摘要:
(Meth)acrylate-based reactive diluent compositions can be used for enabling styrene-free curing of unsaturated polyester resins. The reactive diluent compositions have a (meth)acrylic acid ester monomer and a compatibilizing agent including at least one (meth)acrylate moiety and at least one additional ethylenically unsaturated moiety.
摘要:
The invention relates to an organic peroxide emulsion containing at least one organic peroxide, at least one emulsifier comprising at least one nonionic surfactant including at least one fatty chain and/or a protective colloid agent, a combination of two or more antigels containing no more than 9.5 wt% of a first antifreeze relative to the total weight of the ethanol emulsion, at least a second antifreeze and water. The invention also relates to a method for preparing such an emulsion, the use of such an emulsion for the polymerization or copolymerization of one or more ethylenically unsaturated monomers, and a halogenated vinyl polymer obtained by the use of such an emulsion.
摘要:
A novel promotor which contains an aniline derivative is introduced. By using the promotor alone, the time and temperature of the curing reaction of the vinyl ester resin can be controlled by the unique steric effect and electronic properties of the aniline derivative. A method for preparing the above promotor is also introduced.
摘要:
Systems and processes for rapidly depressurizing a reactor system are disclosed. The systems and processes are particularly useful in the high pressure polymerization of ethylene.
摘要:
The present invention relates to an ethylene polymer comprising moieties according to formula (I): wherein R is a moiety comprising ≥1 and ≤10 carbon atoms; wherein the ethylene polymer has a molecular weight distribution of ≥3.0 and ≤13.0; the ethylene polymer has a melting temperature of ≥115° C.; the ethylene polymer has a density ≥935 and ≤960 kg/m3; the ethylene polymer is essentially free from chromium, hafnium, zirconium and tetrahydrofuran; for the fraction of the ethylene polymer having a molecular weight ≥100 kg/mol, the intrinsic viscosity of the ethylene polymer is related to the molecular weight according to the inequality: log I. V.
摘要:
The invention provides a process to form an ethylene-based polymer, said process comprising polymerizing ethylene in presence of at least the following: A) a free-radical agent; B) an alkylated phenol selected from Formula (I), wherein R1, R2,R3, R4 and R5 are each, independently, hydrogen or an alkyl; and C) a “metal alkyl-containing compound” selected from the group consisting of the following: i) at least one “Group II metal alkyl-containing compound,” ii) at least one “Group III metal alkyl-containing compound,” and iii) a combination of i) and ii).
摘要:
A method for producing a fluorinated polymer, which comprises carrying out polymerization in a container capable of polymerizing a monomer in a pressurized state, in the presence of at least one of specific four organic peroxides, in a polymerization medium containing at least one fluorinated solvent (B) having a boiling point at normal pressure of at most 60° C., using at least a fluorinated monomer (C) having a boiling point at normal pressure higher than said fluorinated solvent (B), and tetrafluoroethylene, at a temperature of at most 70° C. and at least the boiling point at normal pressure of a fluorinated solvent (B) having the lowest boiling point at normal pressure among said fluorinated solvent (B).
摘要:
The invention relates to a high pressure polymerisation process for the preparation of the polyethylene wherein the polymerisation process takes place in the presence of a cobalt containing complex. The cobalt containing complex may be a complex according to Formula (I): Formula (I) wherein y1, y2, y3 and y4 may, independently of one another be the same or different, H, (C1C20) alkyl, (C5-C20) cycloalkyl, (C6-C10) aryl radical, phenyl or hydroxy-phenyl.
摘要:
A poly(lactone) of formula (I) wherein b=0 or 1; the molar ratio of w:r:s:t=(0-30):(99.9-2):(0-98):(0-30), and w+s+t is at least 1; R1′ R2, and R3 are each independently a hydrogen or C1-4 alkyl; R4, R5, R6, and R7 are each independently hydrogen, C1-4 alkyl, or F wherein F is a functional group that imparts a property to the poly(lactone) I, at least one and no more than two of R4′ R5, R6, and R7 are F, and F is the same or different in each instance; Q′ is a C1-30 hydrocarbyl group post-reacted with a crosslinking group and optionally crosslinked with one to five additional polymer backbones, wherein the additional polymer backbone comprises units of formula I; G′ is a single bond to an additional polymer backbone or G′ is a C1-30 hydrocarbyl group crosslinked with one to five additional polymer backbones.
摘要翻译:式(I)的聚(内酯),其中b = 0或1; w:r:s:t =(0-30):(99.9-2):(0-98):(0-30),w + s + t的摩尔比为至少1; R 1'R 2和R 3各自独立地为氢或C 1-4烷基; R4,R5,R6和R7各自独立地为氢,C1-4烷基或F,其中F是赋予聚(内酯)I性质的官能团,R4'R5至少一个且不超过两个 R6,R7分别为F,F为相同或不同; Q'是与交联基团后反应并任选地与一至五个另外的聚合物主链交联的C 1-30烃基,其中另外的聚合物主链包含式I的单元; G'是与另外的聚合物骨架的单键,或者G'是与一至五个另外的聚合物主链交联的C 1-30烃基。
摘要:
Emulsion comprising an oil phase dispersed in an aqueous phase, wherein said oil phase comprises at least 53 wt % of one or more organic peroxides, more than 50 wt % of which have a molecular active oxygen content of at least 7.00 5 wt %, said emulsion satisfying the classification tests for organic peroxide type F. This emulsion allows the safe transport and storage of organic peroxide emulsions with high active oxygen content without the need for larger vent openings or higher design pressure of transport tanks and storage tanks.