METHOD FOR EFFICIENT DISPOSAL OF DIOXIN AND HEAVY METALS BASED ON CALCIUM-BASED HEAT STORAGE OF MSWI FLY ASH

    公开(公告)号:US20240261835A1

    公开(公告)日:2024-08-08

    申请号:US18518418

    申请日:2023-11-22

    CPC classification number: B09B3/70 B09B3/35 B09B3/40 B09B2101/30

    Abstract: A method for efficient disposal of dioxin and heavy metals based on calcium-based heat storage of MSWI fly ash is provided. According to the method, MSWI fly ash washed with water is treated with ammonia, and carbon dioxide is continuously introduced under stirring. The ammonia provides OH− for a carbonation reaction of the MSWI fly ash and promotes removal of sulfate ions. After centrifugation of a reaction solution, calcium carbonate obtained as a solid part is transported to a calcinator of a solar chemical heat reservoir and calcined into calcium oxide by means of solar energy obtained by a solar concentrator. CO2 produced in a calcination process is collected, cooled and liquefied, followed by a carbonation reaction with the calcium oxide in a carbonation radiator. After the operations above are repeated in cycles for several times, carbonated MSWI fly ash is obtained for use as an aggregate or a filler.

    Method of recovering the fly ash
    7.
    发明授权

    公开(公告)号:US12048956B2

    公开(公告)日:2024-07-30

    申请号:US17256876

    申请日:2019-06-04

    CPC classification number: B09B3/40 B07B1/4609 B09B2101/30

    Abstract: A method of recovering fly ash, including a firing step in which raw fly ash powder containing unburned carbon is fired to remove the unburned carbon by burning; measuring the content of unburned carbon in the raw fly ash powder; and obtaining a fine fly ash powder which is a component under a sieve and has a decreased content of unburned carbon as a result of sieve-classifying the raw fly ash powder. The perforation size of the sieve used in the sieve-classifying step is set depending upon the content of unburned carbon in the raw fly ash powder. The sieve has a small perforation size when the content of unburned carbon is large, and the sieve has a large perforation size when the content of unburned carbon is small. The fine fly ash powder, which is the component under the sieve, is recovered through the firing step.

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