公开(公告)号：US12110384B2

公开(公告)日：2024-10-08

申请号：US17277048

申请日：2019-09-26

Applicant: SEKISUI CHEMICAL CO., LTD. ,  TOKUYAMA SEKISUI CO., LTD.

Inventor： Kei Yoshiyama ,  Hiroshi Taniguchi

IPC: C08L27/24 ,  C08L9/06 ,  C08L27/06 ,  C08L33/08 ,  C10M105/34 ,  E06B1/26

CPC classification number: C08L27/24 ,  C08L9/06 ,  C08L27/06 ,  C08L33/08 ,  C10M105/34 ,  E06B1/26

Abstract: The present invention provides a chlorinated vinyl chloride resin composition for a window frame having excellent properties including moldability, heat resistance, and impact resistance and capable of preventing or reducing deformation such as warpage or damage even after exposure to sunlight for a long time. Provided is a chlorinated vinyl chloride resin composition for a window frame, containing a chlorinated vinyl chloride resin and an infrared reflective pigment.

公开(公告)号：US20240327551A1

公开(公告)日：2024-10-03

申请号：US18740741

申请日：2024-06-12

Applicant: SEKISUI CHEMICAL CO., LTD. ,  TOKUYAMA SEKISUI CO., LTD.

Inventor： Norikazu MASHINO ,  Kento MURAKAMI ,  Isao HIGUCHI ,  Yasunari KUSAKA ,  Takashi MURAMOTO

IPC: C08F14/06

CPC classification number: C08F14/06

Abstract: The present invention provides a chlorinated polyvinyl chloride resin that enables excellent continuous productivity in molding and that enables a molded article to have both processability and unevenness-preventing properties. Provided is a chlorinated polyvinyl chloride resin having, in Raman measurement by Raman spectroscopy, an average of a ratio (A/B) of a peak intensity A observed in a range of 660 to 700 cm−1 to a peak intensity B observed in a range of 600 to 650 cm−1 of 0.50 to 2.00, and a standard deviation of the A/B of 0.090 or less.

公开(公告)号：US12037423B2

公开(公告)日：2024-07-16

申请号：US17434515

申请日：2020-03-27

Applicant: SEKISUI CHEMICAL CO., LTD. ,  TOKUYAMA SEKISUI CO., LTD.

Inventor： Norikazu Mashino ,  Kento Murakami ,  Isao Higuchi ,  Yasunari Kusaka ,  Takashi Muramoto

IPC: C08F14/06

CPC classification number: C08F14/06

Abstract: The present invention provides a chlorinated polyvinyl chloride resin that enables excellent continuous productivity in molding and that enables a molded article to have both processability and unevenness-preventing properties. Provided is a chlorinated polyvinyl chloride resin having, in Raman measurement by Raman spectroscopy, an average of a ratio (A/B) of a peak intensity A observed in a range of 660 to 700 cm−1 to a peak intensity B observed in a range of 600 to 650 cm−1 of 0.50 to 2.00, and a standard deviation of the A/B of 0.090 or less.

公开(公告)号：US20220153983A1

公开(公告)日：2022-05-19

申请号：US17436916

申请日：2020-03-27

Applicant: SEKISUI CHEMICAL CO., LTD. ,  TOKUYAMA SEKISUI CO., LTD.

Inventor： Kenichi MATSUMURA ,  Norikazu MASHINO ,  Kento MURAKAMI ,  Nami NAKAJIMA ,  Yasunari KUSAKA ,  Takehisa SUGAYA ,  Masahiko YAMAGATA

IPC: C08L27/24

Abstract: The present invention provides a chlorinated polyvinyl chloride resin that has resistance to thermal decomposition, provides excellent continuous productivity in molding, and imparts both processability and unevenness-preventing properties to a molded article. The present invention relates to a chlorinated polyvinyl chloride resin, containing three components including a A150 component, a B150 component, and a C150 component, and having a percentage of the C150 component (C150 component/(A150 component+B150 component+C150 component)) of less than 8.0%, the three components being identified by measuring the chlorinated polyvinyl chloride resin by a solid echo method using pulse NMR at 150° C. to give a free induction decay curve of 1H spin-spin relaxation, and subjecting the free induction decay curve to waveform separation into three curves derived from the A150 component, the B150 component, and the C150 component in order of shorter relaxation time using the least square method.

公开(公告)号：US20220135783A1

公开(公告)日：2022-05-05

申请号：US17435202

申请日：2020-03-27

Applicant: SEKISUI CHEMICAL CO., LTD. ,  TOKUYAMA SEKISUI CO., LTD.

