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    Acid-catalyzed organic compound conversion
    1.
    发明授权
    Acid-catalyzed organic compound conversion 失效
    酸催化有机化合物转化

    公开(公告)号：US4605803A

    公开(公告)日：1986-08-12

    申请号：US787183

    申请日：1985-10-15

    Applicant: Clarence D. Chang ,  Joseph N. Miale

    Inventor： Clarence D. Chang ,  Joseph N. Miale

    IPC: B01J29/40 ,  B01J29/65 ,  B01J29/70 ,  C07C1/20 ,  C07C1/253

    CPC classification number: B01J29/40 ,  B01J29/65 ,  B01J29/70

    Abstract: This invention relates to acid catalysis of organic compound feedstock, e.g. conversion of oxygenates to hydrocarbons, over catalyst material treated in a special way for increasing the acid catalytic activity thereof. In particular, a novel catalyst activation process is followed to enhance the alpha value of high-silica zeolite catalyst by contact with an ammoniacal solution of an alkali metal aluminate under appropriate conditions of time, temperature and pH.

    Abstract translation: 本发明涉及有机化合物原料的酸催化，例如 在特定方式处理的催化剂材料中，含氧化合物转化为烃类，以增加其酸催化活性。 特别地，遵循新的催化剂活化方法，以通过在合适的时间，温度和pH条件下与碱金属铝酸盐的氨溶液接触来增强高硅石沸石催化剂的α值。

    Oxydehydrogenation process
    4.
    发明授权
    Oxydehydrogenation process 失效
    氧化氢化过程

    公开(公告)号：US4471146A

    公开(公告)日：1984-09-11

    申请号：US463436

    申请日：1983-02-03

    Applicant: Gary R. Strickler

    Inventor： Gary R. Strickler

    IPC: C07C5/48 ,  C07C4/02 ,  C07C1/253

    CPC classification number: C07C5/48

    Abstract: Prepare vinyl aromatic compounds in a fluidized bed by oxydehydrogenation in the presence of an alkaline earth metal-nickel phosphate catalyst.

    Abstract translation: 在碱土金属 - 镍磷酸盐催化剂存在下，通过氧化脱氢在流化床中制备乙烯基芳族化合物。

    Process for the production of dienes from aldehydes
    7.
    发明授权
    Process for the production of dienes from aldehydes 失效
    从醛生产二烯的方法

    公开(公告)号：US4524233A

    公开(公告)日：1985-06-18

    申请号：US649236

    申请日：1984-09-10

    Applicant: Wen-Liang Hsu ,  Neil A. Maly ,  Barry A. Matrana ,  Robert W. Strozier ,  Lawson G. Wideman

    Inventor： Wen-Liang Hsu ,  Neil A. Maly ,  Barry A. Matrana ,  Robert W. Strozier ,  Lawson G. Wideman

    IPC: C07C11/18 ,  B01J27/00 ,  B01J27/16 ,  C07B61/00 ,  C07C1/00 ,  C07C1/207 ,  C07C1/24 ,  C07C11/00 ,  C07C11/12 ,  C07C67/00 ,  C07C1/20 ,  C07C1/253

    CPC classification number: C07C1/24 ,  B01J27/16 ,  C07C2527/167

    Abstract: This invention is directed to a process for the conversion of an aldehyde to a diolefin comprising contacting an aldehyde of 4 to 6 carbon atoms in the vapor phase at a temperature of 300.degree. to 400.degree. C. with a catalyst comprising boron phosphate wherein the initial molar ratio of phosphorous (P) to boron (B) (P/B) is less than 1.0 but greater than 0.6 which is in intimate admixture with from 0.1 to 10 weight percent graphite. More specifically, this invention is concerned with a process for the catalytic dehydration of 2-methylbutanal (2MBA) to isoprene in the vapor phase with a boron phosphate catalyst wherein the improvement comprises the use of a catalyst with a molar ratio of P/B of less than 1.0 but greater than 0.6 which contains from 0.1 to 10 weight percent graphite and 0 to 10 mole percent, based on moles of boron, of ammonia or an amine selected from the group consisting of mono-, di- and/or tri- alkyl amines of 1 to 10 carbon atoms.

    Abstract translation: 本发明涉及一种将醛转化为二烯烃的方法，其包括在300-400℃的温度下，将气相中4至6个碳原子的羰基与包含磷酸二氢钾的催化剂接触，其中初始 磷（P）与硼（B）的摩尔比（P / B）小于1.0但大于0.6，与0.1至10重量％的石墨紧密混合。 更具体地说，本发明涉及使用磷酸三乙酯催化剂在气相中将2-甲基丁醛（2MBA）催化脱水成异戊二烯的方法，其中改进包括使用摩尔比P / B为 小于1.0但大于0.6，其含有0.1至10重量百分比的石墨和0至10摩尔％，以硼的摩尔数为基准，氨或选自单 - ，二 - 和/或三 - 1至10个碳原子的烷基胺。

