公开(公告)号：US20130059993A1

公开(公告)日：2013-03-07

申请号：US13663475

申请日：2012-10-30

Applicant: SHOWA DENKO K.K.

Inventor： Satoshi FUJIBE ,  Nobuyuki KIBINO ,  Tsuneo TAJIMA

IPC: C08F4/82 ,  C07F15/00 ,  C08F132/04

CPC classification number: C07F15/006 ,  C08F4/64048 ,  C08F232/08

Abstract: A catalyst for a polymerization of norbornene monomers includes a transition metal complex represented by a formula (1). A method for producing a norbornene copolymer includes copolymerizing first norbornene monomers corresponding to a first monomer unit represented by a formula (2) and second norbornene monomers corresponding to a second monomer unit represented by a formula (3) in a presence of the catalyst. The transition metal complex is preferably (π-allyl){2-[N-(2,6-diisopropylphenyl)iminomethyl]phenolate}palladium, (π-allyl){2-[N-(2,6-diisopropylphenyl)iminomethyl]-4-fluorophenolate}palladium, (π-allyl)[2-(N-phenyliminomethyl)phenolate]palladium or (π-allyl){2-[N-(2,6-diisopropylphenyl)iminomethyl]-6-methylphenolate}palladium.

Abstract translation: 用于降冰片烯单体的聚合的催化剂包括由式（1）表示的过渡金属络合物。 降冰片烯共聚物的制造方法包括：在催化剂存在下，使对应于由式（2）表示的第一单体单元的第一降冰片烯单体和对应于式（3）所示的第二单体单元的第二降冰片烯单体共聚。 过渡金属配合物优选为（2- {N-（2,6-二异丙基苯基）亚氨基甲基]苯酚盐}钯（{（R） - 烯丙基）{2- [N-（2,6-二异丙基苯基） 亚氨基甲基] -4-氟苯甲酸酯}钯（（+） - [2-（N-苯基亚氨基甲基）苯甲酸酯]钯或（β-烯丙基）{2- [N-（2,6-二异丙基苯基）亚氨基甲基] - 甲基苯酚盐}钯。

公开(公告)号：US5714427A

公开(公告)日：1998-02-03

申请号：US311068

申请日：1994-09-23

Applicant: Andreas Winter ,  Volker Dolle ,  Walter Spaleck

Inventor： Andreas Winter ,  Volker Dolle ,  Walter Spaleck

IPC: C08F4/642 ,  C07F17/00 ,  C08F4/60 ,  C08F4/64 ,  C08F4/646 ,  C08F4/659 ,  C08F4/6592 ,  C08F4/82 ,  C08F10/00 ,  C08F10/06 ,  C08F110/06 ,  C08F210/16

CPC classification number: C08F10/06 ,  C07F17/00 ,  C08F10/00 ,  C08F110/06 ,  C08F210/16 ,  C08F4/65904 ,  C08F4/65912 ,  C08F4/65927 ,  Y10S526/943

Abstract: A catalyst system comprising an aluminoxane and a transition-metal component (metallocene) is used, the transition-metal component comprising at least one zirconocene of the formula I ##STR1## and at least one zirconocene of the formula Ia or alternatively at least 2 zirconocenes of the formula I.

Abstract translation: 使用包含铝氧烷和过渡金属组分（茂金属）的催化剂体系，所述过渡金属组分包含至少一种式I（I）式Ia的氧化锆或者至少2种式 一世。

公开(公告)号：US4338219A

公开(公告)日：1982-07-06

申请号：US910040

申请日：1978-05-26

Applicant: Floyd E. Naylor

Inventor： Floyd E. Naylor

IPC: C08F210/00 ,  C08F210/12 ,  C08F236/04 ,  C08F4/26 ,  C08F4/80 ,  C08F4/82 ,  C08F36/06

CPC classification number: C08F210/12 ,  C08F210/00 ,  C08F236/04

Abstract: The copolymerization of isoolefins with dienes is initiated by nickel source complexes with compounds of titanium or vanadium. For example, isobutylene and butadiene are copolymerized in the presence of a catalyst of bis(1,5-cyclooctadiene)nickel and titanium tetrachloride.