Inventor： Kento MURAKAMI ,  Norikazu MASHINO ,  Isao HIGUCHI ,  Yasunari KUSAKA

IPC: C08L27/24

Abstract: The present invention provides a chlorinated polyvinyl chloride resin that enables a molded article to have both processability and unevenness-preventing properties and also high gloss. Provided is a chlorinated polyvinyl chloride resin having an average of a ratio (A/B) of a peak intensity A observed in a range of 660 to 700 cm−1 to a peak intensity B observed in a range of 600 to 650 cm1 of 0.50 to 2.00 in Raman imaging measurement by Raman spectroscopy, and having a standard deviation of the ratio (A/B) of the peak intensity A to the peak intensity B of 0.100 to 0.200 in Raman measurement by Raman spectroscopy.

公开(公告)号：US20210278422A1

公开(公告)日：2021-09-09

申请号：US17256919

申请日：2019-09-05

Applicant: SEKISUI MEDICAL CO., LTD. ,  TOKUYAMA SEKISUI CO., LTD.

Inventor： Kazuyuki Oishi ,  Hiroaki Taira ,  Tomonori Inoue ,  Ryo Takemoto

IPC: G01N33/72 ,  G01N30/06 ,  G01N30/88

Abstract: Provided is a reagent for measuring hemoglobins capable of satisfactorily causing hemolysis and measuring hemoglobins with high accuracy. The reagent for measuring hemoglobins according to the present invention is a reagent for measuring hemoglobins used for measuring hemoglobins by cation exchange liquid chromatography, including a specific nonionic surfactant or a specific amphoteric surfactant.

公开(公告)号：US20170008981A1

公开(公告)日：2017-01-12

申请号：US15119438

申请日：2015-03-31

Applicant: SEKISUI CHEMICAL CO., LTD. ,  TOKUYAMA SEKISUI CO., LTD.

Inventor： Kenichi MATSUMURA ,  Norikazu MASHINO

IPC: C08F8/22

CPC classification number: C08F8/22 ,  C08F14/06 ,  C08F214/06 ,  C08J5/18 ,  C08J2327/24 ,  C08K5/098 ,  C08K5/10 ,  C08L27/06 ,  C08L27/24 ,  C08L33/12 ,  C08L51/04 ,  C08F2/16 ,  C08F114/06

Abstract: The present invention provides a method for producing a chlorinated polyvinyl chloride which is excellent in thermal stability (initial discoloration resistance, heat-resistant stability) and is capable of providing a transparent article. The present invention relates to a method for producing a chlorinated polyvinyl chloride through thermal chlorination of a reaction solution including a vinyl chloride aqueous suspension that contains a vinyl chloride resin in a hermetically sealable reaction vessel, the method including: step 1 of initiating thermal chlorination by heating the reaction solution to 55° C. to 70° C. and then introducing chlorine into the reaction vessel; step 2 of raising the temperature of the reaction solution while maintaining the temperature inside the reaction vessel not higher than the glass transition temperature of a partially chlorinated polyvinyl chloride; and step 3 of carrying out the thermal chlorination at a predetermined temperature of 85° C. or higher but lower than 115° C. after the chlorine content of the partially chlorinated polyvinyl chloride reaches 58% by weight or more, the steps 1 to 3 being performed under stirring at a net stirring power (Pv) inside the reaction vessel of 0.2 to 2.5 kw/m3 per 1 m3 of the reaction solution.

Abstract translation: 本发明提供热稳定性（初始耐变色性，耐热稳定性）优异的能够提供透明制品的氯化聚氯乙烯的制造方法。 本发明涉及一种氯化聚氯乙烯的制备方法，该方法包括：在密封的反应容器中含有氯乙烯树脂的氯乙烯水悬浮体的反应溶液的热氯化，该方法包括：步骤1，通过 将反应溶液加热至55℃至70℃，然后将氯引入反应容器中; 在保持反应容器内的温度不高于部分氯化聚氯乙烯的玻璃化转变温度的同时提高反应溶液的温度的步骤2; 以及在部分氯化聚氯乙烯的氯含量达到58重量％以上之后，在85℃以上且低于115℃的规定温度下进行热氯化的步骤3，步骤1〜3 在反应容器内的净搅拌功率（Pv）下搅拌进行0.2至2.5kw / m3 / 1m 3反应溶液。

公开(公告)号：US09346901B2

公开(公告)日：2016-05-24

申请号：US14361791

申请日：2012-11-30

Applicant: TOKUYAMA SEKISUI CO., LTD.

