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1.发明授权Cobalt-catalyzed oxidations in volumetrically expanded liquids by compressed gases 有权通过压缩气体在体积扩大的液体中的钴催化氧化公开(公告)号：US08115029B2
公开(公告)日：2012-02-14
申请号：US11934612
申请日：2007-11-02
IPC分类号： C07C51/16
CPC分类号： C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C51/235 , C07C51/265 , C07C51/313 , C07C67/05 , C07C205/57 , C07C2601/14 , C07C49/12 , C07C49/403 , C07C49/603 , C07C49/597 , C07C47/22 , C07C49/78 , C07C63/26 , C07C63/16 , C07C63/24 , C07C59/84 , C07C55/02 , C07C55/14 , C07C59/347 , C07C69/013 , C07C69/003 , C07C69/16 , C07C69/145
摘要： Oxidations of hydrocarbons, cycloalkanes and alkenes, arylalkanes, and a variety of other organic substrates are accomplished by cobalt-N-hydroxysuccinimide co-catalyzed reactions with dioxygen under unusually mild, near ambient conditions of temperature and pressure. The improved safety of the oxidation method and the high yields of product obtained make use of a unique combination of cobalt (II) complexes with N-hydroxysuccinimide. These autoxidation reactions do not have prolonged initiation times. Many of these reactions can be safely performed under normal chemical laboratory conditions and do not require specialized equipment or reagents.
摘要翻译： 碳氢化合物，环烷烃和烯烃，芳基烷烃和各种其他有机基质的氧化通过钴 - N-羟基琥珀酰亚胺与二氧化碳的共催化反应在异常温和的近环境温度和压力条件下完成。 获得的产物的氧化方法的改进的安全性和高产率使得钴（II）配合物与N-羟基琥珀酰亚胺的独特组合。 这些自氧化反应没有延长的引发时间。 许多这些反应可以在正常的化学实验室条件下安全地进行，并且不需要专门的设备或试剂。
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公开(公告)号：US4723022A
公开(公告)日：1988-02-02
申请号：US837681
申请日：1986-03-10
申请人： Richard S. Givens , Robert G. Carlson , Kasturi Srinivasachar , Takeru Higuchi , Osborne S. Wong , Takeru Higuchi
发明人： Richard S. Givens , Robert G. Carlson , Kasturi Srinivasachar , Takeru Higuchi , Osborne S. Wong , Takeru Higuchi
IPC分类号： C07C47/57 , C07C45/00 , C07C47/575 , C07C51/00 , C07C59/125 , C07C65/30 , C07C67/00 , C07C201/00 , C07C205/44 , C07C223/06 , C07C253/00 , C07C255/52 , C07C255/56 , C07C301/00 , C07C309/28 , C07C311/00 , C07D235/02 , C07D317/70 , C09K11/06 , G01N33/52 , G01N33/68 , C07C59/76 , C07C69/76 , C07C87/64
CPC分类号： C07D235/02 , C07C205/44 , C07C309/00 , C07D317/70 , G01N33/52
摘要： A new class of substituted 2,3-naphthalenedicarboxaldehydes (NDA) is disclosed. Such compounds are of the formula: ##STR1## wherein one or more of R.sub.1 -R.sub.8 are various substituting groups. The above compounds react, in the presence of cyanide ion, with compounds containing primary amino groups to form adducts which exhibit a high fluorescent yield and thus are readily detected and measured by fluorometric assaying techniques.
摘要翻译： 公开了一类新的取代的2,3-萘二甲醛（NDA）。 这样的化合物具有下式：其中一个或多个R 1 -R 8是各种取代基。 上述化合物在氰化物离子存在下与含有伯氨基的化合物反应，形成显示出高荧光产率的加合物，因此通过荧光测定技术容易地检测和测量。
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3.发明申请Cobalt-Catalyzed Oxidations in Volumetrically Expanded Liquids by Compressed Gases 有权通过压缩气体在体积膨胀液体中的钴催化氧化公开(公告)号：US20080139841A1
公开(公告)日：2008-06-12
申请号：US11934612
申请日：2007-11-02
CPC分类号： C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C51/235 , C07C51/265 , C07C51/313 , C07C67/05 , C07C205/57 , C07C2601/14 , C07C49/12 , C07C49/403 , C07C49/603 , C07C49/597 , C07C47/22 , C07C49/78 , C07C63/26 , C07C63/16 , C07C63/24 , C07C59/84 , C07C55/02 , C07C55/14 , C07C59/347 , C07C69/013 , C07C69/003 , C07C69/16 , C07C69/145
摘要： Oxidations of hydrocarbons, cycloalkanes and alkenes, arylalkanes, and a variety of other organic substrates are accomplished by cobalt-N-hydroxysuccinimide co-catalyzed reactions with dioxygen under unusually mild, near ambient conditions of temperature and pressure. The improved safety of the oxidation method and the high yields of product obtained make use of a unique combination of cobalt (II) complexes with N-hydroxysuccinimide. These autoxidation reactions do not have prolonged initiation times. Many of these reactions can be safely performed under normal chemical laboratory conditions and do not require specialized equipment or reagents.
