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1.发明授权公开(公告)号：US08389435B2
公开(公告)日：2013-03-05
申请号：US12295454
申请日：2007-03-30
申请人： Masahide Miura , Nobuyuki Takagi , Shinichi Matsumoto , Toshitaka Tanabe , Yasutaka Nagai , Kazuhiko Dohmae , Yasuo Ikeda
发明人： Masahide Miura , Nobuyuki Takagi , Shinichi Matsumoto , Toshitaka Tanabe , Yasutaka Nagai , Kazuhiko Dohmae , Yasuo Ikeda
IPC分类号： B01J23/00 , B01J23/10 , B01J23/42 , B01J23/44 , B01J23/08 , B01J8/02 , B01J8/00 , B01D53/56 , B01D53/86 , B01D53/94 , C01B21/00 , C01B23/00 , C01B25/00 , C01B31/00 , C01B33/00 , C01B35/00 , C01G28/00 , C01G30/00 , B32B5/16 , B32B9/00 , B32B15/02 , B32B17/02 , B32B19/00 , B32B21/02 , B32B23/02 , B32B27/02
CPC分类号： B01J37/0221 , B01D53/945 , B01D2255/206 , B01J23/63 , B01J35/008 , B01J35/026 , B01J35/10 , B01J35/1014 , B01J37/0234 , Y02T10/22 , Y10T428/2991
摘要： A metal oxide catalyst carrier particle has a center portion and an outer skin portion each containing a first metal oxide and a second metal oxide. The center portion and the outer skin portion are different in composition. The mole fraction of the metal of the first metal oxide is higher in the center portion than in the outer skin portion and the mole fraction of the metal of the second metal oxide is higher in the outer skin portion than in the center portion. The second metal oxide is selected from the group consisting of rare earth oxides, except for ceria, and alkali earth metal oxides. In addition, platinum is supported on the metal oxide catalyst carrier particle, thus forming an exhaust gas purification catalyst.
摘要翻译： 金属氧化物催化剂载体颗粒具有分别含有第一金属氧化物和第二金属氧化物的中心部分和外皮部分。 中心部分和外皮部分的组成不同。 第一金属氧化物的金属的摩尔分数在中心部分高于外皮部分，并且第二金属氧化物的金属的摩尔分数在外皮部分中比在中心部分高。 第二金属氧化物选自除二氧化铈以外的稀土氧化物和碱土金属氧化物。 此外，铂负载在金属氧化物催化剂载体颗粒上，从而形成废气净化催化剂。
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公开(公告)号：US5911960A
公开(公告)日：1999-06-15
申请号：US544260
申请日：1995-10-17
申请人： Naoto Miyoshi , Shinichi Matsumoto , Tsuneyuki Tanizawa , Satoshi Iguchi , Toshiaki Tanaka , Shinichi Takeshima , Takaaki Kanazawa , Takahiro Hayashi , Motohisa Saiki , Kazuhiko Dohmae , Kiyoshi Yamazaki , Tadashi Suzuki , Koichi Kasahara , Syuji Tateishi
发明人： Naoto Miyoshi , Shinichi Matsumoto , Tsuneyuki Tanizawa , Satoshi Iguchi , Toshiaki Tanaka , Shinichi Takeshima , Takaaki Kanazawa , Takahiro Hayashi , Motohisa Saiki , Kazuhiko Dohmae , Kiyoshi Yamazaki , Tadashi Suzuki , Koichi Kasahara , Syuji Tateishi
IPC分类号： B01D53/94 , B01J23/58 , B01J23/63 , B01J23/652 , B01J23/656 , B01J23/89 , B01J37/02 , B01D53/60
CPC分类号： B01D53/945 , B01D53/9422 , B01J23/58 , B01J23/63 , B01J23/6522 , B01J23/6562 , B01J23/894 , B01J37/0242 , B01D2255/1021 , B01D2255/1023 , B01D2255/202 , B01D2255/204 , B01D2255/2042 , B01D2255/2063 , B01D2255/2065 , B01D2255/2073 , B01D2255/20738 , B01D2255/20746 , B01D2255/20753 , B01D2255/91 , Y02T10/22
摘要： A catalyst for purifying exhaust gases includes a porous support, at least one catalyst ingredient selected from Pt and Pd, and additional ingredients including (1) at least two rare-earth elements including La, (2) at least one rare-earth element including La and at least one transition element selected from Fe, Ni, Co and Mn, (3) at least two alkali metals, (4) at least one alkali metal and at least one rare-earth element including La, (5) at least one alkali metal and at least one transition element selected from Fe, Ni, Co and Mn, (6) at least two alkaline-earth metals, (7) at least one alkaline-earth metal and at least one rare-earth element including La, or (8) Ba, Li, La, Ce and Zr. A process for purifying an exhaust gas, by contacting the catalyst with an exhaust gas, is also provided.
