公开(公告)号：US07931731B2

公开(公告)日：2011-04-26

申请号：US12544800

申请日：2009-08-20

申请人： Gijsbert Jan Van Heeringen ,  Ewout Martijn Van Jarwaarde ,  Hendrik Jan Van Der Ploeg ,  Cornelis Jacobus Smit

发明人： Gijsbert Jan Van Heeringen ,  Ewout Martijn Van Jarwaarde ,  Hendrik Jan Van Der Ploeg ,  Cornelis Jacobus Smit

IPC分类号： C21B3/00 ,  B01D53/74

CPC分类号： C21B13/0073 ,  B01D53/229 ,  B01D53/75 ,  B01D53/77 ,  B01D2255/20707 ,  B01D2256/16 ,  B01D2257/304 ,  B01D2257/308 ,  B01D2257/408 ,  B01D2257/502 ,  B01D2257/504 ,  C01B3/36 ,  C01B2203/025 ,  C01B2203/04 ,  C01B2203/0405 ,  C01B2203/0415 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/0485 ,  C01B2203/049 ,  C01B2203/0877 ,  C01B2203/0883 ,  C01B2203/0894 ,  C01B2203/1211 ,  C01B2203/1252 ,  C01B2203/147 ,  C01B2203/86 ,  C10J2300/0916 ,  C10J2300/0936 ,  C10J2300/0943 ,  C10J2300/0959 ,  C10J2300/0969 ,  C10J2300/0973 ,  C10J2300/1678 ,  C10K1/08 ,  C21B2100/282 ,  C21B2100/42 ,  C21B2100/64 ,  Y02C10/10 ,  Y02P10/122 ,  Y02P10/128 ,  Y02P10/136 ,  Y02P20/152 ,  Y02P30/30

摘要： A process to prepare elemental iron by contacting an iron ore feed with a reducing gas at a pressure of between 1 and 10 bar to obtain iron and an off-gas includes preparing the reducing gas by performing the following steps: (a) partially oxidizing a mixture comprising a solid or liquid carbonaceous fuel and oxygen at a pressure of between 10 and 80 bar, thereby obtaining a gas comprising H2 and CO; (b) removing CO2 and H2S from the gas obtained in step (a) to obtain an intermediate gas comprising H2 and CO; (c) supplying the intermediate gas obtained in step (b) to a H2-selective membrane to obtain a H2-rich permeate gas and a CO-rich retentate; and (d) heating H2-rich permeate to obtain a heated H2-rich permeate as the reducing gas.

摘要翻译： 通过使铁矿石原料与1〜10巴压力的还原气体接触来制备元素铁，得到铁和废气的方法包括通过以下步骤制备还原气体：（a）将 混合物包含固体或液体含碳燃料和压力为10至80巴的氧气，从而获得包含H 2和CO的气体; （b）从步骤（a）获得的气体中除去CO 2和H 2 S，得到包含H 2和CO的中间气体; （c）将步骤（b）中获得的中间气体供应到H 2选择性膜，以获得富H2的渗透气体和富CO的滞留物; 和（d）加热富H2的渗透物，以获得加热的富H 2的渗透物作为还原气体。

公开(公告)号：US20100031572A1

公开(公告)日：2010-02-11

申请号：US11794515

申请日：2005-12-29

申请人： Joachim Ansorge ,  Scott Bilton ,  Hendrik Jan Van Der Ploeg ,  Arold Marcel Albert Routier ,  Cornelis Jacobus Smit

发明人： Joachim Ansorge ,  Scott Bilton ,  Hendrik Jan Van Der Ploeg ,  Arold Marcel Albert Routier ,  Cornelis Jacobus Smit

IPC分类号： C10J3/46 ,  C10L1/00 ,  C10G47/00 ,  C07C27/06

CPC分类号： C10G1/002 ,  C01B3/16 ,  C01B3/22 ,  C01B3/52 ,  C01B2203/0415 ,  C01B2203/0475 ,  C01B2203/0485 ,  C01B2203/062 ,  C10G2/30 ,  C10G2/32 ,  C10J3/00 ,  C10J2300/093 ,  C10J2300/1618 ,  C10J2300/1659 ,  C10J2300/1823 ,  C10K3/04 ,  C10K3/06

