公开(公告)号：US20060014914A1

公开(公告)日：2006-01-19

申请号：US11180725

申请日：2005-07-14

Applicant: Kazuyuki Takemura ,  Yoichi Konno ,  Kazuki Wakamatsu

Inventor： Kazuyuki Takemura ,  Yoichi Konno ,  Kazuki Wakamatsu

IPC: C08F2/00 ,  B01J19/00 ,  B01J19/18

CPC classification number: B01J8/003 ,  B01J8/1809 ,  B01J8/1872 ,  B01J2208/00619 ,  B01J2208/00752 ,  B01J2208/00761 ,  B01J2219/00033 ,  B01J2219/0004 ,  C08F10/00 ,  C08F110/02 ,  Y10S526/92 ,  C08F2/01

Abstract: An apparatus and method for continuous polymerization of olefin(s), and a method for transferring a polymer powder from one reactor to another in the apparatus are disclosed. The apparatus includes a plurality of serially disposed gas-phase polymerization reactors including a combination of an upstream and downstream reactors and a gas exchange vessel disposed between both reactors. The gas exchange vessel is connected to the upstream and downstream reactors by a first and second transfer conduits, respectively. The gas exchange vessel has a gas distributor plate therein which partitions the gas exchange vessel into an upper section having a gas exchange chamber and a lower section. In the gas exchange chamber, the gas transferred from the upstream reactor together with a polymer powder is exchange at least partly with fresh gas introduced through the gas distributor plate via the lower section. The polymer powder is then transferred to the downstream reactor.

Abstract translation: 公开了一种用于连续聚合烯烃的装置和方法，以及用于在装置中将聚合物粉末从一个反应器转移到另一反应器的方法。 该装置包括多个串联设置的气相聚合反应器，包括上游和下游反应器的组合以及设置在两个反应器之间的气体交换容器。 气体交换容器分别通过第一和第二输送管道连接到上游和下游反应器。 气体交换容器在其中具有气体分配板，其将气体交换容器分隔成具有气体交换室和下部的上部。 在气体交换室中，从上游反应器与聚合物粉末一起转移的气体至少部分地通过下部通过气体分布板引入的新鲜气体进行交换。 然后将聚合物粉末转移到下游反应器。

公开(公告)号：US07465772B2

公开(公告)日：2008-12-16

申请号：US11180725

申请日：2005-07-14

Applicant: Kazuyuki Takemura ,  Yoichi Konno ,  Kazuki Wakamatsu

Inventor： Kazuyuki Takemura ,  Yoichi Konno ,  Kazuki Wakamatsu

IPC: C08F2/34 ,  B01J19/24 ,  F26B17/10

CPC classification number: B01J8/003 ,  B01J8/1809 ,  B01J8/1872 ,  B01J2208/00619 ,  B01J2208/00752 ,  B01J2208/00761 ,  B01J2219/00033 ,  B01J2219/0004 ,  C08F10/00 ,  C08F110/02 ,  Y10S526/92 ,  C08F2/01

Abstract: An apparatus and method for continuous polymerization of olefin(s), and a method for transferring a polymer powder from one reactor to another in the apparatus are disclosed. The apparatus includes a plurality of serially disposed gas-phase polymerization reactors including a combination of an upstream and downstream reactors and a gas exchange vessel disposed between both reactors. The gas exchange vessel is connected to the upstream and downstream reactors by a first and second transfer conduits, respectively. The gas exchange vessel has a gas distributor plate therein which partitions the gas exchange vessel into an upper section having a gas exchange chamber and a lower section. In the gas exchange chamber, the gas transferred from the upstream reactor together with a polymer powder is exchange at least partly with fresh gas introduced through the gas distributor plate via the lower section. The polymer powder is then transferred to the downstream reactor.

