷基，其中R 1基团可以在适当的情况下相同或不同地相互独立地取代，作为 在C = C键裂解的情况下选择性氧化烯烃，在含过氧化物的化合物存在下得到相应的羰基化合物，其中烯烃与含过氧化物的化合物的物质比例在1:2至1的范围内 ：14。