摘要： A method of increasing the hydrogen/carbon monoxide (H2/CO) ratio in a syngas stream derived from a carbonaceous fuel including coal, brown coal, peat, and heavy residual oil fractions, preferably coal. The fuel-derived syngas stream is divided into at least two sub-streams, one of which undergoes a catalytic water shift conversion reaction. The so-obtained converted sub-stream is combined with the non-converted sub-stream(s) to form a second syngas stream with an increased H2/CO ratio. The method of the present invention can provide a syngas with a H2/CO ratio more suitable for efficient hydrocarbon synthesis carried out on a given catalyst, such as in one or more Fischer-Tropsch reactors, as well as being able to accommodate variation in the H2/CO ratio of syngas formed from different qualities of feedstock fuels.

摘要翻译： 一种提高衍生自包括煤，褐煤，泥煤和重残余油馏分，优选煤的含碳燃料的合成气流中的氢/一氧化碳（H 2 / CO）比的方法。 燃料衍生的合成气流被分成至少两个子流，其中之一经历催化水位转换反应。 如此获得的转化子流与未转化的子流合并形成具有增加的H 2 / CO比的第二合成气流。 本发明的方法可以提供具有更适合于在给定催化剂（例如在一个或多个费 - 托反应器中）进行的有效烃合成的H 2 / CO比率的合成气，并且能够适应 不同质量的原料燃料形成的合成气的H2 / CO比。

公开(公告)号：US20090100864A1

公开(公告)日：2009-04-23

申请号：US12167698

申请日：2008-07-03

申请人： Paul Anton DEN HELD ,  Hendrik Jan Van Der Ploeg

发明人： Paul Anton DEN HELD ,  Hendrik Jan Van Der Ploeg

IPC分类号： F25J3/00 ,  F25J3/04

CPC分类号： F25J3/04969 ,  F25J3/04018 ,  F25J3/04024 ,  F25J3/04121 ,  F25J3/04133 ,  F25J3/04303 ,  F25J3/04412 ,  F25J3/04678

摘要： The invention is directed to a process and a system to compress air. The process involves the following steps, (i) compressing air in a compressor, (ii) cooling the compressed air as obtained in step (i) (iii) further compressing the air of step (ii) in a second compressor, (iv) further compressing at least part of the compressed air as obtained in step (iii) in a booster compressor, wherein the compressor in step (i) is an axial compressor, the compressor of step (i) and (iii) are driven by a common first driver and the booster compressor is driven by a separate second driver and wherein the compressors of steps (i) and (iii) are split into two individual casings.

摘要翻译： 本发明涉及一种压缩空气的方法和系统。 该方法包括以下步骤：（i）压缩压缩机中的空气，（ii）冷却步骤（i）（iii）中获得的压缩空气，以进一步压缩第二压缩机中步骤（ii）的空气，（iv） 在步骤（iii）中获得的至少部分压缩空气进一步压缩在增压压缩机中，其中步骤（i）中的压缩机是轴向压缩机，步骤（i）和（iii）的压缩机由公共 第一驱动器和增压压缩机由单独的第二驱动器驱动，并且其中步骤（i）和（iii）的压缩机被分成两个单独的壳体。

公开(公告)号：US20080182912A1

公开(公告)日：2008-07-31

申请号：US11933989

申请日：2007-11-01

申请人： Robert Erwin Van Den Berg ,  Franciscus Gerardus Van Dongen ,  Thomas Paul Von Kossak-Glowczewski ,  Hendrik Jan Van Der Ploeg ,  Pieter Lammert Zuideveld

发明人： Robert Erwin Van Den Berg ,  Franciscus Gerardus Van Dongen ,  Thomas Paul Von Kossak-Glowczewski ,  Hendrik Jan Van Der Ploeg ,  Pieter Lammert Zuideveld