Abstract translation: 公开了一种用于连续聚合烯烃的装置和方法，以及用于在装置中将聚合物粉末从一个反应器转移到另一反应器的方法。 该装置包括多个串联设置的气相聚合反应器，包括上游和下游反应器的组合以及设置在两个反应器之间的气体交换容器。 气体交换容器分别通过第一和第二输送管道连接到上游和下游反应器。 气体交换容器在其中具有气体分配板，其将气体交换容器分隔成具有气体交换室和下部的上部。 在气体交换室中，从上游反应器与聚合物粉末一起转移的气体至少部分地通过下部通过气体分布板引入的新鲜气体进行交换。 然后将聚合物粉末转移到下游反应器。

公开(公告)号：US5381827A

公开(公告)日：1995-01-17

申请号：US157294

申请日：1993-11-26

Applicant: Hiroyuki Koura ,  Yoshizumi Sasaki ,  Kazuki Wakamatsu ,  Kazuyuki Takemura

Inventor： Hiroyuki Koura ,  Yoshizumi Sasaki ,  Kazuki Wakamatsu ,  Kazuyuki Takemura

IPC: B01J8/44 ,  C08F2/34 ,  B01J8/20

CPC classification number: C08F2/34 ,  B01J8/44 ,  Y10T137/85938

Abstract: For use in gas phase polymerization apparatus having an agitator in a fluidized bed polymerization reactor, the present invention provides a gas distributor which has holes, and caps covering the respective holes from above and each having an opening oriented in a substantially horizontal direction at an angle of about 90 to about 135 deg with, and outwardly of, a tangent to a circle centered about the center of the reactor whereby an increase in the gas solid ratio can be prevented in the region above the distributor to ensure efficient discharge of the polymer produced, and the polymer particles can be prevented from falling into a gas room thereunder.

Abstract translation: 为了在流化床聚合反应器中具有搅拌器的气相聚合装置中使用，本发明提供了一种具有孔的气体分配器和从上方覆盖相应孔的盖，每个孔具有在大致水平方向上以一定角度定向的开口 约90度至约135度，并且向外以与​​反应器中心为中心的圆相切，从而可以在分配器上方的区域中防止气体固体比率的增加，以确保生产的聚合物的有效排放 ，并且可以防止聚合物颗粒落入其中的气室中。

公开(公告)号：US20100197865A1

公开(公告)日：2010-08-05

申请号：US12064647

申请日：2006-08-29

Applicant: Hideki Oshima ,  Takashi Sanada ,  Kazuki Wakamatsu

Inventor： Hideki Oshima ,  Takashi Sanada ,  Kazuki Wakamatsu

IPC: C08F255/04

CPC classification number: C08F297/08 ,  C08F297/083 ,  C08L23/12 ,  C08L53/00 ,  C08L2666/06

Abstract: A propylene-ethylene-butene block copolymer is provided which includes from 60 to 85% by weight of a polypropylene portion and from 15 to 40% by weight of a propylene-ethylene-butene random copolymer portion, wherein the copolymer satisfies the requirements (1) and (2) given below. In addition, a molded article including such a propylene-ethylene-butene block copolymer is provided. (1) The random copolymer portion includes a propylene-ethylene random copolymer component (EP) and a propylene-ethylene-butene random copolymer component (EPB) and the copolymer component (EP) has an intrinsic viscosity of from 1.5 to 8 dl/g and an ethylene unit content of from 20 to 50% by weight, and the copolymer component (EPB) has an intrinsic viscosity of from 0.5 to 8 dl/g, an ethylene unit content of from 47 to 77% by weight and a butene unit component of from 3 to 33% by weight and the total of the ethylene unit content and the butene unit content is from 50 to 80% by weight. (2): The propylene-ethylene-butene block copolymer has a melt flow rate of from 5 to 120 g/10 min.

Abstract translation: 提供了丙烯 - 乙烯 - 丁烯嵌段共聚物，其包含60至85重量％的聚丙烯部分和15至40重量％的丙烯 - 乙烯 - 丁烯无规共聚物部分，其中所述共聚物满足要求（1 ）和（2）给出。 此外，提供了包含这种丙烯 - 乙烯 - 丁烯嵌段共聚物的模塑制品。 （1）无规共聚物部分包括丙烯 - 乙烯无规共聚物组分（EP）和丙烯 - 乙烯 - 丁烯无规共聚物组分（EPB），共聚物组分（EP）的特性粘度为1.5至8dl / g 乙烯单元含量为20〜50重量％，共聚物成分（EPB）的特性粘度为0.5〜8dl / g，乙烯单元含量为47〜77重量％，丁烯单元 组分为3至33重量％，乙烯单元含量和丁烯单元含量的总和为50至80重量％。 （2）：丙烯 - 乙烯 - 丁烯嵌段共聚物的熔体流动速率为5〜120g / 10分钟。

