公开(公告)号：US08519056B2

公开(公告)日：2013-08-27

申请号：US11809573

申请日：2007-06-01

Applicant: Lisa Saunders Baugh ,  Enock Berluche

Inventor： Lisa Saunders Baugh ,  Enock Berluche

IPC: C08L45/00 ,  C08L9/00 ,  C08F8/00

CPC classification number: C08F236/20 ,  C08F8/04 ,  C08L23/0823 ,  C08L23/16 ,  C08L23/26 ,  C08L2205/02 ,  C08F210/02 ,  C08L2666/06 ,  C08L2666/04

Abstract: Disclosed is the preparation of compositions which are blends of certain types of hydrogenated ethylene-dicyclopentadiene (E/DCPD) copolymers in combination with elastomeric polymers. An E/DCPD copolymer and an elastomeric polymer are co-dissolved in a common liquid reaction medium which is then subjected to hydrogenation conditions. These hydrogenation conditions serve to hydrogenate in-situ at least a portion of the residual double bonds of the E/DCPD copolymer component and possibly also eliminate any residual unsaturation which might be present in the elastomeric polymers. This combination of materials which has been hydrogenated in-situ can then be co-precipitated to form a polymer composition which can be molded into polyolefin materials of improved structural, thermal and mechanical properties with desirable impact resistance.

Abstract translation: 公开了组合物的制备，其是某些类型的氢化乙烯 - 二环戊二烯（E / DCPD）共聚物与弹性体聚合物的组合的共混物。 将E / DCPD共聚物和弹性体聚合物共溶于通常的液体反应介质中，然后将其进行氢化条件。 这些氢化条件用于原位氢化E / DCPD共聚物组分的残余双键的至少一部分，并且还可以消除可能存在于弹性体聚合物中的任何残余不饱和度。 然后可将这种原位氢化的材料的组合共沉淀形成聚合物组合物，该聚合物组合物可以模塑成具有改善的结构，热和机械性能并具有期望的耐冲击性的聚烯烃材料。

公开(公告)号：US08455598B2

公开(公告)日：2013-06-04

申请号：US13596567

申请日：2012-08-28

Applicant: Lisa Saunders Baugh ,  Enock Berluche ,  Karla Schall Colle

Inventor： Lisa Saunders Baugh ,  Enock Berluche ,  Karla Schall Colle

IPC: C08G61/08 ,  C08F8/04 ,  C08F4/80 ,  C07C255/31

CPC classification number: C08C19/02 ,  C08F4/80 ,  C08F232/00 ,  C08G61/08

Abstract: In a process for producing a functionalized polyalkenamer, at least one monomer comprising a monocyclic olefin having at least one pendant alkyl group bonded thereto, wherein the pendant alkyl group has at least two carbon atoms and is substituted with a polar moiety spaced by at least one carbon atom from the monocyclic olefin, is contacted with a polymerization catalyst under conditions effective to effect ring opening polymerization of the monocyclic olefin and produce the functionalized polyalkenamer.

公开(公告)号：US20110184105A1

公开(公告)日：2011-07-28

申请号：US12892680

申请日：2010-09-28

Applicant: Jihad Mohammed Dakka ,  Edmund John Mozeleski ,  Lisa Saunders Baugh ,  Francisco Manuel Benitez ,  Catherine Anne Faler ,  Allen David Godwin ,  Jörg Friedrich Wilhelm Weber ,  Diana S. Smirnova

Inventor： Jihad Mohammed Dakka ,  Edmund John Mozeleski ,  Lisa Saunders Baugh ,  Francisco Manuel Benitez ,  Catherine Anne Faler ,  Allen David Godwin ,  Jörg Friedrich Wilhelm Weber ,  Diana S. Smirnova

IPC: C08K5/12 ,  C07C69/73 ,  C07C67/08 ,  C09K3/00

CPC classification number: C07C69/612 ,  C07C69/76

Abstract: A process for making non-phthalate, 1,2-phenylene oxo-diester plasticizers for polymer compositions, by selectively hydrogenating naphthalene to form a partially hydrogenated naphthalene, oxygenating said partially hydrogenated naphthalene to form phenylene diacids, and esterifying said phenylene diacids with oxo-alcohols to form 1,2-phenylene oxo-diesters. Also a process for making phenylene oxo-diester plasticizers by selectively brominating xylenes to form bisbromomethylbenzene, catalytic carboalkoxylation of the bromo-compound to form phenylene diacetate, followed by transesterification to form the phenylene oxo-diester.

