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公开(公告)号：US06342605B1
公开(公告)日：2002-01-29
申请号：US09376909
申请日：1999-08-18
IPC分类号： C07F96541
CPC分类号： B01J31/2438 , B01J31/2471 , B01J2531/822 , C07C45/50 , C07F9/65683 , C07F9/657163 , C07C47/02
摘要： Bidentate phosphine ligands of the formula wherein the substituents are as defined in the specification and a process for preparing linear aldehydes by hydroformylating internal olefins using such phosphine ligands.
摘要翻译： 取代基中的二烷基膦配位体如本说明书中所定义，和通过使用这种膦配体加氢甲酰化内烯烃制备线性醛的方法。
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公开(公告)号：US6153800A
公开(公告)日：2000-11-28
申请号：US303680
申请日：1999-05-03
IPC分类号： B01J23/46 , B01J31/18 , B01J31/24 , C07B61/00 , C07C45/50 , C07C51/373 , C07C67/347 , C07C69/716 , C07C253/10 , C07C253/30 , C07C255/17 , C07F9/145 , C07F9/50 , C07F15/00
CPC分类号： C07F9/145 , B01J31/185 , B01J31/2404 , C07C253/30 , C07C45/50 , C07C67/347 , B01J2231/12 , B01J2231/321 , B01J2231/323 , B01J2231/52 , B01J2231/645 , B01J23/464 , B01J23/468 , B01J2531/0266 , B01J2531/822 , B01J2531/827
摘要： Process for the preparation of an aldehyde through hydroformylation of an unsaturated organic compound in the presence of a catalyst system comprising rhodium of iridium and a multidentate organic phosphite ligand, wherein a monodentate phosphine is present.The process according to the invention can advantageously be carried out for the preparation of methyl-5-formylvalerate, which is an intermediate product in the preparation of a caprolactam or adipic acid, which are in turn raw materials for the preparation of nylon-6 and nylon-6,6, respectively.
摘要翻译： 在含有铱铑和多齿有机亚磷酸酯配位体的催化剂体系存在下，通过不饱和有机化合物的羰基化制备醛的方法，其中存在单齿膦。 根据本发明的方法可以有利地用于制备作为制备己内酰胺或己二酸的中间产物的5-甲酰基戊酸甲酯，其又是制备尼龙-6的原料和 尼龙-6,6。
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公开(公告)号：US5338825A
公开(公告)日：1994-08-16
申请号：US067320
申请日：1993-05-25
CPC分类号： C08G67/02
摘要： A process for the preparation of copolymers which comprises reacting carbon monoxide and one or more ethylenically unsaturated compounds under polymerization conditions in the presence of a catalyst system comprising:(a) at least one metal selected from the Groups VI, VII and/or VIII of the Periodic Table; and(b) a stabilizing organic compound attached to (one of) the said metal(s) and containing at least one group capable of forming an additional, non-covalent, bond with (one of) the said metal(s).Also disclosed are products made by the process of the invention, and novel complexes of the general formula [LPdQ] [A].sub.n, wherein Q stands for 2-acylnorborn-1-yl, 2-acylnorborn-3-en-1-yl or a 2-acylethyl group, n is 0 or 1, A stands for a weakly or non-coordinating anion and, if n is 1, L stands for bidentate ligand of the general formula R.sup.1 R.sup.2 M.sup.1 --R--M.sup.2 R.sup.3 R.sup.4, wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 independently represent substituted or nonsubstituted hydrocarbyl groups, M.sup.1 and M.sup.2 independently represent phosphorus, arsenic, antimony or nitrogen and R represents a divalent organic bridging group containing at least one carbon atom in the bridge, or, if n =0, L stands for a sulfonate anion of the general formula R.sup.8 R.sup.9 P--R.sup.10 --SO.sup.-.sub.3 wherein R.sup.8 and R.sup.9 independently represent substituted or non-substituted hydrocarbyl groups and R.sup.10 represents an organic bridging group having 1-4 carbon atoms in the bridge.
