Abstract:
A reinforced rubber article containing a rubber article and a fibrous layer embedded into the rubber article. The fibrous layer contains monoaxially drawn tape elements having a rectangular cross-section and at least a first layer having a draw ratio of at least about 5, a modulus of at least about 2 GPa, a density of at least 0.85 g/cm3. The first layer contains a polymer selected from the group consisting of polyamide, polyester, and co-polymers thereof. Methods of forming the reinforced rubber article are also disclosed.
Abstract translation:一种加固橡胶制品,其包含橡胶制品和嵌入橡胶制品中的纤维层。 纤维层包含具有矩形横截面的单轴拉伸的带状元件,至少第一层具有至少约5的拉伸比,至少约2GPa的模量,至少0.85g / cm 3的密度。 第一层含有选自聚酰胺,聚酯及其共聚物的聚合物。 还公开了形成增强橡胶制品的方法。
Abstract:
A multi-layered fiber including a core, a first layer, and a second layer. The core has an exterior surface portion containing polypropylene. The first layer is disposed on at least a portion of the core and contains a first polymer. The first polymer contains a polymer having at least 70% α-olefin units and is characterized by a melting temperature lower than the melting temperature of the exterior surface portion of the core. The second layer is disposed on at least a portion of the first layer and contains a second polymer. The second polymer contains a co-polymer having at least 50% α-olefin units and is characterized by a number-average molecular weight of about 7,000 g/mol to 50,000 g/mol, a viscosity of between about 2,500 and 150,000 cP measured at 170° C., and a melting temperature lower than the melting temperature of the exterior surface portion of the core. The viscosity of the second polymer is not greater than about 10 percent of the viscosity of the first polymer measured at 170° C. Methods of forming the multi-layered fiber are also disclosed.
Abstract:
A consolidated fibrous structure including a multiplicity of fibrous layers. The fibers of each fibrous layer contain a core, a first layer and a second layer. The core has an exterior surface portion containing polypropylene. The first layer is disposed on at least a portion of the core and contains a first polymer. The first polymer contains a polymer having at least 70% α-olefin units and is characterized by a melting temperature lower than the melting temperature of the exterior surface portion of the core. The second layer is disposed on at least a portion of the first layer and contains a second polymer. The second polymer contains a co-polymer having at least 50% α-olefin units and is characterized by a number-average molecular weight of about 7,000 g/mol to 50,000 g/mol, a viscosity of between about 2,500 and 150,000 cP measured at 170° C., and a melting temperature lower than the melting temperature of the exterior surface portion of the core. The viscosity of the second polymer is not greater than about 10 percent of the viscosity of the first polymer measured at 170° C. At least a portion of the second layers of the fibers in each fibrous layer are fused to at least a portion of other first or second layers of the fibers within the same fibrous layer, at least a portion of the second layers of the fibers of each fibrous layer are fused with at least a portion of the first or second layers of the fibers in an adjacent fibrous layer, and the stiffness of the consolidated fibrous structure is at least 1 N-m. A fibrous layer is also described.
Abstract:
A consolidated fibrous structure including a multiplicity of fibrous layers. The fibers of each fibrous layer contain a core and a skin layer. The core has an exterior surface portion containing polypropylene. The skin layer is disposed on at least a portion of the core and contains a first polymer and a second polymer. The first polymer contains a polymer having at least 70% α-olefin units and is characterized by a melting temperature lower than the melting temperature of the exterior surface portion of the core. The second polymer contains a co-polymer having at least 50% α-olefin units and is characterized by a number-average molecular weight of about 7,000 g/mol to 50,000 g/mol, a viscosity of between about 2,500 and 150,000 cP measured at 170° C., and a melting temperature lower than the melting temperature of the exterior surface portion of the core. The viscosity of the second polymer is not greater than about 10 percent of the viscosity of the first polymer measured at 170° C. At least a portion of the skin layers of the fibers in each fibrous layer are fused to at least a portion of other skin layers of fibers within the same fibrous layer, at least a portion of the skin layers of the fibers of each fibrous layer are fused with at least a portion of the skin layers of the fibers in an adjacent fibrous layer, and the stiffness of the consolidated fibrous structure is at least 1 N-m. A fibrous layer is also described.
