公开(公告)号：US4564715A

公开(公告)日：1986-01-14

申请号：US663828

申请日：1984-10-23

Applicant: John R. Briggs ,  George L. O'Connor ,  John H. Robson

Inventor： John R. Briggs ,  George L. O'Connor ,  John H. Robson

IPC: C07C29/10 ,  C07C31/20 ,  C07C33/035 ,  C07C33/26 ,  C07C35/14

CPC classification number: C07C29/106

Abstract: High selectivity to monoalkylene glycol is obtained by contacting in an associated moiety-forming zone alkylene oxide and a selectivity enhancing, dissociatable metalate anion under conditions sufficient to associate at least a portion of the alkylene oxide with metalate anion, and then contacting the associated moiety with water in a glycol-forming zone to form alkylene glycol. The alkylene glycol can be separated from metalate anion. Desirably, the metalate anion can be recycled to the associated moiety-forming zone.

Abstract translation: 单亚烷基二醇的高选择性是通过在足以使至少一部分环氧烷与金属盐阴离子缔合的条件下，在相关的部分形成区烯化氧和选择性增强的可离解的金属化合物阴离子中接触获得的，然后使相关部分与 在形成乙二醇的区域中形成亚烷基二醇。 亚烷基二醇可以与金属盐阴离子分离。 理想地，金属盐阴离子可以再循环到相关的部分形成区。

公开(公告)号：US4429057A

公开(公告)日：1984-01-31

申请号：US412033

申请日：1982-08-26

Applicant: Bernard D. Dombek ,  George L. O'Connor

Inventor： Bernard D. Dombek ,  George L. O'Connor

IPC: C01G55/00 ,  C07C29/157 ,  C07C27/06

CPC classification number: C07C29/157 ,  C01G55/008

Abstract: A homogeneous catalytic process wherein a gaseous or vaporized reactant stream is continuously introduced into a liquid phase mixture containing (a) a volatile precious metal catalyst, and (b) methanol and/or ethanol as reactant or reaction product, at least a portion of the volatile precious metal being continuously removed from the liquid phase mixture by the effluent gas and/or vapor stream, and such effluent stream is an integral component of a cyclic process stream and/or a vent stream discharged from the process. The improvement is concerned with recovery of the volatilized precious metal and returning it to the liquid phase mixture which comprises passing one or both of said cyclic or vent streams through a liquid body of alcohol selected from the group consisting of methanol, ethanol and mixtures thereof at a temperature sufficiently low to effect the removal of at least a portion of the precious metal contained in said stream, and thereafter periodically or continuously introducing to the liquid phase mixture at least a portion of said liquid body containing the recovered precious metal.

Abstract translation: 一种均相催化方法，其中将气态或蒸发的反应物流连续引入含有（a）挥发性贵金属催化剂和（b）甲醇和/或乙醇作为反应物或反应产物的液相混合物中，至少一部分 挥发性贵金属通过流出气体和/或蒸汽流从液相混合物中连续除去，并且这种流出物流是循环过程流和/或从该过程排出的排放流的整体组分。 该改进涉及挥发的贵金属的回收并将其返回到液相混合物，其包括使所述循环或排出物流中的一个或两个通过选自甲醇，乙醇及其混合物的醇的液体体， 温度足够低以实现除去所述料流中所含的至少一部分贵金属，然后周期地或连续地向液相混合物中引入含有回收的贵金属的所述液体的至少一部分。

公开(公告)号：US4246186A

公开(公告)日：1981-01-20

申请号：US650799

申请日：1976-01-20

Applicant: Madan M. Bhasin ,  George L. O'Connor

Inventor： Madan M. Bhasin ,  George L. O'Connor

IPC: C07C29/151 ,  C07C29/157 ,  C07C29/158 ,  C07C45/49 ,  C07C51/10 ,  C07C27/06

CPC classification number: C07C45/49 ,  C07C29/1512 ,  C07C29/157 ,  C07C29/158 ,  C07C51/10

Abstract: A process for the selective preparation of two-carbon atom oxygenated hydrocarbons, namely acetic acid, ethanol, and acetaldehyde, by continuously contacting a reaction mixture containing hydrogen and carbon monoxide with a rhodium metal catalyst, at a combination of reaction conditions correlated so as to favor the formation of a substantial proportion of these products.

Abstract translation: 通过连续地将含有氢和一氧化碳的反应混合物与铑金属催化剂连续接触，通过反应条件的组合将二碳原子氧化烃，即乙酸，乙醇和乙醛的选择性制备方法相关联，以便 有利于形成相当比例的这些产品。

公开(公告)号：US5162578A

公开(公告)日：1992-11-10

申请号：US61150

申请日：1987-06-12

Applicant: James H. McCain, Jr. ,  Steven W. Kaiser ,  George L. O'Connor

Inventor： James H. McCain, Jr. ,  Steven W. Kaiser ,  George L. O'Connor

IPC: C07B61/00 ,  B01J23/28 ,  B01J23/31 ,  B01J23/88 ,  C07C51/00 ,  C07C51/215 ,  C07C51/25 ,  C07C53/08 ,  C07C67/00

CPC classification number: C07C51/215 ,  B01J23/28 ,  C07C51/25 ,  B01J2523/00 ,  Y02P20/582

Abstract: A process for the higher selective production of acetic acid by the catalytic oxidation with oxygen of ethane, or ethylene, or mixtures thereof, in contact with a mixed catalyst composition containing (A) a calcined mixed oxides catalyst of the formula:Mo.sub.x V.sub.y Z.sub.zwherein Z represents nothing or a metal from a group of metals as hereinafter defined and (B) is an ethylene hydration catalyst and/or an ethylene oxidation catalyst.