IPC分类号： C07C27/00

CPC分类号： C10G2/332 ,  C10G2/32 ,  C10G2300/1022 ,  C10G2300/202 ,  C10G2300/805 ,  C10J3/485 ,  C10J3/845 ,  C10J2200/09 ,  C10J2200/152 ,  C10J2300/0903 ,  C10J2300/093 ,  C10J2300/0943 ,  C10J2300/0959 ,  C10J2300/1659 ,  C10J2300/1678 ,  C10J2300/1823 ,  C10J2300/1846 ,  C10K1/002 ,  C10K1/004 ,  C10K1/005 ,  C10K1/006 ,  C10K1/007 ,  C10K1/04 ,  C10K1/08 ,  C10K1/101 ,  C10K1/143 ,  C10K1/16 ,  C10K1/165 ,  C10K3/04 ,  F02C3/28 ,  F05D2220/722 ,  Y02E20/18

摘要： A process to prepare a paraffinic hydrocarbon from a solid carbonaceous feedstock, preferably coal by performing the following steps, (a) feeding an oxygen comprising gas and the carbonaceous feedstock to a burner positioned horizontal and firing into a reactor vessel, (b) performing a partial oxidation of the carbonaceous feedstock in said burner to obtain a stream of hot synthesis gas which flows upwardly relative to the burner and a liquid slag which flows downwardly relative to the burner, (c) cooling the hot synthesis gas by first cooling the gas to a temperature of between 500 and 900° C. by injecting a gaseous or liquid cooling medium into the synthesis gas and subsequently second cooling the gas in to below 500° C. by directly contacting with water, (d) separating solids from the cooled synthesis gas by means of a water scrubbing process step, (e) performing a water shift reaction on at least part of the scrubbed synthesis gas, (f) separating sulphur compounds, carbon dioxide and other possible impurities from the shifted gas to obtain a purified synthesis gas, and (g) performing a Fischer-Tropsch synthesis using the purified synthesis gas of step (f) to obtain a synthesis product comprising paraffinic hydrocarbons.

摘要翻译： （a）通过进行以下步骤从固体碳质原料，优选煤制备链烷烃，（a）将包含气体和含碳原料的氧气供给到水平放置并燃烧到反应器容器中的燃烧器，（b） 在所述燃烧器中部分氧化碳质原料以获得相对于燃烧器向上流动的热合成气流和相对于燃烧器向下流动的液态炉渣，（c）通过首先将气体冷却至 通过将气体或液体冷却介质注入合成气中并随后通过与水直接接触将气体再次冷却至低于500℃，（d）从冷却的合成物中分离固体，从而将温度介于500和900℃之间 （e）在洗涤的合成气的至少一部分上进行水转化反应，（f）分离硫化合物，二氧化碳 和来自转移气体的其它可能的杂质以获得纯化的合成气，和（g）使用步骤（f）的纯化合成气进行费 - 托合成，以获得包含链烷烃的合成产物。

公开(公告)号：US20120167620A1

公开(公告)日：2012-07-05

申请号：US13320298

申请日：2010-04-12

申请人： Eva Marfilia Van Dorst ,  Gerard De Nazelle ,  Hendrik Jan Van Der Ploeg ,  Rick Van Der Vaart ,  Evert Wesker

发明人： Eva Marfilia Van Dorst ,  Gerard De Nazelle ,  Hendrik Jan Van Der Ploeg ,  Rick Van Der Vaart ,  Evert Wesker

IPC分类号： F25J3/08

CPC分类号： B01D53/002 ,  B01D2257/504 ,  C10K1/00 ,  F23J15/02 ,  F23J2215/50 ,  F23J2900/15061 ,  F25J3/0625 ,  F25J3/0655 ,  F25J3/067 ,  F25J2210/06 ,  F25J2210/70 ,  F25J2230/30 ,  F25J2235/80 ,  F25J2240/80 ,  F25J2260/80 ,  F25J2270/04 ,  F25J2270/12 ,  F25J2270/60 ,  Y02C10/12 ,  Y02E20/326 ,  Y02P20/152

摘要： The present invention provides a method and system for separating CO2 from a gas stream containing CO2. A gas stream having an initial pressure is compressed and subsequently cooled. The compressed and cooled gas stream has an increased pressure and reduced temperature at which the CO2 in the gas stream is at least partially converted to the liquid phase. The liquid phase is separated from the compressed and cooled gas stream, to provide a liquid phase stream and a gas phase stream, wherein the output pressure of the liquid phase stream is higher than the initial pressure of the gas stream.

