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    Oligomerization catalyst system and process for oligomerizing olefins
    1.
    发明授权
    Oligomerization catalyst system and process for oligomerizing olefins 有权
    低聚催化剂体系和烯烃低聚方法

    公开(公告)号：US09352309B2

    公开(公告)日：2016-05-31

    申请号：US12609272

    申请日：2009-10-30

    申请人： Orson L. Sydora

    发明人： Orson L. Sydora

    IPC分类号： C07C2/24 ,  B01J31/02 ,  C08F4/42 ,  B01J31/34 ,  B01J21/02 ,  B01J31/12 ,  C07C2/30 ,  C08F10/00 ,  B01J31/14

    CPC分类号： B01J31/122 ,  B01J31/0237 ,  B01J31/0239 ,  B01J31/0244 ,  B01J31/143 ,  B01J2231/20 ,  B01J2531/62 ,  Y02P20/582 ,  Y10S585/903

    摘要： Among other things, this disclosure provides an olefin oligomerization system and process, the system comprising: a) a transition metal compound; b) a pyrrole compound having independently-selected C1 to C18 organyl groups at the 2- and 5-positions, wherein at least one of the organyl group alpha-carbon atoms attached to the 2- and 5-positions of the pyrrole compound is a secondary carbon atoms; and c) a metal alkyl. For example, the 2,5-diethylpyrrole (2,5-DEP)-based catalyst systems can afford a productivity increases over unsubstituted pyrrole catalyst systems, non-2,5-disubstituted catalyst systems, and 2,5-dimethylpyrrole (2,5-DMP) catalyst systems.

    摘要翻译： 除此之外，本公开提供烯烃低聚体系和方法，该体系包括：a）过渡金属化合物; b）在2-和5-位具有独立选择的C1至C18有机基团的吡咯化合物，其中与吡咯化合物的2-和5-位连接的至少一个有机基团的α-碳原子是 次级碳原子; 和c）金属烷基。 例如，基于2,5-二乙基吡咯（2,5-DEP）的催化剂体系可以提供比未取代的吡咯催化剂体系，非2,5-二取代的催化剂体系和2,5-二甲基吡咯（2， 5-DMP）催化剂体系。

    Oligomerization catalyst system and process for oligomerizing olefins
    4.
    发明授权
    Oligomerization catalyst system and process for oligomerizing olefins 有权
    低聚催化剂体系和烯烃低聚方法

    公开(公告)号：US08471085B2

    公开(公告)日：2013-06-25

    申请号：US12771122

    申请日：2010-04-30

    申请人： Orson L. Sydora

    发明人： Orson L. Sydora

    IPC分类号： C07C2/24 ,  C07C2/02 ,  B01J31/14

    CPC分类号： B01J31/181 ,  B01J31/0244 ,  B01J31/122 ,  B01J31/143 ,  B01J31/1608 ,  B01J2231/20 ,  B01J2531/0288 ,  B01J2531/62 ,  C07C2/32 ,  C07C2531/14 ,  C07C2531/18 ,  C07C2531/34 ,  Y02P20/582 ,  C07C11/107

    摘要： Among other things, this disclosure provides an olefin oligomerization system and process, the system comprising: a) a transition metal compound; b) a pyrrole compound having a hydrogen atom on at the 5-position or the 2- and 5-position of a pyrrole compound and having a bulky substituent located on each carbon atom adjacent to the carbon atom bearing a hydrogen atom at the 5-position or the 2- and 5-position of a pyrrole compound. These catalyst system have significantly improved productivities, selectivities to 1-hexene, and provides higher purity 1-hexene within the C6 fraction than catalyst systems using 2,4-dimethyl pyrrole.

