DYNAMIC UREA BONDS FOR REVERSIBLE AND SELF-HEALING POLYMERS
    9.
    发明申请
    DYNAMIC UREA BONDS FOR REVERSIBLE AND SELF-HEALING POLYMERS 有权
    用于可逆和自我治疗聚合物的动态尿素债券

    公开(公告)号:US20160032054A1

    公开(公告)日:2016-02-04

    申请号:US14776104

    申请日:2014-03-14

    Abstract: The disclosure provides reversible polymers from polyurea by modifying the nitrogen atom with hindered substituents. The reversibility of hindered urea bond (HUB) can be controlled by changing the bulkiness of the substituents, and N-tert-butyl-N-ethylurea (TBEU), with its high binding constant and short lifetime, is applicable in the design of reversible polymer and self-healing materials at mild temperatures without external stimuli. HUB can be used in the design of smart materials with its adjustable reversibility, facile synthesis, and compatibility with many other polymer structures.

    Abstract translation: 本公开通过用受阻的取代基修饰氮原子提供了来自聚脲的可逆聚合物。 受阻脲键(HUB)的可逆性可以通过改变取代基的体积来控制,具有高结合常数和短寿命的N-叔丁基-N-乙基脲(TBEU)可应用于可逆的 聚合物和自愈材料在温和的温度下无外部刺激。 HUB可用于智能材料的设计,具有可调节的可逆性,易于合成,以及与许多其他聚合物结构的相容性。

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