Abstract:
The subject matter of the present invention is a method for producing a biodegradable, non-porous composite material made water-absorbent and/or lipid-absorbent, used for obtaining diversely shaped solid objects to be subsequently loaded with active liquid hydrophilic and/or lipophilic compositions comprising at least one active ingredient intended to be delivered into an environment in a controlled and continuous manner. The absorption of the hydrophilic and/or lipophilic composition by said objects is achieved using a network of hydrophilic and/or lipophilic wicks formed in the non-porous material by the co-absorbents. Said method according to the invention is discontinuous, insofar as it comprises storage steps which are steps involving partial interruption of the process insofar as the intermediate products are storable. Indeed, the storage of the fine powder or meal obtained in the first part of the method requires that the maturation thereof allows the distribution of liquid substances in the mass of powder. The storage of the solid objects obtained promotes a flexible management of later operations for their loading with at least one active liquid composition which takes account of the intended purpose of the active objects. Said objects can be used in agriculture, feed supply, veterinary medicine, animal husbandry, animal feed, hygiene, ambient air treatments, perfumery or in the maintenance of green spaces.
Abstract:
The present invention provides an automobile interior sheet using a bioresin that includes: 5 to 100 parts by weight of a bioresin prepared from a starch extracted from at least one natural plant selected from the group consisting of corn, potato, sweet potato, sugar cane, bamboo, or similarities thereof; 30 to 100 parts by weight of a thermoplastic polyolefin (TPO) resin or a thermoplastic polyurethane (TPU) resin; 5 to 40 parts by weight of a compatibilizer; 0.1 to 1.5 part by weight of a lubricant; and 0.5 to 5 parts by weight of a crosslinking agent.
Abstract:
A biodegradable, polyolefin-based material composition having incorporated therein thermoplastic starch particles is described. The material includes from about 5% to about 45% of a thermoplastic starch (TPS), from about 55% to about 95% of a polyolefin or mixtures of polyolefins, and from about 0.5% to about 8% of a compatibilizer, which has a non-polar backbone and a polar functional monomer or a block copolymer of both the non-polar block and a polar block. A method of forming a film and packaging assemblies made with the polymeric material are also described.
Abstract:
A barrier composition which is injection mouldable and able to be made into a transparent film or incorporated (by co-extrusion and/or lamination) into multi-layer film products, the composition on dry basis: a) from 45 to 90% by weight of a starch and/or a modified starch selected from starches modified by reaction with a hydroxyl alkyl group, an acetate or a dicarboxylic acid anhydride or a grafting polymer; b) from 4 to 12% by weight of a water soluble polymer selected from polyvinyl alcohol, polyvinylacetate, and copolymers of ethylene and vinylalcohol which have a melting point compatible with the molten state of the starch components c) from 5 to 45% by weight of a non-crystallising mixture of sorbitol and at least one other plasticizer selected from glycerol, maltitol, xylitol, mannitol, glycerol trioleate, epoxidised linseed or soybean oil, tributyl citrate, acetyl tri-ethyl citrate, glyceryl triacetate, 2,2,4-trimethyl-1,3-pentanediol diisobutyrate; polyethylene oxide or polyethylene glycol; d) from 0.3 to 2.5% by weight of a C12-22 fatty acid or salt; e) from 0.25% to 3% of an emulsifier system having a hydrophilic lipophilic balance value between 2 and 10. The barrier film may be co-injection moulded with polyethylene terephthalate (PET) or polylactic acid (PLA) for blow moulding into beverage bottles, with polyethylene (PE) or polypropylene (PP) or biodegradable polymers for high gas-barrier containers or closures, or may be co-extruded with polyethylene, polypropylene or polylactic acid for thin film packaging applications or for blow-moulded containers.
Abstract:
A method includes the steps of: adding an organic surface cross-linking agent to a water absorbent resin having a cross-linked structure; adding a liquid permeability improving agent to the water absorbent resin concurrently with or after the addition of the organic surface cross-linking agent; and then adding a lubrication improving agent to the water absorbent resin. This provides a particulate water absorbing agent and a method for producing it, the particulate water absorbing agent being suitable for pneumatic transportation, suffering no decrease in the effect of the liquid permeability improving agent, and excelling in properties such as fluidity and damage resistance after the pneumatic transportation.