Abstract translation: 通过选择性氢化萘以形成部分氢化的萘来制备用于聚合物组合物的非邻苯二甲酸酯，1,2-亚苯基氧代二酯增塑剂的方法，将所述部分氢化的萘氧化以形成亚苯基二酸，并用所述亚苯基二酸酯化所述亚苯基二酸， 醇形成1,2-亚苯基氧代二酯。 也是通过选择性溴化二甲苯以形成双溴甲苯制备亚苯基二氧代二酯增塑剂的方法，溴化合物的催化羰基烷氧基化形成亚苯基二乙酸酯，然后酯交换以形成亚苯基氧代二酯。

公开(公告)号：US20110165355A1

公开(公告)日：2011-07-07

申请号：US12880586

申请日：2010-09-13

Applicant: Jihad Mohammed Dakka ,  Edmund John Mozeleski ,  Lisa Saunders Baugh ,  Jon Edmond Randolph Stanat ,  Karla Schall Colle ,  Francisco Manuel Benitez ,  Peter Stokes James ,  Allen David Godwin ,  Carl Robert Beck

Inventor： Jihad Mohammed Dakka ,  Edmund John Mozeleski ,  Lisa Saunders Baugh ,  Jon Edmond Randolph Stanat ,  Karla Schall Colle ,  Francisco Manuel Benitez ,  Peter Stokes James ,  Allen David Godwin ,  Carl Robert Beck

IPC: B32B1/08 ,  C08K5/04 ,  C08K5/10 ,  C07C55/22 ,  B32B5/02 ,  C07C51/10

CPC classification number: C07C67/38 ,  C08K5/103 ,  Y10T428/139 ,  Y10T442/20 ,  C07C69/30

Abstract: Provided are compositions, processes for making, and processes for using neoalkyl polyol esters and triglycerides as plasticizers. In one form, a neoalkylester triglyceride plasticizers can be produced by (i) drying a polyol feedstream; (ii) contacting in a reactor the dried polyol feedstream with a neoacid feedstream under effective temperature, pressure and time to form a neoalkylester plasticizer effluent stream, and (iii) purifying the neoalkylester plasticizer effluent stream to remove unreacted polyol and unreacted neoacid to form a neoalkylester plasticizer. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or pour point, glass transition temperature, low volatility, increased compatibility, increased hydrolytic stability, and excellent low temperature properties in a range of polymeric resins.

Abstract translation: 提供了组合物，制备方法和使用新烷基多元醇酯和甘油三酸酯作为增塑剂的方法。 在一种形式中，新烷基酯甘油三酯增塑剂可以通过（i）干燥多元醇进料流来制备; （ii）在有效温度，压力和时间下在干燥的多元醇原料流中与干燥的多元醇原料流接触以形成新的烷基酯增塑剂流出物流，和（iii）纯化新烷基酯增塑剂流出物流以除去未反应的多元醇和未反应的新酸，形成 新烷基酯增塑剂。 这种增塑剂可以是无邻苯二甲酸酯，并且提供突出的性能，包括合适的熔点或倾点，玻璃化转变温度，低挥发性，增加的相容性，增加的水解稳定性和在一系列聚合物树脂中的优异的低温性能。

公开(公告)号：US20110009548A1

公开(公告)日：2011-01-13

申请号：US12830606

申请日：2010-07-06

Applicant: Jihad Mohammed DAKKA ,  Edmund Joseph Mozeleski ,  Lisa Saunders Baugh ,  Allen David Godwin ,  Diana S. Smirnova

Inventor： Jihad Mohammed DAKKA ,  Edmund Joseph Mozeleski ,  Lisa Saunders Baugh ,  Allen David Godwin ,  Diana S. Smirnova

IPC: C07C69/74 ,  C08K5/12 ,  C07C67/00

CPC classification number: C07C67/08 ,  C07C5/32 ,  C07C29/147 ,  C07C45/50 ,  C07C51/16 ,  C07C67/26 ,  C07C69/28 ,  C07C69/75 ,  C07C2601/14 ,  C07C2603/68 ,  C08K5/10 ,  C07C35/08 ,  C07C47/32 ,  C07C61/08

Abstract: Oxo-diesters of cyclic olefins, methods of making them and their use as plasticizers in polymer compositions are disclosed.

