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    POLYBUTADIENE
    5.
    发明申请
    POLYBUTADIENE 有权

    公开(公告)号：US20170015766A1

    公开(公告)日：2017-01-19

    申请号：US15300766

    申请日：2015-02-19

    申请人： UBE INDUSTRIES, LTD.

    发明人： Mitsuharu AMBE ,  Yuuto KANOU ,  Takeshi SHODA

    IPC分类号： C08F136/06 ,  C08F4/602

    CPC分类号： C08F136/06 ,  C08F4/6022 ,  C08F4/70 ,  C08F36/06 ,  C08F4/7096

    摘要： The present invention provides a polybutadiene having improved workability and abrasion resistance. A polybutadiene according to the present invention has: (A) a Mooney viscosity (ML1+4,100° C.) being 43 or more; (B) a ratio (Tcp/ML1+4,100° C.) of 5 wt % toluene solution viscosity (Tcp) to Mooney viscosity (ML1+4,100° C.) being 0.9 to 2.3; (C) a stress relaxation time (T80) being 10.0 to 40.0 seconds, which is a time until a torque is attenuated by 80% when the torque at the end of ML1+4,100° C.measurement is 100%; and (D) a molecular weight distribution (Mw/Mn) being 2.50 to 4.00.

    摘要翻译： 本发明提供了具有改进的可加工性和耐磨性的聚丁二烯。 根据本发明的聚丁二烯具有：（A）门尼粘度（ML1 + 4,100℃）为43以上; （B）5重量％甲苯溶液粘度（Tcp）与门尼粘度（ML1 + 4,100℃）的比（Tcp / ML1 + 4,100℃）为0.9〜2.3; （C）应力松弛时间（T80）为10.0〜40.0秒，这是在ML1 + 4,100℃测量结束时的转矩为100％时扭矩减弱80％的时间; （D）分子量分布（Mw / Mn）为2.50〜4.00。

    Catalytic systems made of a complex of rare earths for stereospecific polymerisation of conjugated dienes
    7.
    发明授权
    Catalytic systems made of a complex of rare earths for stereospecific polymerisation of conjugated dienes 有权
    由稀土复合物制成的催化体系用于共轭二烯的立体有择聚合

    公开(公告)号：US08946368B2

    公开(公告)日：2015-02-03

    申请号：US13318022

    申请日：2010-04-27

    申请人： Christophe Boisson ,  Olivier Rolland ,  Julien Thuilliez

    发明人： Christophe Boisson ,  Olivier Rolland ,  Julien Thuilliez

    IPC分类号： C08F36/06 ,  C08F36/08 ,  C08F4/52 ,  C08F4/602

    CPC分类号： C08F4/545 ,  C08F36/04

    摘要： The present invention relates to a multi-component catalytic system that can be used for the cis-1,4 stereospecific polymerization of conjugated dienes. The system is based on: (i) a rare-earth complex of Formula (II) Ln(A)3(B)n, Ln being a rare-earth metal, A a ligand, B a Lewis base or a solvent molecule and n a number from 0 to 3; (ii) an alkylating agent; (iii) a compound based on an aromatic ring and having at least two heteroatoms chosen from the elements O, N, S, P, and corresponding to the Formula (III): in which the R groups each denote hydrogen, an alkyl radical optionally comprising one or more heteroatoms (N, O, P, S, Si) or one or more halogen atoms, a halogen atom, a group based on one or more heteroatoms (N, O, P, S, Si); x and y are integers from 0 to 6; D is a group having a chemical function, one of the atoms of which has a non-bonding pair; L being an atom from column 1 of the Periodic Table.

