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公开(公告)号：US20240117083A1
公开(公告)日：2024-04-11
申请号：US18274281
申请日：2022-03-24
Applicant: DENKA COMPANY LIMITED
Inventor： Seiya TOMIZAWA , Wataru NISHINO , Misaki TADA
CPC classification number: C08F36/18 , C08C4/00 , C08F2/22 , C08L11/02 , C08L2312/00
Abstract: A chloroprene-based polymer, wherein: a 1H-NMR spectrum of the chloroprene-based polymer measured in a deuterochloroform solvent has a peak at 5.80 to 6.00 ppm; when an area of the peak at 5.80 to 6.00 ppm is A and an area of a peak at 4.05 to 6.00 ppm is B, A/B is 1.20/100 or less; the 1H-NMR spectrum of the chloroprene-based polymer measured in a deuterochloroform solvent has a peak at 5.40 to 5.60 ppm; when an area of the peak at 5.40 to 5.60 ppm is D and the area of the peak at 4.05 to 6.00 ppm is B, D/B is 97.20/100 or less, is provided.
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2.发明公开公开(公告)号：US20230416509A1
公开(公告)日：2023-12-28
申请号：US18251300
申请日：2021-09-17
Applicant: Denka Company Limited
Inventor： Misaki ITO , Masao ONOZUKA , Masahiro KATO
Abstract: A method for manufacturing a chloroprene polymer composition, the method including: a polymerization step of polymerizing chloroprene in the presence of at least one rosin acid component selected from the group consisting of a rosin acid and a rosin acid salt to obtain a chloroprene polymer composition containing a chloroprene polymer, in which in the rosin acid component, a mass ratio B1/A1 of a total amount B1 of abietic acid, neoabietic acid, palustric acid, levopimaric acid, and salts thereof with respect to a total amount A1 of dehydroabietic acid, pimaric acid, isopimaric acid, dihydroabietic acid, and salts thereof is 0.10 to 3.00, and a toluene insoluble content of the chloroprene polymer is 50% by mass or more.
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公开(公告)号：US09938363B2
公开(公告)日：2018-04-10
申请号：US14112589
申请日：2012-04-19
Applicant: Thomas-Oliver Neuner , Heiner Stange , Rolf Josten , Rolf Feller , Mesut Fidan
Inventor： Thomas-Oliver Neuner , Heiner Stange , Rolf Josten , Rolf Feller , Mesut Fidan
IPC: C08F136/18 , C08C1/15 , C08F36/18
CPC classification number: C08F136/18 , C08C1/15 , C08F36/18 , C08F2/22
Abstract: The invention relates to methods for isolating and obtaining polychloroprene solids, wherein an aqueous polychloroprene dispersion is brought in contact with steam containing coagulant, whereby the polychloroprene solid coagulates.
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4.发明授权Polychloroprene latex composition, process for production of same, and products of forming thereof 有权聚氯丁二烯胶乳组合物，其生产方法及其成型产品公开(公告)号：US08436102B2
公开(公告)日：2013-05-07
申请号：US13379580
申请日：2010-07-06
Applicant: Ikuka Hashimoto , Misaki Tada , Kosuke Watanabe
Inventor： Ikuka Hashimoto , Misaki Tada , Kosuke Watanabe
IPC: C08F236/18
Abstract: Provided are a polychloroprene latex composition giving immersion-molded articles superior in releasability from the mold during immersion molding and also superior in flexibility, a production method thereof and a molded article prepared by using the same.A polychloroprene latex composition containing an alkyldiphenyletherdisulfonic acid alkali-metal salt in an amount of 0.01 to 1.0 part by mass with respect to 100 parts by mass of a polychloroprene latex is prepared by emulsion polymerization of the monomer in the presence of a rosin acid alkali-metal salt and an alkyldiphenyletherdisulfonic acid alkali-metal salt each in an amount of 3 parts or less by mass with respect to 100 parts by mass of the monomer.
