公开(公告)号：US09546226B2

公开(公告)日：2017-01-17

申请号：US13388811

申请日：2010-05-10

申请人： Atsushi Goto ,  Yoshinobu Tsujii ,  Takeshi Fukuda

发明人： Atsushi Goto ,  Yoshinobu Tsujii ,  Takeshi Fukuda

IPC分类号： C08F20/14 ,  C08F4/40 ,  C08F293/00 ,  C08F12/08 ,  C08F120/14

CPC分类号： C08F4/40 ,  C08F12/08 ,  C08F120/14 ,  C08F293/005 ,  C08F2438/00

摘要： Provided is a low-cost, highly active, environmentally friendly living radical polymerization catalyst which does not require a radical initiator. An organic compound having an oxidation-reduction capability is used as a catalyst. Even if a radical initiator is not used, a monomer can be subjected to a radical polymerization to obtain a polymer having narrow molecular weight distribution. The cost of the living radical polymerization can be remarkably reduced. It is made possible to prevent adverse effects of using a radical initiator. The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages of the catalyst such as low toxicity of the catalyst, low amount of the catalyst necessary, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor (which do not require a post-treatment for a molded article), etc.

摘要翻译： 提供了不需要自由基引发剂的低成本，高活性，环保的活性自由基聚合催化剂。 使用具有氧化还原能力的有机化合物作为催化剂。 即使不使用自由基引发剂，也可以对单体进行自由基聚合，得到分子量分布窄的聚合物。 活性自由基聚合的成本可以显着降低。 可以防止使用自由基引发剂的不利影响。 由于催化剂的优点，催化剂的低毒性，必需的催化剂量低，催化剂的溶解度高，反应条件温和，反应条件好，因此本发明的环保性和经济性优于常规的活性自由基聚合方法。 无着色/无异味（不需要后处理成型品）等

公开(公告)号：US20130338273A1

公开(公告)日：2013-12-19

申请号：US14001824

申请日：2011-11-28

申请人： Hiroyuki Shimanaka ,  Yoshikazu Murakami ,  Shinichio Aoyagi ,  Atsushi Goto ,  Hironori Kaji

发明人： Hiroyuki Shimanaka ,  Yoshikazu Murakami ,  Shinichio Aoyagi ,  Atsushi Goto ,  Hironori Kaji

IPC分类号： C08F299/04

CPC分类号： C08F299/0414 ,  C08F293/005 ,  C09D11/107 ,  C09D11/322 ,  Y10T428/2982

摘要： Disclosed is an emulsion binder containing an A-B block copolymer. The A-B block copolymer has a number average molecular weight of 5,000 to 100,000, and a polydispersity index (weight average molecular weight/number average molecular weight) of not greater than 1.7. The polymer block A has an acid value of 0 to 30 mgKOH/g and a glass transition point of not higher than 60° C. The polymer block B has an acid value of 75 to 250 mgKOH/g. The A-B block copolymer has been neutralized with an alkaline material, and has been allowed to self-emulsify in an aqueous medium to form emulsion particles having an average particle size of 30 to 300 nm.

摘要翻译： 公开了含有A-B嵌段共聚物的乳液粘合剂。 A-B嵌段共聚物的数均分子量为5,000〜100,000，多分散指数（重均分子量/数均分子量）为1.7以下。 聚合物嵌段A的酸值为0〜30mgKOH / g，玻璃化转变温度不高于60℃。聚合物嵌段B的酸值为75〜250mgKOH / g。 A-B嵌段共聚物已经用碱性材料中和，并且在水性介质中自我乳化，形成平均粒度为30〜300nm的乳液颗粒。

公开(公告)号：US08575285B2

公开(公告)日：2013-11-05

申请号：US13062688

申请日：2009-09-08

申请人： Atsushi Goto ,  Yoshinobu Tsujii ,  Takeshi Fukuda

发明人： Atsushi Goto ,  Yoshinobu Tsujii ,  Takeshi Fukuda

IPC分类号： C08F4/00 ,  C08F12/02 ,  C07C19/16 ,  C07C255/50 ,  C07C19/07 ,  C07C25/02 ,  C07C43/247 ,  B01J31/00 ,  B01J27/06 ,  B01J27/135

CPC分类号： C08F4/00 ,  C08F293/005 ,  C08F2438/00

摘要： Provided is a catalyst used for a living radical polymerization method, which contains a central element consisting of carbon and at least one halogen atom binding to the central element. Further, a hydrocarbon compound can be used as a catalyst precursor. A monomer having a radical-reactive unsaturated bond is subjected to a radical polymerization reaction in the presence of the catalyst, consequently a polymer having narrow molecular weight distribution can be obtained, and thus the cost of the living radical polymerization can be remarkably reduced. The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages such as low toxicity of the catalyst, low amount of the catalyst used, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor (no need of any post-treatments for a molded article), and the like.