Abstract translation: 公开了环烯烃的氧代二酯，其制备方法及其作为增塑剂在聚合物组合物中的用途。

公开(公告)号：US20090005279A1

公开(公告)日：2009-01-01

申请号：US11995118

申请日：2006-06-02

Applicant: Margaret May-Som Wu ,  Lisa Saunders Baugh ,  Jo Ann Canich ,  Chia Shian Chee ,  Mark Paul Hagemeister ,  Andrew Jackson ,  Peijun Jiang ,  Gordon H. Lee ,  Frederick Yip-Kwai Lo ,  Steven P. Rucker ,  Shakeel Tirmizi ,  John F. Walzer, JR. ,  Norman Yang

Inventor： Margaret May-Som Wu ,  Lisa Saunders Baugh ,  Jo Ann Canich ,  Chia Shian Chee ,  Mark Paul Hagemeister ,  Andrew Jackson ,  Peijun Jiang ,  Gordon H. Lee ,  Frederick Yip-Kwai Lo ,  Steven P. Rucker ,  Shakeel Tirmizi ,  John F. Walzer, JR. ,  Norman Yang

IPC: C10L1/20 ,  C08F114/14 ,  C08F4/42 ,  C10L1/16

CPC classification number: C07C11/02 ,  C07C2/02 ,  C07C2/34 ,  C07C5/05 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/14 ,  C08F110/14 ,  C08F210/04 ,  C08F210/14 ,  C10M107/10 ,  C10M143/08 ,  C10M2205/026 ,  C10M2205/0265 ,  C10M2205/028 ,  C10M2205/0285 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2220/024 ,  C10N2220/025 ,  C10N2220/026 ,  C10N2220/028 ,  C10N2220/033 ,  C10N2270/00 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/20 ,  C08F2500/02

Abstract: This invention relates to a polyalpha-olefin (and hydrogenated analogs thereof) comprising more than 50 mole % of one or more C5 to C24 alpha-olefin monomers where the polyalpha-olefin has: a) 40 mole % or more of mm triads, b) a Bromine number of Y or greater, where Y is equal to 89.92*(V)′°5863, where V is the Kinematic Viscosity of the polyalpha-olefin measured at 100° C. in cSt, and c) 1,2 disubstituted olefins present at 7 mole % or more, preferably having Z mole % or more of units represented by the formula: where j, k and m are each, independently, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, or 22, n is an integer from 1 to 350, and where Z=8.420*Log(V)−4.048, where V is the kinematic viscosity of the polyalpha-olefin measured at 1000 C in cSt This invention also relates to process to produce such polyalpha-olefins.

Abstract translation: 本发明涉及包含大于50摩尔％的一种或多种C 5〜C 24α-烯烃单体的聚α-烯烃（及其氢化类似物），其中聚α-烯烃具有：a）40摩尔％以上的mm三单元组，b ）Y或更大的溴数，其中Y等于89.92 *（V）'°5863，其中V是在100℃下在cSt中测量的聚α-烯烃的运动粘度，c）1,2二取代 存在7摩尔％以上的烯烃，优选具有Z摩尔％以上的由下式表示的单元：其中j，k和m各自独立地为3，4，5，6，7，8，9，10， 11，12，13，14，15，16，17，18，19，20，21或22，n为1〜350的整数，Z = 8.420 * Log（V）-4.048，其中V为 在1000℃下测量的聚α-烯烃的运动粘度在cSt中本发明还涉及生产这种聚α-烯烃的方法。

公开(公告)号：US20160038872A1

公开(公告)日：2016-02-11

申请号：US14885214

申请日：2015-10-16

Applicant: David Charles CALABRO ,  Lisa Saunders Baugh ,  Pavel Kortunov ,  Benjamin A. McCool ,  Michael Siskin ,  Dennis George Peiffer ,  Quanchang Li