摘要翻译： 本发明提供了一种从含CO 2的气流中分离CO 2的方法和系统。 具有初始压力的气流被压缩并随后冷却。 压缩和冷却的气流具有增加的压力和降低的气体流中的CO 2至少部分地转化为液相的温度。 将液相与压缩和冷却的气流分离，以提供液相物流和气相物流，其中液相物流的输出压力高于气流的初始压力。

公开(公告)号：US08641790B2

公开(公告)日：2014-02-04

申请号：US11794515

申请日：2005-12-29

申请人： Joachim Ansorge ,  Scott Bilton ,  Hendrik Jan Van Der Ploeg ,  Arold Marcel Albert Routier ,  Cornelis Jacobus Smit

发明人： Joachim Ansorge ,  Scott Bilton ,  Hendrik Jan Van Der Ploeg ,  Arold Marcel Albert Routier ,  Cornelis Jacobus Smit

IPC分类号： C01B3/24

CPC分类号： C10G1/002 ,  C01B3/16 ,  C01B3/22 ,  C01B3/52 ,  C01B2203/0415 ,  C01B2203/0475 ,  C01B2203/0485 ,  C01B2203/062 ,  C10G2/30 ,  C10G2/32 ,  C10J3/00 ,  C10J2300/093 ,  C10J2300/1618 ,  C10J2300/1659 ,  C10J2300/1823 ,  C10K3/04 ,  C10K3/06

摘要： A method of increasing the hydrogen/carbon monoxide (H2/CO) ratio in a syngas stream derived from a carbonaceous fuel including coal, brown coal, peat, and heavy residual oil fractions, preferably coal. The fuel-derived syngas stream is divided into at least two sub-streams, one of which undergoes a catalytic water shift conversion reaction. The so-obtained converted sub-stream is combined with the non-converted sub-stream(s) to form a second syngas stream with an increased H2/CO ratio. The method of the present invention can provide a syngas with a H2/CO ratio more suitable for efficient hydrocarbon synthesis carried out on a given catalyst, such as in one or more Fischer-Tropsch reactors, as well as being able to accommodate variation in the H2/CO ratio of syngas formed from different qualities of feedstock fuels.

摘要翻译： 一种提高衍生自包括煤，褐煤，泥煤和重残余油馏分，优选煤的含碳燃料的合成气流中的氢/一氧化碳（H 2 / CO）比的方法。 燃料衍生的合成气流被分成至少两个子流，其中之一经历催化水位转换反应。 如此获得的转化子流与未转化的子流合并形成具有增加的H 2 / CO比的第二合成气流。 本发明的方法可以提供具有更适合于在给定催化剂（例如在一个或多个费 - 托反应器中）进行的有效烃合成的H 2 / CO比率的合成气，并且能够适应 不同质量的原料燃料形成的合成气的H2 / CO比。

公开(公告)号：US07741377B2

公开(公告)日：2010-06-22

申请号：US11933989

申请日：2007-11-01

申请人： Robert Erwin Van Den Berg ,  Franciscus Gerardus Van Dongen ,  Thomas Paul Von Kossak-Glowczewski ,  Hendrik Jan Van Der Ploeg ,  Pieter Lammert Zuideveld

发明人： Robert Erwin Van Den Berg ,  Franciscus Gerardus Van Dongen ,  Thomas Paul Von Kossak-Glowczewski ,  Hendrik Jan Van Der Ploeg ,  Pieter Lammert Zuideveld

IPC分类号： C07C27/00 ,  C01B3/32 ,  C10G47/00

CPC分类号： C10G2/332 ,  C10G2/32 ,  C10G2300/1022 ,  C10G2300/202 ,  C10G2300/805 ,  C10J3/485 ,  C10J3/845 ,  C10J2200/09 ,  C10J2200/152 ,  C10J2300/0903 ,  C10J2300/093 ,  C10J2300/0943 ,  C10J2300/0959 ,  C10J2300/1659 ,  C10J2300/1678 ,  C10J2300/1823 ,  C10J2300/1846 ,  C10K1/002 ,  C10K1/004 ,  C10K1/005 ,  C10K1/006 ,  C10K1/007 ,  C10K1/04 ,  C10K1/08 ,  C10K1/101 ,  C10K1/143 ,  C10K1/16 ,  C10K1/165 ,  C10K3/04 ,  F02C3/28 ,  F05D2220/722 ,  Y02E20/18