Abstract:
Disclosed herein is a composition of matter comprising a blend of discontinuous thermoplastic starch domains in a synthetic polymer, said composition of matter being characterized by an average diameter of thermoplastic starch domains of about 0.2 to about 1.5 microns. Also disclosed are compositions of matter comprising a blend of discontinuous thermoplastic starch domains in a synthetic polymer and being characterized by finished articles having key mechanical properties which are essentially maintained or in some cases improved over pure synthetic polymers. In yet another aspect, the present invention provides a method for making the material of the present invention. In a related aspect, the present invention provides the novel materials issued from the method of making the material. In other aspects, the present invention provides novel finished article compositions in the form of films or molded articles.
Abstract:
A powder metal mixture comprises a lubricant powder conventionally used to produce powder metal parts in combination with a modified lubricant. A lubricant conventionally used to compact and sinter a chosen powder metal mixture is modified by adding to it starch particles smaller than the average metal particle, and optionally, micronized cellulose fibers in so small an amount that the modified lubricant is present in an amount less than 2% by weight of the mixture. The Hall apparent density and the Hall flow rate of a powder metal mixture made with the modified lubricant of starch or (starch+fibers) remains within the ranges deemed desirable for production of compacted powder metal parts. Using the modified lubricant in lieu of the conventional lubricant increases green strength of a part made by compacting the mixture and improves dimensional conformance.
Abstract:
A porous, starch-based pigment and filler product, which comprises a foam, which contains foam bubbles, the average size of which is less than approximately 10 micrometres, and a method of manufacturing it. From the starch, microporous foam can be prepared, which can be stabilized to microcapsules. By means of a suitable choice of the inner diameter and the wall thickness of these capsules the light scattering ability of the material is maximized, which means that the structure has good opacity properties. Good strength properties in relation to the capsule mass is also characteristic of the micro capsule structure.
Abstract:
An expandable starch-based composition includes a starch, a volatile blowing agent, a non-volatile plasticizer, nucleating agent, and a water-resistant polymer. The expandable starch-based composition can be characterized by having a plasticized starch capable of expanding when rapidly heated to above the boiling point of the volatile blowing agent and the softening point of the plasticized starch. The composition can be used in a method of manufacturing an expandable starch-based bead, wherein the method includes: introducing the composition into an extruder; heating and mixing the composition in order to yield a thermoplastic melt; extruding the thermoplastic melt through a die opening to yield an extruded strand; cooling the extruded strand; and cutting the cooled strand in to beads. The beads can be used in a method of manufacturing a biodegradable article, the method includes: providing a plurality of expandable starch-based beads; placing the beads into a mold cavity; rapidly heating the beads to a temperature greater than the boiling point of the volatile blowing agent; causing at least a portion of the expanded beads to adhere together to form an intermediate molded body; and cooling the intermediate molded body to yield the article of manufacture.
Abstract:
Thermoplastic mixture based on biopolymers for producing shaped biodegradable articles with improved properties, preparation of the mixture, and also its use. A novel thermoplastic mixture based on biopolymers, in particular on starch, features the presence of lignin and is used for producing shaped biodegradable articles with improved properties, preferably with improved mechanical properties. The mixture is preferably obtained by preparing, and mixing with one another, A) 100 parts by weight of one or more physiologically nonhazardous, biodegradable, thermoplastically processable polymeric materials selected from the group consisting of polysaccharides and proteins, preferably at least one starch of any type which is native, chemically modified, fermentative, recombinant and/or prepared by biotransformation, and/or derivatives of the starches mentioned; B) from 10 to 100 parts by weight of water; C) from 1 to 100 parts by weight of lignin; D) if desired, up to 50 parts by weight of at least one plasticizer; and E) if desired, up to 200 parts by weight, preferably not more than 100 parts by weight, of other conventional additives; where the components are thermoplastified with introduction of thermal and mechanical energy into the mixture, preferably at an elevated temperature and with simultaneous exertion of shear forces onto the mixture. Surprisingly, the use of lignin with thermoplastic materials based on biopolymers, in particular based on starch, leads to improved thermoplastic materials which have advantages in particular in terms of their mechanical properties or other performance characteristics.