公开(公告)号：US20140030448A1

公开(公告)日：2014-01-30

申请号：US13949420

申请日：2013-07-24

Applicant: AIR PRODUCTS AND CHEMICALS, INC.

Inventor： Heather Regina Bowen ,  Jianheng Li ,  Mark Leonard O'Neill ,  Manchao Xiao ,  Andrew David Johnson ,  Xinjian Lei

IPC: C23C16/30

CPC classification number: C23C16/30 ,  C23C16/325 ,  C23C16/36

Abstract: Disclosed herein are non-oxygen containing silicon-based films, and methods for forming the same. The non-oxygen silicon-based films contain >50 atomic % of silicon. In one aspect, the silicon-based films have a composition SixCyNz wherein x is about 51 to 100, y is 0 to 49, and z is 0 to 50 atomic weight (wt.) percent (%) as measured by XPS. In one embodiment, the non-oxygen silicon-based films were deposited using at least one organosilicon precursor having at least two SiH3 groups with at least one C2-3 linkage between silicon atoms such as 1,4-disilabutane.

Abstract translation: 本文公开了非含氧硅基膜及其形成方法。 非氧硅基膜含有> 50原子％的硅。 在一个方面，硅基膜具有组成SixCyNz，其中x为约51〜100，y为0〜49，z为通过XPS测定的0〜50原子％（重量）％（％）。 在一个实施方案中，使用至少一种具有至少两个SiH 3基团的有机硅前体沉积非氧硅基膜，在硅原子之间具有至少一个C2-3键，例如1,4-二硅烷。

公开(公告)号：US09243324B2

公开(公告)日：2016-01-26

申请号：US13949420

申请日：2013-07-24

Applicant: AIR PRODUCTS AND CHEMICALS, INC.

Inventor： Heather Regina Bowen ,  Jianheng Li ,  Mark Leonard O'Neill ,  Manchao Xiao ,  Andrew David Johnson ,  Xinjian Lei

IPC: C23C16/30 ,  C23C16/32 ,  C23C16/36

CPC classification number: C23C16/30 ,  C23C16/325 ,  C23C16/36

Abstract: Methods for forming non-oxygen containing silicon-based films, that contain >50 atomic % of silicon, are provided herein. In one aspect, the silicon-based films have a composition SixCyNz wherein x is about 51 to 100, y is 0 to 49, and z is 0 to 50 atomic weight (wt.) percent (%) as measured by XPS. In one embodiment, the non-oxygen silicon-based films were deposited using at least one organosilicon precursor having at least two SiH3 groups with at least one C2-3 linkage between silicon atoms such as 1,4-disilabutane.

Abstract translation: 本文提供了含有> 50原子％的硅的形成非含氧硅基膜的方法。 在一个方面，硅基膜具有组成SixCyNz，其中x为约51〜100，y为0〜49，z为通过XPS测定的0〜50原子％（重量）％（％）。 在一个实施方案中，使用至少一种具有至少两个SiH 3基团的有机硅前体沉积非氧硅基膜，在硅原子之间具有至少一个C2-3键，例如1,4-二硅烷。

公开(公告)号：US20150024608A1

公开(公告)日：2015-01-22

申请号：US14511719

申请日：2014-10-10

Applicant: AIR PRODUCTS AND CHEMICALS, INC.

Inventor： Steven Gerard Mayorga ,  Heather Regina Bowen ,  Xinjian Lei ,  Manchao Xiao ,  Haripin Chandra ,  Anupama Mallikarjunan ,  Ronald Martin Pearlstein

IPC: H01L21/02

CPC classification number: H01L21/02211 ,  C01B21/0682 ,  C01B21/0828 ,  C01B33/021 ,  C01B33/126 ,  C01P2002/02 ,  C07F7/025 ,  C07F7/10 ,  C09D1/00 ,  C09D7/20 ,  C23C16/18 ,  C23C16/345 ,  C23C16/401 ,  C23C16/45525 ,  C23C16/45536 ,  C23C16/45542 ,  C23C16/45553 ,  C23C16/46 ,  H01L21/02126 ,  H01L21/02164 ,  H01L21/02167 ,  H01L21/0217 ,  H01L21/02219 ,  H01L21/02271 ,  H01L21/02274 ,  H01L21/0228 ,  H01L21/02532 ,  H01L21/0262 ,  Y10T428/13