摘要： A process to prepare a paraffinic hydrocarbon from a solid carbonaceous feedstock, preferably coal by performing the following steps,(a) feeding an oxygen comprising gas and the carbonaceous feedstock to a burner positioned horizontal and firing into a reactor vessel,(b) performing a partial oxidation of the carbonaceous feedstock in said burner to obtain a stream of hot synthesis gas which flows upwardly relative to the burner and a liquid slag which flows downwardly relative to the burner,(c) cooling the hot synthesis gas by first cooling the gas to a temperature of between 500 and 900° C. by injecting a gaseous or liquid cooling medium into the synthesis gas and subsequently second cooling the gas in to below 500° C. by directly contacting with water, (d) separating solids from the cooled synthesis gas by means of a water scrubbing process step, (e) performing a water shift reaction on at least part of the scrubbed synthesis gas, (f) separating sulphur compounds, carbon dioxide and other possible impurities from the shifted gas to obtain a purified synthesis gas, and (g) performing a Fischer-Tropsch synthesis using the purified synthesis gas of step (f) to obtain a synthesis product comprising paraffinic hydrocarbons.

摘要翻译： （a）通过进行以下步骤从固体碳质原料，优选煤制备链烷烃，（a）将包含气体和含碳原料的氧气供给到水平放置并燃烧到反应器容器中的燃烧器，（b） 在所述燃烧器中部分氧化碳质原料以获得相对于燃烧器向上流动的热合成气流和相对于燃烧器向下流动的液态炉渣，（c）通过首先将气体冷却至 通过将气体或液体冷却介质注入合成气中并随后通过与水直接接触将气体再次冷却至低于500℃，（d）从冷却的合成物中分离固体，从而将温度介于500和900℃之间 （e）在洗涤的合成气的至少一部分上进行水转化反应，（f）分离硫化合物，二氧化碳 和来自转移气体的其它可能的杂质以获得纯化的合成气，和（g）使用步骤（f）的纯化合成气进行费 - 托合成，以获得包含链烷烃的合成产物。

公开(公告)号：US20090133535A1

公开(公告)日：2009-05-28

申请号：US12275041

申请日：2008-11-20

申请人： Gijsbert Jan VAN HEERINGEN ,  Hendrik Jan VAN DER PLOEG ,  Cornelis Jacobus SMIT

发明人： Gijsbert Jan VAN HEERINGEN ,  Hendrik Jan VAN DER PLOEG ,  Cornelis Jacobus SMIT

IPC分类号： C22B9/05

CPC分类号： C01B3/54 ,  C01B3/52 ,  C01B2203/0415 ,  C01B2203/0465 ,  C01B2203/0475 ,  C01B2203/0485 ,  C01B2203/0495 ,  C01B2203/86 ,  C10J3/00 ,  C10J2300/0959 ,  C10J2300/0969 ,  C10K1/34 ,  C21B13/0073 ,  C21B2100/282 ,  C21B2100/42 ,  C21B2100/62 ,  C21C2100/06 ,  Y02P10/122 ,  Y02P10/126 ,  Y02P10/132 ,  Y02P10/136 ,  Y02P10/212 ,  Y02P30/30

摘要： The invention is directed to a process to prepare elemental iron by contacting an iron ore feed with a reducing gas to obtain iron and an off-gas. The reducing gas is prepared by performing the following steps(a) partially oxidizing a mixture comprising a sulphur containing solid carbonaceous fuel and gaseous CO2 as carrier medium with oxygen, by supplying an oxygen containing gas and the solid carbonaceous fuel to a burner, thereby obtaining a gas comprising H2, CO, CO2 and H2S; (b) removing CO2 and H2S from the gas obtained in step (a) to obtain the reducing gas comprising H2 and CO and a first stream comprising CO2 and H2S; (c) reducing the content of H2S in the first stream comprising CO2 and H2S obtained in step (b) in a liquid redox type process and (d) recycling at least part of the CO2 obtained in step (c) to step (a).

