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    Propylene-ethylene random copolymer film
    1.
    发明授权
    Propylene-ethylene random copolymer film 失效
    丙烯 - 乙烯无规共聚物膜

    公开(公告)号：US6057413A

    公开(公告)日：2000-05-02

    申请号：US706754

    申请日：1996-09-03

    申请人： Seiichiro Ima ,  Kazuki Wakamatsu ,  Shigeki Kishiro

    发明人： Seiichiro Ima ,  Kazuki Wakamatsu ,  Shigeki Kishiro

    IPC分类号： B29C47/00 ,  B29K67/00 ,  B29L7/00 ,  C08F2/34 ,  C08F4/60 ,  C08F4/646 ,  C08F4/654 ,  C08F4/658 ,  C08F10/00 ,  C08F210/06 ,  C08F210/16 ,  C08J5/18 ,  C08F4/649

    CPC分类号： C08J5/18 ,  C08F10/00 ,  C08F210/06 ,  C08F210/16 ,  C08J2323/14

    摘要： A propylene-ethylene random copolymer prepared by copolymerizing propylene with ethylene in the substantial absence of a liquid medium with a catalyst system comprising:(A) a solid catalyst component containing magnesium, titanium, a halogen and a first electron donor as an essential component,(B) an organoaluminum compound and(C) a second electron donor compound, wherein an ethylene content (E) of the copolymer is from 3.5 to 7.0% by weight, and wherein a content of a xylene-soluble portion at 20.degree. C. (D) of the copolymer satisfies the relationship D.ltoreq.E+2.0 (% by weight). Films of the copolymer have an excellent appearance (little bleed whitening) and an excellent balance between low-temperature heat-sealing property and rigidity.

    摘要翻译： 基本上不存在液体介质的丙烯与乙烯共聚制备的丙烯 - 乙烯无规共聚物，催化剂体系包含：（A）含有镁，钛，卤素和第一电子给体作为必要组分的固体催化剂组分， （B）有机铝化合物和（C）第二电子给体化合物，其中共聚物的乙烯含量（E）为3.5〜7.0重量％，其中二甲苯可溶部分的含量为20℃ （D）满足D

    Polypropylene random copolymer and film thereof
    2.
    发明授权
    Polypropylene random copolymer and film thereof 失效
    聚丙烯无规共聚物及其膜

    公开(公告)号：US06451936B1

    公开(公告)日：2002-09-17

    申请号：US08465515

    申请日：1995-06-05

    申请人： Hajime Sadatoshi ,  Seiichiro Ima ,  Kazuki Wakamatsu ,  Jiro Mori ,  Eisuke Shiratani

    发明人： Hajime Sadatoshi ,  Seiichiro Ima ,  Kazuki Wakamatsu ,  Jiro Mori ,  Eisuke Shiratani

    IPC分类号： C08F458

    CPC分类号： C08J5/18 ,  C08F10/00 ,  C08F210/06 ,  C08J2323/10 ,  C08F4/6465 ,  C08F210/16 ,  C08F2500/17 ,  C08F2500/12 ,  C08F2500/26 ,  C08F210/08

    摘要： A polypropylene random copolymer obtained by copolymerizing propylene and an &agr;-olefin or propylene, ethylene, and &agr;-olefin using a Ziegler-Natta catalyst substantially in the absence of solvent, wherein propylene content is from 92.3 to 75.0% by weight, the ethylene content (E) is from 0 to 2.7% by weight, and the &agr;-olefin content is from 5.0 to 25.0% by weight, and wherein the content (C) of 20° C. xylene-soluble components in the random copolymer satisfies following formulae (1) to (3); in the copolymer wherein the ethylene content (E) is less than 1.5% by weight, C≦12.0 (weight %)  (1) in the copolymer wherein the ethylene content (E) is from 1.5% by weight to 1.8% by weight, C≦42.0−20.0×E (weight %)  (2) and in the copolymer wherein the ethylene content (E) is from 1.8% by weight to 2.7% by weight, C≦6.0 (weight %)  (3).

    摘要翻译： 通过使用基本上不存在溶剂的齐格勒 - 纳塔催化剂共聚丙烯和α-烯烃或丙烯，乙烯和α-烯烃得到的聚丙烯无规共聚物，其中丙烯含量为92.3〜75.0重量％，乙烯含量 （E）为0〜2.7重量％，α-烯烃含量为5.0〜25.0重量％，无规共聚物中20℃二甲苯可溶成分的含量（C）满足下式 （1）〜（3）所示的共聚物中，乙烯含量（E）为1.5重量％〜1.8重量％的共聚物中，乙烯含量（E）小于1.5重量％ 其中乙烯含量（E）为1.8重量％至2.7重量％的共聚物，

    Polypropylene composition and the film thereof
    5.
    发明授权
    Polypropylene composition and the film thereof 失效
    聚丙烯组合物及其膜

    公开(公告)号：US5654372A

    公开(公告)日：1997-08-05

    申请号：US611759

    申请日：1996-03-08

    申请人： Hajime Sadatoshi ,  Seiichiro Ima ,  Kazuki Wakamatsu ,  Jiro Mori ,  Eisuke Shiratani