摘要翻译： 用于净化废气的催化剂包括多孔载体，至少一种选自Pt和Pd的催化剂成分，以及另外的成分，包括（1）至少两种稀土元素，包括La，（2）至少一种稀土元素，包括 La和至少一种选自Fe，Ni，Co和Mn的过渡元素，（3）至少两种碱金属，（4）至少一种碱金属和至少一种包含La的稀土元素，（5）至少 一种碱金属和至少一种选自Fe，Ni，Co和Mn的过渡元素，（6）至少两种碱土金属，（7）至少一种碱土金属和至少一种包含La的稀土元素 ，或（8）Ba，Li，La，Ce和Zr。 还提供了一种通过使催化剂与废气接触来净化废气的方法。
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3.发明授权Catalyst for purification of exhaust gas, regeneration method for the catalyst, and apparatus and method for purification of exhaust gas using the catalyst 失效用于净化废气的催化剂，催化剂的再生方法，以及使用该催化剂净化废气的装置和方法公开(公告)号：US08105561B2
公开(公告)日：2012-01-31
申请号：US12225692
申请日：2006-12-01
申请人： Miho Hatanaka , Toshitaka Tanabe , Yasutaka Nagai , Toshio Yamamoto , Kazuhiko Dohmae , Nobuyuki Takagi , Masahide Miura , Yasuo Ikeda
发明人： Miho Hatanaka , Toshitaka Tanabe , Yasutaka Nagai , Toshio Yamamoto , Kazuhiko Dohmae , Nobuyuki Takagi , Masahide Miura , Yasuo Ikeda
CPC分类号： B01D53/945 , B01D2255/102 , B01J23/002 , B01J23/63 , B01J23/894 , B01J23/8946 , B01J23/96 , B01J35/006 , B01J35/0066 , B01J35/1014 , B01J37/0201 , B01J37/0205 , B01J37/0207 , B01J37/03 , B01J38/10 , B01J38/12 , B01J2523/00 , F01N3/2006 , F01N11/002 , F01N2550/02 , Y02T10/22 , Y02T10/47 , B01J2523/3706 , B01J2523/48 , B01J2523/3712 , B01J2523/3718 , B01J2523/36
摘要： A catalyst for purification of exhaust gas in which a noble metal is supported on a metal-oxide support wherein, in a oxidation atmosphere, the noble metal exists on the surface of the support in high oxidation state, and the noble metal binds with a cation of the support via an oxygen atom on the surface of the support to form a surface oxide layer and, in a reduction atmosphere, the noble metal exists on the surface of the support in a metal state, and an amount of noble metal exposed at the surface of the support, measured by CO chemisorption, is 10% or more in atomic ratio to a whole amount of the noble metal supported on the support.
摘要翻译： 一种用于净化废气的催化剂，其中贵金属负载在金属氧化物载体上，其中在氧化气氛中贵金属以高氧化态存在于载体的表面上，贵金属与阳离子结合 的载体上的氧原子形成表面氧化物层，并且在还原气氛中，贵金属以金属状态存在于载体的表面上，并且贵金属的量在 通过CO化学吸附测定的载体表面与支撑在载体上的贵金属的全部量的原子比为10％以上。
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公开(公告)号：US20090104088A1
公开(公告)日：2009-04-23
申请号：US12295369
申请日：2007-03-29
申请人： Nobuyuki Takagi , Masahide Miura , Shinichi Matsumoto , Toshitaka Tanabe , Yasutaka Nagai , Miho Hatanaka , Kazuhiko Dohmae , Toshio Yamamoto , Yasuo Ikeda
发明人： Nobuyuki Takagi , Masahide Miura , Shinichi Matsumoto , Toshitaka Tanabe , Yasutaka Nagai , Miho Hatanaka , Kazuhiko Dohmae , Toshio Yamamoto , Yasuo Ikeda
CPC分类号： F01N3/0814 , F01N3/0842 , F01N3/0864 , F01N3/0885 , F01N3/101 , F01N3/22 , F01N13/009 , F01N2270/00 , F01N2370/00 , F01N2560/022 , F01N2560/026 , F01N2570/16 , Y02T10/22
摘要： An exhaust gas purification system includes: a catalyst (3) provided in an exhaust gas passage of an internal combustion engine (1) and having a carrier containing a basic oxide and platinum carried on the carrier; a catalyst (4) for purifying NOx; and oxygen supply means (2).