Inventor： David Charles CALABRO ,  Lisa Saunders Baugh ,  Pavel Kortunov ,  Benjamin A. McCool ,  Michael Siskin ,  Dennis George Peiffer ,  Quanchang Li

IPC: B01D53/14

CPC classification number: B01D53/1493 ,  B01D53/1475 ,  B01D53/62 ,  B01D2252/20415 ,  B01D2252/20421 ,  B01D2252/20426 ,  B01D2252/20431 ,  B01D2252/20478 ,  B01D2252/2056 ,  B01D2252/30 ,  Y02A50/2342 ,  Y02C10/04 ,  Y02C10/06

Abstract: A method is described for separating CO2 and/or H2S from a mixed gas stream by contacting the gas stream with a non-aqueous, liquid absorbent medium of a primary and/or secondary aliphatic amine, preferably in a non-aqueous, polar, aprotic solvent under conditions sufficient for sorption of at least some of the CO2. The solution containing the absorbed CO2 can then be treated to desorb the acid gas. The method is usually operated as a continuous cyclic sorption-desorption process, with the sorption being carried out in a sorption zone where a circulating stream of the liquid absorbent contacts the gas stream to form a CO2-rich sorbed solution, which is then cycled to a regeneration zone for desorption of the CO2 (advantageously at 0.5:1 (approaching 1:1) may be achieved.

Abstract translation: 描述了一种从混合气流中分离CO 2和/或H 2 S的方法，其通过使气流与初级和/或仲脂族胺的非水性液体吸收介质接触，优选非水性，极性，非质子 溶剂在足以吸附至少一些CO 2的条件下进行。 然后可以处理含有吸收的CO 2的溶液以解吸酸性气体。 该方法通常作为连续循环吸附 - 脱附方法运行，吸附在吸附区中进行，其中液体吸收剂的循环流与气体流接触以形成富CO 2的吸附溶液，然后循环至 用于解吸CO 2的再生区（有利地<100℃）。 在释放CO 2时，再生的贫溶液可以再循环到吸附塔。 CO 2：（初级+仲胺）吸附摩尔比> 0.5:1（接近1：1）。

公开(公告)号：US08299281B2

公开(公告)日：2012-10-30

申请号：US12661362

申请日：2010-03-16

Applicant: Jihad Mohammed Dakka ,  Edmund J Mozeleski ,  Lisa Saunders Baugh

Inventor： Jihad Mohammed Dakka ,  Edmund J Mozeleski ,  Lisa Saunders Baugh

IPC: C09F7/02 ,  C07C51/16 ,  C07C51/235 ,  C07C67/48

CPC classification number: C08K5/0016 ,  C07C67/08 ,  C11C3/02 ,  C07C69/30

Abstract: Provided are processes for making, and processes for using triglycerides as plasticizers. Mixed triglyceride plasticizers can be produced by recovery of linear or branched C4 to C13 aldehydes from a hydroformylation product, oxidation to the acid with oxygen and/or air, recovery of the resulting acid, and esterification with a crude glycerol, wherein the total carbon number of the triester groups is from 20 to 25 for greater than or equal to 45 wt % of the plasticizer. The product selectivity obtained from esterifying with crude glycerol is comparable to that of esterifying with pure glycerol. Such plasticizers can be phthalate-free and provide outstanding properties including a suitable melting or glass transition or pour point, low volatility, increased compatibility, and excellent low temperature properties in a range of polymeric resins.

Abstract translation: 提供了制备方法和使用甘油三酯作为增塑剂的方法。 混合甘油三酯增塑剂可以通过从加氢甲酰化产物中回收线性或分支的C 4至C 13醛，用氧气和/或空气氧化成酸，回收所得酸，并用粗甘油进行酯化来制备，其中总碳数 的三聚物组合物的增塑剂的含量为大于或等于45wt％的20至25。 用粗甘油酯化获得的产物选择性与用纯甘油酯化的产物选择性相当。 这种增塑剂可以是无邻苯二甲酸酯，并提供突出的性能，包括合适的熔融或玻璃化转变或倾点，低挥发性，增加的相容性和在一系列聚合物树脂中的优异的低温性能。

