公开(公告)号：US20090005279A1

公开(公告)日：2009-01-01

申请号：US11995118

申请日：2006-06-02

Applicant: Margaret May-Som Wu ,  Lisa Saunders Baugh ,  Jo Ann Canich ,  Chia Shian Chee ,  Mark Paul Hagemeister ,  Andrew Jackson ,  Peijun Jiang ,  Gordon H. Lee ,  Frederick Yip-Kwai Lo ,  Steven P. Rucker ,  Shakeel Tirmizi ,  John F. Walzer, JR. ,  Norman Yang

Inventor： Margaret May-Som Wu ,  Lisa Saunders Baugh ,  Jo Ann Canich ,  Chia Shian Chee ,  Mark Paul Hagemeister ,  Andrew Jackson ,  Peijun Jiang ,  Gordon H. Lee ,  Frederick Yip-Kwai Lo ,  Steven P. Rucker ,  Shakeel Tirmizi ,  John F. Walzer, JR. ,  Norman Yang

IPC: C10L1/20 ,  C08F114/14 ,  C08F4/42 ,  C10L1/16

CPC classification number: C07C11/02 ,  C07C2/02 ,  C07C2/34 ,  C07C5/05 ,  C08F4/65908 ,  C08F4/65912 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/14 ,  C08F110/14 ,  C08F210/04 ,  C08F210/14 ,  C10M107/10 ,  C10M143/08 ,  C10M2205/026 ,  C10M2205/0265 ,  C10M2205/028 ,  C10M2205/0285 ,  C10N2220/021 ,  C10N2220/022 ,  C10N2220/023 ,  C10N2220/024 ,  C10N2220/025 ,  C10N2220/026 ,  C10N2220/028 ,  C10N2220/033 ,  C10N2270/00 ,  C08F2500/03 ,  C08F2500/17 ,  C08F2500/20 ,  C08F2500/02

Abstract: This invention relates to a polyalpha-olefin (and hydrogenated analogs thereof) comprising more than 50 mole % of one or more C5 to C24 alpha-olefin monomers where the polyalpha-olefin has: a) 40 mole % or more of mm triads, b) a Bromine number of Y or greater, where Y is equal to 89.92*(V)′°5863, where V is the Kinematic Viscosity of the polyalpha-olefin measured at 100° C. in cSt, and c) 1,2 disubstituted olefins present at 7 mole % or more, preferably having Z mole % or more of units represented by the formula: where j, k and m are each, independently, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 20, 21, or 22, n is an integer from 1 to 350, and where Z=8.420*Log(V)−4.048, where V is the kinematic viscosity of the polyalpha-olefin measured at 1000 C in cSt This invention also relates to process to produce such polyalpha-olefins.

Abstract translation: 本发明涉及包含大于50摩尔％的一种或多种C 5〜C 24α-烯烃单体的聚α-烯烃（及其氢化类似物），其中聚α-烯烃具有：a）40摩尔％以上的mm三单元组，b ）Y或更大的溴数，其中Y等于89.92 *（V）'°5863，其中V是在100℃下在cSt中测量的聚α-烯烃的运动粘度，c）1,2二取代 存在7摩尔％以上的烯烃，优选具有Z摩尔％以上的由下式表示的单元：其中j，k和m各自独立地为3，4，5，6，7，8，9，10， 11，12，13，14，15，16，17，18，19，20，21或22，n为1〜350的整数，Z = 8.420 * Log（V）-4.048，其中V为 在1000℃下测量的聚α-烯烃的运动粘度在cSt中本发明还涉及生产这种聚α-烯烃的方法。

公开(公告)号：US20080076855A1

公开(公告)日：2008-03-27

申请号：US11897135

申请日：2007-08-29

Applicant: Lothar Reif ,  Christian Lente

Inventor： Lothar Reif ,  Christian Lente

IPC: C08F114/14

CPC classification number: C08F2/22 ,  C08F36/18 ,  C09J111/02

Abstract: The novel process provides latices of homo- and copolymers of chloroprene and of one or more further copolymerizable monomers at a higher reaction rate and hence in an improved space-time yield. The latices obtained have a high gel content, distinctly lower levels of by-products, in particular of chloroprene dimer, than prior art products, and are useful, if appropriate in concentrated form, for a wide variety of applications.

