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公开(公告)号：US08471085B2
公开(公告)日：2013-06-25
申请号：US12771122
申请日：2010-04-30
申请人： Orson L. Sydora
发明人： Orson L. Sydora
CPC分类号： B01J31/181 , B01J31/0244 , B01J31/122 , B01J31/143 , B01J31/1608 , B01J2231/20 , B01J2531/0288 , B01J2531/62 , C07C2/32 , C07C2531/14 , C07C2531/18 , C07C2531/34 , Y02P20/582 , C07C11/107
摘要： Among other things, this disclosure provides an olefin oligomerization system and process, the system comprising: a) a transition metal compound; b) a pyrrole compound having a hydrogen atom on at the 5-position or the 2- and 5-position of a pyrrole compound and having a bulky substituent located on each carbon atom adjacent to the carbon atom bearing a hydrogen atom at the 5-position or the 2- and 5-position of a pyrrole compound. These catalyst system have significantly improved productivities, selectivities to 1-hexene, and provides higher purity 1-hexene within the C6 fraction than catalyst systems using 2,4-dimethyl pyrrole.
摘要翻译： 除此之外，本公开提供烯烃低聚体系和方法，该体系包括：a）过渡金属化合物; b）在吡咯化合物的5-位或2-和5-位上具有氢原子的吡咯化合物，并且位于与在5-位上具有氢原子的碳原子相邻的每个碳原子上具有庞大取代基的吡咯化合物， 位置或吡咯化合物的2-和5-位。 这些催化剂体系对使用2,4-二甲基吡咯的催化剂体系具有显着提高的生产率，对1-己烯的选择性，并且在C6馏分内提供更高纯度的1-己烯。
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公开(公告)号：US20130150605A1
公开(公告)日：2013-06-13
申请号：US13323191
申请日：2011-12-12
IPC分类号： C07F11/00
CPC分类号： C07F11/00 , B01J2231/20 , B01J2531/62 , C07C2/32 , C07C2523/26 , C07F11/005 , C07F13/005 , C07C11/02
摘要： This disclosure provides a process for making transition metal carboxylate compositions by combining in an polar aprotic first solvent a transition metal precursor and a Group 1 or Group 2 metal carboxylate under substantially acid-free and substantially anhydrous conditions, to generate a mixture comprising the transition metal carboxylate composition. Optionally, the transition metal carboxylate composition can be purified, for example, by substantially removing the first solvent provide a residue comprising the transition metal carboxylate composition, and also optionally, further by extracting the transition metal carboxylate composition from the residue with a non-coordinating second solvent to provide an extract comprising the transition metal carboxylate composition.
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公开(公告)号：US09352309B2
公开(公告)日：2016-05-31
申请号：US12609272
申请日：2009-10-30
申请人： Orson L. Sydora
发明人： Orson L. Sydora
IPC分类号： C07C2/24 , B01J31/02 , C08F4/42 , B01J31/34 , B01J21/02 , B01J31/12 , C07C2/30 , C08F10/00 , B01J31/14
CPC分类号： B01J31/122 , B01J31/0237 , B01J31/0239 , B01J31/0244 , B01J31/143 , B01J2231/20 , B01J2531/62 , Y02P20/582 , Y10S585/903
摘要： Among other things, this disclosure provides an olefin oligomerization system and process, the system comprising: a) a transition metal compound; b) a pyrrole compound having independently-selected C1 to C18 organyl groups at the 2- and 5-positions, wherein at least one of the organyl group alpha-carbon atoms attached to the 2- and 5-positions of the pyrrole compound is a secondary carbon atoms; and c) a metal alkyl. For example, the 2,5-diethylpyrrole (2,5-DEP)-based catalyst systems can afford a productivity increases over unsubstituted pyrrole catalyst systems, non-2,5-disubstituted catalyst systems, and 2,5-dimethylpyrrole (2,5-DMP) catalyst systems.