摘要翻译： 排气净化系统包括：设置在内燃机（1）的排气通道中并具有承载在载体上的基本氧化物和铂的载体的催化剂（3） 用于净化NOx的催化剂（4） 和供氧装置（2）。
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5.发明授权公开(公告)号：US08601794B2
公开(公告)日：2013-12-10
申请号：US12599079
申请日：2008-05-09
申请人： Masanori Yamato , Takeru Yoshida , Nobuyuki Takagi , Toshitaka Tanabe , Yasutaka Nagai , Kazuhiko Dohmae , Naoki Takahashi
发明人： Masanori Yamato , Takeru Yoshida , Nobuyuki Takagi , Toshitaka Tanabe , Yasutaka Nagai , Kazuhiko Dohmae , Naoki Takahashi
CPC分类号： B01J38/10 , B01D53/9445 , B01D2255/1021 , B01D2255/206 , B01J23/42 , B01J23/63 , B01J23/96 , B01J38/12 , F01N3/2013 , F01N3/206 , F01N3/22 , F01N2240/16 , F01N2240/28 , F01N2610/04 , Y02A50/2324 , Y02T10/22 , Y02T10/26
摘要： A regeneration apparatus comprises a heater 2 which heats a catalyst 1 at the time of stopping fuel supply to an engine, a pump 4 which supplies an oxidizing gas or a reducing gas to the heated catalyst 1 and a switching valve 3. In the oxidizing step, catalytic poisons, for example hydrocarbon, which are absorbed on a noble metal are oxidized and removed. The particles of the noble metal become oxidized particles as pure oxide and the like. After the oxidizing step, the reducing step is carried out. In the reducing step, particles of the noble metal are reduced and re-dispersed on the support simultaneously and as a result, the particles of the noble metal become fine. Thus, a deteriorated catalyst can be regenerated without interrupting the use of catalyst and also without deteriorating the drivability.
摘要翻译： 再生装置包括加热器2，其在停止对发动机的燃料供给时加热催化剂1，向加热的催化剂1供给氧化气体或还原气体的泵4和切换阀3.在氧化步骤 吸附在贵金属上的催化毒物（例如烃）被氧化和去除。 贵金属的粒子成为纯氧化物等的氧化粒子。 在氧化步骤之后，进行还原步骤。 在还原步骤中，贵金属的颗粒同时还原并再分散在载体上，结果，贵金属的颗粒变细。 因此，可以在不中断催化剂的使用的情况下再生劣化的催化剂，并且也不会降低驱动性。
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6.发明申请公开(公告)号：US20100293921A1
公开(公告)日：2010-11-25
申请号：US12599079
申请日：2008-05-09
申请人： Masanori Yamato , Takeru Yoshida , Nobuyuki Takagi , Toshitaka Tanabe , Yasutaka Nagai , Kazuhiko Dohmae , Naoki Takahashi
发明人： Masanori Yamato , Takeru Yoshida , Nobuyuki Takagi , Toshitaka Tanabe , Yasutaka Nagai , Kazuhiko Dohmae , Naoki Takahashi
CPC分类号： B01J38/10 , B01D53/9445 , B01D2255/1021 , B01D2255/206 , B01J23/42 , B01J23/63 , B01J23/96 , B01J38/12 , F01N3/2013 , F01N3/206 , F01N3/22 , F01N2240/16 , F01N2240/28 , F01N2610/04 , Y02A50/2324 , Y02T10/22 , Y02T10/26
摘要： A regeneration apparatus comprises a heater 2 which heats a catalyst 1 at the time of stopping fuel supply to an engine, a pump 4 which supplies an oxidizing gas or a reducing gas to the heated catalyst 1 and a switching valve 3. In the oxidizing step, catalytic poisons, for example hydrocarbon, which are absorbed on a noble metal are oxidized and removed. The particles of the noble metal become oxidized particles as pure oxide and the like. After the oxidizing step, the reducing step is carried out. In the reducing step, particles of the noble metal are reduced and re-dispersed on the support simultaneously and as a result, the particles of the noble metal become fine. Thus, a deteriorated catalyst can be regenerated without interrupting the use of catalyst and also without deteriorating the drivability.
