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1.发明授权Hydrocarbon oxidations catalyzed by azide-activated metal coordination complexes 失效由叠氮化物活化的金属配位络合物催化的烃氧化反应
公开(公告)号：US4895682A
公开(公告)日：1990-01-23
申请号：US246
申请日：1987-01-02
CPC分类号： B01J31/1815 , B01J27/24 , B01J31/1805 , B01J31/183 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , B01J2531/025 , B01J2531/56 , B01J2531/57 , B01J2531/62 , B01J2531/64 , B01J2531/66 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/825 , B01J2531/827 , B01J2531/842 , B01J2531/845 , C07C2101/14
摘要： Hydrocarbons, and particularly lower molecular weight alkanes and cycloalkanes, may readily be oxidixed with air or O.sub.2 to form such products as alcohols, ketones, and the like selectively in high yields when there is employed as the catalyst a highly active azide-activated metal coordination complex having the structure ##STR1## where M is a transition metal; " " is a ligand; and X is azide. The invention is also directed to certain novel azide-activated metal coordination complex catalysts per se.
摘要翻译： 碳氢化合物，特别是较低分子量的烷烃和环烷烃可以容易地与空气或O 2一起氧化，以高产率选择性地形成醇，酮等产物，当用作催化剂高活性叠氮化物活化金属配位体 具有结构
的复合物，其中M是过渡金属; “”是配体; X为叠氮化物。 本发明还涉及某些新型叠氮化物活化金属配位络合物催化剂本身。 -
2.发明授权Hydrocarbon oxidations catalyzed by nitride-activated metal coordination complexes 失效由氮化物活化的金属配位络合物催化的烃氧化
公开(公告)号：US4895680A
公开(公告)日：1990-01-23
申请号：US000247
申请日：1987-01-02
CPC分类号： B01J31/1815 , B01J27/24 , B01J31/1805 , B01J31/183 , C07C29/50 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C12C11/02 , B01J2531/025 , B01J2531/56 , B01J2531/57 , B01J2531/62 , B01J2531/64 , B01J2531/66 , B01J2531/72 , B01J2531/821 , B01J2531/822 , B01J2531/825 , B01J2531/827 , B01J2531/842 , B01J2531/845 , C07C2101/14
摘要： Hydrocarbon, and particularly lower molecular weight alkanes and cycloalkanes, may readily be oxidized with air or O.sub.2 to form such products as alcohols, ketones, and the like in high yields when there is employed as the catalyst a highly active nitride-activated metal coordination complex having the structure ##STR1## where M is a transition metal; " " is a ligand; and X is a nitride. Certain dimeric forms of the above catalyst are also employed herein. It has also been discovered that Group IV through VIII transition metal nitrides are also highly effective oxidation catalysts for lower molecular weight hydrocarbons such as alkanes.
摘要翻译： 当使用高活性氮化物活化的金属配位络合物作为催化剂时，烃，特别是低分子量烷烃和环烷烃可以容易地用空气或O 2氧化形成醇，酮等产物， 具有结构
，其中M是过渡金属; “”是配体; X是氮化物。 上述催化剂的某些二聚体形式也用于本文。 还发现，IV族至VIII族过渡金属氮化物也是用于低分子量烃如烷烃的高效氧化催化剂。 -
3.发明授权Ruthenium-cobalt carbonyl catalysts for the dealkoxyhydroxymethylation of acetals to form glycol ethers 失效用于乙缩醛脱甲基羟甲基化形成二醇醚的钌 - 钴羰基催化剂
公开(公告)号：US4663489A
公开(公告)日：1987-05-05
申请号：US859514
申请日：1986-05-05
CPC分类号： B01J31/1608 , B01J31/20 , B01J31/2265 , C07C41/01 , C07C41/30 , C07C43/13 , B01J2231/34 , B01J2231/641 , B01J2531/0211 , B01J2531/821 , B01J2531/845
摘要： The cobalt carbonyl catalyst R.sup.5 CCo.sub.3 (CO).sub.9, desirably with Ru.sub.3 (CO).sub.12, wherein R.sup.5 is hydrogen; alkyl, preferably C.sub.1-5 lower alkyl; cycloalkyl or substituted cycloalkyl; cycloalkenyl, such as cyclohexenyl or cyclooctenyl; C.sub.1-12 alkoxy, such as methoxy or propoxy; aryl or alkyl-, cycloalkyl-, alkoxy-, halo-, or cyano-substituted aryl; cyano; or a silyl carbyne moiety of the formula R.sub.3.sup.6 Si, wherein R.sup.6 is alkyl or aryl, effectively catalyzes the dealkoxyhydroxymethylation of aldehyde acetals to form glycol monoethers. Methylal, for example, may be reacted with syngas; i.e., CO and H.sub.2, in the presence of this catalyst system to form the corresponding ethylene glycol monomethyl ether.The novel catalyst combination of R.sup.5 CCo.sub.3 (CO).sub.9 and Ru.sub.3 (CO).sub.12 is likewise claimed herein.