摘要翻译： 提供了用于活性自由基聚合法的催化剂，其包含由碳和与中心元素结合的至少一个卤素原子组成的中心元素。 此外，可以使用烃化合物作为催化剂前体。 具有自由基反应性不饱和键的单体在催化剂的存在下进行自由基聚合反应，因此可以获得具有窄分子量分布的聚合物，从而可显着降低活性自由基聚合的成本。 本发明由于催化剂的毒性低，催化剂用量少，催化剂溶解性高，反应条件温和，无着色/无色性等优点，比现有的活性自由基聚合法更具环保性和经济性， 无异味（不需要对成形品进行后处理）等。

公开(公告)号：US08546282B2

公开(公告)日：2013-10-01

申请号：US13458267

申请日：2012-04-27

申请人： Hiroaki Kinoshita ,  Anne Jans Faber ,  Mathi Rongen ,  Atsushi Goto ,  Makoto Tanabe ,  Yuko Katahira

发明人： Hiroaki Kinoshita ,  Anne Jans Faber ,  Mathi Rongen ,  Atsushi Goto ,  Makoto Tanabe ,  Yuko Katahira

IPC分类号： C03C13/04 ,  C03C3/076 ,  C03C3/062 ,  C03C3/068

CPC分类号： C03C13/046 ,  C03C3/068 ,  C03C3/078 ,  C03C3/097

摘要： A glass for a light guide fiber GA1 is used in a core of a fiber 10 of a light guide, and has a refractive index nd between 1.56 and 1.74. The glass for a light guide fiber GA1 has the following composition: (A) SiO2: 20 to 55 wt %, (B11) B2O3: 0 to 2.0 wt %, (B2) does not contain P2O5 and GeO2, (C1) (BaO+SrO+La2O3+Lu2O3+Ta2O5+Gd2O3+WO3): 39 to 46 wt %, (D1) ZnO: 4 to 16 wt %, (E) does not contain Al2O3, (F) does not contain ZrO2, (G) does not contain PbO and As2O3, (H1) (Na2O+K2O): 4 to 10 wt %, (I) Sb2O3: 0 to 0.050 wt %, and (J1) (Na2SO4+K2SO4): 0.32 to 0.78 wt %.

摘要翻译： 用于光导纤维GA1的玻璃用于光导纤维10的纤芯，折射率nd在1.56与1.74之间。 导光纤维GA1的玻璃具有以下组成：（A）SiO 2：20〜55重量％，（B 11）B 2 O 3：0〜2.0重量％，（B2）不含有P 2 O 5，GeO 2，（C 1） + SrO + La2O3 + Lu2O3 + Ta2O5 + Gd2O3 + WO3）：39〜46wt％，（D1）ZnO：4〜16wt％，（E）不含Al2O3，（F） 不含PbO和As2O3，（H1）（Na2O + K2O）：4〜10重量％，（I）Sb2O3：0〜0.050重量％，（J1）（Na2SO4 + K2SO4）：0.32〜0.78重量％。

公开(公告)号：US20130012626A1

公开(公告)日：2013-01-10

申请号：US13636924

申请日：2011-03-22

申请人： Hiroyuki Shimanaka ,  Yoshikazu Murakami ,  Shinichiro Aoyagi ,  Atsushi Goto ,  Yoshinobu Tsujii

发明人： Hiroyuki Shimanaka ,  Yoshikazu Murakami ,  Shinichiro Aoyagi ,  Atsushi Goto ,  Yoshinobu Tsujii

IPC分类号： C08L53/00 ,  C08K5/3415 ,  C08K5/08 ,  C08K5/3417 ,  C08K5/23

CPC分类号： C09B67/009 ,  C08F293/005 ,  C08F2438/00 ,  C08K9/08 ,  C09B67/0008 ,  C09B67/0013 ,  C09D11/037 ,  C09D11/326 ,  C09D17/00

摘要： Disclosed are a resin-treated pigment characterized in that the resin-treated pigment comprises a pigment and a polymer of an unsaturated bond-containing monomer, a weight ratio of the pigment to the polymer (pigment:polymer) is from 50 to 95 to from 5 to 50, and the polymer is a block copolymer comprising from 5 to 70 mass % of an addition-polymerizable monomer having a UV-absorbing group; a production process of the resin-treated pigment; and a pigment dispersion using the resin-treated pigment.

