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公开(公告)号：US5243079A
公开(公告)日：1993-09-07
申请号：US936491
申请日：1992-08-28
CPC分类号： C08G67/02 , B01J31/064 , B01J31/1683 , B01J31/24 , B01J31/2409 , C07C43/174 , C07F15/0013 , C07F15/0066 , C07F9/5027 , B01J2231/10 , B01J2531/0258 , B01J2531/80 , B01J2531/824
摘要： An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon employs a novel catalyst composition formed from a compound of palladium, the anion of a strong non-hydrohalogenic acid and a novel hexakis phosphine ligand. The process is characterized by a lessened degree of reactor fouling.
摘要翻译： 用于生产一氧化碳和至少一种烯属不饱和烃的线性交替聚合物的改进方法采用由钯的化合物，强非氢卤酸的阴离子和新的六磷化膦配体形成的新型催化剂组合物。 该方法的特征在于反应器结垢程度降低。
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公开(公告)号：US5229343A
公开(公告)日：1993-07-20
申请号：US941338
申请日：1992-09-04
CPC分类号： B01J31/2409 , C07F9/5027 , C07F9/5077 , C08G67/02 , B01J2231/10 , B01J2531/824 , B01J31/2208
摘要： An improved catalyst composition for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon is formed from a compound of palladium, the anion of a strong non-hydrohalogenic acid and a bidentate ligand of phosphorus wherein each monovalent phosphorus substituent is phenyl substituted by at least one alkoxy group on a ring carbon atom ortho to the atom through which the group is connected to a phosphorus atom, and the divalent alkylene bridging group between the phosphorus atoms has a single substituent (other than hydrogen) having atoms of carbon, hydrogen and optionally oxygen.
摘要翻译： 用于生产一氧化碳和至少一种烯键式不饱和烃的线性交替聚合物的改进的催化剂组合物由钯，强非氢卤酸的阴离子和磷的二齿配体形成，其中每个一价磷取代基是 在与磷原子连接的原子邻位的环碳原子上被至少一个烷氧基取代的苯基，磷原子之间的二价亚烷基桥接基团具有单个取代基（除了氢原子） 碳，氢和任选的氧。
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3.发明授权Polymerization of carbon monoxide/olefin with P bidentate ligand having (1) alkoxy phenyl P group and (2) monosubstituted divalent bridging group 失效具有（1）烷基苯基P基团和（2）单取代的多价桥联组合的具有P二价配位体的二氧化碳/烯烃的聚合
公开(公告)号：US5171832A
公开(公告)日：1992-12-15
申请号：US684109
申请日：1991-04-12
CPC分类号： B01J31/2409 , C07F9/5027 , C07F9/5077 , C08G67/02 , B01J2231/10 , B01J2531/80 , B01J2531/824
摘要： An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon employs a novel catalyst composition formed from a compound of palladium, the anion of a strong non-hydrohalogenic acid and a bidentate ligand of phosphorus wherein each monovalent phosphorus substituent is phenyl substituted by at least one alkoxy group on a ring carbon atom ortho to the atom through which the group is connected to phosphorus and the divalent alkylene bridging group has a single substituent (other than hydrogen) having atoms of carbon, hydrogen and optionally oxygen.
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4.发明授权
公开(公告)号：US5169926A
公开(公告)日：1992-12-08
申请号：US684110
申请日：1991-04-12
CPC分类号： C08G67/02 , B01J31/064 , B01J31/1683 , B01J31/24 , B01J31/2409 , C07C43/174 , C07F15/0013 , C07F15/0066 , C07F9/5027 , B01J2231/10 , B01J2531/0258 , B01J2531/80 , B01J2531/824
摘要： An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon employs a novel catalyst composition formed from a compound of palladium, the anion of a strong non-hydrohalogenic acid and a novel hexakis phosphine ligand. The process is characterized by a lessened degree of reactor fouling.
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公开(公告)号：US5212135A
公开(公告)日：1993-05-18
申请号：US936493
申请日：1992-08-28
CPC分类号： C08G67/02 , B01J31/064 , B01J31/1683 , B01J31/24 , B01J31/2409 , C07C43/174 , C07F15/0013 , C07F15/0066 , C07F9/5027 , B01J2231/10 , B01J2531/0258 , B01J2531/80 , B01J2531/824
摘要： An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon employs a novel catalyst composition formed from a compound of palladium, the anion of a strong non-hydrohalogenic acid and a novel hexakis phosphine ligand. The process is characterized by a lessened degree of reactor fouling.
摘要翻译： 用于生产一氧化碳和至少一种烯属不饱和烃的线性交替聚合物的改进方法采用由钯的化合物，强非氢卤酸的阴离子和新的六磷化膦配体形成的新型催化剂组合物。 该方法的特征在于反应器结垢程度降低。
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