公开(公告)号：US11254756B2

公开(公告)日：2022-02-22

申请号：US16445865

申请日：2019-06-19

申请人： W.R. Grace & Co.—Conn.

发明人： Linfeng Chen ,  Tak W. Leung ,  Tao Tao ,  Kuanqiang Gao

IPC分类号： C08F4/64 ,  C08F4/52 ,  C08F4/00 ,  C08F110/06 ,  C08F4/16 ,  C08F4/609 ,  C08F4/642

摘要： Disclosed are catalyst compositions having an internal electron donor which includes a 3,6-di-substituted-1,2-phenylene aromatic diester. Ziegler-Natta catalyst compositions containing the present catalyst compositions exhibit very high hydrogen response, high activity, high selectivity and produce propylene-based olefins with high melt flow rate.

公开(公告)号：US10851189B2

公开(公告)日：2020-12-01

申请号：US16469855

申请日：2018-01-16

申请人： Evonik Operations GmbH

发明人： Kai-Steffen Krannig ,  Jürgen Herwig ,  Andreas Berlineanu ,  Miriam Ammer ,  Philip Kemper ,  Alexander Pschantka ,  Yvonne Groß-Onnebrink ,  Gudula Beuers ,  Margit Bukohl ,  Kirsten Luce ,  Siegfried Jittenmeier

IPC分类号： C08F36/06 ,  C08L9/00 ,  C08F2/06 ,  C08F4/609 ,  C08F4/619 ,  C08F4/70

摘要： The invention relates to polybutadiene, which contains the monomer units derived from 1,3-butadiene having a vinyl double bond in a proportion of 25 to 75 mole percent, having a trans-double bond in a proportion of 0 to 10 mole percent and a cis-double bond in a proportion of 25 to 75 mole percent, wherein the totality of the monomer units (A), (B) and (C) is supplemented to 100 mole percent, and which is characterized in that it has a number-average mole mass of 1,000 to 3,000 g/mole. The invention further relates to a method for producing polybutadienes, the use of the polybutadiene according to the invention and compositions containing polybutadiene according to the invention.

公开(公告)号：US10526427B2

公开(公告)日：2020-01-07

申请号：US16063042

申请日：2016-12-16

申请人： Japan Polypropylene Corporation

发明人： Keiji Fukuda ,  Shouichi Ida ,  Akio Tanna ,  Shigeo Mizukami

IPC分类号： C08F4/659 ,  C08F4/609 ,  C08F4/649 ,  C08F110/06 ,  C08F4/658 ,  C08F10/00

摘要： A method for producing a solid catalyst component (Aa) for α-olefin polymerization, which includes: bringing components (A1) to (A4) into contact with one another in an inert solvent; and without washing the contact product with an inert solvent, aging the contact product by keeping for a holding time of 3 days or more and 180 days or less, regarding the time point that all of the components (A1) to (A4) first come into contact, as a starting point.

公开(公告)号：US20190023815A1

公开(公告)日：2019-01-24

申请号：US16033810

申请日：2018-07-12

申请人： Korea Kumho Petrochemical Co., Ltd.

发明人： Jae Yun KIM ,  Yeong Min JUNG

IPC分类号： C08F2/60 ,  C08F36/06 ,  C08F36/08 ,  C08F36/04 ,  C08F4/12 ,  C08F4/602 ,  C08F4/609 ,  C08L9/00

摘要： Provided is a method of preparing a rubber composition, which includes (a) reacting a conjugated diene-based monomer with one or more of compounds in the presence of a first catalyst; (b) adding a conjugated diene-based monomer to a product of the step (a) and inducing a reaction; and (c) adding a second catalyst and a conjugated diene-based monomer to a product of the step (b) and inducing a reaction.

公开(公告)号：US20180244821A1

公开(公告)日：2018-08-30

申请号：US15756256

申请日：2016-08-29

申请人： Matthew L. Becker ,  Andrew P. Dove ,  Vinh X. Truong ,  Craig A. Bell ,  Ian A. Barker ,  Jiayi Yu

发明人： Matthew L. Becker ,  Andrew P. Dove ,  Vinh X. Truong ,  Craig A. Bell ,  Ian A. Barker ,  Jiayi Yu

IPC分类号： C08F238/00 ,  C08F2/46 ,  C08F4/609

CPC分类号： C08F238/00 ,  C08F2/46 ,  C08F4/6095 ,  C08F2500/01 ,  C08F2500/04 ,  C08F2500/21 ,  C08F228/02

摘要： In various embodiments, the present invention provides a strong, synthetic elastomer materials (and related methods for making same) with mechanical properties that are controlled by the stereochemically-defined double bonds within their backbone, yet have physical properties that are derived from monomer selection and defined, modifiable, chain end groups. The use of the organocatalyzed, stereospecific addition of thiols to activated alkynes, affords isolated high molar mass materials (>100 kDa) via step-growth polymerization with high levels of cis- or trans-double bond content. Furthermore, in various aspects of the present invention, it has been found that changing the monomer composition and chain end groups provides additional control over the materials' physical properties to provide more efficient compounding with polar additives. Using this approach to elastomer synthesis, further end group modification and toughening through various vulcanization strategies are also possible.

