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    Substituted tricyclodecane derivatives, processes for producing same and organoleptic uses thereof
    3.
    发明授权
    Substituted tricyclodecane derivatives, processes for producing same and organoleptic uses thereof 失效
    取代的三环癸烷衍生物，其制备方法和感官用途

    公开(公告)号：US4275251A

    公开(公告)日：1981-06-23

    申请号：US144898

    申请日：1980-04-29

    Applicant: Mark A. Sprecker ,  John B. Hall

    Inventor： Mark A. Sprecker ,  John B. Hall

    IPC: C07C69/03 ,  A23L27/20 ,  A24B3/12 ,  A24B15/34 ,  A61K8/34 ,  A61K8/35 ,  A61K8/37 ,  A61Q13/00 ,  C07C27/00 ,  C07C29/09 ,  C07C29/10 ,  C07C29/17 ,  C07C29/70 ,  C07C35/37 ,  C07C35/46 ,  C07C41/00 ,  C07C41/06 ,  C07C43/188 ,  C07C45/00 ,  C07C45/29 ,  C07C49/643 ,  C07C67/00 ,  C07C67/04 ,  C11B9/00 ,  C07C35/22

    CPC classification number: C07C29/172 ,  A24B15/345 ,  C07C29/095 ,  C07C29/17 ,  C07C29/70 ,  C07C35/37 ,  C07C35/46 ,  C07C45/29 ,  C07C49/643 ,  C11B9/0042 ,  C07C2103/68

    Abstract: Described are substituted tricyclodecane derivatives having the generic structure: ##STR1## wherein Y is a moiety having a structure selected from the group consisting of: ##STR2## wherein one of the dashed lines represents a carbon-carbon single bond and the other of the dashed lines represents a carbon-carbon double bond; wherein R.sub.1 and R.sub.2 represent hydrogen or methyl with the proviso that one of R.sub.1 and R.sub.2 is hydrogen and the other of R.sub.1 and R.sub.2 is methyl; wherein R.sub.3 is hydrogen, C.sub.1 -C.sub.3 acyl, C.sub.3 or C.sub.4 alkyl or C.sub.3 or C.sub.4 alkenyl; wherein R.sub.4, R.sub.5 and R.sub.6 represent hydrogen or methyl with the additional proviso that one of R.sub.4, R.sub.5 and R.sub.6 is methyl and the other two of R.sub.4, R.sub.5 and R.sub.6 is hydrogen. Also described are processes for preparing such substituted tricyclodecane derivatives and processes for using the above defined substituted tricyclodecane derivatives for their organoleptic properties and compositions containing said substituted tricyclodecane derivatives including perfumes, perfumed articles, such as solid or liquid anionic, cationic, nonionic and zwitterionic detergents, fabric softeners and cosmetic powders; foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos; smoking tobacco compositions and smoking tobacco flavoring compositions and smoking tobacco articles containing such smoking tobacco compositions.

    Abstract translation: 描述了具有以下通用结构的取代的三环癸烷衍生物：其中Y是具有选自以下的结构的部分：其中一条虚线表示碳 - 碳单键，另一条为虚线 线代表碳 - 碳双键; 其中R1和R2表示氢或甲基，条件是R1和R2之一是氢，R1和R2中的另一个是甲基; 其中R3是氢，C1-C3酰基，C3或C4烷基或C3或C4链烯基; 其中R4，R5和R6代表氢或甲基，另外条件是R4，R5和R6之一是甲基，R4，R5和R6中的另外两个是氢。 还描述了制备这种取代的三环癸烷衍生物的方法和使用上述定义的取代的三环癸烷衍生物的感官特性的方法和含有所述取代的三环癸烷衍生物的组合物，包括香料，加香制品如固体或液体阴离子，阳离子，非离子和两性离子洗涤剂 ，织物柔软剂和化妆粉; 食品，口香糖，牙膏，药用产品和咀嚼烟草; 吸烟烟草组合物和吸烟烟草调味组合物和含有烟草烟草组合物的烟草制品。

    Apparatus for contacting solids in the form of freeflowing lumps with liquids or gases
    4.
    发明授权
    Apparatus for contacting solids in the form of freeflowing lumps with liquids or gases 失效
    用于将液体或气体以自由流动的块形式的固体接触的装置