摘要翻译： 公开了一种树脂处理颜料，其特征在于，树脂处理颜料包含颜料和含不饱和键的单体的聚合物，颜料与聚合物（颜料：聚合物）的重量比为50〜95〜 5〜50，聚合物是含有5〜70质量％的具有UV吸收性基团的可加成聚合单体的嵌段共聚物; 树脂处理颜料的制造方法; 和使用树脂处理的颜料的颜料分散体。

公开(公告)号：US20120190795A1

公开(公告)日：2012-07-26

申请号：US13388811

申请日：2010-05-10

申请人： Atsushi Goto ,  Yoshinobu Tsujii ,  Takeshi Fukuda

发明人： Atsushi Goto ,  Yoshinobu Tsujii ,  Takeshi Fukuda

IPC分类号： C08F20/14 ,  C07D257/02 ,  C07C211/05 ,  C07C211/07 ,  C07F9/50 ,  C07C211/14 ,  C07C211/10 ,  C07C211/09 ,  C08F20/18 ,  C08F12/08 ,  C08F20/44 ,  C08F20/26 ,  C08F220/26 ,  C08F20/32 ,  C08F265/06 ,  C07C211/22

CPC分类号： C08F4/40 ,  C08F12/08 ,  C08F120/14 ,  C08F293/005 ,  C08F2438/00

摘要： Provided is a low-cost, highly active, environmentally friendly living radical polymerization catalyst which does not require a radical initiator. An organic compound having an oxidation-reduction capability is used as a catalyst. Even if a radical initiator is not used, a monomer can be subjected to a radical polymerization to obtain a polymer having narrow molecular weight distribution. The cost of the living radical polymerization can be remarkably reduced. It is made possible to prevent adverse effects of using a radical initiator. The present invention is significantly more environmentally friendly and economically excellent than conventional living radical polymerization methods, due to advantages of the catalyst such as low toxicity of the catalyst, low amount of the catalyst necessary, high solubility of the catalyst, mild reaction conditions, and no coloration/no odor (which do not require a post-treatment for a molded article), etc.

摘要翻译： 提供了不需要自由基引发剂的低成本，高活性，环保的活性自由基聚合催化剂。 使用具有氧化还原能力的有机化合物作为催化剂。 即使不使用自由基引发剂，也可以对单体进行自由基聚合，得到分子量分布窄的聚合物。 活性自由基聚合的成本可以显着降低。 可以防止使用自由基引发剂的不利影响。 由于催化剂的优点，催化剂的低毒性，必需的催化剂量低，催化剂的溶解度高，反应条件温和，反应条件好，因此本发明的环保性和经济性优于常规的活性自由基聚合方法。 无着色/无异味（不需要后处理成型品）等

公开(公告)号：US20100298499A1

公开(公告)日：2010-11-25

申请号：US12599270

申请日：2008-05-02

申请人： Atsushi Goto ,  Takeshi Fukuda ,  Yoshinobu Tsujii

发明人： Atsushi Goto ,  Takeshi Fukuda ,  Yoshinobu Tsujii

IPC分类号： C08F2/00 ,  C01B25/10 ,  C01B21/00 ,  C07D207/40 ,  C08F4/00

CPC分类号： C08F4/00 ,  C08F2/38

摘要： A highly active and environment-friendly catalyst for use in a living radical polymerization is provided. A catalyst for use in a living radical polymerization method is provided. The catalyst comprises a central element, which is selected from nitrogen and phosphorus, and at least one halogen atom, which is bound to the central element. A monomer having a radical reactive unsaturated bond is subjected to a radical polymerization reaction in the presence of the catalyst, thereby it is possible to obtain a polymer having narrow molecular weight distribution. The present invention has the merits such as low toxicity of the catalyst, a small amount of the catalyst being required, high solubility of the catalyst in the polymerization media, mild reaction conditions, no coloration, no odor (unnecessary post-treatment of molded products). The method of the present invention is more environment-friendly and economical than other living radical polymerization methods.

摘要翻译： 提供了用于活性自由基聚合的高活性和环境友好的催化剂。 提供了一种用于活性自由基聚合方法的催化剂。 催化剂包含选自氮和磷的中心元素和与中心元素结合的至少一个卤素原子。 具有自由基反应性不饱和键的单体在催化剂的存在下进行自由基聚合反应，从而可以得到分子量分布窄的聚合物。 本发明具有催化剂毒性低，需要少量催化剂，催化剂在聚合介质中溶解性高，反应条件温和，无着色，无异味（不需要后处理成型品等）的优点 ）。 本发明的方法比其它活性自由基聚合方法更环保，更经济。

公开(公告)号：US20090147252A1

公开(公告)日：2009-06-11

申请号：US12330623

申请日：2008-12-09

申请人： Atsushi Goto ,  Hiroaki Kinoshita

发明人： Atsushi Goto ,  Hiroaki Kinoshita

IPC分类号： G01N21/01 ,  G01N21/64

CPC分类号： G01N21/6458 ,  G02B21/16 ,  G02B21/367

摘要： A fluorescence observation or fluorescence metering-system includes a low-fluorescence specimen holding member used therein. The low-fluorescence specimen holding member satisfies a condition, BSG′/BSG≦0.6, where BSG′ is an average intensity value of auto-fluorescence from the low-fluorescence specimen holding member and BSG is an average intensity value of auto-fluorescence from a conventional specimen holding member generally used.