Abstract translation: 提供一种聚氯丁二烯胶乳组合物，其提供浸渍模制品中浸渍模塑制品，其浸渍模制过程中脱模性优于模具，并且还具有优异的柔韧性，其制备方法和通过使用该模塑制品制备的模塑制品。 相对于100质量份的聚氯丁二烯胶乳，含有0.01〜1.0质量份烷基二苯醚二磺酸碱金属盐的聚氯丁二烯胶乳组合物是通过在松香酸碱金属盐存在下， 金属盐和烷基二苯醚二磺酸碱金属盐的量相对于100质量份的单体为3份以下。
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公开(公告)号：US07776992B2
公开(公告)日：2010-08-17
申请号：US10556720
申请日：2004-05-12
Applicant: Kosuke Watanabe , Motohiro Ose
Inventor： Kosuke Watanabe , Motohiro Ose
IPC: C08L11/02 , C08F2/30 , C09D111/02 , C09J111/02
CPC classification number: C08F36/18 , C08F2/30 , C08L11/02 , C08L29/04 , C08L71/02 , C08L2666/04 , C08L2666/14 , C09D111/02 , C09J111/02
Abstract: A polychloroprene latex composition which has a low viscosity and which can be made to have a high solid content, obtained by emulsion polymerization of chloroprene alone or chloroprene and a monomer copolymerizable with chloroprene in the presence of a polyvinyl alcohol and a nonionic emulsifier, such as polyoxyethylene alkyl ether.
Abstract translation: 聚氯丁二烯胶乳组合物，其具有低粘度，并且可以制备为具有高固体含量，通过单独氯丁二烯的乳液聚合或氯丁二烯和在聚乙烯醇和非离子乳化剂存在下可与氯丁二烯共聚的单体获得，例如 聚氧乙烯烷基醚。
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Patent Agency Ranking
公开(公告)号：US20100076149A1
公开(公告)日：2010-03-25
申请号：US12624780
申请日：2009-11-24
Applicant: Kosuke Watanabe , Motohiro Ose
Inventor： Kosuke Watanabe , Motohiro Ose
CPC classification number: C08F36/18 , C08F2/30 , C08L11/02 , C08L29/04 , C08L71/02 , C08L2666/04 , C08L2666/14 , C09D111/02 , C09J111/02
Abstract: A nonionic polychloroprene latex composition employing a polyvinyl alcohol as an emulsifier/dispersant has favorable chemical and mechanical stability but has a high viscosity, and therefore it has such drawbacks that its coating method is limited, and it is hardly made to have a high solid content.A polychloroprene latex composition which has a low viscosity and which can be made to have a high solid content, can be obtained by emulsion polymerization of chloroprene alone or chloroprene and a monomer copolymerizable with chloroprene in the presence of a polyvinyl alcohol and a nonionic emulsifier.
Abstract translation: 使用聚乙烯醇作为乳化剂/分散剂的非离子型聚氯丁二烯胶乳组合物具有良好的化学和机械稳定性，但具有高粘度，因此具有限制其涂布方法的缺陷，并且几乎不具有高的固含量 。 通过在聚乙烯醇和非离子乳化剂存在下，单独使用氯丁二烯或氯丁二烯和可与氯丁二烯共聚的单体进行乳液聚合，可获得具有低粘度且可制成具有高固含量的聚氯丁二烯胶乳组合物。
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公开(公告)号：US07169937B2
公开(公告)日：2007-01-30
申请号：US10662902
申请日：2003-09-15
Applicant: Dirk Achten , Michael Klimpel , Emilie Barriau , Lothar Reif , Renke Mottweiler , Heinrich Berg , Zsolt Szentivanyi , Stefan Glander
Inventor： Dirk Achten , Michael Klimpel , Emilie Barriau , Lothar Reif , Renke Mottweiler , Heinrich Berg , Zsolt Szentivanyi , Stefan Glander
IPC: C07D207/30
CPC classification number: C07D207/325 , C07C333/24 , C07D231/12 , C07D233/54 , C07D233/56 , C07D249/08 , C08F2/38 , C08F36/18
Abstract: The present invention relates to dithiocarbamic esters, their preparation and their use for regulating the degree of polymerization during the polymerization of monomers, such as during the polymerization of chloroprene to give polychloroprene, and during the polymerization of 2,3-dichlorobutadiene to give poly-2,3-dichlorobutadiene, and during the copolymerization of chloroprene with 2,3-dichlorobutadiene. The present invention further relates to polymers which are obtainable via the polymerization of monomers in the presence of the dithiocarbamic esters of the invention. The present invention also relates to polymers which contain end groups derived from the dithiocarbamic esters of the present invention.