    Method of producing ethynyl aromatic compounds
    9.
    发明授权
    Method of producing ethynyl aromatic compounds 失效
    制备乙炔基芳族化合物的方法

    公开(公告)号：US4665246A

    公开(公告)日：1987-05-12

    申请号：US588087

    申请日：1984-03-09

    Applicant: Chris Anderson

    Inventor： Chris Anderson

    IPC: C07C15/48 ,  C07C15/50 ,  C07C33/46 ,  C07C45/46 ,  C07C49/80 ,  C07C49/813 ,  C07C13/00 ,  C07C1/253 ,  C07C1/26 ,  C07C1/30 ,  C07C15/00 ,  C07C15/12

    CPC classification number: C07C49/80 ,  C07C15/48 ,  C07C15/50 ,  C07C33/46 ,  C07C45/46 ,  C07C49/813

    Abstract: The process of producing ethynyl aromatic compounds which are useful as intermediates in the preparation of 3-dimensional carbon-carbon structures for aerospace and military applications and as starting materials in the preparation of organic semi-conductors. The ethynyl aromatic compounds may be any of the classes illustrated in FIGS. 1, 2 and 3 of the drawing. Starting compounds for the process may by any compound from the classes illustrated in FIGS. 4, 5 and 6. The starting compound is reacted in the presence of a Friedel-Crafts catalyst in a suitable solvent with an acyl compound from the class illustrated in FIG. 7 to yield a compound within the classes illustrated in FIGS. 8, 9 and 10. The carbonyl groups in this compound are reduced to yield a corresponding alcohol. Each hydroxy group in the alcohol is converted to an easily eliminatable group, e.g., by reacting it with methane sulfonyl chloride, when subjected to basic conditions. The chlorine and the easily eliminatable groups are then eliminated under basic conditions to yield the desired ethynyl aromatic compound.Illustrative examples of products produced by the process of the invention include 4-4'-diethynyldiphenyl methane; 1,2-(4,4'-diethynyldiphenyl) ethane; 1,1-(4,4'-diethynyldiphenyl) ethane; tris(4-ethynyl phenyl) methane; 4-ethynyl toluene; 2,2'-(4,4'-diethynyldiphenyl) propane; and 4-ethynyl biphenyl.

    Abstract translation: 制造乙炔芳族化合物的方法，其可用作制备用于航空航天和军事应用的三维碳 - 碳结构的中间体，并且作为制备有机半导体的起始材料。 乙炔基芳族化合物可以是图1和图2所示的任何一种。 图1,2和3。 用于该方法的起始化合物可以由图1至图6所示的任何化合物进行。 在Friedel-Crafts催化剂存在下，在合适的溶剂中使起始化合物与图1所示的酰基化合物反应。 以产生图1和图2所示的类别的化合物。 8,9和10.将该化合物中的羰基还原，得到相应的醇。 当经受基本条件时，醇中的每个羟基被转化成易消除的基团，例如通过使其与甲磺酰氯反应。 然后在碱性条件下除去氯和易消除的基团，得到所需的乙炔基芳族化合物。 通过本发明方法生产的产品的说明性实例包括4-4'-二乙炔基二苯基甲烷; 1,2-（4,4'-二乙炔基二苯基）乙烷; 1,1-（4,4'-二乙炔基二苯基）乙烷; 三（4-乙炔基苯基）甲烷; 4-乙炔基甲苯; 2,2' - （4,4'-二乙炔基二苯基）丙烷; 和4-乙炔基联苯。

    Preparation of aliphatic carboxylic acid esters
    10.
    发明授权
    Preparation of aliphatic carboxylic acid esters 失效
    脂肪族羧酸酯的制备

    公开(公告)号：US4510320A

    公开(公告)日：1985-04-09

    申请号：US334484

    申请日：1981-12-24

    Applicant: Frederick A. Pesa ,  Anne M. Graham

    Inventor： Frederick A. Pesa ,  Anne M. Graham

    IPC: C07C67/36 ,  C07C69/14 ,  C07C1/06 ,  C07C1/253 ,  C07C9/04 ,  C07C9/06 ,  C07C9/08

    CPC classification number: C07C67/36 ,  C07C69/14

    Abstract: A process is provided for the production of aliphatic acetate esters and gaseous alkanes comprising contacting acetic acid and synthesis gas in the vapor phase at elevated temperature and pressure in the presence of a catalyst containing the mixed oxides of ruthenium and nickel, and optionally an alkali metal oxide and the oxides of cobalt, cadmium, zinc or mixtures thereof. Other carboxylic acids may be substituted for acetic acid as desired.

    Abstract translation: 提供了一种生产脂肪族乙酸酯和气态烷烃的方法，包括在含有钌和镍的混合氧化物的催化剂存在下，在升高的温度和压力下，使蒸气相中的乙酸和合成气，以及任选的碱金属 氧化物和钴，镉，锌的氧化物或其混合物。 其它羧酸可根据需要代替乙酸。

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