Abstract: Described herein are precursors and methods for forming silicon-containing films. In one aspect, there is provided a precursor of Formula I: wherein R1 is selected from linear or branched C3 to C10 alkyl group, linear or branched C3 to C10 alkenyl group, linear or branched C3 to C10 alkynyl group, C1 to C6 dialkylamino group, electron withdrawing group, and C6 to C10 aryl group; R2 is selected from hydrogen, linear or branched C1 to C10 alkyl group, linear or branched C3 to C6 alkenyl group, linear or branched C3 to C6 alkynyl group, C1 to C6 dialkylamino group, C6 to C10 aryl group, linear or branched C1 to C6 fluorinated alkyl group, electron withdrawing group, and C4 to C10 aryl group; optionally wherein R1 and R2 are linked together to form ring selected from substituted or unsubstituted aromatic ring or substituted or unsubstituted aliphatic ring; and n=1 or 2.

Abstract translation: 这里描述的是用于形成含硅膜的前体和方法。 一方面，提供了式I的前体：其中R 1选自直链或支链C 3至C 10烷基，直链或支链C 3至C 10烯基，直链或支链C 3至C 10炔基，C 1至C 6二烷基氨基 吸电子基团和C6〜C10芳基; R 2选自氢，直链或支链C 1至C 10烷基，直链或支链C 3至C 6烯基，直链或支链C 3至C 6炔基，C 1至C 6二烷基氨基，C 6至C 10芳基，直链或支链C 1至 C6氟化烷基，吸电子基和C4〜C10芳基; 任选地，其中R 1和R 2连接在一起形成选自取代或未取代的芳族环或取代或未取代的脂族环的环; n = 1或2。

公开(公告)号：US08940648B2

公开(公告)日：2015-01-27

申请号：US13964658

申请日：2013-08-12

Applicant: Air Products and Chemicals, Inc.

Inventor： Manchao Xiao ,  Xinjian Lei ,  Heather Regina Bowen ,  Mark Leonard O'Neill

IPC: H01L21/31 ,  H01L21/02 ,  C07F7/02 ,  C23C16/40 ,  C23C16/455 ,  H01L21/314 ,  H01L21/316

CPC classification number: H01L21/02211 ,  C07F7/025 ,  C23C16/402 ,  C23C16/45553 ,  H01L21/02164 ,  H01L21/02219 ,  H01L21/02222 ,  H01L21/02271 ,  H01L21/0228 ,  H01L21/3145 ,  H01L21/31608 ,  H01L21/31633

Abstract: A method for depositing a silicon containing film on a substrate using an organoaminosilane is described herein. The organoaminosilanes are represented by the formulas: wherein R is selected from a C1-C10 linear, branched, or cyclic, saturated or unsaturated alkyl group with or without substituents; a C5-C10 aromatic group with or without substituents, a C3-C10 heterocyclic group with or without substituents, or a silyl group in formula C with or without substituents, R1 is selected from a C3-C10 linear, branched, cyclic, saturated or unsaturated alkyl group with or without substituents; a C6-C10 aromatic group with or without substituents, a C3-C10 heterocyclic group with or without substituents, a hydrogen atom, a silyl group with substituents and wherein R and R1 in formula A can be combined into a cyclic group and R2 representing a single bond, (CH2), chain, a ring, C3-C10 branched alkyl, SiR2, or SiH2.