公开(公告)号：US06613850B1

公开(公告)日：2003-09-02

申请号：US09125518

申请日：1998-11-23

Applicant: Hideki Sato ,  Hiroaki Katayama ,  Kazuki Wakamatsu

Inventor： Hideki Sato ,  Hiroaki Katayama ,  Kazuki Wakamatsu

IPC: C08F444

CPC classification number: C07F5/027 ,  B01J21/02 ,  B01J31/14 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/6592 ,  C08F10/00 ,  C08F210/16 ,  C08F2420/02 ,  C08J5/18 ,  C08J2323/02 ,  C08F4/603 ,  C08F4/61908 ,  C08F210/14 ,  C08F2500/12 ,  C08F2500/08 ,  C08F210/08 ,  C08F2500/03 ,  C08F2500/02 ,  C08F2500/10

Abstract: A method for feeding a boron compound, which comprises feeding at least one boron compound selected from (1) to (3) described below in the state suspended or slurried in a solvent continuously to a reactor; a boron compound in the form of fine particles being one or more boron compounds selected from (1) to (3) described below and having a maximum particle diameter of 50 &mgr;m or less; a catalyst component for olefin polymerization consisting of said boron compound in the form of fine particles; a method for producing a boron compound in the form of fine particles which comprises dissolving one or more boron compounds selected from (1) to (3) described below in an aromatic hydrocarbon solvent and then precipitating in an aliphatic hydrocarbon solvent; and a method for producing a boron compound in the form of fine particles which comprises pulverizing one or more boron compounds selected from (1) to (3) described below so that their maximum particle diameter is 50 &mgr;m or less. (1) a boron compound represented by the general formula: BQ1Q2Q3, (2) a boron compound represented by the general formula: G+(BQ1Q2Q3Q4)−, and (3) a boron compound represented by the general formula: (L-H)+(BQ1Q2Q3Q4)−.

Abstract translation: 一种硼化合物的供给方法，其特征在于，将至少一种选自下述（1）〜（3）的硼化合物以在溶剂中悬浮或浆化至反应器的状态; 微粒形式的硼化合物是选自下述（1）至（3）中并且最大粒径为50μm或更小的一种或多种硼化合物; 用于由细颗粒形式的所述硼化合物组成的用于烯烃聚合的催化剂组分; 一种制备细颗粒形式的硼化合物的方法，包括将一种或多种选自下述（1）至（3）的硼化合物溶解在芳烃溶剂中，然后在脂族烃溶剂中沉淀; 以及一种微细颗粒形式的硼化合物的制造方法，其中包括粉碎一种或多种选自下述（1）至（3）的硼化合物，使其最大粒径为50μm以下。 （1）由通式：BQ1Q2Q3表示的硼化合物，（2）由通式G +（BQ1Q2Q3Q4） - 表示的硼化合物，和（3）由通式（LH）+（ BQ1Q2Q3Q4） - 。

公开(公告)号：US5268425A

公开(公告)日：1993-12-07

申请号：US890221

申请日：1992-05-29

Applicant: Motonobu Furuta ,  Kazuki Wakamatsu ,  Takashi Maruyama ,  Mitsuji Tsuji

Inventor： Motonobu Furuta ,  Kazuki Wakamatsu ,  Takashi Maruyama ,  Mitsuji Tsuji

IPC: C08L23/12 ,  C08L51/04 ,  C08L51/06 ,  C08L61/06 ,  C08L63/00 ,  C08L67/00 ,  C08L69/00 ,  C08L71/12 ,  C08L77/00 ,  C08L79/08 ,  C08L81/02 ,  C08L83/04

CPC classification number: C08L51/06 ,  C08L23/12 ,  C08L51/04 ,  C08L71/123 ,  C08L61/06 ,  C08L63/00 ,  C08L67/00 ,  C08L69/00 ,  C08L77/00 ,  C08L79/08 ,  C08L81/02 ,  C08L83/04 ,  Y10S525/905