摘要翻译： 一种制备共聚物的方法，其包括在聚合条件下在催化剂体系存在下使一氧化碳和一种或多种烯属不饱和化合物反应，所述催化剂体系包含：（a）至少一种选自第VI，VII和/或VIII族的金属 周期表; 和（b）连接到所述金属之一上的稳定的有机化合物，并且含有至少一个能够与所述金属之一形成另外的非共价键的基团。 还公开了通过本发明的方法制备的产物，以及通式[LPdQ] [A] n的新型配合物，其中Q代表2-酰基生物素-1-基，2-酰基降冰片烯-3-烯-1-基 或2-氨基乙基，n为0或1，A表示弱配位阴离子和非配位阴离子，如果n为1，则L代表通式为R1R2M1-R-M2R3R4的二齿配体，其中R1，R2， R3和R4独立地表示取代或非取代的烃基，M1和M2独立地表示磷，砷，锑或氮，R表示在桥中含有至少一个碳原子的二价有机桥基，或者如果n = 0，L 代表通式R8R9P-R10-SO-3的磺酸根阴离子，其中R8和R9独立地表示取代或未取代的烃基，R10表示在桥中具有1-4个碳原子的有机桥连基团。
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公开(公告)号：US5243079A
公开(公告)日：1993-09-07
申请号：US936491
申请日：1992-08-28
CPC分类号： C08G67/02 , B01J31/064 , B01J31/1683 , B01J31/24 , B01J31/2409 , C07C43/174 , C07F15/0013 , C07F15/0066 , C07F9/5027 , B01J2231/10 , B01J2531/0258 , B01J2531/80 , B01J2531/824
摘要： An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon employs a novel catalyst composition formed from a compound of palladium, the anion of a strong non-hydrohalogenic acid and a novel hexakis phosphine ligand. The process is characterized by a lessened degree of reactor fouling.
摘要翻译： 用于生产一氧化碳和至少一种烯属不饱和烃的线性交替聚合物的改进方法采用由钯的化合物，强非氢卤酸的阴离子和新的六磷化膦配体形成的新型催化剂组合物。 该方法的特征在于反应器结垢程度降低。
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公开(公告)号：US5004844A
公开(公告)日：1991-04-02
申请号：US372577
申请日：1989-06-28
IPC分类号： B01J31/12 , C07B61/00 , C07C29/141 , C07C29/145 , C07C31/10 , C07C31/12 , C07C33/14 , C07C35/08
CPC分类号： C07C29/145 , C07C29/141 , C07C2101/14 , C07C2101/16 , C07C2102/42
摘要： A process for the preparation of a primary or secondary alcohol, which comprises hydrogenating respectively an aldehyde or ketone in the presence of a catalyst system comprising a platinum compound, an acid having a pKa in the range from about 2 to about 10.5 and a phosphorus compound of the formula R.sup.1 R.sup.2 POH, wherein R.sup.1 and R.sup.2 each independently represents an alkyl group or a phenyl group, at a temperature in the range from about 20.degree. to about 150.degree. C. and at a pressure in the range from about 1 to about 100 bar.
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6.发明授权Carbon monoxide/olefin co-polymerization process with phosphino substituted sulfonic acid catalyst 失效一氧化碳/烯烃共聚过程与膦取代的磺酸催化剂
公开(公告)号：US4855399A
公开(公告)日：1989-08-08
申请号：US140013
申请日：1987-12-31
申请人： Johannes A. Van Doorn , Eit Drent , Petrus W. N. M. Van Leeuwen , Nicolaas Meijboom , Aart B. Van Oort , Richard L. Wife
发明人： Johannes A. Van Doorn , Eit Drent , Petrus W. N. M. Van Leeuwen , Nicolaas Meijboom , Aart B. Van Oort , Richard L. Wife
CPC分类号： C08G67/02 , C07F9/5004 , C07F9/5022
摘要： An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon employs a catalyst composition formed from a palladium salt and a phosphino-substituted sulfonic acid.