    发明人： Hajime Sadatoshi ,  Seiichiro Ima ,  Kazuki Wakamatsu ,  Jiro Mori ,  Eisuke Shiratani

    IPC分类号： C08F297/08 ,  C08L53/00

    CPC分类号： C08L53/00 ,  C08F297/083

    摘要： A polypropylene composition comprising a melt-kneaded polyprolylene composition obtained, using Zieglar-Natta catalyst, by polymerizing a monomer comprising propylene to form a polymer comprising polypropylene (component A) in amount of from 60 to 80% by weight to the total polymer amount in substantially the absence of an inert solvent in a 1st step and then polymerizing a mixture of ethylene content of from 20 to 50% by weight (component B) in a vapor phase to form an ethylene-propylene copolymer (component B) in amount of from 20 to 40% by weight to the total polymer amount in a 2nd step, said polypropylene composition being such that the intrinsic viscosity of component B ([.eta.]B) is at least 2.0 dl/g and the ratio ([.eta.]B/[.eta.]A) of the intrinsic viscosity of the component B to the intrinsic viscosity of the component A ([.eta.]A) is 1.8 or less and the melt flow rate of the polypropylene composition after melt-kneaded being 0.5 to 10 g/10 minutes.

    摘要翻译： 一种聚丙烯组合物，其包含使用齐格列酮 - 纳塔催化剂获得的熔融捏合的聚亚甲基组合物，其通过使包含丙烯的单体聚合以形成聚丙烯（组分A）的聚合物，其量为聚合物总量的60至80重量％ 基本上在第一步骤中不存在惰性溶剂，然后在气相中聚合乙烯含量为20至50重量％（组分B）的混合物以形成乙烯 - 丙烯共聚物（组分B），其量为 在第二步中相对于总聚合物量为20至40重量％，所述聚丙烯组合物使得组分B（ηB）的特性粘度为至少2.0dl / g，并且比率（ηB / 组分B的特性粘度与组分A（ηA）的特性粘度之比为1.8以下，熔融混炼后的聚丙烯组合物的熔体流动速率为0.5〜10g / 10分钟。

    PROPYLENE-ETHYLENE-BUTENE BLOCK COPOLYMER AND MOLDED ARTICLE THEREOF
    7.
    发明申请
    PROPYLENE-ETHYLENE-BUTENE BLOCK COPOLYMER AND MOLDED ARTICLE THEREOF 有权
    丙烯 - 乙烯 - 嵌段共聚物及其成型品

    公开(公告)号：US20100197865A1

    公开(公告)日：2010-08-05

    申请号：US12064647

    申请日：2006-08-29

    申请人： Hideki Oshima ,  Takashi Sanada ,  Kazuki Wakamatsu

    发明人： Hideki Oshima ,  Takashi Sanada ,  Kazuki Wakamatsu

    IPC分类号： C08F255/04

    CPC分类号： C08F297/08 ,  C08F297/083 ,  C08L23/12 ,  C08L53/00 ,  C08L2666/06

    摘要： A propylene-ethylene-butene block copolymer is provided which includes from 60 to 85% by weight of a polypropylene portion and from 15 to 40% by weight of a propylene-ethylene-butene random copolymer portion, wherein the copolymer satisfies the requirements (1) and (2) given below. In addition, a molded article including such a propylene-ethylene-butene block copolymer is provided. (1) The random copolymer portion includes a propylene-ethylene random copolymer component (EP) and a propylene-ethylene-butene random copolymer component (EPB) and the copolymer component (EP) has an intrinsic viscosity of from 1.5 to 8 dl/g and an ethylene unit content of from 20 to 50% by weight, and the copolymer component (EPB) has an intrinsic viscosity of from 0.5 to 8 dl/g, an ethylene unit content of from 47 to 77% by weight and a butene unit component of from 3 to 33% by weight and the total of the ethylene unit content and the butene unit content is from 50 to 80% by weight. (2): The propylene-ethylene-butene block copolymer has a melt flow rate of from 5 to 120 g/10 min.

    摘要翻译： 提供了丙烯 - 乙烯 - 丁烯嵌段共聚物，其包含60至85重量％的聚丙烯部分和15至40重量％的丙烯 - 乙烯 - 丁烯无规共聚物部分，其中所述共聚物满足要求（1 ）和（2）给出。 此外，提供了包含这种丙烯 - 乙烯 - 丁烯嵌段共聚物的模塑制品。 （1）无规共聚物部分包括丙烯 - 乙烯无规共聚物组分（EP）和丙烯 - 乙烯 - 丁烯无规共聚物组分（EPB），共聚物组分（EP）的特性粘度为1.5至8dl / g 乙烯单元含量为20〜50重量％，共聚物成分（EPB）的特性粘度为0.5〜8dl / g，乙烯单元含量为47〜77重量％，丁烯单元 组分为3至33重量％，乙烯单元含量和丁烯单元含量的总和为50至80重量％。 （2）：丙烯 - 乙烯 - 丁烯嵌段共聚物的熔体流动速率为5〜120g / 10分钟。

