Nitride crystal substrate and method for manufacturing the same

    公开(公告)号:US12104279B2

    公开(公告)日:2024-10-01

    申请号:US17649983

    申请日:2022-02-04

    Abstract: There is provided a nitride crystal substrate constituted by group-III nitride crystal, containing n-type impurities, with an absorption coefficient α being approximately expressed by equation (1) by a least squares method in a wavelength range of at least 1 μm or more and 3.3 μm or less.








    α
    =


    N
    e


    K


    λ
    a




    (



    where

    1.5
    ×

    10

    -
    19




    K


    6.
    ×

    10

    -
    19




    ,

    a
    =
    3


    )



    ,




    (
    1
    )









    here, a wavelength is λ (μm), an absorption coefficient of the nitride crystal substrate at 27° C. is α (cm−1), a carrier concentration in the nitride crystal substrate is Ne (cm−3), and K and a are constants, wherein an error of an actually measured absorption coefficient with respect to the absorption coefficient α obtained from equation (1) at a wavelength of 2 μm is within +0.1α, and in a reflection spectrum measured by irradiating the nitride crystal substrate with infrared light, there is no peak with a peak top within a wavenumber range of 1,200 cm−1 or more and 1,500 cm−1 or less.

    N-CO-doped semiconductor substrate

    公开(公告)号:US11990335B2

    公开(公告)日:2024-05-21

    申请号:US17415921

    申请日:2019-12-18

    Abstract: A process for fabricating a single-crystal semiconductor material of group 13 nitride, in particular GaN, including the steps of:



    deposition of at least one single-crystal layer by three-dimensional epitaxial growth on a starting substrate, the layer including areas resulting from the growth of basal facets, and areas resulting from the growth of facets of different orientations, called non-basal facets;
    supply of an n-dopant gas including a first chemical element selected from the chemical elements of group 16 of the periodic table, and at least one second chemical element selected from the chemical elements of group 14 of the periodic table, such that the concentration of the second element in the areas resulting from the growth of the basal facets is higher than 1.0×1017/cm3, and the concentration of the first element in the areas resulting from the growth of the non-basal facets is lower than 2.0×1018/cm3.

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