公开(公告)号：US4000170A

公开(公告)日：1976-12-28

申请号：US492957

申请日：1974-07-29

申请人： Denis Forster ,  Arnold Hershman ,  Donald E. Morris

发明人： Denis Forster ,  Arnold Hershman ,  Donald E. Morris

IPC分类号： C07C53/00 ,  B01J31/00 ,  B01J31/20 ,  C07B61/00 ,  C07C51/00 ,  C07C51/14 ,  C07C61/00 ,  C07C63/00 ,  C07C67/00

CPC分类号： B01J31/20 ,  C07C51/14 ,  B01J2231/321 ,  B01J2531/827 ,  Y10T436/12

摘要： The present invention relates to an improved process for the preparation of carboxylic acids, specifically by the reaction of ethylenically unsaturated compounds with carbon monoxide and water, in the presence of catalyst compositions essentially comprising iridium compounds and complexes, together with an iodide promoter, the improvement being the provision of at least 50 percent by weight of the iridium in the reaction solution in a highly catalytically active form as a species having infrared absorption bands at 2098 cm.sup.-.sup.1 (vs), 2155 cm.sup.-.sup.1 (w), 2180 cm.sup.-.sup.1 (vw, br). By monitoring the infrared absorption spectra of reacting solutions and following the magnitude of the 2098 cm.sup.-.sup.1 band the operating conditions are adjusted so that this band is present in 50 percent or more concentration relative to the infrared absorption spectral bands of the other iridium species in solution. Through this monitoring and control process significantly increased reactor productivity to carboxylic acids is achieved.

公开(公告)号：US06818450B2

公开(公告)日：2004-11-16

申请号：US10150030

申请日：2002-05-17

申请人： David R. Eaton ,  Walter Gavlick ,  Gary Klopf ,  Arnold Hershman ,  Denis Forster

发明人： David R. Eaton ,  Walter Gavlick ,  Gary Klopf ,  Arnold Hershman ,  Denis Forster

IPC分类号： C12P3300

CPC分类号： G01N21/75 ,  C07F9/3813 ,  G01N21/3577 ,  G01N2021/3595 ,  Y10T436/117497 ,  Y10T436/163333 ,  Y10T436/200833 ,  Y10T436/201666 ,  Y10T436/202499

摘要： The present invention is directed to an analytical method for measuring the concentration of an N-(phosphonomethyl)iminodiacetic acid (“NPMIDA”) substrate, an N-(phosphonomethyl)glycine product, formaldehyde, formic acid, N-methyl-N-(phosphonomethyl)glycine (“NMG”), N-methyl-aminomethylphosphonic acid (MAMPA) or aminomethylphosphonic acid (“AMPA”)) in an aqueous mixture thereof, using infrared spectroscopy. The present invention is also directed to a process for oxidizing an N-(phosphonomethyl)iminodiacetic acid substrate to form a N-(phosphonomethyl)glycine product, and as part of the process, measuring the concentration of at least one reactant, product or byproduct of the oxidation reaction using the analytical method of the present invention and controlling the oxidation process in response to the measurement taken.

摘要翻译： 本发明涉及一种用于测量N-（膦酰基甲基）亚氨基二乙酸（“NPMIDA”）底物，N-（膦酰基甲基）甘氨酸产物，甲醛，甲酸，N-甲基-N-（ 膦酰基甲基）甘氨酸（“NMG”），N-甲基 - 氨基甲基膦酸（MAMPA）或氨基甲基膦酸（“AMPA”））在其水性混合物中。 本发明还涉及一种氧化N-（膦酰基甲基）亚氨基二乙酸底物以形成N-（膦酰基甲基）甘氨酸产物的方法，作为该方法的一部分，测量至少一种反应物，产物或副产物的浓度 的氧化反应使用本发明的分析方法，并且响应于测量而控制氧化过程。

公开(公告)号：US3989751A

公开(公告)日：1976-11-02

申请号：US531946

申请日：1974-12-12

申请人： Denis Forster ,  Arnold Hershman

发明人： Denis Forster ,  Arnold Hershman

IPC分类号： C07C51/14 ,  C07C51/54 ,  C07C51/56

CPC分类号： C07C51/54 ,  C07C51/14 ,  C07C51/56

摘要： The present invention relates to an improved process for the preparation of organic carboxylic acid anhydrides, specifically by the reaction of ethylenically unsaturated compounds having 2 to 30 carbon atoms with carbon monoxide and carboxylic acids or substances which yield carboxylic acids under reaction conditions at a temperature of 50.degree. C to 300.degree. C and a partial pressure of carbon monoxide of from 1 to 200 atm. in the presence of a catalyst composition essentially comprised of1. a cobalt or nickel compound, and2. an iodide component subject to the conditions that the atomic ratio of iodide to cobalt or nickel is from 1:1 to 300:1,3. a catalyst preserver or regenerator component selected from the group consisting of hydrogen or a compound capable of giving rise to hydrogen under the reaction conditions. The process is particularly suited to the production of propionic anhydride.

