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    Production of elastomeric functionalized olefin polymers
    1.
    发明申请
    Production of elastomeric functionalized olefin polymers 有权
    弹性体官能化烯烃聚合物的生产

    公开(公告)号：US20090062475A1

    公开(公告)日：2009-03-05

    申请号：US12231384

    申请日：2008-09-02

    申请人： Lisa Saunders Baugh ,  Enock Berluche ,  Karla Schall Colle

    发明人： Lisa Saunders Baugh ,  Enock Berluche ,  Karla Schall Colle

    IPC分类号： C08C19/02 ,  C08F232/00 ,  C08F22/30 ,  C08F4/42

    CPC分类号： C08C19/02 ,  C08F4/80 ,  C08F232/00 ,  C08G61/08

    摘要： In a process for producing a functionalized polyalkenamer, at least one monomer comprising a monocyclic olefin having at least one pendant alkyl group bonded thereto, wherein the pendant alkyl group has at least two carbon atoms and is substituted with a polar moiety spaced by at least one carbon atom from the monocyclic olefin, is contacted with a polymerization catalyst under conditions effective to effect ring opening polymerization of the monocyclic olefin and produce the functionalized polyalkenamer.

    摘要翻译： 在制备官能化的聚链烯聚合物的方法中，至少一种包含具有至少一个与其键合的侧链烷基的单环烯烃的单体，其中所述侧基烷基具有至少两个碳原子并且被极性部分取代，所述极性部分被至少一个 来自单环烯烃的碳原子在有效地实现单环烯烃的开环聚合的条件下与聚合催化剂接触并产生官能化的聚链烷醇。

    Linear functional copolymers of ethylene with precise and minimum run length distributions and method of making thereof
    4.
    发明申请
    Linear functional copolymers of ethylene with precise and minimum run length distributions and method of making thereof 失效
    具有精确和最小游程长度分布的乙烯的线性官能团共聚物及其制备方法

    公开(公告)号：US20050137369A1

    公开(公告)日：2005-06-23

    申请号：US10962086

    申请日：2004-10-08

    申请人： Lisa Baugh ,  Stephen Lehman ,  Kenneth Wagener ,  Donald Schulz ,  Enock Berluche

    发明人： Lisa Baugh ,  Stephen Lehman ,  Kenneth Wagener ,  Donald Schulz ,  Enock Berluche

    IPC分类号： C08F210/02 ,  C08F210/16 ,  C08F4/80

    CPC分类号： C08F210/02 ,  C08F210/16 ,  C08F4/80 ,  C08F236/20 ,  C08F2500/02 ,  C08F2500/03 ,  C08F220/10 ,  C08F218/00 ,  C08F218/08 ,  C08F232/00

    摘要： The present invention is related to a linear functional polymer having repeating units A, B and D. Unit A represents —CH2—, unit B represents and unit D represents where R1 represents a polar functional group. There are at least four A units separating each B unit, each D unit, and each B and D unit. The value y represents the total number of B units and is an integer greater than or equal to 1. The total number of D units is represented by h and is an integer greater than or equal to 0. And x represents the total number of A units and is an integer sufficient that the molar fraction of the B and D units in the linear functional polymer is represented by a value j defined by the equation: j = y + h x + y + h ≤ 0.032 . The present invention is also directed to a method for preparing such linear functional polymers by copolymerizing a first polar substituted monomer and a second non-polar unsubstituted monomer.

    摘要翻译： 本发明涉及具有重复单元A，B和D的线性官能聚合物。单元A表示-CH 2 - ，单元B表示，单元D表示其中R 1 表示极性官能团。 每个B单元，每个D单元和每个B和D单元分开至少四个A单元。 值y表示B个单位的总数，并且是大于或等于1的整数.D单位的总数由h表示，并且是大于或等于0的整数。x表示A的总数 单元，并且是足以使线性官能聚合物中B和D单元的摩尔分数由以下等式定义的值j表示的整数： < MATH OVERFLOW =“SCROLL”> j = y + h x + y + > <= 0.032

    Polymerization using late transition metal catalyst complexes formed in situ
    5.
    发明授权
    Polymerization using late transition metal catalyst complexes formed in situ 失效
    使用晚期形成的过渡金属催化剂复合物进行聚合

    公开(公告)号：US06506859B1

    公开(公告)日：2003-01-14

    申请号：US09642487

    申请日：2000-08-18

    申请人： Abhimanyu O. Patil ,  Robert T. Stibrany ,  Stephen Zushma ,  Enock Berluche ,  Donald N. Schulz

    发明人： Abhimanyu O. Patil ,  Robert T. Stibrany ,  Stephen Zushma ,  Enock Berluche ,  Donald N. Schulz