摘要翻译： 钴羰基催化剂R5CCo3（CO）9，理想地含有Ru 3（CO）12，其中R 5是氢; 烷基，优选C 1-5低级烷基; 环烷基或取代的环烷基; 环烯基，例如环己烯基或环辛烯基; C 1-12烷氧基，如甲氧基或丙氧基; 芳基或烷基 - ，环烷基 - ，烷氧基 - ，卤代或氰基取代的芳基; 氰基; 或式R36Si的甲硅烷基卡宾部分，其中R6是烷基或芳基，有效地催化醛缩醛的脱烷基羟甲基化以形成二醇单醚。 甲缩醛例如可以与合成气反应; 即CO和H 2，在该催化剂体系的存在下形成相应的乙二醇单甲醚。 本文还要求R5CCo3（CO）9和Ru3（CO）12）的新型催化剂组合。
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4.发明授权Ruthenium-cobalt carbonyl metal cluster catalysts for the dealkoxyhydroxymethylation of acetals to form glycol ethers 失效钌钴羰基金属簇催化剂，用于乙缩醛脱甲基羟甲基化形成二醇醚
公开(公告)号：US4618729A
公开(公告)日：1986-10-21
申请号：US782807
申请日：1985-10-02
CPC分类号： B01J31/20 , C07C41/01 , C07C41/30 , B01J2231/34 , B01J2231/641 , B01J2531/0211 , B01J2531/821 , B01J2531/845
摘要： The ruthenium-cobalt carbonyl metal cluster catalyst Co.sub.2 Ru(CO).sub.11 effectively catalyzes the dealkoxyhydroxymethylation of aldehyde acetals to form glycol monoethers. Methylal, for example, may be reacted with syngas, i.e., CO and H.sub.2, in the presence of this ruthenium-cobalt cluster catalyst to form the monomethyl ether of ethylene glycol.
摘要翻译： 钌钴羰基金属簇催化剂Co2Ru（CO）11有效地催化醛缩醛的脱烷基羟甲基化形成二醇单醚。 在这种钌 - 钴簇催化剂的存在下，例如甲缩醛可与合成气（即CO和H 2）反应，形成乙二醇的单甲基醚。
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5.发明授权Hydrogenolysis of 2,5-norbornadiene saturated endo-endo hexacyclic dimer 失效2,5-降冰片二烯饱和内 - 内六环二聚体的氢解
公开(公告)号：US4278823A
公开(公告)日：1981-07-14
申请号：US102726
申请日：1979-12-13
CPC分类号： C07C13/64 , C07C5/13 , C07C2103/90 , C07C2523/42 , C07C2523/44 , C07C2523/46 , C07C2523/755
摘要： Hydrogenolysis of a saturated endo-endo dihydronorbornadiene hexacyclic dimer involves the use of a catalytic amount of a Group VIII metal and the presence of hydrogen. The resulting pentacyclic isomers can be used as a diluent for depressing the freezing point of the saturated hexacyclic dimer which is a component of a high density missile fuel.
摘要翻译： 饱和内消旋二氢龙脑二烯六环二聚体的氢解涉及使用催化量的VIII族金属和氢的存在。 所得到的五环异构体可用作抑制作为高密度导弹燃料组分的饱和六环二聚体的凝固点的稀释剂。
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公开(公告)号：US4229612A
公开(公告)日：1980-10-21
申请号：US7112
申请日：1979-01-29
申请人： Lewis W. Hall, Jr. , David L. Kerr , Elmer J. Hollstein , Harry K. Myers, Jr. , Abraham Schneider
发明人： Lewis W. Hall, Jr. , David L. Kerr , Elmer J. Hollstein , Harry K. Myers, Jr. , Abraham Schneider
摘要： The removal of color bodies from an olefinic or saturated endo-endo hexacyclic homodimer of norbornadiene or mixtures thereof is accomplished by the use of a serpentine clay. Also acid bentonite clay or a montmorillonite clay can be used to remove the color bodies from the saturated dimer. The saturated dimer has a high density and a high heat of combustion making it useful as a missile fuel. Removal of the color bodies avoids possible catalyst poisoning in the hydrogenation of the olefinic to the saturated dimer. Also removal of the color bodies from the saturated dimer eliminates the possible problem of a material precipitating out on engine turbine blades and causing maintenance or operational problems.