摘要翻译： 除此之外，本公开提供烯烃低聚体系和方法，该体系包括：a）过渡金属化合物; b）在2-和5-位具有独立选择的C1至C18有机基团的吡咯化合物，其中与吡咯化合物的2-和5-位连接的至少一个有机基团的α-碳原子是 次级碳原子; 和c）金属烷基。 例如，基于2,5-二乙基吡咯（2,5-DEP）的催化剂体系可以提供比未取代的吡咯催化剂体系，非2,5-二取代的催化剂体系和2,5-二甲基吡咯（2， 5-DMP）催化剂体系。
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4.发明申请Phosphinyl Amidine Compounds, Metal Complexes, Catalyst Systems, and Their Use to Oligomerize or Polymerize Olefins 有权磷化脒化合物，金属络合物，催化剂体系及其用于低聚或聚合烯烃的用途公开(公告)号：US20120309965A1
公开(公告)日：2012-12-06
申请号：US13519825
申请日：2010-12-29
IPC分类号： B01J31/24 , C07C2/02 , C07F9/6533 , C07F9/6539 , C07F9/50 , C07F19/00
CPC分类号： C07F11/005 , B01J31/143 , B01J31/18 , B01J31/188 , B01J31/189 , B01J31/2295 , B01J2231/20 , B01J2531/62 , B01J2531/824 , B01J2531/828 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2/32 , C07C2/36 , C07C2531/14 , C07C2531/24 , C07D233/54 , C07D265/30 , C07F9/28 , C07F9/46 , C07F9/5004 , C07F9/5022 , C07F9/6533 , C07F9/6539 , C07F11/00 , C07F19/005 , C08F4/78 , C08F10/00 , C08F110/02 , C08F210/16 , C08G61/04 , C08F4/69068 , C08F210/14
摘要： N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.
摘要翻译： 描述了N2-氧膦基脒化合物，N2-氧膦基脒基化物，N2-氧膦基脒金属盐络合物，N2-氧膦基脒基金属盐络合物。 还公开了制备N 2 - 氧膦基脒化合物，N 2 - 氧膦基脒基化物，N 2 - 氧膦基脒金属盐络合物和N 2 - 氧膦基脒基金属盐络合物的方法。 还公开了使用N 2 - 氧膦基脒金属盐络合物和N 2 - 氧膦基脒基金属盐络合物的催化剂体系以及使用N 2 - 氧膦基脒化合物，N 2 - 氧膦基脒基化物，N 2 - 氧膦基脒金属盐络合物和N 2 - 氧化脒基金属盐络合物，用于烯烃的低聚和/或聚合。
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5.发明申请公开(公告)号：US20120172645A1
公开(公告)日：2012-07-05
申请号：US12980457
申请日：2010-12-29
申请人： Orson L. Sydora
发明人： Orson L. Sydora
CPC分类号： C07F9/46 , B01J31/143 , B01J31/189 , B01J2231/20 , B01J2531/62 , C07C2/36 , C07C2531/24 , C07F11/00 , Y02P20/52 , C07C11/02 , C07C11/107
摘要： This disclosure provides for a process for preparing a catalyst system comprising a) contacting a metal compound, a diphosphino aminyl ligand metal complex, and a metal alkyl for a time period to form a mixture; and b) aging the mixture. The disclosure also provides for olefin oligomerization process comprising: a) contacting i) a metal compound, ii) a diphosphino aminyl ligand, and iii) a metal alkyl to form a mixture; b) aging the mixture; c) contacting the aged mixture with an olefin monomer; and d) forming an olefin oligomer product.
摘要翻译： 本公开内容提供了一种制备催化剂体系的方法，包括：a）使金属化合物，二膦基乙炔基配体金属络合物和金属烷基接触一段时间以形成混合物; 和b）老化混合物。 本公开还提供了烯烃低聚方法，其包括：a）使i）金属化合物，ii）二膦基乙烯基配体和iii）金属烷基接触以形成混合物; b）老化混合物; c）使老化的混合物与烯烃单体接触; 和d）形成烯烃低聚物产物。
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6.发明申请公开(公告)号：US20120083609A1
公开(公告)日：2012-04-05
申请号：US12895945
申请日：2010-10-01
IPC分类号： C07D207/323
CPC分类号： C07D207/323
摘要： The present invention discloses processes for producing substituted pyrrole compounds, such as 2,5-disubstituted pyrroles. Synthetic processes which directly convert substituted furan compounds to substituted pyrrole compounds, via a reaction of the substituted furan compound with ammonia and/or an ammonium salt in the presence of a catalyst, also are described.