    IPC分类号： C08F442

    CPC分类号： C08F10/00 ,  C08F110/02 ,  C08F210/02 ,  C08F4/54 ,  C08F2500/03 ,  C08F220/12

    摘要： The invention is directed towards the formation of polymers and copolymers using late transition metal polymerization catalyst complexes which are formed in situ. In the first process step of the instant invention, a composition having the formula MXZn is simultaneously contacted with a ligand and an activating cocatalyst. Referring to the formula, M is selected from the group consisting of Cu, Ag, and Au; X is selected from the group consisting of halides, hydride, triflate, acetates, borates, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolates, carbon monoxide, cyanate, olefins, and any other moiety into which a monomer can insert; Z is selected from the group consisting of halides, hydride, triflate, acetates, borates, C1 through C12 alkyl, C1 through C12 alkoxy, C3 through C12 cycloalkyl, C3 through C12 cycloalkoxy, aryl, thiolates, carbon monoxide, cyanate, olefins, a neutral coordinating ligand, and any other moiety into which a monomer can insert; n equals 0, 1 or 2. In the second process step of the instant invention, olefinic monomers are contacted with the activated catalyst composition under polymerization conditions.

    摘要翻译： 本发明涉及使用在原位形成的后过渡金属聚合催化剂络合物形成聚合物和共聚物。 在本发明的第一工艺步骤中，具有式MXZn的组合物与配体和活化助催化剂同时接触。 参考式，M选自Cu，Ag和Au; X选自卤化物，氢化物，三氟甲磺酸盐，乙酸盐，硼酸盐，C1至C12烷基，C1至C12烷氧基，C3至C12环烷基，C3至C12环烷氧基，芳基，硫醇盐，一氧化碳，氰酸盐，烯烃和 单体可以插入的任何其他部分; Z选自卤化物，氢化物，三氟甲磺酸盐，乙酸盐，硼酸盐，C1至C12烷基，C1至C12烷氧基，C3至C12环烷基，C3至C12环烷氧基，芳基，硫醇盐，一氧化碳，氰酸盐，烯烃， 中性配位配体和单体可插入的任何其它部分; n等于0,1或2.在本发明的第二工艺步骤中，烯烃单体在聚合条件下与活化的催化剂组合物接触。

    Maleimide copolymers and method for inhibiting hydrate formation
    6.
    发明授权
    Maleimide copolymers and method for inhibiting hydrate formation 失效
    马来酰亚胺共聚物和抑制水合物形成的方法

    公开(公告)号：US5744665A

    公开(公告)日：1998-04-28

    申请号：US659550

    申请日：1996-06-06

    申请人： Christine Ann Costello ,  Enock Berluche ,  Russell Harlan Oelfke ,  Larry Dalton Talley

    发明人： Christine Ann Costello ,  Enock Berluche ,  Russell Harlan Oelfke ,  Larry Dalton Talley

    IPC分类号： C09K8/52 ,  C10L3/06 ,  C10L3/10 ,  F17D1/05 ,  C07C9/00

    CPC分类号： C09K8/52 ,  C10L3/06 ,  C10L3/10 ,  F17D1/05 ,  C09K2208/22 ,  Y10S585/95 ,  Y10T137/0391

    摘要： Novel maleimide copolymers have at least two monomeric units, a maleimide unit and a vinyl unit having a pendant group, the pendant group having two to twenty-one carbon atoms, at least one nitrogen atom and at least one oxygen atom. The copolymer has an average molecular weight between about 1,000 and about 6,000,000. Preferred maleimide copolymers include acrylamide/maleimide copolymers, N-vinyl amide/maleimide copolymers, vinyl lactam/maleimide copolymers, alkenyl cyclic imino ether/maleimide copolymers, and acryloylamide/maleimide copolymers. The substantially water soluble maleimide copolymers are useful for inhibiting the formation of clathrate hydrates in a fluid having hydrate-forming constituents by reducing the rate of nucleation, growth, and/or agglomeration of gas hydrate crystals in a petroleum fluid stream, thereby inhibiting the formation of a hydrate blockage in the pipe conveying the petroleum fluid stream. The inhibitor can be used conveniently at low concentrations, for example in the range of from about 0.01% to about 5% by weight of the water present in the oil or gas stream, to effectively treat a petroleum fluid having a water phase.

    摘要翻译： 新型马来酰亚胺共聚物具有至少两个单体单元，马来酰亚胺单元和具有侧基的乙烯基单元，侧基具有2至21个碳原子，至少一个氮原子和至少一个氧原子。 共聚物的平均分子量为约1,000至约6,000,000。 优选的马来酰亚胺共聚物包括丙烯酰胺/马来酰亚胺共聚物，N-乙烯基酰胺/马来酰亚胺共聚物，乙烯基内酰胺/马来酰亚胺共聚物，烯基环亚氨基醚/马来酰亚胺共聚物和丙烯酰胺/马来酰亚胺共聚物。 基本上水溶性的马来酰亚胺共聚物可用于通过降低石油流体物流中气体水合物晶体的成核，生长和/或附聚的速率来抑制在具有水合物形成成分的流体中形成笼形水合物，由此抑制形成 在输送石油流体的管道中存在水合物堵塞。 抑制剂可以以低浓度方便地使用，例如在油或气流中存在的水的约0.01重量％至约5重量％的范围内，以有效地处理具有水相的石油流体。