Abstract translation: 该新方法提供氯丁二烯和一种或多种其它可共聚单体的均聚物和共聚物的胶乳，反应速率更高，因此提高了时空产率。 获得的胶乳具有高凝胶含量，明显低于现有技术产品的副产物，特别是氯丁二烯二聚物的水平，并且如果适合，以浓缩形式用于各种应用中是有用的。

公开(公告)号：US20030114620A1

公开(公告)日：2003-06-19

申请号：US10287914

申请日：2002-11-05

Inventor： Kirkwood Storer Cottman

IPC: C08F114/14 ,  C08F114/16

CPC classification number: C08F210/14 ,  C08F240/00

Abstract: This invention is based upon the unexpected discovery that the reactivity of the most important monomers commonly used in synthesizing tackifier resins with aluminum halide catalysts can be enhanced by conducting the polymerization in the presence of an allylic halide. For instance, the conversions of 2-methyl-2-butene, cis-piperylene, and cyclopentene that are attained in polymerizations that are catalyzed with aluminum halide catalysts are increased by conducting the polymerization in the presence of an allylic halide, such as allyl chloride. Increased monomer conversion is of great commercial importance because it leads to an increased level of efficiency and reactor capacity. The present invention more specifically discloses a process for synthesizing a resin having characteristics that make it particularly useful as a tackifier resin, said process comprising the polymerization of an unsaturated hydrocarbon monomer mixture in the presence of aluminum halide and an allylic halide, wherein the unsaturated hydrocarbon monomer mixture is comprised of unsaturated hyrdocarbon monomers containing from about 4 to about 18 carbon atoms. The subject invention further reveals a process for synthesizing a resin having characteristics that make it particularly useful as a tackifier resin, said process comprising the polymerization of an unsaturated hydrocarbon monomer mixture in the presence of aluminum halide and an allylic halide, wherein the unsaturated hydrocarbon monomer mixture is comprised of monomers including but not limited to 2-methyl-2-butene, cis-piperylene, trans-piperylene, cyclopentene, and additional unsaturated hyrdocarbon monomers containing from about 4 to about 18 carbon atoms.

公开(公告)号：US4125697A

公开(公告)日：1978-11-14

申请号：US838294

申请日：1977-09-30

Applicant: Hans-Jurgen Pettelkau ,  Bodo Ehrig ,  Karl Nothen ,  Dietrich Rosahl

Inventor： Hans-Jurgen Pettelkau ,  Bodo Ehrig ,  Karl Nothen ,  Dietrich Rosahl

IPC: B01J19/00 ,  B01J19/18 ,  C08F2/00 ,  C08F36/18 ,  C08F2/22 ,  C08F114/14

CPC classification number: B01J19/002 ,  B01J19/18 ,  C08F36/18 ,  B01J2219/00063 ,  B01J2219/00094 ,  B01J2219/00171 ,  B01J2219/185

Abstract: Object of the invention is a process for polymerizing chloroprene in aqueous emulsion in a certain apparatus which prevents formation of deposits and so-called "popcorn" polymers.

Abstract translation: 本发明的目的是在某种防止沉积物形成和所谓的“爆米花”（polycorn）“聚合物的装置中聚合氯丁二烯在水乳液中的方法。

公开(公告)号：US4069391A

公开(公告)日：1978-01-17

申请号：US757239

申请日：1977-01-06

Applicant: David H. Blount

Inventor： David H. Blount

IPC: C01B33/00 ,  C08F8/42 ,  C08F14/14 ,  C08F14/16 ,  C08F14/02 ,  C08F30/08 ,  C08F114/14

CPC classification number: C08F14/16 ,  C01B33/00 ,  C08F14/14 ,  C08F8/42

Abstract: Allyl halides are polymerized by a catalyst, silicic or silicoformic acids, to produce poly(allyl halide) polymer and poly(allyl alcohol) polymer.

Abstract translation: 烯丙基卤化物通过催化剂，硅酸或硅酸聚合，生成聚（烯丙基卤）聚合物和聚（烯丙醇）聚合物。

公开(公告)号：US3240690A

公开(公告)日：1966-03-15

申请号：US85666659

申请日：1959-12-02

Applicant: DOW CORNING

Inventor： MURCH ROBERT M

IPC: C08F114/14

CPC classification number: C08F114/14

公开(公告)号：US09221948B2

公开(公告)日：2015-12-29

申请号：US14486224

申请日：2014-09-15

Applicant: CHEMTURA CORPORATION

Inventor： Larry D. Timberlake ,  Mark V. Hanson ,  Narayan Subramaniam ,  William R. Fielding ,  Matthew S. Burge

IPC: C08K5/5397 ,  C08G65/48 ,  C08F114/14 ,  C08L77/06 ,  C08K5/5313 ,  C08K7/14 ,  C08L77/00

CPC classification number: C08G65/48 ,  C08F114/14 ,  C08K5/53 ,  C08K5/5313 ,  C08K5/5397 ,  C08K7/14 ,  C08L77/00 ,  C08L77/06 ,  C08L2201/02

Abstract: A flame-retardant resin composition comprises a base resin (A), such as a polyamide resin, and an aromatic organophosphorus oligomer or polymer.