摘要翻译： 本发明涉及一种通过使铁矿石进料与还原气体接触以制备铁质和废气来制备元素铁的方法。 通过以下步骤（a）通过向燃烧器供应含氧气体和固体碳质燃料，将包含含硫固体碳质燃料和气态CO 2的混合物作为载体介质与氧气进行部分氧化来制备还原气体，从而获得 包括H 2，CO，CO 2和H 2 S的气体; （b）从步骤（a）中获得的气体中除去CO 2和H 2 S，得到包含H 2和CO的还原气体和包含CO 2和H 2 S的第一流; （c）在液体氧化还原型方法中降低包含步骤（b）中获得的CO 2和H 2 S的第一流中的H 2 S含量，和（d）将步骤（c）中获得的至少部分CO 2再循环到步骤（a） 。

公开(公告)号：US20100050812A1

公开(公告)日：2010-03-04

申请号：US12544800

申请日：2009-08-20

申请人： Gijsbert Jan Van Heeringen ,  Ewout Martijn Van Jarwaarde ,  Hendrik Jan Van Der Ploeg ,  Cornelis Jacobus Smit

发明人： Gijsbert Jan Van Heeringen ,  Ewout Martijn Van Jarwaarde ,  Hendrik Jan Van Der Ploeg ,  Cornelis Jacobus Smit

IPC分类号： C21B3/02 ,  C21B15/00

CPC分类号： C21B13/0073 ,  B01D53/229 ,  B01D53/75 ,  B01D53/77 ,  B01D2255/20707 ,  B01D2256/16 ,  B01D2257/304 ,  B01D2257/308 ,  B01D2257/408 ,  B01D2257/502 ,  B01D2257/504 ,  C01B3/36 ,  C01B2203/025 ,  C01B2203/04 ,  C01B2203/0405 ,  C01B2203/0415 ,  C01B2203/047 ,  C01B2203/0475 ,  C01B2203/0485 ,  C01B2203/049 ,  C01B2203/0877 ,  C01B2203/0883 ,  C01B2203/0894 ,  C01B2203/1211 ,  C01B2203/1252 ,  C01B2203/147 ,  C01B2203/86 ,  C10J2300/0916 ,  C10J2300/0936 ,  C10J2300/0943 ,  C10J2300/0959 ,  C10J2300/0969 ,  C10J2300/0973 ,  C10J2300/1678 ,  C10K1/08 ,  C21B2100/282 ,  C21B2100/42 ,  C21B2100/64 ,  Y02C10/10 ,  Y02P10/122 ,  Y02P10/128 ,  Y02P10/136 ,  Y02P20/152 ,  Y02P30/30

摘要： A process to prepare elemental iron by contacting an iron ore feed with a reducing gas at a pressure of between 1 and 10 bar to obtain iron and an off-gas includes preparing the reducing gas by performing the following steps: (a) partially oxidizing a mixture comprising a solid or liquid carbonaceous fuel and oxygen at a pressure of between 10 and 80 bar, thereby obtaining a gas comprising H2 and CO; (b) removing CO2 and H2S from the gas obtained in step (a) to obtain an intermediate gas comprising H2 and CO; (c) supplying the intermediate gas obtained in step (b) to a H2-selective membrane to obtain a H2-rich permeate gas and a CO-rich retentate; and (d) heating H2-rich permeate to obtain a heated H2-rich permeate as the reducing gas.

摘要翻译： 通过使铁矿石原料与1〜10巴压力的还原气体接触来制备元素铁，得到铁和废气的方法包括通过以下步骤制备还原气体：（a）将 混合物包含固体或液体含碳燃料和压力为10至80巴的氧气，从而获得包含H 2和CO的气体; （b）从步骤（a）获得的气体中除去CO 2和H 2 S，得到包含H 2和CO的中间气体; （c）将步骤（b）中获得的中间气体供应到H 2选择性膜，以获得富H2的渗透气体和富CO的滞留物; 和（d）加热富H2的渗透物，以获得加热的富H 2的渗透物作为还原气体。