公开(公告)号：US4734538A

公开(公告)日：1988-03-29

申请号：US946483

申请日：1986-12-24

Applicant: George L. O'Connor ,  Steven W. Kaiser ,  James H. McCain

Inventor： George L. O'Connor ,  Steven W. Kaiser ,  James H. McCain

IPC: C07B61/00 ,  B01J29/04 ,  B01J29/83 ,  B01J29/84 ,  B01J29/85 ,  C01B25/45 ,  C01B37/06 ,  C01B37/08 ,  C01B39/10 ,  C01B39/12 ,  C01B39/54 ,  C07C1/00 ,  C07C1/24 ,  C07C11/18 ,  C07C67/00 ,  C07C1/253

CPC classification number: C07C1/24 ,  C07C2529/85

Abstract: Aldehydes can be converted to dienes by contacting the aldehydes with a non-zeolitic molecular sieve. Preferably the non-zeolitic molecular sieve has, in its calcined form, an adsorption of isobutane of at least about 2 percent by weight of the non-zeolitic molecular sieve at a partial pressure of 500 torr and a temperature of 20.degree. C. The non-zeolitic molecular sieves can achieve good conversion rates and selectivities for the reaction. The reaction is especially useful for the conversion of 2-methylbutyraldehyde to isoprene.

公开(公告)号：US4485822A

公开(公告)日：1984-12-04

申请号：US461878

申请日：1983-01-28

Applicant: George L. O'Connor ,  Ralph E. Oswald ,  Marc A. Heppding

Inventor： George L. O'Connor ,  Ralph E. Oswald ,  Marc A. Heppding

IPC: A61B5/097 ,  A61B5/08

CPC classification number: A61B5/097 ,  Y10S128/26

Abstract: A system and method for interfacing a patient with apparatus for monitoring gaseous components of the exhalation of said patient. The system includes a low dead space volume disc filter for blocking patient secretions and natural and manufactured humidification, improved sampling configuration, and apparatus for supporting endotracheal and tracheal tubes and the like with minimum discomfort to the patient. Special provision is made for supporting the endotracheal tube for a neonate, including a wire support requiring only minimal taping.

Abstract translation: 用于将患者与用于监测所述患者的呼气的气体组分的装置接口的系统和方法。 该系统包括用于阻断患者分泌物和自然和制造的加湿，改进的取样配置的低死空间体积盘式过滤器，以及用于支持气管内和气管管等的装置，对患者的最小不适。 特别规定支持气管插管用于新生儿，其中包括仅需最小胶带的电线支架。

公开(公告)号：US4153623A

公开(公告)日：1979-05-08

申请号：US814736

申请日：1977-07-11

Applicant: Leonard Kaplan ,  Wellington E. Walker ,  George L. O'Connor

Inventor： Leonard Kaplan ,  Wellington E. Walker ,  George L. O'Connor

IPC: C07C29/158 ,  C07C27/06 ,  C07C31/06

CPC classification number: C07C29/158

Abstract: This invention relates to the manufacture of such valuable chemicals as polyhydric alcohols, their ether and ester derivatives, oligomers of such alcohols and their ether and ester derivatives by reacting hydrogen and oxides of carbon in the presence of a rhodium carbonyl complex and a compound of aluminum.

Abstract translation: 本发明涉及在羰基铑化合物和铝化合物的存在下，通过使氢和碳氧化物反应来制造这种有价值的化学品作为多元醇，它们的醚和酯​​衍生物，这些醇的低聚物及其醚和酯衍生物 。

公开(公告)号：US4244889A

公开(公告)日：1981-01-13

申请号：US105244

申请日：1979-12-19

Applicant: William J. Bartley ,  George L. O'Connor

Inventor： William J. Bartley ,  George L. O'Connor

IPC: C07B61/00 ,  B01J23/00 ,  C07C67/00 ,  C07C231/00 ,  C07C231/10 ,  C07C233/04 ,  C07C102/00

CPC classification number: C07C231/00

Abstract: A heterogeneous process for selectively producing acetamides in which the acyl nitrogen is otherwise bonded to methyl, ethyl, hydrogen or combinations thereof which comprises contacting a mixture of carbon monoxide, hydrogen and a nitrogen-containing compound selected from the group consisting of ammonia, nitric oxide and mixtures thereof with a heterogeneous solid catalyst comprising rhodium and manganese. The acetamides of the invention are formed in a collective amount of at least 25 weight percent of the total amide products of the reaction.

Abstract translation: 用于选择性生产乙酰胺的非均相方法，其中酰基氮以其它方式与甲基，乙基，氢或其组合键合，其包括使一氧化碳，氢气和含氮化合物的混合物与氨，一氧化氮 及其与包含铑和锰的非均相固体催化剂的混合物。 本发明的乙酰胺以总反应的总酰胺产物的至少25重量％的总量形成。