公开(公告)号：US09120117B2

公开(公告)日：2015-09-01

申请号：US13761763

申请日：2013-02-07

申请人： Christopher John Ellison ,  Carlton Grant Willson ,  Julia Cushen ,  Christopher M. Bates

发明人： Christopher John Ellison ,  Carlton Grant Willson ,  Julia Cushen ,  Christopher M. Bates

IPC分类号： B05D1/00 ,  B05D3/00 ,  B05D5/00 ,  B05C21/00 ,  C08G63/695 ,  C08F112/14 ,  G03F7/00 ,  B82Y10/00 ,  B82Y40/00

CPC分类号： C09D167/00 ,  B05C21/005 ,  B05D1/005 ,  B05D3/00 ,  B05D5/00 ,  B82Y10/00 ,  B82Y40/00 ,  C08F8/02 ,  C08F112/14 ,  C08F2810/40 ,  C08G63/6952 ,  G03F7/0002 ,  Y10T428/24851 ,  Y10T428/31504

摘要： A diblock copolymer system that self-assembles at very low molecular weights to form very small features is described. One polymer in the block copolymer contains silicon, and the other polymer is a polylactide. The block copolymer may be synthesized by a combination of anionic and ring opening polymerization reactions. This block copolymer may form nanoporous materials that can be used as etch masks in lithographic patterning.

摘要翻译： 描述了以非常低分子量自组装形成非常小的特征的二嵌段共聚物体系。 嵌段共聚物中的一种聚合物含有硅，另一种聚合物是聚丙交酯。 嵌段共聚物可以通过阴离子和开环聚合反应的组合来合成。 该嵌段共聚物可以形成可用作光刻图案化中的蚀刻掩模的纳米多孔材料。

公开(公告)号：US20100068168A1

公开(公告)日：2010-03-18

申请号：US12450872

申请日：2008-04-18

申请人： Jie Song ,  Jianwen Xu

发明人： Jie Song ,  Jianwen Xu

IPC分类号： C08G18/61 ,  A61K31/74 ,  A61P19/00

CPC分类号： A61L27/18 ,  A61L27/50 ,  A61L31/06 ,  A61L2400/16 ,  C08G18/61 ,  C08G63/6952 ,  C08G77/045 ,  C08G77/38 ,  C08G77/445 ,  C08L83/04

摘要： The invention relates to materials comprising siloxanes, preferably the materials have thermal-responsive properties. In some embodiments, the invention relates to silsesquioxane groups functionalized with polymers. In another embodiment, silsequioxane-polymer conjugates comprise polylactone segments. The silsequioxane-polymer conjugates may be crosslinked together to form a material, and these materials may be functionalized with bioactive compounds so that the materials have desirable biocompatibility or bioactivity when used in medical devices. In further embodiments, the invention relates to composite materials that contain a polymer matrix and aggregates, and in some embodiments, methods of making, and methods of using these materials. Preferably, the aggregates are calcium phosphate aggregates. Preferably, the material is resistant to fracture. In further embodiments, the materials are used in surgical procedures of bone replacement. In further embodiments, the materials contain polyhedral silsesquioxanes and/or biodegradable segments.

摘要翻译： 本发明涉及包含硅氧烷的材料，优选该材料具有热响应特性。 在一些实施方案中，本发明涉及用聚合物官能化的倍半硅氧烷基团。 在另一个实施方案中，硅二恶烷 - 聚合物共轭物包含聚内酯片段。 硅氧烷 - 聚合物共轭物可以一起交联以形成材料，并且这些材料可以用生物活性化合物官能化，使得当用于医疗装置时，这些材料具有期望的生物相容性或生物活性。 在另外的实施方案中，本发明涉及包含聚合物基质和聚集体的复合材料，并且在一些实施方案中涉及制备方法和使用这些材料的方法。 优选地，聚集体是磷酸钙聚集体。 优选地，该材料耐断裂。 在另外的实施方案中，所述材料用于骨置换的外科手术中。 在另外的实施方案中，材料含有多面体倍半硅氧烷和/或可生物降解的片段。

公开(公告)号：US20040210020A1

公开(公告)日：2004-10-21

申请号：US10825945

申请日：2004-04-16

发明人： Eberhard Esselborn ,  Sascha Oestreich ,  Cornelia Schroter

IPC分类号： C08G077/04

CPC分类号： C08G77/388 ,  C08G18/10 ,  C08G18/61 ,  C08G18/672 ,  C08G63/6952 ,  C09D175/16

摘要： Innovative polyester siloxane acrylates obtainable by reacting one or more organically modified polysiloxanes with one or more polyisocyanates having in each case at least two isocyanate groups and one or more polyester acrylates or polyester methacylates and their use as additives in radiation-curable coatings and printing inks for improving the resistance of the coating toward soiling of all kinds.