    Method for feeding boron compounds, fine particles of boron compounds, catalyst components for the polymerization of olefins comprising them, and processes for the production of the particles
    8.
    发明授权
    Method for feeding boron compounds, fine particles of boron compounds, catalyst components for the polymerization of olefins comprising them, and processes for the production of the particles 有权
    硼化合物的供给方法，硼化合物的微粒，包含它们的烯烃聚合的催化剂成分，以及粒子的制造方法

    公开(公告)号：US06613850B1

    公开(公告)日：2003-09-02

    申请号：US09125518

    申请日：1998-11-23

    申请人： Hideki Sato ,  Hiroaki Katayama ,  Kazuki Wakamatsu

    发明人： Hideki Sato ,  Hiroaki Katayama ,  Kazuki Wakamatsu

    IPC分类号： C08F444

    CPC分类号： C07F5/027 ,  B01J21/02 ,  B01J31/14 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  C08F2420/02 ,  C08J5/18 ,  C08J2323/02 ,  C08F4/603 ,  C08F4/61908 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/08 ,  C08F210/08 ,  C08F2500/03 ,  C08F2500/02 ,  C08F2500/10

    摘要： A method for feeding a boron compound, which comprises feeding at least one boron compound selected from (1) to (3) described below in the state suspended or slurried in a solvent continuously to a reactor; a boron compound in the form of fine particles being one or more boron compounds selected from (1) to (3) described below and having a maximum particle diameter of 50 &mgr;m or less; a catalyst component for olefin polymerization consisting of said boron compound in the form of fine particles; a method for producing a boron compound in the form of fine particles which comprises dissolving one or more boron compounds selected from (1) to (3) described below in an aromatic hydrocarbon solvent and then precipitating in an aliphatic hydrocarbon solvent; and a method for producing a boron compound in the form of fine particles which comprises pulverizing one or more boron compounds selected from (1) to (3) described below so that their maximum particle diameter is 50 &mgr;m or less. (1) a boron compound represented by the general formula: BQ1Q2Q3, (2) a boron compound represented by the general formula: G+(BQ1Q2Q3Q4)−, and (3) a boron compound represented by the general formula: (L-H)+(BQ1Q2Q3Q4)−.

    摘要翻译： 一种硼化合物的供给方法，其特征在于，将至少一种选自下述（1）〜（3）的硼化合物以在溶剂中悬浮或浆化至反应器的状态; 微粒形式的硼化合物是选自下述（1）至（3）中并且最大粒径为50μm或更小的一种或多种硼化合物; 用于由细颗粒形式的所述硼化合物组成的用于烯烃聚合的催化剂组分; 一种制备细颗粒形式的硼化合物的方法，包括将一种或多种选自下述（1）至（3）的硼化合物溶解在芳烃溶剂中，然后在脂族烃溶剂中沉淀; 以及一种微细颗粒形式的硼化合物的制造方法，其中包括粉碎一种或多种选自下述（1）至（3）的硼化合物，使其最大粒径为50μm以下。 （1）由通式：BQ1Q2Q3表示的硼化合物，（2）由通式G +（BQ1Q2Q3Q4） - 表示的硼化合物，和（3）由通式（LH）+（ BQ1Q2Q3Q4） - 。

    Gas distributor for use in gas phase polymerization apparatus
    9.
    发明授权
    Gas distributor for use in gas phase polymerization apparatus 失效
    用于气相聚合装置的气体分配器

    公开(公告)号：US5381827A

    公开(公告)日：1995-01-17

    申请号：US157294

    申请日：1993-11-26

    申请人： Hiroyuki Koura ,  Yoshizumi Sasaki ,  Kazuki Wakamatsu ,  Kazuyuki Takemura

    发明人： Hiroyuki Koura ,  Yoshizumi Sasaki ,  Kazuki Wakamatsu ,  Kazuyuki Takemura

    IPC分类号： B01J8/44 ,  C08F2/34 ,  B01J8/20

    CPC分类号： C08F2/34 ,  B01J8/44 ,  Y10T137/85938

    摘要： For use in gas phase polymerization apparatus having an agitator in a fluidized bed polymerization reactor, the present invention provides a gas distributor which has holes, and caps covering the respective holes from above and each having an opening oriented in a substantially horizontal direction at an angle of about 90 to about 135 deg with, and outwardly of, a tangent to a circle centered about the center of the reactor whereby an increase in the gas solid ratio can be prevented in the region above the distributor to ensure efficient discharge of the polymer produced, and the polymer particles can be prevented from falling into a gas room thereunder.

    摘要翻译： 为了在流化床聚合反应器中具有搅拌器的气相聚合装置中使用，本发明提供了一种具有孔的气体分配器和从上方覆盖相应孔的盖，每个孔具有在大致水平方向上以一定角度定向的开口 约90度至约135度，并且向外以与​​反应器中心为中心的圆相切，从而可以在分配器上方的区域中防止气体固体比率的增加，以确保生产的聚合物的有效排放 ，并且可以防止聚合物颗粒落入其中的气室中。