Abstract: Disclosed are thermoplastic resin compositions, comprising:(a) a polyphenylene ether resin or a resin composition containing a poplyphenylene ether,(b) a modified propylene polymer, or a propylene based resin composition containing the modified propylene polymer and/or a propylene polymer, and(c) optionally, a rubbery substance,wherein the proportion of the component (a) to the sum of the components (a) and (b) is 1 to 90% by weight, and that of the component (b) to the sum of the components (a) and (b) is 99 to 10% by weight, and when the component (c) is present, the proportion of the component (c) to the sum of the components (a) and (b) is 1 to 50 parts by weight per 100 parts by weight of (a) plus (b).

Abstract translation: 公开了热塑性树脂组合物，其包含：（a）聚苯醚树脂或含有苯撑醚的树脂组合物，（b）改性丙烯聚合物或含有改性丙烯聚合物和/或丙烯聚合物的丙烯类树脂组合物， 和（c）任选的橡胶状物质，其中成分（a）与成分（a）和（b）之和的比例为1〜90重量％，成分（b）相对于 组分（a）和（b）的总和为99至10重量％，当存在组分（c）时，组分（c）与组分（a）和（b）之和的比例 相对于（a）加（b）每100重量份为1〜50重量份。

公开(公告)号：US4883842A

公开(公告)日：1989-11-28

申请号：US172786

申请日：1988-03-28

Applicant: Shigeo Tanaka ,  Jiro Sakai ,  Tomohisa Fukao ,  Kizuku Wakatsuki ,  Kazuki Wakamatsu

Inventor： Shigeo Tanaka ,  Jiro Sakai ,  Tomohisa Fukao ,  Kizuku Wakatsuki ,  Kazuki Wakamatsu

IPC: C08L23/02 ,  C08L23/24 ,  C09K9/02

CPC classification number: C09K9/02 ,  C08L23/02 ,  C08L23/24

Abstract: There is disclosed resin composition comprising 1 to 99% by weight of a polymer A and 1 to 99% by weight of a polymer B, the polymer A and B having refractive indexes which permit satisfaction of the relation:a.ltoreq.0.015 and b-a.gtoreq.0.005wherein a and b are the minimum and the maximum, respectively, of absolute value of the difference between the refractive indexes of the polymers A and B in the temperature range of 20.degree. to 100.degree. C.; said composition being useful as a functional resin for buildings, etc.

公开(公告)号：US4801650A

公开(公告)日：1989-01-31

申请号：US93286

申请日：1987-09-04

Applicant: Kizuku Wakatsuki ,  Kazuki Wakamatsu

Inventor： Kizuku Wakatsuki ,  Kazuki Wakamatsu

IPC: C08F2/00 ,  C08F2/04 ,  C08F2/06 ,  C08F8/50 ,  C08F10/00 ,  C08F210/14 ,  C08F255/00 ,  C08F255/08 ,  C08F297/08 ,  C08L23/18

CPC classification number: C08F210/14

Abstract: A process for producing a 4-methylpentene-1 copolymer comprising copolymerizing 4-methylpentene-1 with other .alpha.-olefin in a hydrocarbon solvent in the presence of a Ziegler-Natta catalyst and a resin composition containing the 4-methylpentene-1 copolymer are disclosed. The copolymerization comprises a first stage in which (A) a homopolymer or random copolymer of 4-methylpentene-1 having an .alpha.-olefin content of not more than 3 mol % and an intrinsic viscosity of at least 2.5 dl/g is prepared and a second stage in which (B) a random copolymer having an .alpha.-olefin content higher than that of the polymer (A) and no higher than 9 mol % and an intrinsic viscosity of at least 2.5 dl/g is prepared, and the produced copolymer insoluble in the solvent is separated to recover a 4-methylpentene-1 copolymer containing from 5 to 80% by weight of the polymer (A). The process produces a solvent-insoluble copolymer in an increased yield without impairing transparency of the copolymer.