摘要翻译： 再生装置包括加热器2，其在停止对发动机的燃料供给时加热催化剂1，向加热的催化剂1供给氧化气体或还原气体的泵4和切换阀3.在氧化步骤 吸附在贵金属上的催化毒物（例如烃）被氧化和去除。 贵金属的粒子成为纯氧化物等的氧化粒子。 在氧化步骤之后，进行还原步骤。 在还原步骤中，贵金属的颗粒同时还原并再分散在载体上，结果，贵金属的颗粒变细。 因此，可以在不中断催化剂的使用的情况下再生劣化的催化剂，并且也不会降低驱动性。
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7.发明申请公开(公告)号：US20100004117A1
公开(公告)日：2010-01-07
申请号：US12295454
申请日：2007-03-30
申请人： Masahide Miura , Nobuyuki Takagi , Shinichi Matsumoto , Toshitaka Tanabe , Yasutaka Nagai , Kazuhiko Dohmae , Yasuo Ikeda
发明人： Masahide Miura , Nobuyuki Takagi , Shinichi Matsumoto , Toshitaka Tanabe , Yasutaka Nagai , Kazuhiko Dohmae , Yasuo Ikeda
CPC分类号： B01J37/0221 , B01D53/945 , B01D2255/206 , B01J23/63 , B01J35/008 , B01J35/026 , B01J35/10 , B01J35/1014 , B01J37/0234 , Y02T10/22 , Y10T428/2991
摘要： A metal oxide catalyst carrier particle has a center portion and an outer skin portion each containing a first metal oxide and a second metal oxide. The center portion and the outer skin portion are different in composition. The mole fraction of the metal of the first metal oxide is higher in the center portion than in the outer skin portion and the mole fraction of the metal of the second metal oxide is higher in the outer skin portion than in the center portion. The second metal oxide is selected from the group consisting of rare earth oxides, except for ceria, and alkali earth metal oxides. In addition, platinum is supported on the metal oxide catalyst carrier particle, thus forming an exhaust gas purification catalyst.
摘要翻译： 金属氧化物催化剂载体颗粒具有分别含有第一金属氧化物和第二金属氧化物的中心部分和外皮部分。 中心部分和外皮部分的组成不同。 第一金属氧化物的金属的摩尔分数在中心部分高于外皮部分，并且第二金属氧化物的金属的摩尔分数在外皮部分比在中心部分高。 第二金属氧化物选自除二氧化铈以外的稀土氧化物和碱土金属氧化物。 此外，铂负载在金属氧化物催化剂载体颗粒上，从而形成废气净化催化剂。
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公开(公告)号：US08225601B2
公开(公告)日：2012-07-24
申请号：US12295369
申请日：2007-03-29
申请人： Nobuyuki Takagi , Masahide Miura , Shinichi Matsumoto , Toshitaka Tanabe , Yasutaka Nagai , Miho Hatanaka , Kazuhiko Dohmae , Toshio Yamamoto , Yasuo Ikeda
发明人： Nobuyuki Takagi , Masahide Miura , Shinichi Matsumoto , Toshitaka Tanabe , Yasutaka Nagai , Miho Hatanaka , Kazuhiko Dohmae , Toshio Yamamoto , Yasuo Ikeda
IPC分类号： F01N3/00
CPC分类号： F01N3/0814 , F01N3/0842 , F01N3/0864 , F01N3/0885 , F01N3/101 , F01N3/22 , F01N13/009 , F01N2270/00 , F01N2370/00 , F01N2560/022 , F01N2560/026 , F01N2570/16 , Y02T10/22
摘要： An exhaust gas purification system includes: a catalyst (3) provided in an exhaust gas passage of an internal combustion engine (1) and having a carrier containing a basic oxide and platinum carried on the carrier; a catalyst (4) for purifying NOx; and oxygen supply means (2).
