摘要:
Provided are a hydrocarbon resin and a method of preparing the same, wherein thermal polymerization of a diolefin and an olefin is performed, thus obviating a catalyst removal process, material supply problems can be solved, and a hydrogenated hydrocarbon resin can be prepared using a catalyst, which is inexpensive and is easy to handle, thereby realizing a yield and a preparation process that enable real-world application thereof. The hydrogenated hydrocarbon resin prepared by the method of the invention has excellent compatibility and a low specific viscosity, and can thus be efficiently used as a tackifier or an adhesive in a variety of fields.
摘要:
To provide a β-pinene polymer excellent in heat resistance while having thermoplasticity, and further also having excellent strength, without impairing the inherent characteristics of small specific gravity and excellent transparency. A desired β-pinene polymer having a weight average molecular weight of 90,000 to 1,000,000 and a glass transition temperature of 80° C. or more was obtained by polymerizing β-pinene in the presence of a bifunctional vinyl compound.
摘要:
Methods for the addition polymerization of cycloolefins using a cationic Group 10 metal complex and a weakly coordinating anion of the formula: [(R′)zM(L′)x(L″)y]b[WCA]d wherein [(R′)zM(L′)x(L″)y] is a cation complex where M represents a Group 10 transition metal; R′ represents an anionic hydrocarbyl containing ligand; L′ represents a Group 15 neutral electron donor ligand; L″ represents a labile neutral electron donor ligand; x is 1 or 2; and y is 0, 1, 2, or 3; and z is 0 or 1, wherein the sum of x, y, and z is 4; and [WCA] represents a weakly coordinating counteranion complex; and b and d are numbers representing the number of times the cation complex and weakly coordinating counteranion complex are taken to balance the electronic charge on the overall catalyst complex.
摘要:
Disclosed is a method for preparing a cycloolefin polymer containing polar functional groups, comprising the steps of: a) preparing a catalyst mixture including i) a precatalyst; ii) a first cocatalyst; and iii) a second cocatalyst; and b) subjecting a monomer solution comprising a norbornene-based compound containing a polar functional group to an addition polymerization reaction in the presence of an organic solvent and the catalyst mixture, wherein the product yield of the prepared polymer is 50% by weight or more based on the total weight of the monomer.
摘要:
The present invention provides a method for preparing a polymer by precipitation polymerization, comprising the steps of mixing an antisolvent a), a monomer b), and a catalyst c), and while polymerizing the monomers, simultaneously precipitating a polymer formed by the monomers b) in a solid phase.
摘要:
Disclosed is a method for preparing a cycloolefin polymer containing polar functional groups, comprising: preparing a catalyst mixture including i) a precatalyst, containing a Group 10 transition metal having a ligand containing oxygen ions bonded to the metal; ii) a first cocatalyst which is an organic compound containing a Group 15 element; and iii) a second cocatalyst which is capable of providing an anion and weakly coordinating to the metal of the precatalyst; and subjecting a monomer solution comprising a norbornene-based compound containing a polar functional group to an addition polymerization reaction in the presence of an organic solvent and the catalyst mixture, at a temperature of 80-200° C., the total amount of the organic solvent being 50-800% by weight based on the total weight of the monomer contained in the monomer solution, and the product yield of the polymer being 50% by weight or more based on the total weight of the monomer.
摘要:
A wavelength plate laser optical system which is a wavelength plate using a stretched and oriented film containing a cyclic olefin based resin, and which has values of the formula (a): Re(λ)/λ, (wherein λ represents a wavelength (nm) of the laser beam; and Re(λ) represents a retardation value (nm) of the laser beam having transmitted through the wavelength plate) against two laser beams having a different wavelength such that the value is ((0.2 to 0.3)+X) for a first laser beam and that the value is ((0.8 to 1.2)+Y) for a second laser beam, respectively (wherein X represents 0 or the number of an integral multiple of 0.5; and Y represents 0 or an integer of 1 or more). It is possible to provide a wavelength plate for optical information recording and reproducing devices, which is excellent in initial characteristics, is hardly affected by the use environment and the manufacturing environment, is excellent in long-term reliability, and is corresponding to two laser beams having a different wavelength.
摘要翻译:波长板激光光学系统,其是使用包含环状烯烃类树脂的拉伸取向膜的波长板,并且具有式(a)的值:Re(λ)/λ,(其中λ表示波长(nm ),并且Re(λ)表示穿过波长板的激光束的延迟值(nm)对于具有不同波长的两个激光束,使得值为((0.2〜0.3)+ X ),第二激光束的值为((0.8〜1.2)+ Y)(其中,X表示0或0.5的整数倍,Y表示0或整数倍) 1个或更多)。 可以提供一种光学信息记录和再现装置的波长板,其初始特性优异,几乎不受使用环境和制造环境的影响,具有优异的长期可靠性,并且对应于两个激光束 具有不同的波长。
摘要:
Disclosed is a method for preparing a cycloolefin polymer containing polar functional groups, comprising the steps of: a) preparing a catalyst mixture including i) a precatalyst; ii) a first cocatalyst; and iii) a second cocatalyst; and b) subjecting a monomer solution comprising a norbornene-based compound containing a polar functional group to an addition polymerization reaction in the presence of an organic solvent and the catalyst mixture, wherein the product yield of the prepared polymer is 50% by weight or more based on the total weight of the monomer.
摘要:
Ruthenium and osmium carbene compounds that are stable in the presence of a variety of functional groups and can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins are disclosed. Also disclosed are methods of making the carbene compounds. The carbene compounds are of the formula where M is Os or Ru; R is hydrogen; R is selected from the group consisting of hydrogen, substituted or unsubstituted alkyl, and substituted or unsubstituted aryl; X and X are independently selected from any anionic ligand; and L and L are independently selected from any neutral electron donor. The ruthenium and osmium carbene compounds of the present invention may be synthesized using diazo compounds, by neutral electron donor ligand exchange, by cross metathesis, using acetylene, using cumulated olefins, and in a one-pot method using diazo compounds and neutral electron donors. The ruthenium and osmium carbene compounds of the present invention may be used to catalyze olefin metathesis reactions including, but not limited to, ROMP, RCM, depolymerization of unsaturated polymers, synthesis of telechelic polymers, and olefin synthesis.
摘要:
A method for synthesizing cyclic polymers using transition metal alkylidene complexes as reaction catalysts is provided, wherein the complexes contain a cyclic group. Polymerization is carried out on the catalyst, using cyclic olefin monomers that undergo ring insertion polymerization, and no linear intermediates are generated. Following completion of polymerization, the cyclic polymer detaches from the complex via an intramolecular chain transfer reaction and the catalytic complex is regenerated. The invention also provides novel transition metal alkylidene complexes useful as catalysts in the aforementioned process, as well as novel cyclic hydrocarbons.