摘要翻译： 本发明涉及一种制备有机羧酸酐的改进方法，特别是通过具有2-30个碳原子的烯属不饱和化合物与一氧化碳和羧酸或在反应条件下在温度为 50℃至300℃，一氧化碳分压为1至200atm。 在催化剂组合物的存在下，基本上由以下组成的催化剂组合物1.钴或镍化合物和2.根据碘化物对钴或镍的原子比从1：1至300的条件的一种碘化物组分：

公开(公告)号：US3944604A

公开(公告)日：1976-03-16

申请号：US390268

申请日：1973-08-21

申请人： Arnold Hershman ,  Denis Forster

发明人： Arnold Hershman ,  Denis Forster

IPC分类号： C07C53/122 ,  B01J23/00 ,  B01J31/00 ,  B01J31/02 ,  B01J31/04 ,  B01J31/26 ,  C07B61/00 ,  C07C51/00 ,  C07C51/14 ,  C07C67/00

CPC分类号： B01J31/0231 ,  B01J31/04 ,  B01J31/26 ,  C07C51/14 ,  B01J2231/323

摘要： The present invention relates to an improved process for the preparation of propionic acid, specifically by the reaction of ethylene with carbon monoxide and water at mild pressure, in the presence of catalyst compositions essentially comprising critical proportions of cobalt compounds with an iodide promoter.

摘要翻译： 本发明涉及在基本上包含临界比例的钴化合物与碘化物促进剂的催化剂组合物的存在下，特别是通过乙烯与一氧化碳和水在轻微的压力下反应来制备丙酸的改进方法。

公开(公告)号：US4029748A

公开(公告)日：1977-06-14

申请号：US492958

申请日：1974-07-29

申请人： Denis Forster ,  Arnold Hershman ,  Donald E. Morris

发明人： Denis Forster ,  Arnold Hershman ,  Donald E. Morris

IPC分类号： B01J31/00 ,  B01J31/20 ,  C01G55/00 ,  C07B61/00 ,  C07C51/14 ,  C07F15/00 ,  C01G1/04

CPC分类号： C07F15/0033 ,  B01J31/20 ,  C01G55/00 ,  C01G55/007 ,  C07C51/14 ,  B01J2231/321 ,  B01J2531/827 ,  B01J31/2291 ,  B01J31/2295

摘要： The complexes [Ir(CO).sub.3 I], [HIr(CO).sub.3 I.sub.2 ], [HIr(CO).sub.2 I.sub.2 (H.sub.2 O)], [RIr(CO).sub.2 I.sub.2 ], [(RCO)Ir(CO).sub.2 I.sub.2 ] where R is an alkyl radical, are described. Processes for preparing the aforesaid complexes are described and in addition a new process for preparation of [Ir(CO).sub.3 I.sub.3 ] is described.

摘要翻译： 配合物[Ir（CO）3I]，[HIr（CO）3I2]，[HIr（CO）2I2（H2O）]，[RIr（CO）2I2]，[（RCO）Ir（CO） 描述了烷基。 描述了制备上述配合物的方法，并描述了制备[Ir（CO）3 I 3]的新方法。

公开(公告)号：US07164049B2

公开(公告)日：2007-01-16

申请号：US10400558

申请日：2003-03-27

申请人： Jerry R. Ebner ,  Zhi Guo ,  Arnold Hershman ,  Loraine M. Klein ,  William D. McGhee ,  Mark Paster ,  Indra Prakash

发明人： Jerry R. Ebner ,  Zhi Guo ,  Arnold Hershman ,  Loraine M. Klein ,  William D. McGhee ,  Mark Paster ,  Indra Prakash