Abstract:
A reinforced rubber article comprising a rubber article and a fibrous layer embedded into the rubber article. The fibrous layer contains monoaxially drawn fibers having at least a first layer, where the first layer contains a polymer, a plurality of void-initiating particles, and a plurality of voids. Methods of forming the reinforced rubber article are also disclosed.
Abstract:
A reinforced rubber article containing a rubber article and a fibrous layer embedded into the rubber article. The fibrous layer contains monoaxially drawn tape elements having at least a first layer, an upper surface and a lower surface. The first layer comprises a blend of polyester and nylon 6. Methods of forming the reinforced rubber article are also disclosed.
Abstract:
A multi-layered fiber containing a core and a skin layer. The core has an exterior surface portion containing polypropylene. The skin layer is disposed on at least a portion of the core and contains a first polymer and a second polymer. The first polymer contains a polymer having at least 70% α-olefin units and is characterized by a melting temperature lower than the melting temperature of the exterior surface portion of the core. The second polymer contains a co-polymer having at least 50% α-olefin units and is characterized by a number-average molecular weight of about 7,000 g/mol to 50,000 g/mol, a viscosity of between about 2,500 and 150,000 cP measured at 170° C., and a melting temperature lower than the melting temperature of the exterior surface portion of the core. The viscosity of the second polymer is not greater than about 10 percent of the viscosity of the first polymer measured at 170° C. Methods of forming the multi-layered fiber are also disclosed.
Abstract:
A method of consolidating thermoplastic fibrous layers. The method begins with providing a plurality of fibers, where the fibers have a core with an exterior surface portion comprising polypropylene and a first layer disposed on at least a portion of the core. The first layer contains a first polymer, where the first polymer contains at least 70% α-olefin units and is characterized by a melting temperature less than the melting temperature of the exterior surface of the core. These fibers are formed into a fibrous layer. Next, a second layer is applied to the fibrous layer such that the second layer covers at least a portion of the first layers of the fibers. The second layer contains a second polymer being a co-polymer having at least 50% α-olefin units which is characterized by a number-average molecular weight of about 7,000 g/mol to 50,000 g/mol, a viscosity of between about 2,500 and 150,000 cP measured at 170° C., and a melting temperature lower than the melting temperature of the exterior surface of the core. The viscosity of the second polymer is less than a tenth of the viscosity of the first polymer measured at 170° C. Next, heat and optionally pressure are applied to the fibrous layer causing at least a portion of the second layers of the fibers in each fibrous layer to fuse to other first or second layers of the fibers within the same fibrous layer, at least a portion of the second layers of the fibers of each fibrous layer fuse with at least a portion of the first or second layers of the fibers in an adjacent fibrous layer, and at least a portion of the interstices to be filled with a blend of the first and second polymers, where the blend filling the interstices comprises at least 80% wt the second polymer.
Abstract:
A winder liner for unvulcanized rubber material comprising a first woven layer, a second woven layer, and a polymer layer. The first and second woven layers each contain a plurality of warp tape elements in a warp direction interwoven with a plurality of weft tape elements in a weft direction and a plurality of interstices between the warp and weft tape elements. The polymer layer is disposed on the inner surfaces of the first woven layer and the second woven layer and in the interstices of the first woven layer and the second woven layer. The polymer layer contains a first polymer comprising a co-polymer having at least 50% α-olefin units and is characterized by a number-average molecular weight of about 7,000 to 500,000 g/mol, and a viscosity of between about 2,500 and 150,000 cP measured at 170° C.
Abstract:
A reinforced rubber article comprising a rubber article and a fibrous layer embedded into the rubber article. The fibrous layer comprises monoaxially drawn fibers having at least a first layer, where the first layer contains a polymer and a plurality of voids. The voids are in an amount of between about 3 and 15 percent by volume of the first layer. Methods of forming the reinforced rubber article are also disclosed.