摘要:
A synthesis gas production apparatus (reformer) to be used for a synthesis gas production step in a GTL (gas-to-liquid) process is prevented from being contaminated by metal components. A method of suppressing metal contamination of a synthesis gas production apparatus operating for a GTL process that includes a synthesis gas production step of producing synthesis gas by causing natural gas and gas containing steam and/or carbon dioxide to react with each other for reforming in a synthesis gas production apparatus in which, at the time of separating and collecting a carbon dioxide contained in the synthesis gas produced in the synthesis gas production step and recycling the separated and collected carbon dioxide as source gas for the reforming reaction in the synthesis gas production step, a nickel concentration in the recycled carbon dioxide is not higher than 0.05 ppmv.
摘要:
The invention is a process for separating acid gases from synthesis gas and treating the resulting solids. A mixture comprising synthesis gas and acid gas is contacted with a fluid that reacts with said acid gas to form a particulate solid dispersed in a fluid. The slurry comprising fluid and particulate solid is filtered to separate the particulate solid from the fluid by means of a regenerable filter. The particulate solids are removed from the regenerable filter by back-washing with a back-washing fluid to form a pumpable slurry comprising a mixture of particulate solids and back-washing fluid. The slurry is gasified to form synthesis gas and vitrified solids.
摘要:
In a process for the production of hydrogen-rich gas from a gas containing hydrogen, carbon monoxide, carbon dioxide and other components by contacting the gas in a formate synthesis zone with an aqueous solution containing alkali metal carbonate and/or bicarbonate under conditions effective to produce an effluent aqueous solution containing the corresponding formate and an effluent gas containing the other components of the gas, and thereafter catalytically decomposing the formate in a formate decomposition zone under conditions effective to produce a hydrogen-rich gas and an aqueous solution which contains alkali metal carbonate and/or bicarbonate, the improvement comprising further contacting the gas and the aqueous solution in a catalytic formate synthesis zone prior to decomposing the formate.
摘要:
The invention relates to a process and a plant for producing pure hydrogen from an input gas containing hydrogen and hydrocarbons, in particular from a hydrogen-containing refinery off-gas, by steam reforming in a steam reforming stage and multi-stage hydrogen enrichment. According to the invention the input gas containing hydrogen and hydrocarbons is separated in a first hydrogen enrichment stage into a hydrogen-enriched substream and a hydrogen-depleted substream, wherein at least a portion of the hydrogen-enriched substream is supplied to a second hydrogen enrichment stage or introduced into the pure hydrogen product stream and at least a portion of the hydrogen-depleted substream is supplied to the steam reforming stage as a reforming feed stream or as part thereof and/or to the burners as a fuel gas stream.
摘要:
A fuel cell system 100 includes: a reformer 1 configured to generate a hydrogen-containing gas by using a raw material; a fuel cell 6 configured to generate electric power by using the hydrogen-containing gas; an ammonia remover 5 configured to remove ammonia from the hydrogen-containing gas generated in the reformer before the hydrogen-containing gas is supplied to the fuel cell; a fluid passage configured to allow the ammonia remover to be in communication with the atmosphere; an on-off valve 8 provided on the fluid passage and configured to allow and block the communication between the ammonia remover and the atmosphere; and a controller 80 configured to open the on-off valve in at least one of a water draining process and a water loading process of the ammonia remover.
摘要:
A fuel cell system 100 includes: a reformer 1 configured to generate a hydrogen-containing gas by using a raw material; a fuel cell 6 configured to generate electric power by using the hydrogen-containing gas; an ammonia remover 5 configured to remove ammonia from the hydrogen-containing gas generated in the reformer before the hydrogen-containing gas is supplied to the fuel cell; a fluid passage configured to allow the ammonia remover to be in communication with the atmosphere; an on-off valve 8 provided on the fluid passage and configured to allow and block the communication between the ammonia remover and the atmosphere; and a controller 80 configured to open the on-off valve in at least one of a water draining process and a water loading process of the ammonia remover.
摘要:
The invention is directed to a process to prepare elemental iron by contacting an iron ore feed with a reducing gas to obtain iron and an off-gas. The reducing gas is prepared by performing the following steps(a) partially oxidizing a mixture comprising a sulphur containing solid carbonaceous fuel and gaseous CO2 as carrier medium with oxygen, by supplying an oxygen containing gas and the solid carbonaceous fuel to a burner, thereby obtaining a gas comprising H2, CO, CO2 and H2S; (b) removing CO2 and H2S from the gas obtained in step (a) to obtain the reducing gas comprising H2 and CO and a first stream comprising CO2 and H2S; (c) reducing the content of H2S in the first stream comprising CO2 and H2S obtained in step (b) in a liquid redox type process and (d) recycling at least part of the CO2 obtained in step (c) to step (a).
摘要:
The invention provides a process for the removal of COS from a first synthesis gas stream comprising COS and H2S, the process having the steps of: (a) converting COS in the first synthesis gas stream to H2S by contacting the first synthesis gas stream with a COS-hydrolysing catalyst in the presence of water in a hydrolysis zone to obtain a second synthesis gas stream depleted of COS and enriched in H2S; (b) removing H2S from the second synthesis gas stream by contacting the second synthesis gas stream with a solid adsorbent in a H2S removal zone to obtain a third synthesis gas stream depleted of H2S and depleted of COS
摘要:
Methods and systems are disclosed for using industrial waste for the production of hydrogen gas. The method includes examining a ph level of the industrial waste, removing contaminate from the industrial waste, conditioning and concentrating the industrial waste to a proton-rich solution, and using the resulting proton-rich solution as the proton source in a hydrogenase catalyzed hydrogen production system.
摘要:
A method of obtaining purified hydrogen and purified carbon monoxide from crude synthesis gas. A first crude synthesis gas stream is passed through a first separation zone to separate a hydrogen stream from a stream comprising carbon monoxide and methane. The carbon monoxide and methane are subjected to thermal reforming to produce a second crude synthesis gas, which is passed through a second separation zone to separate carbon monoxide from the second crude synthesis gas stream.