IPC分类号： C07C27/00

CPC分类号： C07C303/24 ,  C07C17/275 ,  C07C29/095 ,  C07C29/12 ,  C07C29/124 ,  C07C29/132 ,  C07C29/147 ,  C07C29/149 ,  C07C45/002 ,  C07C45/38 ,  C07C47/02 ,  C07K5/06113 ,  Y02P20/127 ,  C07C19/01 ,  C07C305/08 ,  C07C31/125

摘要： 3,3-Dimethylbutanal is prepared from 3,3-dimethylbutanol. Intermediate 3,3-dimethylbutanol is obtained by reacting ethylene, isopropylene and a mineral acid to produce a 3,3-dimethylbutyl ester which is hydrolyzed to the alcohol. The hydrolysis step is effectively carried out by reactive distillation. Alternatively, 3,3-dimethylbutanal is prepared from 3,3-dimethylbutanol obtained by reduction of the corresponding carboxylic acid or 1,2-epoxy-3,3-dimethylbutane, or by hydrolysis of 1-halo-3,3-dimethylbutane. Fixed bed gas phase and stirred tank liquid phase processes are provided for converting 3,3-dimethylbutanol to 3,3-dimethylbutanal by catalytic dehydrogenation.

摘要翻译： 3,3-二甲基丁醛由3,3-二甲基丁醇制备。 中间体3,3-二甲基丁醇通过使乙烯，异丙烯和无机酸反应得到3,3-二甲基丁酯，将其水解成醇。 水解步骤通过反应蒸馏有效地进行。 或者，通过还原相应的羧酸或1,2-环氧-3,3-二甲基丁烷或通过1-卤代-3,3-二甲基丁烷的水解得到的3,3-二甲基丁醇制备3,3-二甲基丁醛。 提供固定床气相和搅拌釜液相方法，通过催化脱氢将3,3-二甲基丁醇转化为3,3-二甲基丁醛。

公开(公告)号：US3969398A

公开(公告)日：1976-07-13

申请号：US465976

申请日：1974-05-01

申请人： Arnold Hershman

发明人： Arnold Hershman

IPC分类号： C07F9/38 ,  A01N57/20 ,  A01P13/00 ,  A01P21/00 ,  B01J21/00 ,  C07B61/00 ,  C07F9/40 ,  C07F9/44

CPC分类号： C07F9/3813

摘要： A process for the production of N-phosphonomethyl glycine by the oxidation of N-phosphonomethylimino diacetic acid utilizing a molecular oxygen-containing gas as the oxidant in the presence of a catalyst consisting essentially of activated carbon. The N-phosphonomethyl glycine produced is useful as a herbicide or plant growth regulant.

摘要翻译： 通过在基本上由活性炭组成的催化剂存在下，通过使用含分子氧的气体作为氧化剂，通过N-膦酰基甲基亚氨基二乙酸的氧化来生产N-膦酰基甲基甘氨酸的方法。 产生的N-膦酰基甘氨酸可用作除草剂或植物生长调节剂。

公开(公告)号：US07348459B2

公开(公告)日：2008-03-25

申请号：US11552395

申请日：2006-10-24

申请人： Jerry R. Ebner ,  Zhi Guo ,  Arnold Hershman ,  Loraine M. Klein ,  William D. McGhee ,  Mark D. Paster ,  Indra Prakash

发明人： Jerry R. Ebner ,  Zhi Guo ,  Arnold Hershman ,  Loraine M. Klein ,  William D. McGhee ,  Mark D. Paster ,  Indra Prakash

IPC分类号： C07C45/29

CPC分类号： C07C303/24 ,  C07C17/275 ,  C07C29/095 ,  C07C29/12 ,  C07C29/124 ,  C07C29/132 ,  C07C29/147 ,  C07C29/149 ,  C07C45/002 ,  C07C45/38 ,  C07C47/02 ,  C07K5/06113 ,  Y02P20/127 ,  C07C19/01 ,  C07C305/08 ,  C07C31/125

摘要： 3,3-Dimethylbutanal is prepared from 3,3-dimethybutanol. Intermediate 3,3-dimethylbutanol is obtained by reacting ethylene, isopropylene and a mineral acid to produce a 3,3-dimethylbutyl ester which is hydrolyzed to the alcohol. The hydrolysis step is effectively carried out by reactive distillation. Alternatively, 3,3-dimethylbutanal is prepared from 3,3-dimethylbutanol obtained by reduction of the corresponding carboxylic acid or 1,2-epoxy-3,3-dimethylbutane, or by hydrolysis of 1-halo-3,3-dimethylbutane. Fixed bed gas phase and stirred tank liquid phase processes are provided for converted 3,3-dimethylbutanol to 3,3-dimethylbutanal by catalytic dehydrogenation.