摘要翻译： 通过使一种或多种有机改性的聚硅氧烷与一种或多种多异氰酸酯反应获得的创新的聚酯硅氧烷丙烯酸酯，每种多异氰酸酯在每种情况下都具有至少两个异氰酸酯基团和一种或多种聚酯丙烯酸酯或聚酯甲基丙烯酸酯，以及它们作为可辐射固化涂料和印刷油墨中的添加剂的用途 提高涂层对各种污染的抵抗力。

公开(公告)号：US5194473A

公开(公告)日：1993-03-16

申请号：US525729

申请日：1990-05-21

申请人： Hosei Shinoda ,  Masami Ohtaguro ,  Shigeru Iimuro

发明人： Hosei Shinoda ,  Masami Ohtaguro ,  Shigeru Iimuro

IPC分类号： A61L17/00 ,  A61K47/34 ,  A61L17/12 ,  A61L17/14 ,  A61L27/00 ,  A61L27/26 ,  A61L31/00 ,  A61L31/04 ,  C08G63/08 ,  C08G63/68 ,  C08G63/695 ,  C08G77/42 ,  C08G77/445 ,  C08L67/00 ,  C08L67/04 ,  C08L83/10 ,  C08L83/12

CPC分类号： C08G77/445 ,  A61L17/12 ,  A61L17/145 ,  A61L27/26 ,  A61L31/041 ,  C08G63/6952 ,  C08L67/04 ,  C08L83/12

摘要： In preparing bioabsorbable polyesters containing glycolic acid unit and/or lactic acid unit by the polymerization of glycolide and/or lactide, compositions comprising polyester-silicone copolymers obtained by conducting polymerization in the presence of silicones and the effect of merely mixing the above bioabsorbable polyesters with certain kind of silicones upon the modification, thereby attaining flexibility in particular, of the bioabsorbable polyesters, are disclosed.

公开(公告)号：US09834700B2

公开(公告)日：2017-12-05

申请号：US14827876

申请日：2015-08-17

申请人： Board of Regents, The University of Texas System

发明人： Christopher J. Ellison ,  Carlton Grant Willson ,  Julia Cushen ,  Christopher M. Bates

IPC分类号： C09D167/00 ,  B05D1/00 ,  B05D3/00 ,  B05D5/00 ,  C08G63/695 ,  B05C21/00 ,  C08F112/14 ,  G03F7/00 ,  B82Y10/00 ,  B82Y40/00 ,  C08F8/02

CPC分类号： C09D167/00 ,  B05C21/005 ,  B05D1/005 ,  B05D3/00 ,  B05D5/00 ,  B82Y10/00 ,  B82Y40/00 ,  C08F8/02 ,  C08F112/14 ,  C08F2810/40 ,  C08G63/6952 ,  G03F7/0002 ,  Y10T428/24851 ,  Y10T428/31504

摘要： The present invention includes a diblock copolymer system that self-assembles at very low molecular weights to form very small features. In one embodiment, one polymer in the block copolymer contains silicon, and the other polymer is a polylactide. In one embodiment, the block copolymer is synthesized by a combination of anionic and ring opening polymerization reactions. In one embodiment, the purpose of this block copolymer is to form nanoporous materials that can be used as etch masks in lithographic patterning.