    摘要翻译： 本发明涉及可用于共轭二烯的顺式-1,4-立体有择聚合的多组分催化体系。 该系统基于：（i）式（II）Ln（A）3（B）n的稀土络合物，Ln是稀土金属，A a配体，B路易斯碱或溶剂分子，以及 na数从0到3; （ii）烷基化剂; （iii）基于芳环并且具有至少两个选自元素O，N，S，P的杂原子并且对应于式（III）的化合物：其中R基团各自表示氢，任选的烷基 包括一个或多个杂原子（N，O，P，S，Si）或一个或多个卤素原子，卤素原子，基于一个或多个杂原子（N，O，P，S，Si）的基团。 x和y是0〜6的整数; D是具有化学功能的基团，其原子之一具有非键合对; L是周期表第1列的原子。

    PROCESS FOR THE PREPARATION OF AN UNSUPPORTED, SOLID METALLOCENE CATALYST SYSTEM AND ITS USE IN POLYMERIZATION OF OLEFINS
    9.
    发明申请
    PROCESS FOR THE PREPARATION OF AN UNSUPPORTED, SOLID METALLOCENE CATALYST SYSTEM AND ITS USE IN POLYMERIZATION OF OLEFINS 有权
    制备不需要的固体金属催化剂体系的方法及其在烯烃聚合中的应用

    公开(公告)号：US20120309913A1

    公开(公告)日：2012-12-06

    申请号：US13513450

    申请日：2010-12-03

    申请人： Nicolas Ronan ,  Peter Denifl

    发明人： Nicolas Ronan ,  Peter Denifl

    IPC分类号： C08F4/42 ,  C08F4/52 ,  C08F4/602 ,  C08F10/06 ,  C08F4/76

    CPC分类号： C08F10/00 ,  C08F4/65927 ,  C08F12/20 ,  C08F12/22 ,  C08F110/06 ,  C08F293/005 ,  C08F2410/01 ,  C08F2438/01 ,  C08F4/65912 ,  C08F2500/12

    摘要： Process for the preparation of an unsupported, heterogeneous olefin polymerization catalyst system, comprising an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC 2007) in the form of solid particles comprising the steps of a) preparing a solution (A) comprising ai) an organometallic compound of a transition metal of Group 3 to 10 of the Periodic Table (IUPAC 2007) or of an actinide or lanthanide, a2) a cocatalyst comprising an element of group 13 of the Periodic Table (IUPAC 2007) and a3) a solvent (A-1), b) preparing a liquid/liquid emulsion system by dispersing the solution (A) in a solvent (B) essentially immiscible with said solution (A) in the presence of a polystyrene-b-fluoro polystyrene copolymer of the formula (I) in which n is a number from 10 to 100, m is a number from 1 to 40, x is a number from 5 to 16, y is a number from 11 to 33, provided that m, n, x and y are selected in a way that the block copolymer is soluble in the solvent B or the solution A in such an extent that a stable emulsion is formed by adding the block copolymer, b1) the solvent (B) constitutes the continuous phase of the emulsion, b2) the solution (A) constitutes in the form of droplets the dispersed phase and b3) the organometallic compound and the cocatalyst are present in the droplets, c) solidifying said dispersed phase to convert said droplets to solid particles and optionally recovering said particles to obtain said catalyst system; an unsupported, heterogeneous olefin polymerization catalyst, obtainable by the process and the use of the catalyst in olefin polymerization.

    摘要翻译： 制备无支撑的非均相烯烃聚合催化剂体系的方法，其包含固体颗粒形式的元素周期表第3至10族的过渡金属的有机金属化合物（IUPAC 2007），包括以下步骤：a）制备溶液 （A）包含ai）周期表第3至10族过渡金属的有机金属化合物（IUPAC 2007）或锕系元素或镧系元素，a2）包含元素周期表第13族元素的助催化剂（IUPAC 2007 ）和a3）溶剂（A-1），b）通过将溶液（A）分散在基本上与所述溶液（A）不混溶的溶剂（B）中，在聚苯乙烯-b的存在下制备液体/液体乳液体系 式（I）的氟代聚苯乙烯共聚物，其中n为10至100的数，m为1至40的数，x为5至16的数，y为11至33的数，条件是 m，n，x和y以嵌段共聚物可溶于溶剂中的方式选择 t B或溶液A，通过加入嵌段共聚物形成稳定的乳液，b1）溶剂（B）构成乳液的连续相，b2）溶液（A）以液滴的形式构成 分散相和b3）有机金属化合物和助催化剂存在于液滴中，c）固化所述分散相以将所述液滴转化为固体颗粒，并任选地回收所述颗粒以获得所述催化剂体系; 一种无支撑的非均相烯烃聚合催化剂，可通过烯烃聚合中的方法和使用催化剂获得。