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公开(公告)号：US07073201B2
公开(公告)日：2006-07-11
申请号：US10108434
申请日：2002-03-29
Applicant: Kiyoshi Sunada , Kunio Kaneda , Mikio Yamaguchi
Inventor： Kiyoshi Sunada , Kunio Kaneda , Mikio Yamaguchi
IPC: B63C11/04 , C09J115/02
CPC classification number: C08J3/241 , A41D31/0016 , B32B7/12 , C08F36/18 , C08J2311/00 , C08L11/02 , C09J5/00 , C09J111/02 , C09J2411/00 , Y10T428/249985 , C08F2/26
Abstract: A two part aqueous adhesive comprising a main agent containing a polychloroprene latex as a main component and a curing agent, the main agent and the curing agent being separated during storing or transporting.
Abstract translation: 包含含有聚氯丁二烯胶乳作为主要成分的主剂和固化剂的两部分水性粘合剂，主剂和固化剂在储存或运输期间被分离。
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公开(公告)号：US6034173A
公开(公告)日：2000-03-07
申请号：US605931
申请日：1996-02-23
Applicant: Nathalie Peresleni Rivet
Inventor： Nathalie Peresleni Rivet
CPC classification number: C08F36/18
Abstract: The present invention relates to the preparation of (co)polychloroprene latex in water emulsion, in the presence of an emulsifying system which comprises a first step (A) wherein a fraction f.sub.1 of monomers is used together with an emulsifying system which comprises a non-carboxylic ionic emulsifying agent (Ea1), a non-ionic emulsifying agent with a low HLB (Eb1) and a non-ionic emulsifying agent with a high HLB (Eb2), and a second step (B) wherein the reaction medium of step (A) is fed with the remaining fraction f.sub.2 of (co)monomers and the remaining emulsifying system.
Abstract translation: 本发明涉及制备（共）聚氯丁二烯胶乳在水乳液中，在乳化体系的存在下，其包括第一步（A），其中单体的一部分f1与乳化体系一起使用， 羧酸离子乳化剂（Ea1），具有低HLB（Eb1）的非离子乳化剂和具有高HLB（Eb2）的非离子乳化剂和第二步（B）），其中步骤 A）与（共）单体的剩余部分f2和剩余的乳化体系一起进料。
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公开(公告)号：US5767214A
公开(公告)日：1998-06-16
申请号：US893989
申请日：1997-07-16
Applicant: Nathalie Peresleni Rivet , Fran.cedilla.ois Sauterey
Inventor： Nathalie Peresleni Rivet , Fran.cedilla.ois Sauterey
IPC: C08F2/22 , C08F2/32 , C08F36/18 , C08F136/18 , C08F236/18 , C08L11/00
CPC classification number: C08F36/18
Abstract: Process for preparing (co)polychloroprene rubber, comprising: a first step (a) in which a portion of a polymerizable composition is partially polymerized according to a batchwise process, a second step (b) in which the residual polymerizable composition is sequentially fed to the reaction mixture coming from the step (a), a possible third step (c) in which the reaction mixture coming from the step (b) is polymerized up to the desired conversion rate.
Abstract translation: 制备（共）聚氯丁二烯橡胶的方法，包括：第一步骤（a），其中一部分可聚合组合物根据间歇方法部分聚合;第二步（b），其中将残留的可聚合组合物顺序加入到 来自步骤（a）的反应混合物，其中来自步骤（b）的反应混合物的第三步骤（c）聚合至所需的转化率。
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