    公开(公告)号：US6017499A

    公开(公告)日：2000-01-25

    申请号：US809209

    申请日：1997-03-10

    Applicant: Gert Albert

    Inventor： Gert Albert

    IPC: B01J8/38 ,  B01J8/10 ,  B01J19/28 ,  C07B41/02 ,  C07C29/70 ,  C07C31/32 ,  C07C35/46 ,  C07C37/66 ,  C07C39/44 ,  B01J7/02

    CPC classification number: B01J8/10 ,  B01J19/28 ,  C07C29/70 ,  B01J2208/00132 ,  B01J2208/00274 ,  B01J2208/0053 ,  B01J2219/00081 ,  B01J2219/00108 ,  B01J2219/00159 ,  B01J2219/182

    Abstract: The invention is directed to an apparatus for contacting in a reactor solids in the form of free-flowing lumps with liquids or for contacting solids with liquids and gases by bringing the reactants into contact with each other, said reactor comprising a housing containing a screen in the area of which contacting takes place whereinthe screen is a rotary screen drum 5,the screen drum 5 rotates in a bottom vat during the operation, said vat holding a gaseous or liquid medium reacting with the solids, andthe bottom vat 10 can be lowered such that the solids in the screen drum 5 and the medium in the bottom vat 10 can be separated from each other whenever it is desired to alter or interrupt the chemical reaction or physical process.

    Abstract translation: PCT No.PCT / DE95 / 01552 Sec。 371日期1997年3月10日 102（e）1997年3月10日PCT 1995年11月4日PCT PCT。 公开号WO96 / 14150 PCT 日期1996年5月17日本发明涉及一种用于使反应器中的自由流动团块形式的固体与液体接触或通过使反应物彼此接触而使固体与液体和气体接触的装置，所述反应器包括壳体 在其中屏幕是旋转筛筒5的情况下进行接触的区域中的筛网，筛筒5在操作期间在底槽中旋转，所述槽保持与固体反应的气态或液体介质，底部 可以降低桶10，使得当期望改变或中断化学反应或物理过程时，筛筒5中的固体和底槽10中的介质可以彼此分离。

    Substituted tricyclodecane derivatives, processes for producing same and organoleptic uses thereof
    5.
    发明授权
    Substituted tricyclodecane derivatives, processes for producing same and organoleptic uses thereof 失效

    公开(公告)号：US4418010A

    公开(公告)日：1983-11-29

    申请号：US456979

    申请日：1983-01-10

    Applicant: Mark A. Sprecker ,  John B. Hall

    Inventor： Mark A. Sprecker ,  John B. Hall

    IPC: A24B15/34 ,  C07C29/09 ,  C07C29/17 ,  C07C29/70 ,  C07C35/37 ,  C07C35/46 ,  C07C45/29 ,  C11B9/00

    CPC classification number: C11B9/0042 ,  A24B15/345 ,  C07C29/095 ,  C07C29/172 ,  C07C29/70 ,  C07C35/37 ,  C07C35/46 ,  C07C45/29 ,  C07C2102/42

    Abstract: Described are substituted tricyclodecane derivatives having the generic structure: ##STR1## wherein Y is a moiety having a structure selected from the group consisting of: ##STR2## wherein one of the dashed lines represents a carbon-carbon single bond and the other of the dashed lines represents a carbon-carbon double bond; wherein R.sub.1 and R.sub.2 represent hydrogen or methyl with the proviso that one of R.sub.1 and R.sub.2 is hydrogen and the other of R.sub.1 and R.sub.2 is methyl; wherein R.sub.3 is hydrogen, C.sub.1 -C.sub.3 acyl, C.sub.3 or C.sub.4 alkyl or C.sub.3 or C.sub.4 alkenyl; wherein R.sub.4, R.sub.5 and R.sub.6 represent hydrogen or methyl with the additional proviso that one of R.sub.4, R.sub.5 and R.sub.6 is methyl and the other two of R.sub.4, R.sub.5 and R.sub.6 is hydrogen. Also described are processes for preparing such substituted tricyclodecane derivatives and processes for using the above defined substituted tricyclodecane derivatives for their organoleptic properties and compositions containing said substituted tricyclodecane derivatives including perfumes, perfumed articles, such as solid or liquid anionic, cationic, nonionic and zwitterionic detergents, fabric softeners and cosmetic powders; foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos; smoking tobacco compositions and smoking tobacco flavoring compositions and smoking tobacco articles containing such smoking tobacco compositions.