摘要翻译： 排气净化系统包括：设置在内燃机（1）的排气通道中并具有承载在载体上的基本氧化物和铂的载体的催化剂（3） 用于净化NOx的催化剂（4） 和供氧装置（2）。
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公开(公告)号：US20090266053A1
公开(公告)日：2009-10-29
申请号：US12295393
申请日：2007-03-29
申请人： Nobuyuki Takagi , Masahide Miura , Shinichi Matsumoto , Toshitaka Tanabe , Yasutaka Nagai , Miho Hatanaka , Kazuhiko Dohmae , Toshio Yamamoto , Yasuo Ikeda
发明人： Nobuyuki Takagi , Masahide Miura , Shinichi Matsumoto , Toshitaka Tanabe , Yasutaka Nagai , Miho Hatanaka , Kazuhiko Dohmae , Toshio Yamamoto , Yasuo Ikeda
CPC分类号： F01N3/22 , F01N3/0878 , F01N11/002 , F01N13/011 , Y02T10/20 , Y02T10/47
摘要： An exhaust gas purification system includes: at least two catalysts (1a, 1b) disposed in parallel with each other on an exhaust gas passage of an internal combustion engine (3) and having a carrier containing a basic oxide and platinum carried on the carrier; and oxygen supply means (2) for supplying oxygen to the catalysts (1a, 1b).
摘要翻译： 排气净化系统包括：至少两个催化剂（1a，1b），其在内燃机（3）的排气通道上彼此平行设置，并且具有载体上载有碱性氧化物和铂的载体; 以及用于向催化剂（1a，1b）供给氧的供氧装置（2）。
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10.发明申请Catalyst for Purification of Exhaust Gas, Regeneration Method for the Catalyst, and Apparatus and Method for Purification of Exhaust Gas Using the Catalyst 失效用于净化废气的催化剂，催化剂的再生方法以及使用催化剂净化废气的装置和方法公开(公告)号：US20090170689A1
公开(公告)日：2009-07-02
申请号：US12225692
申请日：2006-12-01
申请人： Miho Hatanaka , Toshitaka Tanabe , Yasutaka Nagai , Toshio Yamamoto , Kazuhiko Dohmae , Nobuyuki Takagi , Masahide Miura , Yasuo Ikeda
发明人： Miho Hatanaka , Toshitaka Tanabe , Yasutaka Nagai , Toshio Yamamoto , Kazuhiko Dohmae , Nobuyuki Takagi , Masahide Miura , Yasuo Ikeda
CPC分类号： B01D53/945 , B01D2255/102 , B01J23/002 , B01J23/63 , B01J23/894 , B01J23/8946 , B01J23/96 , B01J35/006 , B01J35/0066 , B01J35/1014 , B01J37/0201 , B01J37/0205 , B01J37/0207 , B01J37/03 , B01J38/10 , B01J38/12 , B01J2523/00 , F01N3/2006 , F01N11/002 , F01N2550/02 , Y02T10/22 , Y02T10/47 , B01J2523/3706 , B01J2523/48 , B01J2523/3712 , B01J2523/3718 , B01J2523/36
摘要： A catalyst for purification of exhaust gas in which a noble metal is supported on a metal-oxide support wherein, in a oxidation atmosphere, the noble metal exists on the surface of the support in high oxidation state, and the noble metal binds with a cation of the support via an oxygen atom on the surface of the support to form a surface oxide layer and, in a reduction atmosphere, the noble metal exists on the surface of the support in a metal state, and an amount of noble metal exposed at the surface of the support, measured by CO chemisorption, is 10% or more in atomic ratio to a whole amount of the noble metal supported on the support.
摘要翻译： 一种用于净化废气的催化剂，其中贵金属负载在金属氧化物载体上，其中在氧化气氛中贵金属以高氧化态存在于载体的表面上，贵金属与阳离子结合 的载体上的氧原子形成表面氧化物层，并且在还原气氛中，贵金属以金属状态存在于载体的表面上，并且贵金属的量在 通过CO化学吸附测定的载体表面与支撑在载体上的贵金属的全部量的原子比为10％以上。
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