摘要翻译： 碳氢化合物，环烷烃和烯烃，芳基烷烃和各种其他有机基质的氧化通过钴 - N-羟基琥珀酰亚胺与二氧化碳的共催化反应在异常温和的近环境温度和压力条件下完成。 获得的产物的氧化方法的改进的安全性和高产率使得钴（II）配合物与N-羟基琥珀酰亚胺的独特组合。 这些自氧化反应没有延长的引发时间。 许多这些反应可以在正常的化学实验室条件下安全地进行，并且不需要专门的设备或试剂。
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公开(公告)号：US06783539B1
公开(公告)日：2004-08-31
申请号：US10113426
申请日：2002-03-29
IPC分类号： A61B1703
CPC分类号： A61L24/001
摘要： A phototriggerable composition and method for use in crosslinking protein such as collagen comprising application of a tethered diazopyruvate composition followed by irradiation, whereby the composition results in the sutureless wound closure of, for example, a tendon or cornea.
摘要翻译： 一种用于交联蛋白质如胶原蛋白的可光触发组合物和方法，包括施用连接的重氮丙酮酸组合物，然后进行照射，由此组合物导致例如腱或角膜的无缝合伤口闭合。
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5.发明授权Chemiluminescence method for assaying compounds containing primary amino groups using 1-cyano-2-substituted benz(f)- or naphth(f)-isoindole fluorescers 失效使用1-氰基-2-取代苯并（f） - 或萘（f） - 异吲哚荧光剂测定含有伯氨基的化合物的化学发光法
公开(公告)号：US4758520A
公开(公告)日：1988-07-19
申请号：US837671
申请日：1986-03-10
申请人： Bodgan Matuszewski , Richard S. Givens , Robert G. Carlson , Takeru Higuchi , Takao Kawasaki , Osborne S. Wong
发明人： Bodgan Matuszewski , Richard S. Givens , Robert G. Carlson , Takeru Higuchi , Takao Kawasaki , Osborne S. Wong
IPC分类号： G01N33/50 , C07C69/63 , C07D209/58 , C07D209/62 , C09K11/07 , G01N21/76 , G01N33/52 , G01N33/68 , G01N33/84
CPC分类号： G01N33/84 , G01N33/52 , G01N33/6809 , Y10T436/142222 , Y10T436/172307 , Y10T436/173845 , Y10T436/200833 , Y10T436/203332 , Y10T436/206664
摘要： A chemiluminescence method for assaying compounds containing primary amino groups using 1-cyano-2-substituted benz(f)- or naphth(f)-isoindole fluorescers is disclosed. The 1-cyano-2-substituted benz(f)- or naphth(f)-isoindole (CBI or CNI) is formed by reacting a compound containing a primary amino group with naphthalene-2-3-dicarboxaldehyde or anthracene-2,3-dicarboxaldehyde in the presence of cyanide ion. The reaction product of hydrogen peroxide with an oxalate ester is then combined with the CBI or CNI to form an analyte which exhibits chemiluminescence. A detector is used to measure the chemiluminescence emission from the chemiluminescence derivatized analytes. Compounds containing primary amino groups which may be assayed according to the present invention include primary amines, amino acids, peptides and catecholamines. The method can also be adapted to the analysis of trace amounts of cyanide ion and hydrogen peroxide.
摘要翻译： 公开了使用1-氰基-2-取代的苯并（f） - 或萘（f） - 异吲哚荧光剂测定含有伯氨基的化合物的化学发光方法。 1-氰基-2-取代的苯并（f） - 或（f） - 异吲哚（CBI或CNI）是通过使含有伯氨基的化合物与萘-2,3-二甲醛或蒽-23 在氰化物离子存在下加入二甲醛。 然后将过氧化氢与草酸酯的反应产物与CBI或CNI组合以形成显示化学发光的分析物。 检测器用于测量化学发光衍生分析物的化学发光。 可以根据本发明测定的含有伯氨基的化合物包括伯胺，氨基酸，肽和儿茶酚胺。 该方法也可适用于痕量氰化物离子和过氧化氢的分析。
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