    摘要翻译： 除此之外，本公开提供烯烃低聚体系和方法，该体系包括：a）过渡金属化合物; b）在吡咯化合物的5-位或2-和5-位上具有氢原子的吡咯化合物，并且位于与在5-位上具有氢原子的碳原子相邻的每个碳原子上具有庞大取代基的吡咯化合物， 位置或吡咯化合物的2-和5-位。 这些催化剂体系对使用2,4-二甲基吡咯的催化剂体系具有显着提高的生产率，对1-己烯的选择性，并且在C6馏分内提供更高纯度的1-己烯。

    System and method of deactivating and quenching an oligomerization catalyst
    6.
    发明授权
    System and method of deactivating and quenching an oligomerization catalyst 有权
    使低聚催化剂失活和淬灭的系统和方法

    公开(公告)号：US08049052B2

    公开(公告)日：2011-11-01

    申请号：US12609631

    申请日：2009-10-30

    申请人： Bruce E Kreischer ,  Orson L Sydora ,  Ronald D Knudsen

    发明人： Bruce E Kreischer ,  Orson L Sydora ,  Ronald D Knudsen

    IPC分类号： C07C2/22

    CPC分类号： B01J31/122 ,  B01J31/0237 ,  B01J31/0239 ,  B01J31/0244 ,  B01J31/143 ,  B01J2231/20 ,  B01J2531/62 ,  Y02P20/582 ,  Y10S585/903

    摘要： A method of deactivate a catalyst system is described. The method may include contacting a reactor effluent comprising a catalyst system, an oligomerized olefin, and diluent with a kill agent to at least partially deactivate the catalyst system, separating the reactor effluent into one or more first streams comprising oligomerized olefin and diluent, the one or more first streams being substantially devoid of the at least partially deactivated catalyst, and a second stream comprising the deactivated catalyst; and contacting the second stream with a quench agent.

    摘要翻译： 描述了使催化剂体系失活的方法。 该方法可以包括将包含催化剂体系，低聚烯烃和稀释剂的反应器流出物与杀灭剂接触以使催化剂体系至少部分失活，将反应器流出物分离成一个或多个包含低聚烯烃和稀释剂的第一流， 或更多的第一物流基本上不含至少部分失活的催化剂，以及包含失活的催化剂的第二物流; 并使第二流与骤冷剂接触。

    Preparation of transition metal carboxylates
    7.
    发明授权
    Preparation of transition metal carboxylates 有权
    过渡金属羧酸盐的制备

    公开(公告)号：US08957235B2

    公开(公告)日：2015-02-17

    申请号：US13323191

    申请日：2011-12-12

    申请人： Orson L Sydora ,  Ronald D Knudsen ,  Eduardo J Baralt

    发明人： Orson L Sydora ,  Ronald D Knudsen ,  Eduardo J Baralt

    IPC分类号： C07F11/00 ,  C07F13/00

    CPC分类号： C07F11/00 ,  B01J2231/20 ,  B01J2531/62 ,  C07C2/32 ,  C07C2523/26 ,  C07F11/005 ,  C07F13/005 ,  C07C11/02

    摘要： This disclosure provides a process for making transition metal carboxylate compositions by combining in an polar aprotic first solvent a transition metal precursor and a Group 1 or Group 2 metal carboxylate under substantially acid-free and substantially anhydrous conditions, to generate a mixture comprising the transition metal carboxylate composition. Optionally, the transition metal carboxylate composition can be purified, for example, by substantially removing the first solvent provide a residue comprising the transition metal carboxylate composition, and also optionally, further by extracting the transition metal carboxylate composition from the residue with a non-coordinating second solvent to provide an extract comprising the transition metal carboxylate composition.

    摘要翻译： 本公开提供了通过在极性非质子传递的第一溶剂中过渡金属前体和基本上无酸和基本上无水的条件下的第1族或第2族金属羧酸盐组合来制备过渡金属羧酸盐组合物的方法，以产生包含过渡金属 羧酸盐组合物。 任选地，过渡金属羧酸盐组合物可以例如通过基本上除去第一溶剂提供包含过渡金属羧酸盐组合物的残余物，还可以任选地进一步通过非配位性的从残余物中提取过渡金属羧酸盐组合物来纯化 第二溶剂以提供包含过渡金属羧酸盐组合物的提取物。