    Substituted tricyclodecane derivatives, processes for producing same and organoleptic uses thereof
    6.
    发明授权
    Substituted tricyclodecane derivatives, processes for producing same and organoleptic uses thereof 失效

    公开(公告)号：US4386023A

    公开(公告)日：1983-05-31

    申请号：US335564

    申请日：1981-12-29

    Applicant: Mark A. Sprecker ,  John B. Hall

    Inventor： Mark A. Sprecker ,  John B. Hall

    IPC: A24B15/34 ,  C07C29/09 ,  C07C29/17 ,  C07C29/70 ,  C07C35/37 ,  C07C35/46 ,  C07C45/29 ,  C07C49/643 ,  C11B9/00 ,  A61K7/00

    CPC classification number: C11B9/0042 ,  A24B15/345 ,  C07C29/095 ,  C07C29/172 ,  C07C29/70 ,  C07C35/37 ,  C07C35/46 ,  C07C45/29 ,  C07C49/643 ,  C07C2103/60 ,  C07C2103/66

    Abstract: Described are substituted tricyclodecane derivatives having the generic structure: ##STR1## wherein Y is a moiety having a structure selected from the group consisting of: ##STR2## wherein one of the dashed lines represents a carbon-carbon single bond and the other of the dashed lines represents a carbon-carbon double bond; wherein R.sub.1 and R.sub.2 represent hydrogen or methyl with the proviso that one of R.sub.1 and R.sub.2 is hydrogen and the other of R.sub.1 and R.sub.2 is methyl; wherein R.sub.3 is hydrogen, C.sub.1 -C.sub.3 acyl, C.sub.3 or C.sub.4 alkyl or C.sub.3 or C.sub.4 alkenyl; wherein R.sub.4, R.sub.5 and R.sub.6 represent hydrogen or methyl with the additional proviso that one of R.sub.4, R.sub.5 and R.sub.6 is methyl and the other two of R.sub.4, R.sub.5 and R.sub.6 is hydrogen. Also described are processes for preparing such substituted tricyclodecane derivatives and processes for using the above defined substituted tricyclodecane derivatives for their organoleptic properties and compositions containing said substituted tricyclodecane derivatives including perfumes, perfumed articles, such as solid or liquid anionic, cationic, nonionic and zwitterionic detergents, fabric softeners and cosmetic powders; foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos; smoking tobacco compositions and smoking tobacco flavoring compositions and smoking tobacco articles containing such smoking tobacco compositions.

    Method for producing scyllo-inositol
    8.
    发明授权
    Method for producing scyllo-inositol 有权
    鲨肌醇的制备方法

    公开(公告)号：US07745671B2

    公开(公告)日：2010-06-29

    申请号：US10576030

    申请日：2004-10-14

    Applicant: Masanori Yamaguchi ,  Yuichi Kita ,  Tetsuya Mori ,  Kenji Kanbe ,  Akihiro Tomoda ,  Atsushi Takahashi ,  Wakako Ichikawa

    Inventor： Masanori Yamaguchi ,  Yuichi Kita ,  Tetsuya Mori ,  Kenji Kanbe ,  Akihiro Tomoda ,  Atsushi Takahashi ,  Wakako Ichikawa

    IPC: C07C35/16 ,  C07H1/06 ,  C07C35/46

    CPC classification number: C12P7/02 ,  C07C29/145 ,  C12N9/0004 ,  C12N9/0006 ,  C12P7/18 ,  C12P7/26