公开(公告)号：US08742045B2

公开(公告)日：2014-06-03

申请号：US13375853

申请日：2010-06-03

申请人： Atsushi Goto ,  Jeong Sik Kim ,  Yoshinobu Tsujii ,  Takeshi Fukuda

发明人： Atsushi Goto ,  Jeong Sik Kim ,  Yoshinobu Tsujii ,  Takeshi Fukuda

IPC分类号： C08F4/609

CPC分类号： C08F2/38 ,  C08F4/04 ,  C08F4/40 ,  C08F293/005

摘要： Provided is a method of living radical polymerization which does not necessitate complicated and intricate synthesis of a dormant species and which is highly efficient. A halogenated derivative compound is used as a dormant species for initiating living radical polymerization. The derivative compound is obtained by halogenating an alcohol compound having a non-conjugated structure or an amine compound having a non-conjugated structure with a halogenating agent capable of halogenating an alcohol or amine. A radical produced by elimination of halogen from the halogenated derivative compound is allowed to react with the unsaturated bond of the monomer. Thus, the monomer, which has a radical-reactive unsaturated bond, is polymerized by living radical polymerization. Preferably, the halogenating agent is a compound (NIS or the like) which also has a function as a catalyst.

摘要翻译： 提供了一种活性自由基聚合的方法，其不需要复杂且复杂的合成休眠物质并且是高效的。 卤化衍生化合物用作起始活性自由基聚合的休眠物质。 通过将具有非共轭结构的醇化合物或具有非共轭结构的胺化合物与能够卤化醇或胺的卤化剂卤化，得到衍生化合物。 通过从卤化衍生物化合物中除去卤素而产生的自由基与单体的不饱和键反应。 因此，具有自由基反应性不饱和键的单体通过活性自由基聚合而聚合。 优选地，卤化剂是也具有催化剂功能的化合物（NIS等）。

公开(公告)号：US20100222530A1

公开(公告)日：2010-09-02

申请号：US12650834

申请日：2009-12-31

申请人： Linfeng Chen ,  Tak W. Leung ,  Tao Tao

发明人： Linfeng Chen ,  Tak W. Leung ,  Tao Tao

IPC分类号： C08F4/60 ,  C08F4/609

CPC分类号： C08F4/6494 ,  C08F4/76 ,  C08F110/06 ,  C08F4/651 ,  C08F4/6465

摘要： Disclosed are procatalyst compositions having an internal electron donor which include a substituted phenylene aromatic diester and optionally an electron donor component. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit high activity and produce propylene-based olefins with broad molecular weight distribution.

摘要翻译： 公开了具有内电子给体的前催化剂组合物，其包括取代的亚苯基芳族二酯和任选的电子给体组分。 包含本发明的前催化剂组合物的齐格勒 - 纳塔催化剂组合物表现出高活性并产生具有宽分子量分布的丙烯基烯烃。

公开(公告)号：US07276566B2

公开(公告)日：2007-10-02

申请号：US11336346

申请日：2006-01-20

申请人： Natarajan Muruganandam ,  Kersten Anne Terry ,  Michael D. Awe ,  John H. Oskam

发明人： Natarajan Muruganandam ,  Kersten Anne Terry ,  Michael D. Awe ,  John H. Oskam

IPC分类号： C08F4/609 ,  C08F4/6392 ,  C08F4/64 ,  C08F4/646

CPC分类号： B01J37/0045 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/6592 ,  C08F4/65925 ,  C08F10/00 ,  C08F110/02 ,  C08F210/16 ,  C08F4/65904 ,  C08F2500/12 ,  C08F210/06 ,  C08F4/64148

摘要： A method for preparing a spray dried catalyst and a low viscosity, low foam spray dried catalyst system for olefin polymerization are provided. In one aspect, the method includes preparing a catalyst system including one or more components selected from metallocenes, non-metallocenes, and activators, adding mineral oil to the catalyst system to form a slurry, and adding one or more liquid alkanes having three or more carbon atoms to the slurry in an amount sufficient to reduce foaming and viscosity of the slurry. In one aspect, the catalyst system includes one or more catalysts selected from metallocenes, non-metallocenes, and a combination thereof, wherein the catalyst system is spray dried. The system further includes mineral oil to form a slurry including a catalyst system, and one or more liquid alkanes having three or more carbon atoms in an amount sufficient to reduce foaming and viscosity of the slurry.

