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公开(公告)号:US10647734B2
公开(公告)日:2020-05-12
申请号:US16340431
申请日:2017-11-29
发明人: Brian D. Rekken
IPC分类号: C07F7/10 , B01J27/138 , B01J31/02 , B01J31/12
摘要: A method for dehydrocoupling silanes and amines. The method comprises contacting: (a) an aliphatic amine; (b) a silane; and (c) a catalyst which is ZnX2, wherein X is alkyl, chloride, bromide, iodide, trifluoromethanesulfonate, bis(trifluoromethane)sulfonamide, tosylate, methanesulfonate or O3S(CF2)XCF3 wherein x is an integer from 1 to 10.
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公开(公告)号:US10273254B2
公开(公告)日:2019-04-30
申请号:US15567272
申请日:2016-06-17
摘要: A process for preparing an acryloyloxysilane, comprising: reacting a metal salt of a carboxylic acid having the formula [CR22═CR1CO−]aMa+ (I), with a haloorganoalkoxysilane having the formula XR3Si(OR4)nR53-n (II) at a temperature of from 50 to 160° C. and in the presence of a catalyst, and in the presence of water, an alcohol comprising 1 to 5 carbon atoms, or a combination of water and an alcohol comprising 1 to 5 carbon atoms, to form a mixture comprising an acryloyloxysilane and a metal halide having the formula Ma+X−a (III), wherein R1 is H, R7COO−Ma+, or C1-C6 hydrocarbyl, each R2 is independently R1 or [COO−]Ma+, Ma+ is an alkali metal cation or alkaline earth metal cation, a is 1 or 2, X is halo, R3 is C1-C6 hydrocarbylene, each R4 is independently C1-C10 hydrocarbyl, each R5 is independently R1 and n is an integer from 1 to 3.
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公开(公告)号:US10246473B2
公开(公告)日:2019-04-02
申请号:US15567391
申请日:2016-06-17
发明人: Michael A. Depierro , Sean P Reisch
摘要: A process for purifying an acryloyloxysilane comprising subjecting a mixture comprising an acryloyloxysilane, a haloorganoalkoxysilane, and an alkane-based non-polar solvent to a temperature and pressure sufficient to vaporize a portion of the non-polar solvent, the haloorganoalkoxysilane, or the non-polar solvent and the haloorganoalkoxysilane from the mixture to produce a purified mixture comprising the acryloyloxysilane. The examples disclose a three-step short-path distillation process, where in the first two passes, the residue-fraction is the one containing the product, whereas in the third path, the distillate is containing the purified product.
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公开(公告)号:US20180299705A1
公开(公告)日:2018-10-18
申请号:US15580104
申请日:2016-06-07
CPC分类号: G02F1/0147 , G02B1/04 , G02F1/009 , H01L33/501 , H01L33/502 , H01L33/507 , H01L33/56 , H01L2933/005
摘要: A smart optical material characterized in that when the material is at ambient temperature (≤30° C.), it is opaque to at least one color light in the visible light spectrum and when the material is at an elevated temperature of at least 80° C., it is substantially transparent to the at least one color light. The smart optical material is also characterized as having before thermal aging an elongation-at-break of at least 15% and after thermal aging in air at 200° C. for seven days an elongation-at-break that is unchanged or is at least 12% and has decreased by from >0% to less than 50%. Also included are related formulations, methods, uses, articles and devices.
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公开(公告)号:US20180211842A1
公开(公告)日:2018-07-26
申请号:US15414913
申请日:2017-01-25
发明人: Won Woong CHUNG , Sun hye HWANG , Youn Joung CHO , Jung Sik CHOI , Xiaobing ZHOU , Brian David REKKEN , Byung Keun HWANG , Michael David TELGENHOFF
CPC分类号: H01L21/28282 , H01L21/02164 , H01L21/0217 , H01L21/02211 , H01L21/0228
摘要: A method for fabricating a semiconductor device includes forming a structure with a height difference on a substrate and forming a dielectric layer structure on the structure using an atomic layer deposition (ALD) method. Forming the dielectric layer structure includes forming a first dielectric layer including silicon nitride on the structure with the height difference. Forming the first dielectric layer includes feeding a first gas including pentachlorodisilane (PCDS) or diisopropylamine pentachlorodisilane (DPDC) as a silicon precursor, and a second gas including nitrogen components into a chamber including the substrate such that the first dielectric layer is formed in situ on the structure having the height difference.
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公开(公告)号:US09963546B2
公开(公告)日:2018-05-08
申请号:US15115321
申请日:2015-03-10
IPC分类号: C08G77/38 , C08G65/00 , C08L33/08 , C09D183/08 , C08G77/395 , C08G77/48 , C08G77/50 , C08G77/385 , C08L35/02 , C09D135/02
CPC分类号: C08G65/007 , C08G77/38 , C08G77/385 , C08G77/395 , C08G77/48 , C08G77/50 , C08G2650/04 , C08G2650/16 , C08G2650/64 , C08L33/08 , C08L35/02 , C08L2203/16 , C08L2205/03 , C09D135/02 , C09D183/08 , C08K3/36 , C08K5/5425
摘要: A fluorinated compound having at least one (meth)acrylate functional group disclosed. A curable composition comprising the fluorinated compound and polyfunctional acrylate, a cured product formed from the curable composition, and method of forming the cured product are also disclosed.
