Naphthalene diimide-Zn(II) complex having selectivity for pyrophosphate, preparation method thereof and detecting method of pyrophosphate using the same
    1.
    发明授权
    Naphthalene diimide-Zn(II) complex having selectivity for pyrophosphate, preparation method thereof and detecting method of pyrophosphate using the same 有权
    对焦磷酸盐具有选择性的萘二酰亚胺-Zn(II)络合物及其制备方法和使用其的焦磷酸盐的检测方法

    公开(公告)号:US07563897B2

    公开(公告)日:2009-07-21

    申请号:US11968120

    申请日:2007-12-31

    IPC分类号: C07F15/00 C12Q1/68 G01N33/53

    摘要: The present invention provides a novel fluorescent chemosensor including a naphthalene diimide-Zn(II) complex, which can efficiently recognize pyrophosphate (PPi) at pH 7.4. The fluorescent chemosensor exhibits a new kind of excimer fluorescence, which is selective for PPi in 100% aqueous solution. Further, since the naphthalene diimide-Zn(II) complex of the present invention does not couple with inorganic phosphate (Pi) or adenosine triphosphate (ATP) and has high selectivity for PPi, it can be usefully used to detect pyrophosphate (PPi), which serves to transfer signals and store energy in living organisms.

    摘要翻译: 本发明提供了一种新颖的荧光化学传感器,其包括萘二酰亚胺-Zn(II)络合物,其可以有效地识别pH 7.4的焦磷酸盐(PPi)。 荧光化学传感器显示出新型的准分子荧光,其对于100%水溶液中的PPi是选择性的。 此外,由于本发明的萘二酰亚胺-Zn(II)配合物不与无机磷酸盐(Pi)或三磷酸腺苷(ATP)偶联,对PPi具有高选择性,因此可用于检测焦磷酸(PPi), 其用于传递信号并将能量储存在活生物体中。

    NAPHTHALENE DIIMIDE-ZN(II) COMPLEX HAVING SELECTIVITY FOR PYROPHOSPHATE, PREPARATION METHOD THEREOF AND DETECTING METHOD OF PYROPHOSPHATE USING THE SAME
    2.
    发明申请
    NAPHTHALENE DIIMIDE-ZN(II) COMPLEX HAVING SELECTIVITY FOR PYROPHOSPHATE, PREPARATION METHOD THEREOF AND DETECTING METHOD OF PYROPHOSPHATE USING THE SAME 有权
    具有磷酸选择性的萘二甲酰基-D-二炔(II)复合物,其制备方法和使用其的磷酸酯的检测方法

    公开(公告)号:US20080261196A1

    公开(公告)日:2008-10-23

    申请号:US11968120

    申请日:2007-12-31

    IPC分类号: C12Q1/00 C07D401/14

    摘要: The present invention provides a novel fluorescent chemosensor including a naphthalene diimide-Zn(II) complex, which can efficiently recognize pyrophosphate (PPi) at pH 7.4. The fluorescent chemosensor exhibits a new kind of excimer fluorescence, which is selective for PPi in 100% aqueous solution. Further, since the naphthalene diimide-Zn(II) complex of the present invention does not couple with inorganic phosphate (Pi) or adenosine triphosphate (ATP) and has high selectivity for PPi, it can be usefully used to detect pyrophosphate (PPi), which serves to transfer signals and store energy in living organisms.

    摘要翻译: 本发明提供了一种新颖的荧光化学传感器,其包括萘二酰亚胺-Zn(II)络合物,其可以有效地识别pH 7.4的焦磷酸盐(PPi)。 荧光化学传感器显示出新型的准分子荧光,其对于100%水溶液中的PPi是选择性的。 此外,由于本发明的萘二酰亚胺-Zn(II)配合物不与无机磷酸盐(Pi)或三磷酸腺苷(ATP)偶联,对PPi具有高选择性,因此可用于检测焦磷酸(PPi), 其用于传递信号并将能量储存在活生物体中。