Abstract translation: 异烯烃与二烯的共聚是由与钛或钒化合物的镍源配合物引发的。 例如，在双（1,5-环辛二烯）镍和四氯化钛的催化剂存在下，异丁烯和丁二烯共聚。

公开(公告)号：US11795285B2

公开(公告)日：2023-10-24

申请号：US18070538

申请日：2022-11-29

Applicant: PROMERUS, LLC ,  MERCK PATENT GMBH

Inventor： Oleksandr Burtovyy ,  Pawel Miskiewicz ,  Hyun-Jin Yoon ,  Patrick Schellin ,  Manuel Hamburger

IPC: C08J5/18 ,  C08F4/82 ,  C09D4/00 ,  C09D5/32 ,  B33Y70/00 ,  C08F132/08 ,  C08K5/3475 ,  C09D145/00 ,  H10K50/844

CPC classification number: C08J5/18 ,  B33Y70/00 ,  C08F4/82 ,  C08F132/08 ,  C08K5/3475 ,  C09D4/00 ,  C09D5/32 ,  C09D145/00 ,  C08F2410/01 ,  C08J2345/00 ,  H10K50/844

Abstract: Embodiments in accordance with the present invention encompass compositions encompassing a latent organo-ruthenium compound, a photosensitizer, one or more monomers which undergo ring open metathesis polymerization (ROMP) and at least two distinct types of UV blockers, where when said composition is exposed to suitable actinic radiation forms a substantially transparent film or a three dimensional object. Surprisingly, the compositions are very stable at ambient conditions to temperatures up to 80° C. for several weeks and undergo mass polymerization only when subjected to actinic radiation under inert atmosphere such as for example a blanket of nitrogen. Accordingly, compositions of this invention are useful in various opto-electronic applications, including as 3D printing materials, coatings, encapsulants, fillers, leveling agents, among others.

公开(公告)号：US20230167256A1

公开(公告)日：2023-06-01

申请号：US18070538

申请日：2022-11-29

Applicant: PROMERUS, LLC ,  MERCK PATENT GMBH

Inventor： OLEKSANDR BURTOVYY ,  PAWEL MISKIEWICZ ,  HYUN-JIN YOON ,  PATRICK SCHELLIN ,  MANUEL HAMBURGER

IPC: C08J5/18 ,  C08F132/08 ,  C08F4/82 ,  C08K5/3475 ,  C09D145/00 ,  C09D5/32 ,  C09D4/00 ,  B33Y70/00

CPC classification number: C08J5/18 ,  C08F132/08 ,  C08F4/82 ,  C08K5/3475 ,  C09D145/00 ,  C09D5/32 ,  C09D4/00 ,  B33Y70/00 ,  C08F2410/01 ,  C08J2345/00 ,  H01L51/5253

Abstract: Embodiments in accordance with the present invention encompass compositions encompassing a latent organo-ruthenium compound, a photosensitizer, one or more monomers which undergo ring open metathesis polymerization (ROMP) and at least two distinct types of UV blockers, where when said composition is exposed to suitable actinic radiation forms a substantially transparent film or a three dimensional object. Surprisingly, the compositions are very stable at ambient conditions to temperatures up to 80° C. for several weeks and undergo mass polymerization only when subjected to actinic radiation under inert atmosphere such as for example a blanket of nitrogen. Accordingly, compositions of this invention are useful in various opto-electronic applications, including as 3D printing materials, coatings, encapsulants, fillers, leveling agents, among others.

公开(公告)号：US11471867B2

公开(公告)日：2022-10-18

申请号：US16609197

申请日：2018-06-22

Applicant: GWANGJU INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Sukwon Hong ,  Seunghwan Byun

IPC: B01J31/22 ,  C07F15/00 ,  C08G61/00 ,  C07B35/08 ,  C08F4/82

Abstract: The present invention relates to a novel ligand for forming a ruthenium complex, a ruthenium complex catalyst, a production method therefor and a use thereof. The ligand for forming a ruthenium complex and the ruthenium complex catalyst, according to the present invention, exhibit high catalytic activity, high selectivity, and stability.

公开(公告)号：US5525688A

公开(公告)日：1996-06-11

申请号：US342805

申请日：1994-11-21

Applicant: Bruce Novak ,  Timothy J. Deming

Inventor： Bruce Novak ,  Timothy J. Deming

IPC: B01J31/04 ,  B01J31/22 ,  C08F4/82

CPC classification number: C08F4/82 ,  B01J31/2239 ,  B01J31/2291 ,  B01J2531/0205 ,  B01J2531/847

Abstract: A .pi.-allylnickel/counterion complex is reacted with a hologenated ketone to produce a highly active polymerization initiator.