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公开(公告)号:US09957364B2
公开(公告)日:2018-05-01
申请号:US15114575
申请日:2014-12-11
发明人: Dongchan Ahn , James S Hrabal , Christopher L Wong
CPC分类号: C08J7/16 , B01D53/228 , B01D67/0093 , B01D71/70 , B01D2323/30 , C08F4/52 , C08F220/18 , C08J5/18 , C08J7/04 , C08J2383/05 , C08J2383/06 , C08J2383/07 , C08J2483/07 , C08L33/06 , C08F2220/1825 , C08F2222/1013
摘要: Various embodiments disclosed related to modified elastomer surfaces and methods of making and using the same. In various embodiments, the present invention provides a method of modifying the surface of an elastomer. The method can include contacting a polymerizable composition and at least part of a surface of an elastomer. The polymerizable composition can include a free-radical polymerizable monomers, an organoborane-organonitrogen free-radical initiator, and an amine-reactive compound. The method can include at least partially polymerizing the polymerizable composition, to provide a polymerization product of the polymerizable composition on the surface of the elastomer.
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公开(公告)号:US09902811B2
公开(公告)日:2018-02-27
申请号:US14769131
申请日:2014-02-21
发明人: Stanton James Dent , Tomohiro Iimura , Yusuke Miyamoto , Yoshitsugu Morita , Fumito Nishida , Emil Radkov , Jacob William Steinbrecher , Hiroaki Yoshida , Makoto Yoshitake
IPC分类号: C08G77/398 , C08G77/08 , C08L83/14 , C09K11/02 , C09K11/77 , H01L33/50 , C08G77/58 , C08G77/12 , C08G77/20
CPC分类号: C08G77/08 , C08G77/12 , C08G77/20 , C08G77/398 , C08G77/58 , C08G2190/00 , C08K5/56 , C08L83/00 , C08L83/14 , C09K11/025 , C09K11/7706 , H01L33/50 , H01L2224/45144 , H01L2224/48091 , H01L2224/48247 , H01L2924/181 , H01L2924/00012 , H01L2924/00014 , H01L2924/00
摘要: This invention relates to a curable silicone composition comprising: (A) a straight-chain organopolysiloxane having at least two alkenyl groups in a molecule; (B) an organopolysiloxane represented by the following average unit formula: (R1SiO3/2)a(R12SiO2/2)b(R13SiO1/2)c(SiO4/2)d(XO1/2)e wherein, R1 each independently represent an alkyl group having from 1 to 12 carbons, an alkenyl group having from 2 to 12 carbons, an aryl group having from 6 to 20 carbons, an aralkyl group having from 7 to 20 carbons, or a group in which some or all of the hydrogen atoms of these groups are substituted with halogen atoms, with the proviso that at least two R1 in a molecule are the alkenyl groups, X is a hydrogen atom or an alkyl group, a is a number from 0 to 0.3, b is 0 or a positive number, c is a positive number, d is a positive number, e is a number from 0 to 0.4, a+b+c+d=1, c/d is a number from 0 to 10, and b/d is a number from 0 to 0.5; (C) an organopolysiloxane having at least two silicon-bonded hydrogen atoms in a molecule; (D) a cerium-containing organopolysiloxane; and (E) a hydrosilylation reaction catalyst. The curable silicone composition does not develop cracks due to thermal aging and can form a cured product having little yellow discoloration.
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9.
公开(公告)号:US20180021747A1
公开(公告)日:2018-01-25
申请号:US15541583
申请日:2016-03-15
发明人: Mark Berglund , Aaron Coppernoll , Patrick James Harder , Dimitris Katsoulis , Vladimir Pushkarev
IPC分类号: B01J8/18 , C01B33/06 , C01B33/107
CPC分类号: B01J8/1836 , B01J8/1818 , B01J8/1827 , B01J2208/00407 , B01J2208/0053 , B01J2208/00681 , B01J2208/00805 , C01B33/06 , C01B33/1071
摘要: A method is useful for maintaining a uniformly fluidized bed in a fluidized bed apparatus. The method includes the steps of charging a mixture of particles including copper silicide particles and fluidization additive particles into the fluidized bed apparatus, and uniformly fluidizing the particles at a temperature of at least 400° C. in the fluidized bed apparatus.
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公开(公告)号:US20170362816A1
公开(公告)日:2017-12-21
申请号:US15533782
申请日:2015-12-16
CPC分类号: E04B1/40 , E04B1/7608 , E04F13/0801 , Y02A30/261 , Y02B30/94
摘要: An anchor for securing together interior and exterior building components includes a first end having an outer side for engaging the interior building component and an inner side opposite the outer side. The anchor further includes a second end having an outer side and an inner side opposite the outer side of the second end for engaging the exterior building component. A thermal break for reducing thermal bridging between the exterior and interior building components is disposed in a space between the inner sides of the ends and has a first coupling surface bonded to the inner side of the first end and a second coupling surface bonded to the inner side of the second end. An assembly includes the anchor for securing together the interior and exterior building components.
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