摘要翻译： 通过使用蛇纹石粘土来实现从降冰片二烯的烯属或饱和内六角六环同系二聚体或其混合物中去除着色体。 酸性膨润土或蒙脱石粘土也可用于从饱和二聚体中除去颜色体。 饱和二聚体具有高密度和高的燃烧热，使其可用作导弹燃料。 去除颜色体可以避免在烯烃氢化成饱和二聚体时催化剂中毒。 从饱和二聚体中去除颜色体也消除了在发动机涡轮叶片上析出物质并导致维护或操作问题的可能问题。
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公开(公告)号：US4225736A
公开(公告)日：1980-09-30
申请号：US30967
申请日：1979-04-17
申请人： Harry K. Myers, Jr.
发明人： Harry K. Myers, Jr.
CPC分类号： C10L1/04 , C07C13/40 , C07C13/42 , C07C2/406 , C07C2101/14 , C07C2101/16 , C07C2102/42 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Novel codimer (I) of norbornadiene and 1,3-cyclohexadiene and its hydrogenated derivative (II), having the following structures: ##STR1## and processes for preparing both are disclosed. Product (II) can be used as a high energy fuel. Process for codimer I involves use of three component homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and one of three alkyl aluminum chlorides.
摘要翻译： 具有以下结构的降冰片二烯和1,3-环己二烯及其氢化衍生物（II）的新型同分异构体（I）及其制备方法公开。 产品（II）可用作高能燃料。 编码I的方法涉及使用钴或钴乙酰丙酮化合物的三组分均相催化体系，1,2-双二苯基膦基乙烷和三种烷基氯化铝之一。
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公开(公告)号：US4169863A
公开(公告)日：1979-10-02
申请号：US888905
申请日：1978-03-22
CPC分类号： C07C13/68 , C07C2103/86 , C07C2531/14 , C07C2531/22 , C07C2531/24
摘要： Norbornadiene and an alkyne are catalytically codimerized in the presence of a homogeneous catalytic system of cobaltic or cobaltous acetylacetonate, 1,2-bisdiphenylphosphino ethane and an alkyl alluminum chloride. Also, novel codimers of norbornadiene and an alkyne containing at least three carbons are disclosed. After hydrogenation, resulting codimers can be used as high energy fuels or diluents for such fuels.
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公开(公告)号：US4100338A
公开(公告)日：1978-07-11
申请号：US829313
申请日：1977-08-31
CPC分类号： C08F32/08
摘要： Norbornadiene is catalytically polymerized to a solid white polymer in the presence of a catalytic system of nickel acetylacetonate or a nickel-phosphine complex and an alkyl aluminum chloride. The polymer can be used as a solid high energy fuel.
摘要翻译： 在乙酰丙酮镍或镍 - 膦配合物和烷基氯化铝的催化体系存在下，降冰片二烯被催化聚合成固体白色聚合物。 聚合物可以用作固体高能燃料。
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公开(公告)号：US5648590A
公开(公告)日：1997-07-15
申请号：US292164
申请日：1994-08-17
CPC分类号： C07C5/2781 , C07C2521/06 , C07C2523/656 , C07C2523/745 , C07C2523/75 , C07C2523/889
摘要： Acyclic hydrocarbons having 4 to 7 carbon atoms per molecule are isomerized in the liquid phase by contact with a solid superacid catalyst comprising sulfated oxide or hydroxide of a metal selected from the group consisting of Group III and Group IV metals, to obtain high octane number blending components for motor fuel and/or valuable chemical and fuel intermediates.
摘要翻译： 每分子具有4至7个碳原子的非环状烃通过与包含选自III和IV族金属的金属的硫酸化氧化物或氢氧化物的固体超强酸催化剂接触而在液相中异构化，以获得高辛烷值共混 汽车燃料和/或有价值的化学和燃料中间体的组分。
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