摘要翻译： 荧光观察或荧光计量系统包括其中使用的低荧光样品保持构件。 低荧光样品保持构件满足条件BSG'/ BSG <= 0.6，其中BSG'是来自低荧光样品保持构件的自发荧光的平均强度值，BSG是自发荧光的平均强度值 通常使用的常规样品保持构件。

公开(公告)号：US07311204B2

公开(公告)日：2007-12-25

申请号：US11411069

申请日：2006-04-26

申请人： Yasuhiro Nishi ,  Atsushi Goto ,  Taiji Watanabe

发明人： Yasuhiro Nishi ,  Atsushi Goto ,  Taiji Watanabe

IPC分类号： B65D81/02

CPC分类号： B31D5/0073 ,  B65B55/20 ,  B65D81/052 ,  B65D81/058

摘要： A packing member for packing an article, includes a medium accommodating portion for accommodating medium; a non-return valve for passing the medium to the medium accommodating portion and stopping the medium away from the medium accommodating portion; an introducing portion for introducing the medium into the medium accommodating portion with the non-return valve from an outside of the packing member to balloon the medium accommodating portion; and a sealing region, disposed upstream of the non-return valve with respect to a direction of the introduction of the medium from the introducing portion toward the non-return valve, for sealing against the introduction of the medium to prevent leakage from the introducing portion to an outside of the packing member, the sealing region being sealed to keep the medium in the medium accommodating portion.

摘要翻译： 一种用于包装物品的包装件，包括用于容纳介质的介质容纳部分; 用于将介质传送到介质容纳部分并使介质停止于介质容纳部分的止回阀; 引导部分，用于将介质从打包构件的外部引导到具有止回阀的介质容纳部分中以使介质容纳部分气球; 以及密封区域，其设置在所述止回阀的上游侧，所述密封区域相对于介质从所述引入部朝向所述止回阀的方向引入，用于密封所述介质的引入，以防止从所述引入部分泄漏 到密封部件的外部，密封区域被密封以将介质保持在介质容纳部分中。

公开(公告)号：US20070049715A1

公开(公告)日：2007-03-01

申请号：US11459370

申请日：2006-07-24

申请人： Atsushi Goto ,  Takeshi Fukuda ,  Yoshinobu Tsujii

发明人： Atsushi Goto ,  Takeshi Fukuda ,  Yoshinobu Tsujii

IPC分类号： C08F112/02 ,  B01J27/135 ,  B01J27/06 ,  B01J31/00

CPC分类号： B01J31/122 ,  B01J31/22 ,  B01J2531/42 ,  B01J2531/52 ,  C08F112/08 ,  C08F220/14

摘要： A highly active and environment-friendly catalyst for use in a living radical polymerization is provided. A catalyst for use in a living radical polymerization method is provided. The catalyst comprises a central element, which is selected from germanium, tin and antimony, and at least one halogen atom, which is bound to the central element. A monomer having a radical reactive unsaturated bond is subjected to a radical polymerization reaction under the presence of the catalyst, thereby it is possible to obtain a polymer having narrow molecular weight distribution. The present invention has the merits such as low toxicity of the catalyst, a small amount of the catalyst can be used, high solubility of the catalyst, mild reaction conditions, no coloration, no odor (unnecessary post-treatment of molded products). The method of the present invention is more environment-friendly and economical than a conventional living radical polymerization method.

摘要翻译： 提供了用于活性自由基聚合的高活性和环境友好的催化剂。 提供了一种用于活性自由基聚合方法的催化剂。 该催化剂包括选自锗，锡和锑的中心元素和与中心元素结合的至少一个卤素原子。 具有自由基反应性不饱和键的单体在催化剂的存在下进行自由基聚合反应，从而可以得到分子量分布窄的聚合物。 本发明具有催化剂毒性低，可使用少量催化剂，催化剂溶解性高，反应条件温和，无着色，无异味（成型品不必要后处理）等优点。 本发明的方法比常规的活性自由基聚合方法更环保且更经济。