Abstract translation: 阻燃性树脂组合物包含聚酰胺树脂等基础树脂（A）和芳族有机磷低聚物或聚合物。

公开(公告)号：US20100249351A1

公开(公告)日：2010-09-30

申请号：US12795035

申请日：2010-06-07

Applicant: Lothar Reif ,  Stephen Pask

Inventor： Lothar Reif ,  Stephen Pask

IPC: C08F114/14 ,  C08G18/00 ,  C08F118/02 ,  C08F236/06 ,  C08F136/06 ,  C08F36/02 ,  B29C45/00 ,  B29C47/00 ,  B29C67/24

CPC classification number: C08C19/08 ,  B60C1/00 ,  C08F8/50

Abstract: A novel process is used to prepare synthetic rubbers (B) which feature very narrow molecular weight distribution and a correspondingly low value for the polydispersity index. The preparation process encompasses the treatment of a synthetic rubber with ultrasound, where the resultant synthetic rubber (B) has a lower weight-average molecular weight (Mw) than the synthetic rubber (A) used. The resultant synthetic rubbers (B) have excellent suitability for processing via extruder processes or injection-moulding processes.

公开(公告)号：US20030199636A1

公开(公告)日：2003-10-23

申请号：US10458506

申请日：2003-06-10

Inventor： Kirkwood Storer Cottman

IPC: C08F114/14

CPC classification number: C08F240/00 ,  C08F210/14

Abstract: This invention is based upon the unexpected discovery that the reactivity of the most important monomers commonly used in synthesizing tackifier resins with aluminum halide catalysts can be enhanced by conducting the polymerization in the presence of an allylic halide. For instance, the conversions of 2-methyl-2-butene, cis-piperylene, and cyclopentene that are attained in polymerizations that are catalyzed with aluminum halide catalysts are increased by conducting the polymerization in the presence of an allylic halide, such as allyl chloride. Increased monomer conversion is of great commercial importance because it leads to an increased level of efficiency and reactor capacity. The present invention more specifically discloses a process for synthesizing a resin having characteristics that make it particularly useful as a tackifier resin, said process comprising the polymerization of an unsaturated hydrocarbon monomer mixture in the presence of aluminum halide and an allylic halide, wherein the unsaturated hydrocarbon monomer mixture is comprised of unsaturated hyrdocarbon monomers containing from about 4 to about 18 carbon atoms, and wherein said process is conducted in the absence of tantalum compounds. The subject invention further reveals a process for synthesizing a resin having characteristics that make it particularly useful as a tackifier resin, said process comprising the polymerization of an unsaturated hydrocarbon monomer mixture in the presence of aluminum halide and an allylic halide, wherein the unsaturated hydrocarbon monomer mixture is comprised of monomers including but not limited to 2-methyl-2-butene, cis-piperylene, trans-piperylene, cyclopentene, and additional unsaturated hyrdocarbon monomers containing from about 4 to about 18 carbon atoms, wherein said process is conducted in the absence of tantalum compounds.

Abstract translation: 本发明基于意想不到的发现，通过在烯丙基卤化物存在下进行聚合可以提高通常用于合成增粘树脂与卤化铝催化剂的最重要的单体的反应性。 例如，在用卤化铝催化剂催化的聚合中获得的2-甲基-2-丁烯，顺 - 戊间二烯和环戊烯的转化率通过在烯丙基卤化物如烯丙基氯的存在下进行聚合而增加 。 增加的单体转化率具有很大的商业重要性，因为它导致提高的效率和反应器容量水平。 本发明更具体地公开了一种具有使其特别用作增粘树脂的特性的树脂的方法，所述方法包括在卤化铝和烯丙基卤的存在下聚合不饱和烃单体混合物，其中不饱和烃 单体混合物由含有约4至约18个碳原子的不饱和羧基碳单体组成，并且其中所述方法在不存在钽化合物的情况下进行。 本发明还揭示了一种具有使其特别用作增粘树脂的特性的树脂的方法，所述方法包括在卤化铝和烯丙基卤化物存在下聚合不饱和烃单体混合物，其中不饱和烃单体 混合物由包括但不限于2-甲基-2-丁烯，顺式 - 戊间二烯，反式 - 戊间二烯，环戊烯和含有约4至约18个碳原子的其它不饱和羧基碳单体组成的单体组成，其中所述方法在 没有钽化合物。

公开(公告)号：US3481914A

公开(公告)日：1969-12-02

申请号：US3481914D

申请日：1965-05-14

Applicant: SHELL OIL CO

Inventor： HOLLER HOWARD V ,  YOUNGMAN EDWARD A

IPC: C08F114/14 ,  C08F297/06 ,  C08F15/02 ,  C08F3/02

CPC classification number: C08F297/06 ,  C08F114/14