公开(公告)号：US5847055A

公开(公告)日：1998-12-08

申请号：US894482

申请日：1997-08-22

申请人： Josef Wunsch ,  Walter Maier

发明人： Josef Wunsch ,  Walter Maier

IPC分类号： C08F4/602 ,  C07F17/00 ,  C08F4/609 ,  C08F4/619 ,  C08F4/64 ,  C08F4/649 ,  C08F4/76 ,  C08F10/00 ,  C08F12/00 ,  C08F12/04 ,  C08F20/10 ,  C08F36/02 ,  C08F8/42

CPC分类号： C08F10/00 ,  C07F17/00 ,  C08F12/04 ,  C08F4/619 ,  Y10S526/943

摘要： A catalyst system of the formula I X M (Z.sup.1).sub.z.sbsb.1 (Z.sup.2).sub.z.sbsb.2 (Z.sup.3).sub.z.sbsb.3 I where X is C.sub.1 -C.sub.10 -alkyl, 5- to 7-membered cycloalkyl, C.sub.1 -C.sub.10 -alkoxy, C.sub.6 -C.sub.15 -aryl or a compound of the formula II ##STR1## where R.sup.1 to R.sup.5 are substituents as defined in the specification,M is a metal of transition groups II to VIII of the Periodic Table of the Elements, Z.sup.1 to Z.sup.3 are polymers of vinylaromatic compounds, dienes, acrylates or their mixtures and .sub.Z1 to .sub.Z3 are 0, 1, 2 or 3, where.ltoreq..sub.Z1 +.sub.Z2 +.sub.Z3 .ltoreq.3.

摘要翻译： PCT No.PCT / EP96 / 00597 371日期1997年8月22日 102（e）日期1997年8月22日PCT提交1996年2月13日PCT公布。 公开号WO96 / 26226 日期：1996年8月29日A式IXM（Z1）z1（Z2）z2（Z3）z3 I的催化剂体系，其中X为C1-C10-烷基，5-至7-元环烷基，C1-C10-烷氧基，C6- C 15 - 芳基或式II化合物其中R 1至R 5是说明书中所定义的取代基，M是元素周期表的转变基团II至VIII的金属，Z 1至Z 3是 乙烯基芳族化合物，二烯，丙烯酸酯或它们的混合物，Z 1至Z 3分别为0,1,2或3，其中Z 1 + Z 2 + Z 3为3。

公开(公告)号：US5686543A

公开(公告)日：1997-11-11

申请号：US655676

申请日：1996-05-30

申请人： Kyouyu Yasuda ,  Akio Takashima

发明人： Kyouyu Yasuda ,  Akio Takashima

IPC分类号： C08F4/70 ,  C08F2/06 ,  C08F4/60 ,  C08F4/602 ,  C08F4/609 ,  C08F4/80 ,  C08F36/06 ,  C08F136/06

CPC分类号： C08F36/06

摘要： A process for producing a polybutadiene rubber having a cis-1,4 content of 94% or more, a ratio of weight average molecular weight to number average molecular weight of 2.5 to 3.5 as measured by a gel permeation chromatography and a Mooney viscosity (ML.sub.1+4, 100.degree. C.) of 20 to 100, which process comprises polymerizing 1,3-butadiene in an inert organic solvent with a catalyst comprising as the main components (a) a nickel compound; (b) a specific fluorine compound; (c) a trialkylaluminum; and (d) a halogenated aldehyde and/or a quinone compound. The use of the specific catalyst enables the production in a high yield of a polybutadiene rubber which maintains the abrasion resistance, high impact resilience and low heat buildup which are the characteristics of polybutadiene rubber and has a small die swell when extruded in the form of a blend with a natural rubber and is excellent in physical properties of vulcanizate.

摘要翻译： 制备顺式-1,4含量为94％以上的聚丁二烯橡胶的方法，通过凝胶渗透色谱法测定的重均分子量与数均分子量的比例为2.5〜3.5，门尼粘度（ML1 +4,100℃）为20〜100，该方法包括在惰性有机溶剂中用包含作为主要组分（a）的镍化合物的催化剂聚合1,3-丁二烯; （b）特定的氟化合物; （c）三烷基铝; 和（d）卤化醛和/或醌化合物。 使用特定的催化剂使得能够以高产率的聚丁二烯橡胶生产，其保持作为聚丁二烯橡胶的特性的耐磨性，高回弹性和低热积聚性，并且当以下列形式挤出时具有小的模头膨胀 与天然橡胶混合，硫化胶的物理性能优良。