Abstract translation: 将pilyallynickel /抗衡离子络合物与氢化酮反应以产生高活性聚合引发剂。

公开(公告)号：US5171832A

公开(公告)日：1992-12-15

申请号：US684109

申请日：1991-04-12

Applicant: Johannes J. Keijsper ,  Alexander W. van der Made

Inventor： Johannes J. Keijsper ,  Alexander W. van der Made

IPC: C08F4/82 ,  B01J31/24 ,  B01J31/28 ,  C07F9/50 ,  C08F210/00 ,  C08G67/00 ,  C08G67/02

CPC classification number: B01J31/2409 ,  C07F9/5027 ,  C07F9/5077 ,  C08G67/02 ,  B01J2231/10 ,  B01J2531/80 ,  B01J2531/824

Abstract: An improved process for the production of linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon employs a novel catalyst composition formed from a compound of palladium, the anion of a strong non-hydrohalogenic acid and a bidentate ligand of phosphorus wherein each monovalent phosphorus substituent is phenyl substituted by at least one alkoxy group on a ring carbon atom ortho to the atom through which the group is connected to phosphorus and the divalent alkylene bridging group has a single substituent (other than hydrogen) having atoms of carbon, hydrogen and optionally oxygen.

公开(公告)号：US4501866A

公开(公告)日：1985-02-26

申请号：US633814

申请日：1984-07-23

Applicant: David M. Roggeman ,  Shrikant R. Malani ,  Jung W. Kang

Inventor： David M. Roggeman ,  Shrikant R. Malani ,  Jung W. Kang

IPC: C08F4/00 ,  C08F2/04 ,  C08F2/06 ,  C08F4/54 ,  C08F4/60 ,  C08F4/70 ,  C08F36/06 ,  C08F136/06 ,  C08F4/82

CPC classification number: C08F136/06

Abstract: A method for preparing high cis-1,4 polybutadiene by a continuous process which involves the continuous polymerization of 1,3-butadiene in solution under adiabatic conditions is provided. The method comprises the steps of: (I) feeding continuously to a single agitated polymerization reactor: (a) a monomer stream comprising 1,3-butadiene in a hydrocarbon solvent; (b) a preformed .pi. allyl catalyst stream formed by admixing a carboxylated metal oxy borate compound represented by the formulae (RCOOMO).sub.3 B or (ROCOOMO).sub.2 B-OR' wherein R and R' are alkyl radicals containing from 7 to 17 carbon atoms and M is nickel or cobalt, an organo aluminum compound, an alcohol, a small amount of 1,3-butadiene and a hydrocarbon solvent; and (c) a cocatalyst stream comprising a boron trifluoride complex with an alcohol; and (II) withdrawing continuously from said reactor high cis-1,4 polybutadiene at the same rate as said monomer, preformed catalyst and cocatalyst streams are fed to the reactor.In an additional embodiment of the invention, a method of preparing a preformed .pi. allyl catalyst having improved stability and solubility in hydrocarbon solvent is provided.High cis-1,4 polybutadiene polymers produced by the method of the invention have good green strength and tack and may be used as tire rubbers and impact modifiers for plastics.

Abstract translation: 提供了一种通过连续方法制备高顺式-1,4聚丁二烯的方法，该方法涉及在绝热条件下在溶液中连续聚合1,3-丁二烯。 该方法包括以下步骤：（I）连续进料到单一搅拌聚合反应器中：（a）在烃溶剂中包含1,3-丁二烯的单体料流; （b）通过将由式（RCOOMO）3B或（ROCOOMO）2B-OR'表示的羧化金属硼酸硼酸盐化合物（RCOOMO）2B-OR'（其中R和R'是含有7至17个碳原子的烷基）和 M是镍或钴，有机铝化合物，醇，少量的1,3-丁二烯和烃溶剂; 和（c）包含三氟化硼配合物与醇的助催化剂流; 和（II）以与所述单体相同的速率从所述反应器高顺式-1,4-聚丁二烯中连续排出，将预制的催化剂和助催化剂物流进料到反应器中。 在本发明的另外的实施方案中，提供了一种制备具有改进的在烃溶剂中的稳定性和溶解度的预制的丙烯酸烯丙酯的方法。 通过本发明方法制备的高顺-1,4聚丁二烯聚合物具有良好的生坯强度和粘性，并可用作塑料的轮胎橡胶和抗冲击改性剂。

公开(公告)号：US4105845A

公开(公告)日：1978-08-08

申请号：US446427

申请日：1974-02-27

Applicant: Floyd E. Naylor

Inventor： Floyd E. Naylor

IPC: C08F210/00 ,  C08F210/12 ,  C08F236/04 ,  C08F4/80 ,  C08F4/82

CPC classification number: C08F210/12 ,  C08F210/00 ,  C08F236/04

Abstract: The copolymerization of isoolefins with dienes is initiated by nickel source complexes with compounds of titanium or vanadium. For example, isobutylene and butadiene are copolymerized in the presence of a catalyst of bis(1,5-cyclooctadiene)nickel and titanium tetrachloride.

Abstract translation: 异烯烃与二烯的共聚是由与钛或钒化合物的镍源配合物引发的。 例如，在双（1,5-环辛二烯）镍和四氯化钛的催化剂存在下，异丁烯和丁二烯共聚。