摘要翻译： 本发明公开了制备取代吡咯化合物如2,5-二取代吡咯的方法。 还描述了在催化剂存在下通过取代的呋喃化合物与氨和/或铵盐的反应直接将取代的呋喃化合物转化为取代的吡咯化合物的合成方法。
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7.发明授权Phosphinyl amidine compounds, metal complexes, catalyst systems, and their use to oligomerize or polymerize olefins 有权磷化脒化合物，金属络合物，催化剂体系及其烯烃低聚或聚合的用途公开(公告)号：US08680003B2
公开(公告)日：2014-03-25
申请号：US13519825
申请日：2010-12-29
IPC分类号： B01J31/18 , C07D265/30 , C07D233/54 , C07F9/28
CPC分类号： C07F11/005 , B01J31/143 , B01J31/18 , B01J31/188 , B01J31/189 , B01J31/2295 , B01J2231/20 , B01J2531/62 , B01J2531/824 , B01J2531/828 , B01J2531/842 , B01J2531/845 , B01J2531/847 , C07C2/32 , C07C2/36 , C07C2531/14 , C07C2531/24 , C07D233/54 , C07D265/30 , C07F9/28 , C07F9/46 , C07F9/5004 , C07F9/5022 , C07F9/6533 , C07F9/6539 , C07F11/00 , C07F19/005 , C08F4/78 , C08F10/00 , C08F110/02 , C08F210/16 , C08G61/04 , C08F4/69068 , C08F210/14
摘要： N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.
摘要翻译： 描述了N2-氧膦基脒化合物，N2-氧膦基脒基化物，N2-氧膦基脒金属盐络合物，N2-氧膦基脒基金属盐络合物。 还公开了制备N 2 - 氧膦基脒化合物，N 2 - 氧膦基脒基，N 2 - 氧膦基脒金属盐络合物和N 2 - 氧膦酰基脒基金属盐络合物的方法。 还公开了使用N 2 - 氧膦基脒金属盐络合物和N 2 - 氧膦基脒基金属盐络合物的催化剂体系以及使用N 2 - 氧膦基脒化合物，N 2 - 氧膦基脒基化物，N 2 - 氧膦基脒金属盐络合物和N 2 - 氧化脒基金属盐络合物，用于烯烃的低聚和/或聚合。
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公开(公告)号：US20130150642A1
公开(公告)日：2013-06-13
申请号：US13323328
申请日：2011-12-12
CPC分类号： B01J31/04 , B01J31/143 , B01J31/181 , B01J31/2226 , B01J31/2239 , B01J2231/20 , B01J2531/62
摘要： This disclosure provides for new catalyst systems and new methods for preparing and using the catalyst systems for generating a trimerization product. In an aspect, the new catalyst systems comprise a chromium carboxylate that is prepared by anhydrous metathesis. In another aspect, the catalyst system comprise a chromium carboxylate that is prepared by anhydrous metathesis and a metal pyrrolide compound. The catalyst systems imparts improved performance and/or reduced catalyst system cost to an olefin trimerization process.
摘要翻译： 本公开提供了新的催化剂体系和用于制备和使用催化剂体系以产生三聚产物的新方法。 一方面，新的催化剂体系包含通过无水复分解制备的羧酸铬。 另一方面，催化剂体系包含通过无水复分解和金属吡咯化合物制备的羧酸铬。 催化剂体系赋予烯烃三聚过程改进的性能和/或降低的催化剂体系成本。
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9.发明授权公开(公告)号：US08362278B2
公开(公告)日：2013-01-29
申请号：US12895945
申请日：2010-10-01
IPC分类号： C07D207/323
CPC分类号： C07D207/323
摘要： The present invention discloses processes for producing substituted pyrrole compounds, such as 2,5-disubstituted pyrroles. Synthetic processes which directly convert substituted furan compounds to substituted pyrrole compounds, via a reaction of the substituted furan compound with ammonia and/or an ammonium salt in the presence of a catalyst, also are described.
摘要翻译： 本发明公开了制备取代吡咯化合物如2,5-二取代吡咯的方法。 还描述了在催化剂存在下通过取代的呋喃化合物与氨和/或铵盐的反应直接将取代的呋喃化合物转化为取代的吡咯化合物的合成方法。
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10.发明申请公开(公告)号：US20100113257A1
公开(公告)日：2010-05-06
申请号：US12609189
申请日：2009-10-30
IPC分类号： B01J31/00
CPC分类号： B01J31/122 , B01J31/0237 , B01J31/0239 , B01J31/0244 , B01J31/143 , B01J2231/20 , B01J2531/62 , Y02P20/582 , Y10S585/903
摘要： A system and method for preparing and using a metal precursor diluent composition are described. The composition includes a metal precursor, and about 18% to about 80% by weight of an olefinic diluent having between 6 and 18 carbon atoms. Such compositions may be used in oligomerization catalyst systems.
摘要翻译： 描述了制备和使用金属前体稀释剂组合物的系统和方法。 该组合物包含金属前体，约18％至约80％重量的具有6至18个碳原子的烯烃稀释剂。 这种组合物可用于低聚催化剂体系。
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