摘要翻译： 3,3-二甲基丁醛由3,3-二甲基丁醇制备。 中间体3,3-二甲基丁醇通过使乙烯，异丙烯和无机酸反应得到3,3-二甲基丁酯，将其水解成醇。 水解步骤通过反应蒸馏有效地进行。 或者，通过还原相应的羧酸或1,2-环氧-3,3-二甲基丁烷或通过1-卤代-3,3-二甲基丁烷的水解得到的3,3-二甲基丁醇制备3,3-二甲基丁醛。 提供固定床气相和搅拌釜液相方法，通过催化脱氢将3,3-二甲基丁醇转化为3,3-二甲基丁醛。

公开(公告)号：US20070106086A1

公开(公告)日：2007-05-10

申请号：US11552395

申请日：2006-10-24

申请人： Jerry Ebner ,  Zhi Guo ,  Arnold Hershman ,  Loraine Klein ,  William McGhee ,  Mark Paster ,  Indra Prakash

发明人： Jerry Ebner ,  Zhi Guo ,  Arnold Hershman ,  Loraine Klein ,  William McGhee ,  Mark Paster ,  Indra Prakash

IPC分类号： C07C45/29 ,  C07K5/04

CPC分类号： C07C303/24 ,  C07C17/275 ,  C07C29/095 ,  C07C29/12 ,  C07C29/124 ,  C07C29/132 ,  C07C29/147 ,  C07C29/149 ,  C07C45/002 ,  C07C45/38 ,  C07C47/02 ,  C07K5/06113 ,  Y02P20/127 ,  C07C19/01 ,  C07C305/08 ,  C07C31/125

摘要： 3,3-Dimethylbutanal is prepared from 3,3-dimethylbutanol. Intermediate 3,3-dimethylbutanol is obtained by reacting ethylene, isopropylene and a mineral acid to produce a 3,3-dimethylbutyl ester which is hydrolyzed to the alcohol. The hydrolysis step is effectively carried out by reactive distillation. Alternatively, 3,3-dimethylbutanal is prepared from 3,3-dimethylbutanol obtained by reduction of the corresponding carboxylic acid or 1,2-epoxy-3,3-dimethylbutane, or by hydrolysis of 1-halo-3,3-dimethylbutane. Fixed bed gas phase and stirred tank liquid phase processes are provided for converted 3,3-dimethylbutanol to 3,3-dimethylbutanal by catalytic dehydrogenation.

摘要翻译： 3,3-二甲基丁醛由3,3-二甲基丁醇制备。 中间体3,3-二甲基丁醇通过使乙烯，异丙烯和无机酸反应得到3,3-二甲基丁酯，将其水解成醇。 水解步骤通过反应蒸馏有效地进行。 或者，通过还原相应的羧酸或1,2-环氧-3,3-二甲基丁烷或通过1-卤代-3,3-二甲基丁烷的水解得到的3,3-二甲基丁醇制备3,3-二甲基丁醛。 提供固定床气相和搅拌釜液相方法，通过催化脱氢将3,3-二甲基丁醇转化为3,3-二甲基丁醛。

公开(公告)号：US4792620A

公开(公告)日：1988-12-20

申请号：US21384

申请日：1987-03-03

申请人： Frank E. Paulik ,  Arnold Hershman ,  Walter R. Knox ,  James F. Roth

发明人： Frank E. Paulik ,  Arnold Hershman ,  Walter R. Knox ,  James F. Roth

IPC分类号： B01J31/20 ,  C07C51/10 ,  C07C51/12 ,  C07C51/14 ,  C07C67/36

CPC分类号： B01J31/0231 ,  B01J31/1895 ,  B01J31/20 ,  B01J31/2409 ,  C07C51/10 ,  C07C51/12 ,  C07C51/14 ,  C07C67/36 ,  B01J2231/34 ,  B01J2531/822

摘要： A catalyst system having high activity and selectivity to carbonylation products comprises a rhodium-containing catalytically active component and a halogen-containing promoter component, the halogen being selected from the group consisting of bromine, iodine, bromide compounds, and iodide compounds.

摘要翻译： 对羰基化产物具有高活性和选择性的催化剂体系包括含铑催化活性组分和含卤素促进剂组分，卤素选自溴，碘，溴化物和碘化合物。