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公开(公告)号：US4166076A
公开(公告)日：1979-08-28
申请号：US869563
申请日：1978-01-16
IPC分类号： B01J31/00 , C07B61/00 , C07C1/00 , C07C2/46 , C07C2/52 , C07C13/20 , C07C13/263 , C07C67/00 , C07F9/141 , C07C3/21 , C07C3/035
CPC分类号： C07C2/465 , C07C2/52 , C07F9/1411 , C07C2101/16 , C07C2101/18 , C07C2531/02
摘要： 1,5-Dimethyl-1,5-cyclooctadiene and 1,4-dimethyl-4-vinyl-1-cyclohexene are prepared by contacting isoprene with a catalyst obtained by mixing a nickel compound, a reducing agent capable of reducing the nickel to zerovalent nickel, and a trihydrocarbyl phosphite, arsenite or antimonite wherein at least one of the three hydrocarbyl groups is a substituted hydrocarbyl group CF.sub.3 --(CF.sub.2).sub.n C(H)(R)--, in which n.gtoreq.0 and R is an optionally substituted hydrocarbyl group. Only very small amounts of the undesired 1,6-dimethyl-1,5-cyclooctadiene are formed.
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公开(公告)号：US5354340A
公开(公告)日：1994-10-11
申请号：US150934
申请日：1993-11-10
CPC分类号： C08G67/02
摘要： A process for the preparation of copolymers of carbon monoxide and one or more ethylenically unsaturated compounds by contacting the monomers, under polymerization conditions, with a catalyst system comprising a) a source of cations of one or more metals of Group VIII of the Periodic Table and b) a bidentate ligand, and c) a minor amount of a compound containing a hydride moiety. Copolymers made by this process generally have low molecular weights.
摘要翻译： 一种制备一氧化碳和一种或多种烯键式不饱和化合物的共聚物的方法，其通过使聚合条件下的单体与催化剂体系接触，所述催化剂体系包括：a）周期表第VIII族的一种或多种金属的阳离子源，以及 b）二齿配体，和c）少量含有氢化物部分的化合物。 通过该方法制备的共聚物通常具有低分子量。
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公开(公告)号：US5225386A
公开(公告)日：1993-07-06
申请号：US783593
申请日：1991-10-28
IPC分类号： C08G67/02
CPC分类号： C08G67/02
摘要： An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon of at least 3 carbon atoms employs a novel catalyst composition formed from a palladium compound, the anion of a strong non-hydrohalogenic acid, an aliphatic bidentate ligand of phosphorus and a polyalkoxyalkane.
摘要翻译： 用于生产一氧化碳和至少一种具有至少3个碳原子的至少一种烯属不饱和烃的线性交替聚合物的改进方法使用由钯化合物，强非氢卤酸的阴离子，脂族二齿 磷配体和聚烷氧基烷烃。
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10.发明授权Catalytic polymerization of CO/olefin with ortho polar substituted aryl bidentate p ligand 失效邻苯基取代芳基二齿配位体CO /烯烃的催化聚合
公开(公告)号：US4843145A
公开(公告)日：1989-06-27
申请号：US89373
申请日：1987-08-26
CPC分类号： C08G67/02 , B01J31/2409 , B01J2531/824 , B01J31/1895
摘要： An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon comprises contacting under polymerization conditions the carbon monoxide and hydrocarbon in the presence of a catalyst composition formed from a compound of certain Group VIII metals, e.g., palladium, an anion of a non-hydrohalogenic acid having a pKa above about 2 but below about 6, and a bidentate ligand of phosphorus wherein at least one of the monovalent phosphorus substituents is aromatic and substituted in a position ortho to the phosphorus with a polar substitutent.
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