公开(公告)号：US20160237283A1

公开(公告)日：2016-08-18

申请号：US15026635

申请日：2014-10-02

申请人： LUNA INNOVATIONS INCORPORATED

发明人： Bryan KOENE ,  Bhadresh MAISURIA ,  Tammy METROKE ,  Alaina MCGREGOR

IPC分类号： C09D5/00 ,  C09D175/06

CPC分类号： C09D5/00 ,  C08G18/246 ,  C08G18/325 ,  C08G18/4277 ,  C08G18/718 ,  C08G63/6952 ,  C08G63/912 ,  C08K3/36 ,  C09D7/62 ,  C09D167/04 ,  C09D175/06

摘要： Durable, transparent, inorganic-organic hybrid hydrophobic coating materials for glass, metal or plastic substrates are provided. The coating materials are generally an acid catalyzed condensation reaction product comprised of an organic polymeric silane (e.g., a polyol functionalized with a silane through a urethane linkage or a polyamine functionalized with a silane through a urea linkage, such as isocyanatopropyltrimethoxysilane or isocyanatopropyltriethoxysilane), an inorganic metal alkoxide (e.g., silicon alkoxides such as tetraethoxysilane or tetramethoxysilane) and a fluorinated silane (e.g., (3,3,3-trifluoropropyl)trimethoxysilane or nonafluorohexyltrimethoxysilane).

摘要翻译： 提供用于玻璃，金属或塑料基材的耐用，透明，无机 - 有机混合疏水涂层材料。 涂料通常是由有机聚合硅烷（例如，通过氨基甲酸酯键或硅烷经官能化的多胺，通过脲键官能化的多胺，例如异氰酸根合丙基三甲氧基硅烷或异氰酸根合丙基三乙氧基硅烷）组成的酸催化缩合反应产物， 无机金属醇盐（例如，四烷氧基硅烷或四甲氧基硅烷等硅醇盐）和氟化硅烷（例如，（3,3,3-三氟丙基）三甲氧基硅烷或非氟己基三甲氧基硅烷）。

公开(公告)号：US20140309379A1

公开(公告)日：2014-10-16

申请号：US14313526

申请日：2014-06-24

申请人： Makoto SOYAMA ,  Akinobu NAKAMURA ,  Masatoshi IJI

发明人： Makoto SOYAMA ,  Akinobu NAKAMURA ,  Masatoshi IJI

IPC分类号： C08G63/91

CPC分类号： C08G63/912 ,  C08G63/08 ,  C08G63/6952 ,  C08G81/00

摘要： Disclosed are a polysiloxane-modified polylactic acid resin, composition using same, molded article, and production method, whereby it is possible to produce a molded article via a simple method, and where said article may be used in applications demanding a high level of impact resistance as an alternative to ABS resin or the like, has a similar level of impact resistance as said substances, has superior flexibility with respect to rupture bending strain and tensile breaking strain, and has bleed resistance. The polysiloxane-modified polylactic acid resin has a segment which is a polylactic acid compound, and a segment which is an amino polysiloxane compound which has an amine group. With respect to the amino poly-siloxane compound, amine groups are on average contained in the range of 0.01 to 2.5% inclusive by mass, and with respect to the polylactic acid compound, are on average contained in the range of 3 to 300 ppm inclusive by mass.

摘要翻译： 公开了聚硅氧烷改性的聚乳酸树脂，使用它们的组合物，成型制品和制造方法，由此可以通过简单的方法制备模塑制品，并且其中所述制品可以用于要求高水平冲击的应用中 作为ABS树脂等的替代物，具有与所述物质相似的耐冲击性水平，相对于断裂弯曲应变和拉伸断裂应变具有优异的柔韧性，并且具有耐渗流性。 聚硅氧烷改性聚乳酸​​树脂具有作为聚乳酸化合物的链段和作为具有胺基的氨基聚硅氧烷化合物的链段。 对于氨基多硅氧烷化合物，胺基平均含有0.01〜2.5质量％的范围，相对于聚乳酸化合物，平均含有3〜300ppm的范围 的质量。