Abstract translation: 本文描述了使用有机氨基硅烷在基板上沉积含硅膜的方法。 有机基氨基硅烷由下式表示：其中R选自具有或不具有取代基的C1-C10直链，支链或环状饱和或不饱和的烷基; 具有或不具有取代基的C 5 -C 10芳族基团，具有或不具有取代基的C 3 -C 10杂环基或具有或不具有取代基的式C中的甲硅烷基，其选自C 3 -C 10直链，支链，环状，饱和或 有或没有取代基的不饱和烷基; 具有或不具有取代基的C 6 -C 10芳族基团，具有或不具有取代基的C 3 -C 10杂环基，氢原子，具有取代基的甲硅烷基，并且其中式A中的R和R可以组合成环状基团，并且R 2表示 单键，（CH2），链，环，C3-C10支链烷基，SiR2或SiH2。

公开(公告)号：US09627193B2

公开(公告)日：2017-04-18

申请号：US14511719

申请日：2014-10-10

Applicant: AIR PRODUCTS AND CHEMICALS, INC.

Inventor： Steven Gerard Mayorga ,  Heather Regina Bowen ,  Xinjian Lei ,  Manchao Xiao ,  Haripin Chandra ,  Anupama Mallikarjunan ,  Ronald Martin Pearlstein

IPC: C07F7/02 ,  H01L21/02 ,  C09D1/00 ,  C07F7/10 ,  C23C16/18 ,  C23C16/40 ,  C23C16/455 ,  C23C16/46

CPC classification number: H01L21/02211 ,  C01B21/0682 ,  C01B21/0828 ,  C01B33/021 ,  C01B33/126 ,  C01P2002/02 ,  C07F7/025 ,  C07F7/10 ,  C09D1/00 ,  C09D7/20 ,  C23C16/18 ,  C23C16/345 ,  C23C16/401 ,  C23C16/45525 ,  C23C16/45536 ,  C23C16/45542 ,  C23C16/45553 ,  C23C16/46 ,  H01L21/02126 ,  H01L21/02164 ,  H01L21/02167 ,  H01L21/0217 ,  H01L21/02219 ,  H01L21/02271 ,  H01L21/02274 ,  H01L21/0228 ,  H01L21/02532 ,  H01L21/0262 ,  Y10T428/13

Abstract: Described herein are precursors and methods for forming silicon-containing films. In one aspect, there is provided a precursor of Formula I: wherein R1 is selected from linear or branched C3 to C10 alkyl group, linear or branched C3 to C10 alkenyl group, linear or branched C3 to C10 alkynyl group, C1 to C6 dialkylamino group, electron withdrawing group, and C6 to C10 aryl group; R2 is selected from hydrogen, linear or branched C1 to C10 alkyl group, linear or branched C3 to C6 alkenyl group, linear or branched C3 to C6 alkynyl group, C1 to C6 dialkylamino group, C6 to C10 aryl group, linear or branched C1 to C6 fluorinated alkyl group, electron withdrawing group, and C4 to C10 aryl group; optionally wherein R1 and R2 are linked together to form ring selected from substituted or unsubstituted aromatic ring or substituted or unsubstituted aliphatic ring; and n=1 or 2.

公开(公告)号：US08993072B2

公开(公告)日：2015-03-31

申请号：US13622117

申请日：2012-09-18

Applicant: Air Products and Chemicals, Inc.

Inventor： Manchao Xiao ,  Xinjian Lei ,  Mark Leonard O'Neill ,  Bing Han ,  Ronald Martin Pearlstein ,  Haripin Chandra ,  Heather Regina Bowen ,  Agnes Derecskei-Kovacs

IPC: C07F7/02 ,  H05H1/24 ,  C23C16/00 ,  C07F7/12 ,  C23C16/40 ,  C23C16/455 ,  H01L21/02

CPC classification number: C07F7/025 ,  C07F7/12 ,  C23C16/402 ,  C23C16/45536 ,  C23C16/45553 ,  H01L21/02126 ,  H01L21/02164 ,  H01L21/02219 ,  H01L21/0228 ,  H01L21/02532 ,  H01L21/0262