公开(公告)号：US08263712B2

公开(公告)日：2012-09-11

申请号：US12231384

申请日：2008-09-02

Applicant: Lisa Saunders Baugh ,  Enock Berluche ,  Karla Schall Colle

Inventor： Lisa Saunders Baugh ,  Enock Berluche ,  Karla Schall Colle

IPC: C08F8/04 ,  C08G61/08 ,  C08F4/80 ,  C07C255/31

CPC classification number: C08C19/02 ,  C08F4/80 ,  C08F232/00 ,  C08G61/08

Abstract: In a process for producing a functionalized polyalkenamer, at least one monomer comprising a monocyclic olefin having at least one pendant alkyl group bonded thereto, wherein the pendant alkyl group has at least two carbon atoms and is substituted with a polar moiety spaced by at least one carbon atom from the monocyclic olefin, is contacted with a polymerization catalyst under conditions effective to effect ring opening polymerization of the monocyclic olefin and produce the functionalized polyalkenamer.

Abstract translation: 在制备官能化的聚链烯聚合物的方法中，至少一种包含具有至少一个与其键合的侧链烷基的单环烯烃的单体，其中所述侧基烷基具有至少两个碳原子并且被极性部分取代，所述极性部分被至少一个 来自单环烯烃的碳原子在有效地实现单环烯烃的开环聚合的条件下与聚合催化剂接触并产生官能化的聚链烷醇。

公开(公告)号：US20120071605A1

公开(公告)日：2012-03-22

申请号：US12012380

申请日：2008-02-01

Applicant: Lisa Saunders Baugh ,  Bryan R. Chapman ,  Enock Berluche

Inventor： Lisa Saunders Baugh ,  Bryan R. Chapman ,  Enock Berluche

IPC: C08L45/00 ,  C08L51/06 ,  C08L47/00

CPC classification number: C08L23/0823 ,  C08L23/16 ,  C08L53/00 ,  C08L2314/06 ,  C08L2666/24 ,  C08L2666/06

Abstract: This invention relates to a polymer composition comprising a blend comprising: (a) greater than 30 wt (based upon the weight of the composition) of a cyclic olefin polymer having a Tg greater than 60° C. and having a Tm heat of fusion (ΔHf) of 40 J/g or less selected from the group consisting of: i) copolymers comprising at least one acyclic olefin and at least 15 mole % of one or more cyclic olefins; ii) partially or completely hydrogenated copolymers comprising at least one acyclic olefin and at least 15 mole % of one or more cyclic olefins; iii) metathesis copolymers comprising two or more cyclic olefins; iv) partially or completely hydrogenated metathesis copolymers comprising two or more cyclic olefins; v) metathesis homopolymers comprising cyclic olefins; vi) partially or completely hydrogenated metathesis homopolymers comprising cyclic olefins; and vii) mixtures thereof; (b) from 1 to 50 wt % (based upon the weight of the composition) of an acyclic olefin polymer modifier having a glass transition temperature of less than 0° C.; (c) from 0.1 to 50 wt % (based upon the weight of the composition) of a non-functionalized plasticizer having a kinematic viscosity at 100° C. of 3 to 3000 cSt, a viscosity index of 120 or more, a pour point of 0° C. or less and a flash point of 200° C. or more.

Abstract translation: 本发明涉及一种包含共混物的聚合物组合物，其包含：（a）大于30重量％（基于组合物的重量）的Tg大于60℃并具有Tm熔化热的环状烯烃聚合物 40J / g或更低，选自：i）包含至少一种非环烯烃和至少15摩尔％的一种或多种环烯烃的共聚物; ii）部分或完全氢化的共聚物，其包含至少一种非环烯烃和至少15摩尔％的一种或多种环烯烃; iii）包含两个或更多个环烯烃的复分解共聚物; iv）包含两种或多种环烯烃的部分或完全氢化的复分解共聚物; v）包含环烯烃的复分解均聚物; vi）包含环状烯烃的部分或完全氢化的复分解均聚物; 和vii）其混合物; （b）1至50重量％（基于组合物的重量）的玻璃化转变温度低于0℃的无环烯烃聚合物改性剂; （c）0.1至50重量％（基于组合物的重量）的在100℃下的运动粘度为3至3000cSt，粘度指数为120或更大的非官能化增塑剂，倾点 为0℃以下，闪点为200℃以上。