    Blends of co-precipitated hydrogenated ethylene-dicyclpentadiene and elastomeric polymers to provide impact modified structural polyolefins
    7.
    发明授权
    Blends of co-precipitated hydrogenated ethylene-dicyclpentadiene and elastomeric polymers to provide impact modified structural polyolefins 有权
    共沉淀的氢化乙烯 - 二环戊二烯和弹性体聚合物的共混物以提供冲击改性的结构聚烯烃

    公开(公告)号：US08519056B2

    公开(公告)日：2013-08-27

    申请号：US11809573

    申请日：2007-06-01

    申请人： Lisa Saunders Baugh ,  Enock Berluche

    发明人： Lisa Saunders Baugh ,  Enock Berluche

    IPC分类号： C08L45/00 ,  C08L9/00 ,  C08F8/00

    CPC分类号： C08F236/20 ,  C08F8/04 ,  C08L23/0823 ,  C08L23/16 ,  C08L23/26 ,  C08L2205/02 ,  C08F210/02 ,  C08L2666/06 ,  C08L2666/04

    摘要： Disclosed is the preparation of compositions which are blends of certain types of hydrogenated ethylene-dicyclopentadiene (E/DCPD) copolymers in combination with elastomeric polymers. An E/DCPD copolymer and an elastomeric polymer are co-dissolved in a common liquid reaction medium which is then subjected to hydrogenation conditions. These hydrogenation conditions serve to hydrogenate in-situ at least a portion of the residual double bonds of the E/DCPD copolymer component and possibly also eliminate any residual unsaturation which might be present in the elastomeric polymers. This combination of materials which has been hydrogenated in-situ can then be co-precipitated to form a polymer composition which can be molded into polyolefin materials of improved structural, thermal and mechanical properties with desirable impact resistance.

    摘要翻译： 公开了组合物的制备，其是某些类型的氢化乙烯 - 二环戊二烯（E / DCPD）共聚物与弹性体聚合物的组合的共混物。 将E / DCPD共聚物和弹性体聚合物共溶于通常的液体反应介质中，然后将其进行氢化条件。 这些氢化条件用于原位氢化E / DCPD共聚物组分的残余双键的至少一部分，并且还可以消除可能存在于弹性体聚合物中的任何残余不饱和度。 然后可将这种原位氢化的材料的组合共沉淀形成聚合物组合物，该聚合物组合物可以模塑成具有改善的结构，热和机械性能并具有期望的耐冲击性的聚烯烃材料。

    Transition metal polymerization catalysts, their synthesis and use in olefin polymerization
    10.
    发明授权
    Transition metal polymerization catalysts, their synthesis and use in olefin polymerization 有权
    过渡金属聚合催化剂，它们在烯烃聚合中的合成和应用

    公开(公告)号：US07351845B2

    公开(公告)日：2008-04-01

    申请号：US11333639

    申请日：2006-01-17

    申请人： Lisa S. Baugh ,  Enock Berluche ,  Paul V. Hinkle ,  Francis C. Rix

    发明人： Lisa S. Baugh ,  Enock Berluche ,  Paul V. Hinkle ,  Francis C. Rix

    IPC分类号： C07F15/00 ,  C07F9/00 ,  C07F9/02

    CPC分类号： C07F15/045 ,  C07F15/04 ,  C08F4/619 ,  C08F10/00 ,  C08F110/02 ,  C08F2500/20 ,  C08F4/7013

    摘要： A transition metal ligand complex has the following formula: wherein R1 and R2 (each occurrence) independently represent an aryl, alkyl, or cycloalkyl group having up to 20 carbon atoms; R3 and R4 (each occurrence) independently represent an aryl, alkyl, or cycloalkyl group having up to 20 carbon atoms; R5 represents an aryl, alkyl, or cycloalkyl group having up to 20 carbon atoms, provided that R4 and R5 may be joined to form a cyclic structure; R6 represents an alkyl or aryl group having up to 20 carbon atoms; and Mt represents a transition metal selected from Group 7, 8, 9, 10, 11, or 12 of the Periodic Table of the Elements.

    摘要翻译： 过渡金属配体络合物具有下式：其中R 1和R 2（每次出现）独立地表示具有至多20个碳原子的芳基，烷基或环烷基 ; R 3和R 4（每次出现）独立地表示具有至多20个碳原子的芳基，烷基或环烷基; R 5表示具有至多20个碳原子的芳基，烷基或环烷基，条件是R 4和R 5可以连接到 形成循环结构; R 6表示具有至多20个碳原子的烷基或芳基; 而Mt表示选自元素周期表第7,8,9,10,11或12族的过渡金属。