公开(公告)号：US4254237A

公开(公告)日：1981-03-03

申请号：US30523

申请日：1979-04-16

Applicant: Akinobu Shiga ,  Masahiro Kakugo ,  Hajime Sadatoshi ,  Kazuki Wakamatsu ,  Hiroshi Yoshioka

Inventor： Akinobu Shiga ,  Masahiro Kakugo ,  Hajime Sadatoshi ,  Kazuki Wakamatsu ,  Hiroshi Yoshioka

IPC: C08F297/00 ,  C08F297/08

CPC classification number: C08F297/086

Abstract: A process for producing propylene-ethylene block copolymers by a three-step polymerization technique using a stereoregular catalyst, characterized in that the first-step polymerization is carried out by supplying propylene alone or a propylene/ethylene mixture so that the ethylene/propylene reaction ratio is 6/94 or less, thereby polymerizing 60 to 95% by weight of the total polymerization amount, the second-step polymerization is carried out by supplying a propylene/ethylene mixture so that the ethylene/propylene reaction ratio is 15/85 to 79/21, thereby polymerizing 1 to 20% by weight of the total polymerization amount, and the third-step polymerization is carried out by supplying a propylene/ethylene mixture so that the ethylene/propylene reaction ratio is 50/50 to 89/11, thereby polymerizing 4 to 35% by weight of the total polymerization amount, with the ethylene/propylene reaction ratio in the third step made larger than that in the second step. Said process can give propylene-ethylene block copolymers markedly well balanced in impact strength, stiffness, transparency and impact blushing.

Abstract translation: 一种通过使用立体规则催化剂的三步聚合技术制备丙烯 - 乙烯嵌段共聚物的方法，其特征在于第一步聚合是通过仅供应丙烯或丙烯/乙烯混合物进行的，以使乙烯/丙烯反应比 为6/94以下，由此聚合60〜95重量％的总聚合量，第二步聚合是通过供给丙烯/乙烯混合物进行的，以使乙烯/丙烯反应比为15/85〜79 / 21，由此聚合1至20重量％的总聚合量，第三步聚合通过供应丙烯/乙烯混合物进行，使得乙烯/丙烯反应比为50/50至89/11， 从而聚合4〜35重量％的总聚合量，第3步骤中的乙烯/丙烯反应比例大于第2步骤。 所述方法可以使丙烯 - 乙烯嵌段共聚物在冲击强度，刚度，透明度和冲击冲刷中显着地平衡。

公开(公告)号：US20050154131A1

公开(公告)日：2005-07-14

申请号：US10988520

申请日：2004-11-16

Applicant: Susumu Kanzaki ,  Kazuki Wakamatsu

Inventor： Susumu Kanzaki ,  Kazuki Wakamatsu

IPC: B29C45/00 ,  C08F2/00 ,  C08F2/01 ,  C08F2/34 ,  C08F4/654 ,  C08F10/00 ,  C08F10/06 ,  C08F210/02 ,  C08F210/06 ,  C08J5/00 ,  C08L23/14 ,  C08L23/16 ,  C08L53/00

CPC classification number: C08F10/00 ,  C08F210/06 ,  C08L23/14 ,  C08L2205/02 ,  C08L2314/02 ,  C08F4/6492 ,  C08L2666/06 ,  C08F210/16 ,  C08F2500/17 ,  C08F2500/12

Abstract: Disclosed is a propylene-based polymer including from 51 to 75% by weight of a propylene-ethylene random copolymer component (A) having an intrinsic viscosity [η]A, measured in tetralin at 135° C., of 5 dl/g or more and an ethylene content of not less than 8% by weight but less than 20% by weight, and from 25 to 49% by weight of a propylene-based polymer component (B) obtained by polymerizing monomers mainly including propylene, the component having an intrinsic viscosity [η]B, measured in tetralin at 135° C., of 1.2 dl/g or less, wherein said amounts of the components (A) and (B) are each based on the combined weight of these components.

Abstract translation: 公开了一种丙烯类聚合物，其包含51至75重量％的在135℃下在四氢化萘中测量的特性粘度ηA SUP的丙烯 - 乙烯无规共聚物组分（A） ，5dl / g以上，乙烯含量为8重量％以上且20重量％以下，25〜49重量％的丙烯系聚合物成分（B），其通过聚合单体 主要包括丙烯，在135℃下在四氢化萘中测得的特性粘度ηB的组分为1.2dl / g或更低，其中组分（A）和（ B）各自基于这些组件的组合重量。