公开(公告)号：US07534850B2

公开(公告)日：2009-05-19

申请号：US12098649

申请日：2008-04-07

申请人： Yuuji Kimura ,  Hideaki Tanaka ,  Genichirou Enna

发明人： Yuuji Kimura ,  Hideaki Tanaka ,  Genichirou Enna

IPC分类号： C08G63/02 ,  C08L31/00

CPC分类号： C08G63/6952 ,  C08G63/664 ,  C08G63/912

摘要： A silyl group-containing polymer which can be cured quickly and strongly, and from which a cured product excellent in antifouling properties and weather resistance while maintaining favorable rubber elasticity can be obtained, and having the following formula (1): wherein R1: a group having a hydroxyl group(s) removed from a monohydroxy or polyhydroxy compound having t hydroxyl group(s) in its molecule, R2: a bivalent organic group, R3: a C1-20 monovalent organic group which may have a substituent, X: a hydroxyl group or a hydrolysable group, Y: a bivalent group of the following formula (A) or (B), “a”: an integer of from 1 to 3, r: an integer of from 1 to 1,000, and t: an integer of from 1 to 8, provided that when the silyl group-containing polymer of formula (1) has a plurality of Y's in its molecule, the plurality of Y's may be the same or different, and when t is from 2 to 8, a plurality of monovalent groups bonded to R1 may be the same or different: in the formula (A), R4: a C2-8 alkylene group, and in the formula (B), R5: a C2-4 alkylene Group; and its production process.

摘要翻译： 可以快速且强烈地固化的含甲硅烷基的聚合物，并且可以获得具有优异的防污性和耐候性同时保持良好的橡胶弹性的固化产物，并且具有下式（1）：其中R1：一个基团 具有从其分子中具有t羟基的单羟基或多羟基化合物除去的羟基，R2：二价有机基团，R3：可具有取代基的C1-20一价有机基团，X：a 羟基或可水解基团，Y：下式（A）或（B）的二价基团，“a”：1〜3的整数，r：1〜1000的整数，t： 1至8的整数，条件是当式（1）的含甲硅烷基的聚合物在其分子中具有多个Y时，多个Y可以相同或不同，并且当t为2至8时， 与R1结合的多个一价基团可以相同或不同：在式（A）中，R 4：C 2-8 亚烷基，在式（B）中，R 5为C 2-4亚烷基; 及其生产工艺。

公开(公告)号：US20160312041A1

公开(公告)日：2016-10-27

申请号：US15101535

申请日：2014-12-01

申请人： PPG Coatings Europe B.V. ,  Universite de Bretagne-Sud

发明人： Fabrice Azemar ,  Isabelle Linossier ,  Karine Rehel ,  Fabienne Fay

IPC分类号： C09D5/16 ,  B05D7/24 ,  B63B59/04 ,  C09D183/10

CPC分类号： C09D5/1675 ,  B05D7/24 ,  B63B59/04 ,  C08G63/6952 ,  C08G77/445 ,  C09D167/04 ,  C09D183/10

摘要： A self-polishing and/or antifouling coating composition comprising a binder, wherein the binder comprises a copolymer comprising (i) units of A and (ii) units of B and/or C: wherein R1 and R2 are each independently H, a C1-C6 alkyl group or phenyl, R3 is H, a C1-C6 alkyl group or phenyl, R4 is optional and, when present, is a C1-C3 alkylene group, R′3 is H, a C1-C6 alkyl group or phenyl, and R′4 is optional and, when present, is a C1-C3 alkylene group.

公开(公告)号：US20150353763A1

公开(公告)日：2015-12-10

申请号：US14827876

申请日：2015-08-17

申请人： Board of Regents, The University of Texas System

发明人： Christopher J. Ellison ,  Carlton Grant Willson ,  Julia Cushen ,  Christopher M. Bates

IPC分类号： C09D167/00

CPC分类号： C09D167/00 ,  B05C21/005 ,  B05D1/005 ,  B05D3/00 ,  B05D5/00 ,  B82Y10/00 ,  B82Y40/00 ,  C08F8/02 ,  C08F112/14 ,  C08F2810/40 ,  C08G63/6952 ,  G03F7/0002 ,  Y10T428/24851 ,  Y10T428/31504

摘要： The present invention includes a diblock copolymer system that self-assembles at very low molecular weights to form very small features. In one embodiment, one polymer in the block copolymer contains silicon, and the other polymer is a polylactide. In one embodiment, the block copolymer is synthesized by a combination of anionic and ring opening polymerization reactions. In one embodiment, the purpose of this block copolymer is to form nanoporous materials that can be used as etch masks in lithographic patterning.

摘要翻译： 本发明包括以非常低的分子量自组装形成非常小的特征的二嵌段共聚物体系。 在一个实施方案中，嵌段共聚物中的一种聚合物含有硅，另一种聚合物是聚丙交酯。 在一个实施方案中，嵌段共聚物通过阴离子和开环聚合反应的组合合成。 在一个实施方案中，该嵌段共聚物的目的是形成可用作光刻图案化中的蚀刻掩模的纳米多孔材料。