Abstract: Described herein are precursors and methods of forming films. In one aspect, there is provided a precursor having Formula I: XmR1nHpSi(NR2R3)4-m-n-p  I wherein X is selected from Cl, Br, I; R1 is selected from linear or branched C1-C10 alkyl group, a C2-C12 alkenyl group, a C2-C12 alkynyl group, a C4-C10 cyclic alkyl, and a C6-C10 aryl group; R2 is selected from a linear or branched C1-C10 alkyl, a C3-C12 alkenyl group, a C3-C12 alkynyl group, a C4-C10 cyclic alkyl group, and a C6-C10 aryl group; R3 is selected from a branched C3-C10 alkyl group, a C3-C12 alkenyl group, a C3-C12 alkynyl group, a C4-C10 cyclic alkyl group, and a C6-C10 aryl group; m is 1 or 2; n is 0, 1, or 2; p is 0, 1 or 2; and m+n+p is less than 4, wherein R2 and R3 are linked or not linked to form a ring.

Abstract translation: 这里描述的是形成膜的前体和方法。 一方面，提供了具有式I的前体：XmR1nHpSi（NR2R3）4-m-n-p1其中X选自Cl，Br，I; R 1选自直链或支链C 1 -C 10烷基，C 2 -C 12烯基，C 2 -C 12炔基，C 4 -C 10环烷基和C 6 -C 10芳基; R2选自直链或支链C1-C10烷基，C3-C12烯基，C3-C12炔基，C4-C10环烷基和C6-C10芳基; R3选自支链C 3 -C 10烷基，C 3 -C 12烯基，C 3 -C 12炔基，C 4 -C 10环烷基和C 6 -C 10芳基; m为1或2; n为0,1或2; p为0,1或2; 并且m + n + p小于4，其中R2和R3连接或未连接形成环。

公开(公告)号：US20130330937A1

公开(公告)日：2013-12-12

申请号：US13964658

申请日：2013-08-12

Applicant: Air Products and Chemicals, Inc.

Inventor： Manchao Xiao ,  Xinjian Lei ,  Heather Regina Bowen ,  Mark Leonard O'Neill

IPC: H01L21/02

CPC classification number: H01L21/02211 ,  C07F7/025 ,  C23C16/402 ,  C23C16/45553 ,  H01L21/02164 ,  H01L21/02219 ,  H01L21/02222 ,  H01L21/02271 ,  H01L21/0228 ,  H01L21/3145 ,  H01L21/31608 ,  H01L21/31633

Abstract: A method for depositing a silicon containing film on a substrate using an organoaminosilane is described herein. The organoaminosilanes are represented by the formulas: wherein R is selected from a C1-C10 linear, branched, or cyclic, saturated or unsaturated alkyl group with or without substituents; a C5-C10 aromatic group with or without substituents, a C3-C10 heterocyclic group with or without substituents, or a silyl group in formula C with or without substituents, R1 is selected from a C3-C10 linear, branched, cyclic, saturated or unsaturated alkyl group with or without substituents; a C6-C10 aromatic group with or without substituents, a C3-C10 heterocyclic group with or without substituents, a hydrogen atom, a silyl group with substituents and wherein R and R1 in formula A can be combined into a cyclic group and R2 representing a single bond, (CH2), chain, a ring, C3-C10 branched alkyl, SiR2, or SiH2.

Abstract translation: 本文描述了使用有机氨基硅烷在基板上沉积含硅膜的方法。 有机基氨基硅烷由下式表示：其中R选自具有或不具有取代基的C1-C10直链，支链或环状饱和或不饱和的烷基; 具有或不具有取代基的C 5 -C 10芳族基团，具有或不具有取代基的C 3 -C 10杂环基或具有或不具有取代基的式C中的甲硅烷基，其选自C 3 -C 10直链，支链，环状，饱和或 有或没有取代基的不饱和烷基; 具有或不具有取代基的C 6 -C 10芳族基团，具有或不具有取代基的C 3 -C 10杂环基，氢原子，具有取代基的甲硅烷基，并且其中式A中的R和R可以组合成环状基团，并且R 2表示 单键，（CH2），链，环，C3-C10支链烷基，SiR2或SiH2。