Inventor： Masatoshi Harada

IPC: C08F8/22 ,  C08F14/06 ,  C08F114/06

CPC classification number: C08F114/06 ,  C08F8/22 ,  C08F14/06

Abstract: Chlorinated vinyl chloride resin may be produced through a heat chlorination reaction of an aqueous suspension of vinyl chloride resin in a hermetically sealable reaction vessel, the method including carrying out a first heat chlorination reaction while raising the temperature of an aqueous suspension of a vinyl chloride resin powder to a predetermined temperature within the range of 85° C. to 95° C., and subsequently carrying out a second heat chlorination reaction at the predetermined temperature.

Abstract translation: 氯化氯乙烯树脂可以通过氯乙烯树脂的水性悬浮液在可密封的反应容器中的热氯化反应来制备，该方法包括进行第一热氯化反应同时提高氯乙烯树脂的水悬浮液的温度 粉末至85℃至95℃范围内的预定温度，随后在预定温度下进行第二次热氯化反应。

公开(公告)号：US20140345886A1

公开(公告)日：2014-11-27

申请号：US14360821

申请日：2012-11-29

Applicant: SEKISUI CHEMICAL CO., LTD. ,  TOKUYAMA SEKISUI CO., LTD. ,  SEKISUI CHEMICAL HOKKAIDO CO., LTD.

Inventor： Hideaki Yano ,  Kenji Otsuka ,  Masaki Tono ,  Katsuhiro Nakazato ,  Ryota Yamasugi ,  Kenichi Matsumura

IPC: A62C2/06

CPC classification number: A62C2/065 ,  B29C48/12 ,  B29C48/131 ,  B29C48/16 ,  B29C48/19 ,  B29C48/30 ,  B29C48/304 ,  C08K5/12 ,  C08K13/02 ,  C08L23/16 ,  C08L27/24

Abstract: A thermally expandable multilayer packing for building material, having protruding parts and a body portion in the cross-sectional shape based a plane perpendicular to the longitudinal direction. The thermally expandable multilayer packing includes both a thermally expandable resin composition layer and a thermoplastic resin composition layer, wherein the thermally expandable resin composition forming the thermally expandable resin composition layer contains 100 parts by weight of a resin component containing a chlorinated polyvinyl chloride resin and/or an EPDM, 3 to 300 parts by weight of a thermally expandable graphite, 3 to 200 parts by weight of an inorganic filler and 20 to 200 parts by weight of a plasticizer. The thermally expandable resin composition layer and the thermoplastic resin composition layer are formed by simultaneous co-extrusion using the thermally expandable resin composition and the thermoplastic resin composition.

Abstract translation: 一种用于建筑材料的热膨胀多层填料，具有突出部分和基于垂直于纵向方向的平面的横截面形状的主体部分。 热膨胀性多层填料包括热膨胀性树脂组合物层和热塑性树脂组合物层，其中形成热膨胀性树脂组合物层的热膨胀性树脂组合物含有100重量份含有氯化聚氯乙烯树脂的树脂组分和/ EPDM，3〜300重量份的热膨胀性石墨，3〜200重量份的无机填料和20〜200重量份的增塑剂。 热膨胀性树脂组合物层和热塑性树脂组合物层通过使用热膨胀性树脂组合物和热塑性树脂组合物的同时共挤出而形成。

公开(公告)号：US12110385B2

公开(公告)日：2024-10-08

申请号：US17436910

申请日：2020-03-27

Applicant: SEKISUI CHEMICAL CO., LTD. ,  TOKUYAMA SEKISUI CO., LTD.

Inventor： Kenichi Matsumura ,  Norikazu Mashino ,  Kento Murakami ,  Nami Nakajima ,  Yasunari Kusaka ,  Takehisa Sugaya ,  Masahiko Yamagata

IPC: C08F8/22 ,  C08L27/24

CPC classification number: C08L27/24 ,  C08F8/22 ,  C08L2201/08 ,  C08L2203/30 ,  C08F8/22 ,  C08F114/06 ,  C08K7/14 ,  C08L27/24 ,  C08L27/24 ,  C08L51/04

Abstract: The present invention provides a chlorinated polyvinyl chloride resin that not only has high heat resistance and high mechanical strength but also is excellent in molding processability and is very easy to soften and additionally enables production of a molded article with high gloss. The present invention relates to a chlorinated polyvinyl chloride resin, containing three components including a A150 component, a B150 component, and a C150 component, and having a percentage of the C150 component (C150 component/(A150 component+B150 component+C150 component)) of 8.0% or more and 30.0% or less, the three components being identified by measuring the chlorinated polyvinyl chloride resin by a solid echo method using pulse NMR at 150° C. to give a free induction decay curve of 1H spin-spin relaxation, and subjecting the free induction decay curve to waveform separation into three curves derived from the A150 component, the B150 component, and the C150 component in order of shorter relaxation time using the least square method.