    Abstract: It is intended to provide a novel NAD+-independent myo-inositol 2-dehydrogenase which converts myo-inositol into scyllo-inosose in the absence of NAD+; a novel enzyme scyllo-inositol dehydrogenase which stereospecifically reduces scyllo-inosose into scyllo-inositol in the presence of NADH or NADPH; and a novel microorganism which belongs to the genus Acetobacter or Burkholderia and can convert myo-inositol into scyllo-inositol. By using these enzymes or the microorganism, scyllo-inositol is produced. Furthermore, scyllo-inositol is purified by adding boric acid and a metal salt to a liquid mixture containing scyllo-inositol and a neutral saccharide other than scyllo-inositol to form a scyllo-inositol/boric acid complex, separating the complex from the liquid mixture, dissolving the thus separated complex in an acid to give an acidic solution or an acidic suspension and then purifying scyllo-inositol from the acidic solution or the acidic suspension.

    Abstract translation: 旨在提供一种新的NAD +独立肌醇2-脱氢酶，其在不存在NAD +的情况下将肌醇转化为鲨肌内糖; 在NADH或NADPH的存在下，立体选择性地将鲨肌内糖降解成鲨肌醇的新型鲨肌醇肌醇脱氢酶; 和属于醋杆菌属或伯克霍尔德氏菌属的新型微生物，可将肌醇转化为鲨肌醇。 通过使用这些酶或微生物，产生鲨肌醇。 此外，通过向含有鲨肌醇和除了鲨肌醇之外的中性糖的液体混合物中加入硼酸和金属盐以形成鲨肌醇/硼酸络合物，将所述络合物与液体混合物分离，将鲨肌醇纯化 将如此分离的络合物溶解在酸中，得到酸性溶液或酸性悬浮液，然后从酸性溶液或酸性悬浮液中纯化鲨肌醇。

    Substituted tricyclodecane derivatives, processes for producing same and organoleptic uses thereof
    10.
    发明授权
    Substituted tricyclodecane derivatives, processes for producing same and organoleptic uses thereof 失效

    公开(公告)号：US4337212A

    公开(公告)日：1982-06-29

    申请号：US305470

    申请日：1981-09-25

    Applicant: Mark A. Sprecker ,  John B. Hall

    Inventor： Mark A. Sprecker ,  John B. Hall

    IPC: A24B15/34 ,  C07C29/09 ,  C07C29/17 ,  C07C29/70 ,  C07C35/37 ,  C07C35/46 ,  C07C45/29 ,  C07C49/643 ,  C11B9/00 ,  C07C69/96

    CPC classification number: C11B9/0042 ,  A24B15/345 ,  C07C29/095 ,  C07C29/17 ,  C07C29/70 ,  C07C35/37 ,  C07C35/46 ,  C07C45/29 ,  C07C49/643 ,  C07B2200/07 ,  C07C2103/68

    Abstract: Described are substituted tricyclodecane derivatives having the generic structure: ##STR1## wherein Y is a moiety having a structure selected from the group consisting of: ##STR2## wherein one of the dashed lines represents a carbon-carbon single bond and the other of the dashed lines represents a carbon-carbon double bond; wherein R.sub.1 and R.sub.2 represent hydrogen or methyl with the proviso that one of R.sub.1 and R.sub.2 is hydrogen and the other of R.sub.1 and R.sub.2 is methyl; wherein R.sub.3 is hydrogen, C.sub.1 -C.sub.3 acyl, C.sub.3 or C.sub.4 alkyl or C.sub.3 or C.sub.4 alkenyl; wherein R.sub.4, R.sub.5 and R.sub.6 represent hydrogen or methyl with the additional proviso that one of R.sub.4, R.sub.5 and R.sub.6 is methyl and the other two of R.sub.4, R.sub.5 and R.sub.6 is hydrogen. Also described are processes for preparing such substituted tricyclodecane derivatives and processes for using the above defined substituted tricyclodecane derivatives for their organoleptic properties and compositions containing said substituted tricyclodecane derivatives including perfumes, perfumed articles, such as solid or liquid anionic, cationic, nonionic and zwitterionic detergents, fabric softeners and cosmetic powders; foodstuffs, chewing gums, toothpastes, medicinal products and chewing tobaccos; smoking tobacco compositions and smoking tobacco flavoring compositions and smoking tobacco articles containing such smoking tobacco compositions.

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